Professional Documents
Culture Documents
1. General
· Solid wastes are the wastes arising from human activities and are normally solid as opposed to liquid or
gaseous and are discarded as useless or unwanted. Focused on urban waste (MSW) as opposed to
agricultural, mining and industrial wastes.
· Integrated Solid Waste Management (ISWM) is the term applied to all the activities associated with the
management of society's wastes.
· Solid wastes have a great potential to pollute the air and water, wastes discarded in the streets led to the
breeding of rats and the associated fleas.
· Materials Flow - The best way to reduce solid wastes is not to create them in the first place. Other methods
include: decrease consumption of raw material and increase the rate of recovery of waste materials.
· Technological advances - Increased use of plastics and fast, pre-prepared foods.
C o lle c tio n
D ispo sal
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Sources, Composition, and Properties of Solid Waste
C. Industrial Wastes
· SIC (Standard Industrial Classification) codes. Excludes process and hazardous wastes.
· SIC 32 - Stone, clay and glass products from the manufacture of flat glass etc., yielding glass, gypsum
(sulfur source) abrasives, etc.
D. Agricultural Wastes
· Enormous quantities from planting, harvesting from row, field, tree and vine crops and animal husbandry,
feedlots.
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2. Composition of Solid Waste
· Composition describes the individual components that make up solid waste and the distribution of these
components by weight.
· Knowing the composition is becoming critical:
- Selection and operation of equipment and facilities
- Feasibility of resource and energy recovery
- Design of disposal facilities
· The residential and commercial component is typically 62% of MSW.
· Components of MSW excluding specials, recycled materials and food wastes:
- Organic, combustible, paper and yard wastes are predominate.
- Inorganic, non-combustible, glass and tin cans.
· Composition with and without food wastes, with and without recycling.
3. Variation in Distribution
· Highly variable, local studies should be considered, collected data is expensive and of limited value; make
sure that collected data is useful before collecting.
· Location, warmer more affluent communities generate more wastes.
· Season, More food wastes in the dry season; more glass and metals in the wet season.
· Economics and others.
· The amount of moisture that can be retained in a waste sample subject to the downward pull of gravity.
Water in excess of FC will flow out of the waste as leachate.
· 50-60% for uncompacted, commingled waste from residential and commercial sources.
E. Permeability (hydraulic conductivity) of Compacted MSW
· Measures the movement of gasses and liquids in landfills.
K = Cd2 = k eq. 4-7, p.76
· k= 10-11 to 10-12 m2 in the vertical and 10-10 in the horizontal.
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2. Chemical Properties of MSW
A. Proximate Analysis
· Includes the following tests:
- Moisture
- Volatile combustible matter
- Fixed carbon (combustible residue after volatile matter is removed)
- Ash (weight of residue after combustion in an open crucible
· Fusing point of ash - temperature at which the ash forms a solid (clinker) by fusion and agglomeration.
2000-2200°F.
· Magazines are:
- 4.1% moisture
- 66.4% volatile matter
- 7.0% fixed carbon
- 22.5% non-combustible
- energy content, 4600 Btu/lb as collected.
- Note: rubber as in tires and plastics have a very high energy content.
B. Ultimate Analysis of SW Components
· Determination of the percent C, H, O, N, S, and ash.
· Opportunity to calculate chemical formula, which then can be used in various chemical and biological
reactions.
· Magazines are:
- 32.9 % C
- 5.0 % H
- 38.6 % O
- .1 % N
- .1 % S
- 23.3 % ash
C. Energy Content of SW Components
· Potentially critical element in incineration. Can be measured or calculated.
· DuLong Formula:
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- Organic compounds containing a sulfur radical can lead to the formation of methyl mercaptan and
aminobutyric acid.
· Breeding of flies takes 9-11 days.
C. Biological Transformations
· Used to:
- Reduce weight and volume
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- To produce compost
- To produce methane
· Principal MOs:
- bacteria
- fungi
- yeasts
- actinomycetes
· Aerobic composting, biological decomposition
· Anaerobic digestion yields methane.
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· In combustion products. Have been found in emission gases and residual material (ash) especially heavy
metals, barium, chromium, silver.
