KENDRIYA VIDYALAYA SANGATHAN: HYDERABAD REGION

TERM-2 MAX MARKS: 35

SUBJECT: CHEMISTRY TIME: 2HOURS

GENERALINSTRUCTIONS:-
1. THERE ARE 12 QUESTIONS IN THIS QUESTION PAPER WITH INTERNAL CHOICE

2. SECTION A:QUESTION NO 1 TO 3 ARE VERY SHORT ANSWER TYPE; AND EACH

QUESTION CARRIES 2 MARKS.
3. SECTiOft B:QUE5TiOft NO 4 TO 11 ARE SHOAT ANSWER TYPE ; CA8RYTftG 3
MARKS EACH.(THERE WILL BE INTERNAL CHOICE IN THIS SECTION)

4. SECTIONC:QUESTION NO 12 15 CASE BASED QUESTION ; CARRYING 5 MARKS.

S.ALLDUESTlONSARECOlMPUdORY.

6.USE OF LOG TABLES AND CALCULATORS ARE NOT ALLOWED.

SECTION- A
Q.No Question Marks
1. What happens to the internal energy of the system if 2
i. Work Is done on the system
i. Work is done by the system

2. i. What is the effect of increasing pressure and temperature on 2

the equilibrium.
Nt + 3Ht‹ -• 2NH3
ii All Bronsted acids are not Lewis acids. Why?

3 2
Give the reason for the following
[SiF6] 2 is known where as [SiCI6] 2 is not
ii. Boron is unable to form BF6- 3
 SECTION .B
4 3
Explain the followin8
i) Boyle’s law ii) Avagadro’s Law
O
iii) IFI terms of Charles law explain why -273 C is the lowest
temperature.
(OR)
Explain the folfowmg
i. What is P.V isotherm
ii. Under what conditions do gases deviate from Charles law.
iii. Write Vanderwaal’s equation for one mole of a gas

5. i. For an isolated system AU = 0 What will be AS ? 3

ii.For the reaction 2CIg --—-3' Chl/ What are the signs of AS
and BH
iii. Why does entropy increase on mixing of two gases?

(OR)
Calculate the standard enthalpy of formation of CH OH(I) from the
following data:
tit CHtOH(I) + 3/2 0 — C //@t 2H2O(l)t rH”' 726 M IT\0 ”

(ii) C(g) + 0 (g) 4 CO2t8) ; WHO= -393 M mol”’

(iii) He(z) + O,(g) -3• HCO (I); 6/H”= -286 kJ mol-’

6. i. Why are Potassium and Caesium rather than Lithium used in 3

photoelectric ceIIs7
ii. Comment dn each of the following observations
a. The mobilities of alkali metal ions in aqueous solution are
Li”< Na*< K*<Rb*<Cs*
b. BaO is soluble but BaS 4 is insoluble in water.
7. I.Why is LIF almost Insoluble In water whereas LiCI soluble not 3
only in water but also in acetone?
ii. Why are alkali metals not found in nature
iii. Alkaline earth metals impart a characteristic colour but Be
and Mg cannot give why?
 When alkali metals are heated in excess of air, what)s the
nature of oxides formed?
li. Which is having more reducing characteristics alkali
metats or alkaline earth metals give reason.
8 iii. Ækali metal when dissolved in Ammonia give6lue colour 7
Give the reason for the following 3
T. Graphlte Is used as agood lubricant
ii. A mixture ofd))ute NaOH and Aluminium piece is used
to open a drain
iii. PbCk is a good oxidizing agent.

Complete the following reactioxs 3

(i) CHU-CH=CHz+ HBr - —•3'

m c«,- a-œ »i‹æx—+

(iii) CH,-—c›‹2 + Huo + O —du. I¢MnO

10 Explain the following 3

). Wurtz reaction give one example
ii. Decarboxylatfon gke one example
iii. Frledal craft alkylation give one example

11
L IdentfyA and B in the fNkxHng 3
A< Na =CH-H2o- •6HySOy+hgso4 {Œf C)
ii.Out of Benzene and Tou)ene which will undergo nftration easily and

Ili. Wrfte the two isomeric forms of But2-enE›

(OR)
 i.How can you convert the following compounds
aWetylene to Nitro Benzene
Ix1- Bromo.propaneto2- Bromo propane
ii.Give one chemical test to distinguish between Ethene and Ethyne.

12. Many body fluids e.g., blood or urine have definite pH and S
any deviation in their pH indicates malfunctioning of the
body. The control ofpH Is also very important In many
ct›emicaI and biochemical processes. Many medical and
sosrr›et¡cfermulatfons.require that these be kegtand
administered at a particular pH.
Bufler so\utions are prepared in laboratory are two types.
They are (al acfdlc buffer solutions and (b) basic buffer

For the removal of phosphate ion In the

qualitative inorganic analysis after second group
using CHtCDOH + .CtJ›COONa buffer.
For precipitation of hydroxides ofthlrd group of
qualitative analysi, a buffer, NFItCI + NHyOH, is used.
Buffers are used in industrial processes such as manufacture of
paper, dyes, fms, palots, 8rugs,stc buffers arealso employed io
agriculture, dairy products and preservation ofvarious types of
foods and fruits. Henderson’s equation Is used to determine @ of
buffer solutions.
gased on die aboveinformation answer the foJ\owfng quesbons
1. Define Buffer solution.
2. What Is Acidic Buffer give one example
3. How blood acts as a buffer
4. Write Hendersons equation
5. What Is basic buffer solution give one example
 KENDRIYA VIDYALAYA SANGATHAN: HYDERABAD REGION
TERM-2 MAX MARKS: 35

SUBJECT: CHEMISTRY TIME: 2HOURS

5.No Answers
|1 i.If work is done on the system internal energy increases.
i.if work is done by the system Internal enérgy will decreases.

L I?ressure.increases reaction.moves to foruzard direction

Temperature increases reaction moves to backward direction and
yield of ammonia decreases.
1/2
ii. Bronsted Acids can donate H* easily but thev not be able to
donate electrons so all Bronsted acids are not lewis acids 1

3 I.tSIFm]”’ is known where as [SiCb]- is not known beœuse Chlorlne ls large 1

size so it could not accommodate around Sillcon atoms.
ii. Due æ absence ofd’orbîtai"Boron cannot forms:BF«-

4 i. According to Boyle’s law at constant temperaNre the volume of a given 1

mass of gas Is inversely proportional to Its pressure
II. Avagadro’s law states that equal volumes of all gases contains same 1
number of molecules at constant temperature and pressure
ii. At -273°CVofume will be zero and below this temperaNre the volume 1
wflt be negative ItIndicates -273°C is the lowest temperature.

i,A graph between P and V of a éxed amount of gas at constant temperature 1

is called p-v.isotherrn. Each line Is called Isotherm
ii At low temperate and high pressure gases deviate from Charles law 1

5 i. For an isolated system AU = o and for a process to be spontaneous, the 1

value ofd›S must be positive.
ii. The glven reaction involves the formation ofO-CI bond. The process 1
involves a release of energy sD AH will be—ye similarly randomness also
decreases hence entropy decreases so dS is .
iii. By mixing.of two.gases randomness increases so entropy increases 1

to«
 C(g} +.2Mt(g) +.¥ O›{g) - -3' CHaOH(I) 2 ,
Adding eqs. (li) and 2(ill) and subtracting (I), we get above equation.
Therefore -393 + 2 x -286— (-726) 1
-393— 572+ 726 = -239 mol”’

6 I. They have lowest ionisatión enérgy as compared to lithlum therefore they 1

can Ióst electrons easily and prefered in photoelectrtc cells.
II, lt Is because M* is rnost hydrated due to smallest catton where as Cs’ fs 1
least hydrated due to larger slze
III Because Ba5Ot possess more lattlce energy than BaO

7 i. lt is beœuse UF hàs high lattiœ energy as compared to UCI

”LiClls solutfle ›n water”because dfiIawest”Iattice energy simlarly ISO is
covalent therefore it Is also soluble In acetone.
i It Is because they are highly reactive metals so they always exlst In the 1
form of compound
lit Ba and Mg have high ior›Isation energy they do mit absorb light from 1
visible region for excitadon of electrons so they do not impan color to
the Rame
OR)
THE oxides forraad are baste ie oature Li forms monaxide,.zIa locos 1
peroxide where as K, Rb, Cs forms superoxides
Alkali metals have more reducing character than Alkaline earth 1
metals because alkali metals easily loses etectrons due to low
lonisation energy
When Alkali metals dissolve in liquid ammonia gives blue colour 1
due to the presence of Ammoniated electrons which observes
energy in tha visible region D ht.
8 i. Graphite is soft and slippery and have high meldng point so it is used as a 1
lubricant in machine to mduce friction
li AI dissolved In dll NaOH to evolve Hydrogen gas . The pressure nf Hydrogen 1
gas is used to open Jammed drain
iii Stability of +4 oxidation state decreases down the group due to Inert pair 1
effect so Pb easily changes into Pb^ it indicates PbCI, is a good oxidizing

9. i. CHU- CH2" CH2Br 1

1
lti.CHU— CHU 1

OH OH

1 10 I i. 2 moles of Alkyl Halide when treated with Na in preseñce ofd Ether X

 form.1 Alkanes.
R-Cl + 2 Na • CI-R -4 R — R + 2 NaCI(hr ie R - Alkyl group)
ii. sodium or potassium salts of carboxylic acids whOFI tfRated with soda lime
undergo decarboxylation to form Alka nes
RCOONa + NaOH (CaO)-4 RH + N, ,CO,
iii Benzene is treated with A|kyl halidE in the presence of lewis acid undergo
electrophilic substitution to form Alk\’\ Benzene.

+ CH3-II---AlCI‹G

11 i. A - CH-C-Na and B - CH3CHO ?+1/2

ii. Toulene readily undergo nitration r’asiIy because it contains electron 1
donating group so it activates benzene ring due to it undergo electrophilic 1
substitution easily.

Or

1
12. bL ”' O “' n hich resist change in pH by addition of acid or base is called 11
l u
£°
ii. IvIi«ture of weat acid and its conjugate base salt is called acidic buffer
eg. CHtCOOH + CHtCOONa {any other example)

iii. When any acid substance enters the blood stream the
1
bicarbonate ions neutralise the hydronium ion forming carbonic
acid and water. Carbonic acid is already part of the buffering
system of blood thus hydronium ions are removed preventing the
pH of blood becoming acidic.
iv. pH pk, + loa I ”]/[HA] 1
v. mixture of weak base and its conjugate acid salt is called basic
buffer NH‹OH + N 4 {any other example)

NARAgINGA RA0 (t 1
D65VI