Pyrolysis Oil

Safety Data Sheet

Version: 1.0
Issue date: 1/4/2021

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

CAS-No. : 69013-21-4
Chemical name : Pyrolysis oil

1.2. Other means of identification

Synonyms : P - Oil
Other means of identification : Pyrolysis Oil and blends
EC-No. : 273-782-6

1.3. Recommended use of the chemical and restrictions on use

Recomended use : Raw material for chemistry
Restrictions on use : The product should not be used for purposes other than those shown above without first
referring to the supplier and obtaining written handling instructions

1.4. Supplier's details

Manufacturer
Environmental Solutions (Asia) Pte Ltd
101, Tuas South Avenue 2,
637226 - Singapore
T +65 6653 2299 - F +65 6653 2290

1.5. Emergency telephone number

Emergency number : +65 9792 2840

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Physical hazards : Flammable liquids, Category 2
Health hazards : Acute toxicity (inhal.), Category 4
: Germ cell mutagenicity, Category 1B
: Carcinogenicity, Category 1A
: Reproductive toxicity, Category 2
: Specific target organ toxicity — Repeated exposure, Category 2
: Aspiration hazard, Category 1
Environmental hazards : Hazardous to the aquatic environment — Chronic Hazard, Category 2
2.2. Label elements
Hazard pictograms (GHS SG) :

Signal word (GHS SG) : Danger

Hazard statements (GHS SG)
: Highly flammable liquid and vapour. (H225)
May be fatal if swallowed and enters airways. (H304)
Harmful if inhaled. (H332)
May cause genetic defects. (H340)
May cause cancer. (H350)
Suspected of damaging the unborn child. (H361d)
May cause damage to organs through prolonged or repeated exposure. (H373)
Toxic to aquatic life with long lasting effects. (H411)

Precautionary statements
Prevention : Obtain special instructions before use. (P201)
Do not handle until all safety precautions have been read and understood. (P202)
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. (P210)
Keep container tightly closed. (P233)
Ground/bond container and receiving equipment. (P240)
Use explosion-proof electrical, lighting, ventilating equipment. (P241)
Use only non-sparking tools. (P242)
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Pyrolysis Oil
Safety Data Sheet
According to SS 586 Part 3: 2014

Take precautionary measures against static discharge. (P243)

Do not breathe mist, vapours. (P260)
Avoid breathing dust/fume/gas/mist/vapours/spray. (P261)
Use only outdoors or in a well-ventilated area. (P271)
Avoid release to the environment. (P273)
Wear eye protection, protective gloves, protective clothing. (P280)
Response : IF SWALLOWED: Immediately call a doctor, a POISON CENTER. (P301+P310)
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower. (P303+P361+P353)
IF INHALED: Remove person to fresh air and keep comfortable for breathing. (P304+P340)
IF exposed or concerned: Get medical advice/attention. (P308+P313)
Call a doctor, a POISON CENTER if you feel unwell. (P312)
Get medical advice/attention if you feel unwell. (P314)
Do NOT induce vomiting. (P331)
In case of fire: Use media other than water to extinguish. (P370+P378)
Collect spillage. (P391)
Storage : Store in a well-ventilated place. Keep cool. (P403+P235)
Store locked up. (P405)
Disposal : Dispose of contents/container to hazardous or special waste collection point, in accordance
with local, regional, national and/or international regulation. (P501)
2.3. Other hazards
No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances
Name Product identifier Concentration (%) GHS SG classification
Pyrolysis Oil (CAS-No.) 69013-21-4 100 Flam. Liq. 2, H225
(Main constituent) (EC-No.) 273-782-6 Acute Tox. 4 (Inhalation), H332
Muta. 1B, H340
Carc. 1A, H350
Repr. 2, H361d
STOT RE 2, H373
Asp. Tox. 1, H304
Aquatic Chronic 2, H411

Substance is complex UVCB. This UVCB contains: Paraffinic hydrocarbons. Olefinic hydrocarbons. Naphthenic hydrocarbons. Aromatics
hydrocarbons.

3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Call a physician immediately.
Inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a
doctor if you feel unwell.
Skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing.
Eye contact : Rinse eyes with water as a precaution.
Ingestion : Do not induce vomiting. Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after ingestion : Risk of lung oedema.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapour.
Hazardous decomposition products in case of : Toxic fumes may be released.
fire
5.3. Special Protective actions for the fire fighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

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Pyrolysis Oil
Safety Data Sheet
According to SS 586 Part 3: 2014

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
No additional information available
6.1.1. For non-emergency personnel
Emergency procedures : No open flames, no sparks, and no smoking. Only qualified personnel equipped with suitable
protective equipment may intervene. Do not breathe dust/fume/gas/mist/vapours/spray.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment. Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Collect spillage.
Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public
waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Ground/bond container and receiving
equipment. Use only non-sparking tools. Take precautionary measures against static
discharge. Flammable vapours may accumulate in the container. Use explosion-proof
equipment. Wear personal protective equipment. Obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Take all necessary
technical measures to avoid or minimize the release of the product on the workplace. Limit
quantities of product at the minimum necessary for handling and limit the number of exposed
workers. Provide local exhaust or general room ventilation. Floors, walls and other surfaces in
the hazard area must be cleaned regularly. Do not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ground/bond container and receiving equipment.
Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
7.3. Specific end use(s)
Raw material for chemistry.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No additional information available

8.2. Monitoring
No additional information available

8.3. Appropriate engineering controls

Appropriate engineering controls : Ensure good ventilation of the work station.

8.4. Personal protective equipment

Hand protection : Nitrile rubber (NBR). The breakthrough time of the selected gloves must be greater than the
intended use period.

Eye protection : Wear security glasses which protect from splashes. Safety glasses

Skin and body protection : Wear suitable protective clothing

Respiratory protection : Wear respiratory protection. [In case of inadequate ventilation] wear respiratory protection.

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Pyrolysis Oil
Safety Data Sheet
According to SS 586 Part 3: 2014

Personal protective equipment symbol(s)

Environmental exposure controls : Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Orange brown
Odour : Aromatic
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 7 °C
Freezing point : No data available
Boiling point : 170 °C
Flash point : 15 °C (ASTM D 93)
Auto-ignition temperature : > 225 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Not applicable
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : 0.80 – 0.85
Density : 0.75 g/ml @40 Celcius (IP 131/57)
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Partition coefficient n-octanol/water (Log Kow) : No data available
Viscosity, kinematic : 1.98 mm²/s (ASTM D 445)
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available

9.2. Other information

Fire point : 20 °C (ASTM D 93)
Pour point : < -15 °C (ASTM D 97)
Calorific value : 9829.35 kcal/kg (Bomb calorimeter 12/58)
Sulphur content : 0.246 % wt (ASTM D 129-00)
Carbon residue : 0.5 % wt (ASTM D 189-65)
Ash content : 0.036 % wt (ASTM D 48)

SECTION 10: Stability and reactivity

10.1. Reactivity
Highly flammable liquid and vapour.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition.
10.5. Incompatible materials
Oxidizing agent.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

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Pyrolysis Oil
Safety Data Sheet
According to SS 586 Part 3: 2014

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.

Pyrolysis Oil (69013-21-4)

LD50 oral > 5000 mg/g
LD50 dermal > 2000 mg/kg bodyweight
LC50 Inhalation - Rat 4.1 mg/l/4h
Additional information The data are derived from the evaluations or test results achieved with similar products

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.

Reproductive toxicity : Suspected of damaging the unborn child.

STOT-single exposure : Not classified

STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard : May be fatal if swallowed and enters airways.

Pyrolysis Oil (69013-21-4)

Hydrocarbon Yes
Viscosity, kinematic 1.98 mm²/s (ASTM D 445)
Density 0.75 g/ml @40 Celcius (IP 131/57)

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Toxic to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short- : Not classified
term (acute)
Hazardous to the aquatic environment, long- : Toxic to aquatic life with long lasting effects.
term (chronic)

12.2. Persistence and degradability

Pyrolysis Oil (69013-21-4)
Persistence and degradability No additional information available
12.3. Bioaccumulative potential
Pyrolysis Oil (69013-21-4)
Bioaccumulative potential No additional information available
12.4. Mobility in soil
Pyrolysis Oil (69013-21-4)
Mobility in soil No additional information available

12.5. Other adverse effects

Ozone : Not classified
Other adverse effects : No additional information available

SECTION 13: Disposal considerations

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Additional information : Flammable vapours may accumulate in the container.

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Pyrolysis Oil
Safety Data Sheet
According to SS 586 Part 3: 2014

SECTION 14: Transport information

14.1. UN number
UN-No.(UN RTDG) : 3295
UN-No. (IMDG) : 3295
UN-No. (IATA) : 3295

14.2. Proper Shipping Name

Proper Shipping Name (UN RTDG) : HYDROCARBONS, LIQUID, N.O.S.
Proper Shipping Name (IMDG) : HYDROCARBONS, LIQUID, N.O.S.
Proper Shipping Name (IATA) : Hydrocarbons, liquid, n.o.s.

14.3. