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CHEMISTRY 5070/04
Paper 4 Alternative to Practical October/November 2007
1 hour
Candidates answer on the Question Paper.
No Additional Materials are required.
Write your name, Centre number and candidate number in the spaces at the top of this page.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE ON ANY BARCODES.
A B C
50
10 20 30 40 50
40
30
20
10
.................................................. [1]
[Total: 2]
ethene
heat
test tube
(a) Insert in the boxes the names of the substances used in the experiment. [2]
(b) What does this method of collection suggest about the solubility of ethene in water?
......................................................................................................................................[1]
(c) Why must the delivery tube be removed from the water before the apparatus is allowed
to cool?
......................................................................................................................................[1]
test ...................................................................................................................................
observation ..................................................................................................................[2]
[Total: 6]
start line
A
L M N P X Y
......................................................................................................................................[1]
A ......................................................................................................................................
B ..................................................................................................................................[1]
(c) A student who did the same experiment used an ink pen to draw the start line instead of
a pencil. How would this student’s results have been different from the results shown in
the diagram above? Explain your answer.
..........................................................................................................................................
......................................................................................................................................[2]
(d) Use the diagram to deduce which of the substances L, M, N or P are present in
mixture X, .........................................................................................................................
mixture Y. .....................................................................................................................[1]
..................................................................................................................................
..............................................................................................................................[1]
(ii) Which of the substances L, M, N or P has a Rf value of 0.45? Show how you
obtained your answer.
substance ..................................................[1]
[Total: 7]
......................................................................................................................................[1]
(b) Calculate
(c) Using your answers to (b)(i) and (ii) calculate the maximum mass of barium sulphate
that could be produced in the reaction.
[Ar: Ba, 137; S, 32; O, 16]
............................................... g [1]
The barium sulphate was removed from the solution by filtration. It was dried and weighed.
(d) The mass of barium sulphate obtained was 3.35 g. Calculate the percentage yield of
barium sulphate.
.............................................. % [1]
......................................................................................................................................[1]
(f) Suggest a different barium salt that could have been used instead of barium nitrate to
produce barium sulphate.
......................................................................................................................................[1]
[Total: 7]
5 A student used the apparatus shown below to separate ethanol and water by fractional
distillation.
thermometer
water out
condenser
water in
receiver
liquid
heat
[Total: 1]
A solution of F was mixed with an acidified solution of barium chloride but no precipitate was
produced.
A solution of F was mixed with an acidified solution of silver nitrate and a white precipitate
was produced.
[Total: 1]
2H2O2 2H2O + O2
Three experiments were done using different solutions of hydrogen peroxide but keeping the
mass of manganese(IV) oxide constant.
volume of
oxygen
evolved Y Z
0
0 time
(a) X Y Z
(b) Y X Z
(c) Y Z X
(d) Z Y X
[Total: 1]
Which of the graphs below correctly shows the temperature changes that occur when
potassium iodide is stirred with water until there is no further change of temperature?
[R.T. = room temperature]
temperature
(a)
R.T.
time
(b) temperature
R.T.
time
(c) temperature
R.T.
time
(d) temperature
R.T.
time
[Total: 1]
(a) HCOOH
(b) CH3COOH
(c) C2H5COOH
A sample of C was added to a previously weighed beaker, which was then reweighed.
............................................... g [1]
50.0 cm3 of 1.00 mol/dm3 sulphuric acid (an excess) was transferred to the beaker containing
the sample of C. This mixture was warmed gently while being stirred and then left to stand
for a few minutes. The unreacted solid settled at the bottom of the beaker leaving a coloured
solution.
Copper(II) oxide reacts with sulphuric acid but copper does not react.
..............................................................................................................................[1]
(ii) How was the unreacted copper removed from the solution?
..............................................................................................................................[1]
(iii) Write an equation for the reaction between copper(II) oxide and sulphuric acid.
..............................................................................................................................[1]
The solution which remained after the copper was removed, was transferred to a volumetric
flask and made up to 250 cm3 with distilled water. This was solution D.
25.0 cm3 of D was transferred into a conical flask and a few drops of indicator was added. A
burette was filled with a solution of 0.100 mol/dm3 sodium hydroxide. This was run into the
conical flask containing D and the indicator until the end-point was reached.
(c) What was the colour of the solution in the conical flask
26
40 45
0 19
14
27
41 46
1 20
15
28
42 47
2 21
16
titration number 1 2 3
Summary
Tick (✓) the best titration results. Using these results, the average volume of 0.100 mol / dm3
(e) Calculate the number of moles of sodium hydroxide in the average volume of
0.100 mol /dm3 sodium hydroxide in (d).
(f) Calculate the number of moles of sulphuric acid which reacted with the sodium
hydroxide in (e).
(g) Using your answer in (f), calculate the number of moles of sulphuric acid in 250 cm3 of
solution D.
(h) Calculate the number of moles of sulphuric acid in 50.0 cm3 of 1.00 mol / dm3 sulphuric
acid.
(i) By subtracting your answer in (g) from your answer in (h), calculate the number of moles
of sulphuric acid which reacted with the copper(II) oxide in C.
(j) Using your equation in (b)(iii), deduce the number of moles of copper(II) oxide in the
sample of C.
........................................... g [1]
........................................... % [1]
[Total: 17]
In cases where a colour change is involved, both the initial and final colours should be
stated.
[Total: 5]
A student was provided with solution H, sulphuric acid, and solution J, 1.00 mol / dm3 aqueous
sodium hydroxide.
The diagrams below show parts of the thermometer stems for the maximum temperature
recorded in each experiment.
30 30 30 30
20 20 20 20
80 cm3
H 60 cm3H 40 cm3
H 20 cm3 H
+20 cm3 J +40 cm3 J +60 cm3 J +80 cm3 J
(a) You are to record these temperatures in the table below and then calculate the rise in
temperature for each of the four mixtures.
60 40
40 60
20 80
[2]
10 10
8 8
6 6
temperature
rise / °C
4 4
2 2
0 0
100 80 60 40 20 0 volume of H / cm3
0 20 40 60 80 100 volume of J / cm3
[2]
............................................. °C [1]
(ii) the volumes of H and J which would produce this temperature rise.
H ............................................... cm3
J ............................................... cm3
[1]
(d) Solution J was 1.00 mol / dm3 sodium hydroxide. H was sulphuric acid. Using your
answers to (c)(ii), calculate the concentration of H.
......................................................................................................................................[3]
The total volume and the initial temperature were the same as in the original
experiment.
Suggest
........................................................[1]
(ii) the volumes of H and J that would produce this temperature rise.
........................................................[1]
[Total: 11]
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