· In landfill. Trace organic constituents have been found in atmosphere, in extracted gases and in leachate.
Source may be direct or derived.
· MSW should be measured as a weight as opposed to a volume because the weight measurements are
consistent and reproducible while the volume can vary considerably attendant to compaction. Ultimately,
however, the capacity of a landfill is a volume consideration.
· Units - lb/capita.day for residential and commercial, a repeatable measure of production for industry and
agriculture e.g. lb of manure/chicken.
· Estimation of Waste Quantities -
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- Load-count analysis - A landfill without scales may estimate the vehicular capacity and the number of
vehicles of that capacity.
- Material Balance
Accumulation = inflow - outflow + generation
= SMin - SMout + rw
Note: Always write rw as positive in the parent equation and make a negative substitution as required in the
final analysis.
1. Material Flow Diagram
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· »One ton/capita.year »2000 lb/365days/year = 5.48 lb/capita.day. More precisely, 3.82 lb/capita.day for
residential and commercial and 6.16 lb/capita.day total. The total is augmented by hazardous, institutional,
construction and demolition, municipal services wastes and treatment plant sludges. Residential and
commercial is typically 60% of the total.
· Special Wastes
- batteries - 10household batteries/capita.year
- used oil - .80 gal/capita.year
· Rate Variation
- The larger the data base, the less the variation.
- For a residence, peak day factor of 3.0, minimum day factor of .20
2. Handling
Low rise < stories; medium rise 4-7 stories; high rise > 7 stories
A. Low Rise
· Single family detached and attached
· Single family detached
- separate recyclables at the MRF, not at the home
- variety of storage containers and mixed waste: plastic bags, 32 gallon galvanized or plastic, cardboard boxes
-90 gallons containers equipped with wheels, mixed waste
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B. Low and Medium Rise
· Basement storage by residents and moving of the container by maintenance personnel.
· Large outdoor containers, located in special areas that are emptied mechanically by the collection truck.
4. Processing at Dwellings
· Incineration of food - No significant decrease in the weight or volume of the MSW,
· Separation - very effective if you can engender meaningful participation.
· Compaction - individual units under the counter, collection and processing by large units. Potentially
counterproductive if the wastes are to sorted at a MRF; also, compaction may foster contamination.
5. Composting
· The biological conversion of the biodegradable organic fraction of the MSW resulting in a volume
reduction and producing a useful by-product
· Isolate a 3ft square area with chicken wire and dump the yard wastes. Food wastes may be stirred into the
mix if odor and vermin problems can be obviated.
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· Water and turn occasionally, once/week. Perhaps ready to use after 1 year, put in at top, take out at bottom.
· Produces a humus-like material which is a soil conditioner, not a fertilizer.
1. Waste Collection
A. General
· Major cost element of solid waste disposal - typically 50-70% of the total and therefore, demands major
attention especially with final disposal getting so much press.
· Collection includes:
- picking up MSW from sources
- hauling to the emptying location
- emptying of the truck or container
B. Collection of Commingled Wastes, Low Rise, Detached:
· The waste is commingled or heaped together as opposed to source separation e.g. picking out class,
cardboard
· Collection services:
- curb - (manual or mechanical) most common, homeowner moves the container back and forth between the
curb from the storage location. Larger 90 gallon containers require placement in the street, perhaps at a
precise angle in cul-de-sacs.
- alley - Narrow utility thoroughfare in the rear of residences; not uncommon in older communities,
Claremont, Pomona.
- backyard carry - collectors retrieve the container from the storage location, empty it and return the
container to the storage location.
· Manual methods of collection:
- direct lifting and carrying
- rim roll
- small lifting devices
- satellite vehicles, Cushmans
C. Collection of Commingled Wastes, Others.
· Low and medium rise apartments, high rise apartments, commercial industrial facilities. Smaller containers
handled by maintenance personal for curb side collection, larger containers done mechanically.
· Much collection is done at night and very early morning to avoid the traffic.
D. Collection of Waste at the Source
· The generator separates the waste as opposed to commingled wastes.
· Methods include:
- Curbside collection using standard or specially designed vehicles.
- Standard vehicles can be used to pick up just newspaper or just can on some kind of appropriate time cycle;
perhaps every other week or the third Thursday of the month for glass.
- Specially designed vehicles include:
- closed body recycling trucks
- recycling trailers
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- modified flatbed trucks
- open-bin recycling trucks
- compartmentalized trailers
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· Does not include actually picking up the loaded container or redepositing the empty container nor the time
spent at the location where the waste is unloaded.
· HCS- The time required to reach the location where the waste will be emptied, starting when the container has
been loaded on the truck and continuing through unloading until the truck arrives at the location where the
empty container is to be redeposited.
· SCS - The time required to reach the location where the full vehicle will be emptied and continuing until the
truck arrives at the location where the first container will be emptied for the next route.
4. Collection Routes
A. General
· Use a heuristic (common sense), trial and error approach consistent with the philosophy of collecting the
most waste with least resources in the context of constraints such as equipment breakdowns, holidays and
vacations, good labor practices and the following guidelines:
- Crew size and vehicles must be known and coordinated.
- Routes should begin and end near arteries
- Topographic and physical boundaries should be route boundaries.
- Start at the top of a hill and work downward.
- Last collection point should be near disposal site.
- Traffic problems should be dealt with early in the morning.
- Extremely large load should be dealt with early in the morning.
B. Layout of Collection Routes
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· Location maps showing data concerning the sources including location, collection frequency, number of
containers
· Data analysis, try to balance the routes in accordance with pickups and time.
· Preliminary layout of routes, start at the depot and do a route. An idea of truck capacity vs. loads is in order.
· Fine tune the preliminary design.
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· Large capacity - San Francisco model. A large pit at a lower level is surrounded by unloading collection
vehicles. Two bull dozers break up the wastes and push the wastes into hoppers which discharge into the
transfer vehicles.
C. Combined Direct-Load and Discharge Load Transfer Stations.
· Usually a multipurpose facility: perhaps a transfer station and a MRF.
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· Largest pneumatic system at Disney World in Florida. May be suitable for high density areas feeding a
central collection point. Complex control valves and isolation equipment. Difficult to imagine a half eaten
ice cream bar being moved along. Easy to imagine health and odor problems.
· Hydraulic system - Macerate the waste and pipe it to a remote location. Potential for great economies
except scarcity of water in LA. Ocean water? Must the transport water be treated?
1. General
· Methods used to recover source separated material:
- Curbside collection
- Homeowner delivery to drop-off centers
· Further separation of source separated material as well as separation of commingled waste
- MRF's Material Recovery Facilities
- MR/TFs Material Recovery/Transfer Facilities, a facility of the future which may include:
-drop-off center
-materials separation facility
- composting
- bioconversion
- production of refuse derived fuel (DRF)
- transfer and transport facility
6. Combustion
A. General
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· Object:
- Reduce the volume (85-95% reduction) and weight of wastes.
- Recover conversion products and energy.
· Major concerns:
- Air pollution.
- Siting, NIMBY.
B. Description of Combustion Process
- Unload into a storage pit, usually a 2 day volume. The tipping area should minimize unloading waiting time
with reason.
- An overhead crane drops material into a charging chute which directs the wastes to the furnace. The operator
tries to get an even mix and remove non-combustible items such as mattresses or engine blocks.
- The waste falls on grates and is mass fired. Air is typically introduced.
- Gases and small particles rise to the combustion chamber and burn at 1600°F.
- Heat is recovered from the gases using water-filled tubes in the combustion chamber and a boiler that
produces steam which is converted to electricity in a generator.
- Air pollution is controlled including NOx, SO2 and particulates.
- Clean gases are discharged to the stack.
- Ash and unburned material are quenched (cooled with water). The water and residue must be properly
disposed of. See p.641 for an excellent discussion of air pollution systems.
C. Types of Combustors
· Mass fired. Use unseparated, commingled MSW. Predominate in US, 68%. Pick out the bicycles and
refrigerators, burn the rest. The energy content is probably extremely variable.
· RDF (Refuse Derived Fuel) fired. 23%. Produced from the organic fraction and can be made with
consistency to meet energy, moisture, ash content specifications. Forms include: shredded, fluff, pellets or
cubes. Also, since metals, plastics etc. are not burned, air emissions are cleaner.
D. Volume Reduction
· Typically 90% volume reduction of the materials that were combusted. Demolition wastes, white goods,
cars etc. were never considered.
· Always a residue and ash left over after combustion consisting of glass, tin cans, iron and steel.
E. Issues With Combustion Facilities
· Siting. As with MRF's, a remote location with plenty of buffer zone.
· Air Emissions. May exceed the cost of the combustion facilities. Most pressing issue in the LA area.
Important consideration in the decision between mass-fired and RDF systems.
· Disposal of residues, bottom ash, fly ash, scrubber product. Typically disposed of in land fill.
· Liquid Emissions. Sources: ash removal, wet scrubbers.
· Economics. Standardized life cycle costing.
7. Composting
A. General
· The organic fraction of MSW (less plastic, rubber and leather) is converted into an earthy, humus-like,
material by the action of bacteria and other microbes.
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P ro te in s
A min o a c id s
Lip id s
C a rb o s + O 2 +N u trie n ts + M O s C o mp o s t + N e w C e lls + D e a d C e lls +
C e llu lo s e
Lig n in C O 2 + H 20 + N O 3 + S O 4 + h e a t
A sh
· Objectives:
- Convert the MSW into a biologically stable material which is reduced in volume.
- Destroy unwanted biologicals: pathogens, weeds, insect eggs.
- Retain the maximum nutrient (N, K, pH).
- To produce a valuable, soil amendment product. Not a fertilizer. Lousy C:N ratio.
B. Process Description
· Howard et al in India in 1930.
· Three basic steps:
- Preprocessing MSW
- Segregating degradable matter, removing engine blocks, tin cans.
- moisture content.
- fertilizer content perhaps by adding sewer sludge
- Decomposition
- windrow
- static pile
- in-vessel
- Preparation for market.
- grinding
- screening
- blending
- additives
- bagging
C. Design and Control
- Particle size
- Seeding, mixing and turning
- Oxygen requirement (aerobic process)
- Moisture content
- C:N ratio
D. Composting Techniques
· Agitated and Static. With agitated, the material is turned; with static, air is blown through the material.
· Windrow composting.
- Most common agitated method.
- The material to be composted is shredded into 1-3" pieces and the moisture is adjusted between 50-60%.
-The material is formed into triangular shapes called windrows which may be 6-7' high and 1`4-16' at the base.
- The windrows are tuned twice a week to maintain aerobic decomposition and the temperature is maintained at
131°F (55°C).
- Takes 3-4 weeks and cured for an additional 3-4 weeks without turning.
· Aerated Static Pile (also Beltville or ARS process)
- MSW is placeed on top of exhaust piping in mounds 7'-8' high.
- Each pile has its own blower to deliver air, oxygen.
- 3-4 weeks of processing with an equal period for curing.
· In-Vessel. Inside an enclosed vessel. Proprietary.
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- Plug flow and dynamic systems.
- Takes 1-2 weeks and 4-12 weeks of curing.
E. What Can Be Composted (Applications)
· Yard wastes. Ranges from minimal which may take 3 years to high level in container which can be done in
several weeks.
· MSW (organic fraction). Metals or household hazardous waste can easily contaminate the compost. If a
high quality product is desired, source separation is a must.
· MSW (commingled, partially processed). Not suitable as a gardener's compost; use as an intermediate cover
if allowed.
· MSW (with sewer sludge). May avoid sludge dewatering. Increases the nutrient and moisture contents of
the mix; may also contain heavy metals. A 2:1, MSW: sludge is recommended as a starting point.
F. Issues With Composting Facilities
· Odors. Usually caused by:
- Low C:N ratios
- Poor temperature control
- Excessive moisture
- Poor mixing
- Can be controlled with various towers and facilities and odor-masking agents and enzymes.
· Pathogens. Usually destroyed by normal composting parameters of 55°C for 15-20 days
· Heavy metals. Particles are created when the waste is shredded and these particles may become attached to
the lighter fractions.
· Definition of acceptable compost
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DISPOSAL OF SOLID WASTES AND RESIDUAL MATTER
1. Overview
· Solid wastes are components identified for disposal including residues:
- not recycled
- that remain after processing at a MRF
- that remain after recovery of conversion products and/or energy
· Landfilling, by far, is the most common disposal method.
2. Landfills - General
A. Definitions
· Landfills are physical facilities perhaps encompassing several hundred acres used for the disposal of
residual solid wastes in the surface soils of the earth. Landfills are engineered facilities involving a daily
cover material typically 6" of soil.
· A cell is the volume of MSW material placed in a day plus the cover material. The cover controls the
following functions:
- blowing debris
- vectors
- water seepage
· A lift consists of one or more cells over the active area of the landfill and considered with over material
represents the height of the landfill.
B. Site Preparation
· Important considerations include:
- drainage-away from landfill
- excavation and preparation of bottom and sides
- stockpiling of cover material
- placement of monitoring equipment
C. Placement of Wastes
· The waste is placed in cells continuing upward and outward from the compaction face.
· spread in 18-24" layers from the delivery vehicle and compacted. It is important to compact in thin layers.
· heights from 8-12'
· widths (in and out distance) 10-30'
· length of working face, perhaps 100'
D. Landfill Classification
Classification Waste
I Hazardous Waste
II Designated Waste
III MSW
E. Landfilling Methods
1.) Excavated Cell/Trench
· A depression is dug in the earth and subsequently filled:
· plenty of cover material and water table not near the surface
· Cells are typically square up to 1000', side slopes 1.5:1 to 2:1
· trenches 200-1000' long, reflects volume of daily operation
· 3-10'deep, not too deep as to present a safety hazard for burial
· 15-50' wide, turn equipment around
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2.) Area
· used when pre-excavation is not appropriate perhaps because of high ground water
· limited cover material perhaps using imported soils
· liners and leachate control systems are installed
· a berm, earthen embankment, is constructed and serves as a starting point for cells and lifts
3.) Canyon/Depression
· filling in a hole, ravine, quarry that already exists
· drainage is critical
4. Landfill Gases
A. Overview
organic matter + H2O ®(bacteria) biodegraded organic matter + CH 4 + CO2 + other gases
(water is required for this reaction to go forward)
B. Composition and Generation of Gases
· Primarily CH4 (methane) and CO2 (carbon dioxide); methane (.7167 g/L) has a density less than air
(1.2928 g/L) and will rise perhaps to building basements where it may collect and be explode; CO 2 is
heavier than air (1.9768 g/L) and will sink to the GWT and perhaps cause chemical problems.
· Also N, O, Sulfides (odors) etc. and trace gases.
· Trace gases such as acetone, toluene etc. are associated with the deposition of hazardous wastes, more in
older landfills.
· Generation takes place in four phases:
- Phase I - Initial Adjustment - aerobic phase, mainly N2 and O2 being generated.
- Phase II - Transition- going anaerobic, pH of leachate (if any) will drop.
- Phase III - Acid -
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- hydrolysis - a chemical reaction, higher molecular compounds (proteins, lipids etc.) are transformed
into simpler compounds that the MO's can metabolize.
- acidogenesis - microbial conversion of above compounds into lower mass compounds such as acetic
acid.
- Phase IV - Methane Fermentation -A second group of microbes (strict anaerobes) converts the phase III
material into CH4 (methane) and CO2 (carbon dioxide).
- Phase V - Maturation - die off
· Volume - 14.0 ft3/lb of biodegradable organic solids destroyed (see eq 11-2). Function of lignin content.
Lignin is the organic glue that binds trees and plants together.
C. Movement of Landfill Gas
· Mechanisms include diffusion, migration of a gas from a higher to a lower concentration and convection,
the internal pressure of the landfill is greater than atmospheric pressure.
· Convection velocity 1-15 cm/d.
· Most methane (lighter than air) is vented to the atmosphere, however, both CH4 (methane) and CO2
(carbon dioxide) have been found in concentrations of up to 40% at lateral distances of up to 400' from the
edges of unlined landfills. CO2 is heavier than air and sinks perhaps to the GWT where it is readily soluble
in water and forms carbonic acid. The carbonic acid lowers the pH which increases the hardness and
mineral content via solubilization.
D. Control of Landfill Gases
Passive and active controls. With passive systems, the pressure of the gas that is generated serves as the
driving force for the movement of gas. Active systems used an induced vacuum to control the flow of gas.
1.) Passive Control
· Vents
· Trenches (interceptor to collect)
· Trenches/walls (barrier to redirect)
2.) Active
· Extraction wells
· Extraction trenches
· Air dams
5. Leachate
Leachate is defined as the liquid that has percolated through solid waste and has extracted dissolved or
suspended materials. The liquid usually enters the landfill from external sources such as drainage, precipitation
and ground water.
A. Composition of Leachate
· Function of the time i.e. landfill phase: BOD/COD ratio .5 initially, .05-.2 in mature landfills. The BOD is
consumed and the mature landfills contain humic and fuvic acids which are not readily biodegradable.
· Mature landfill: BOD 100-200 mg/l, pH 6.6-7.5, Total Iron 20-200 mg/l
B. Water Balance
· Water entering as precipitation
· Water entering in solid waste - typically MSW is 20% moisture
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· Water entering in cover material. Field Capacity(FC) is the maximum amount of moisture that can be
contained in the cover material: 6-12% for sands, 23-31 for clay loams. FC is the quantity of water than can
be held against the pull of gravity, eq. 11-17
· Water consumed in the formation of gas. (Rapidly Biodegradable Volatile Solids)
Water consumed = = 0.0119 lbH2O/ft3
· Water lost as water vapor pV=nRT, .0022lb H2O/ft3 landfill gas
· Water balance equation:
DSsw=Wsw+WTS+WCM+WA(R)-WLG-WWV-WE+WB(L) eq 11-18
· The FC is compared to the amount of water present calculated in part by using the water balance
equation. If the amount of water present > FC, leachate will be formed.
C. Movement of Leachate
· Darcy's Law predicts the rate of seepage of leachate from the bottom of the landfill.
Q = -KA
K is the coefficient of permeability also and is 1333ft/day for uniform coarse sand and .000003ft/day for
colloidal clay.
· Breakthrough Time is the time in years for leachate to penetrate a clay liner.
t=
D. Fate of Constituents of Leachate in Subsurface Migration
· The constituents, of course, are the main reason for concern.
· heavy metals - Removal is a function of the cation exchange capacity (CEC) of the soil and defined as meq
of cations/100 grams of soil e.g. 100 meq/100g for organic colloids and 10meq/100g for clays. Should not
be a problem.
· trace organics - adsorption (the process of collecting soluble substances that are in solution on a suitable
surface) is the most common removal mechanism.
E. Control of Leachate
· As the leachate travels through the soil many of its harmful characteristics will be lessened by filtration and
adsorption, however, best practice calls for elimination or containment.
· Liner Systems: geomembrane, clay, geosynthetic clay, combinations
The geotextile is a thin synthetic material which minimizes the intermixing of different soil layers. The
geonet is a thin synthetic material which serves as a drainage layer, instead or sand. The geomembrane is a
thin synthetic material which serves as an impervious barrier.
· Collection Systems sloped terraces and piped bottoms.
F. Management Options
· Recycle
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· Evaporate (possible air quality problems in LA area)
· Treatment
· Integrated systems including wetlands etc.
7. Settlement of Landfills
· Nominal angle of repose for waste material is 1.5 to 1. 3:1 most commonly used for side slope.
· If height is over 50', use benches which not only help slope stability but serve as roadways, places to put gas
and water pipes.
· Settlement occurs as the material decomposes and weight is lost as gas and leachate (as much as 40% of
original mass).
· As the overburden increases, compaction and settlement occurs. Maximum specific weight from 1750 to
2150 lb/yd3. Eq. 11-30. 90% of the ultimate occurs in the first 5 years.
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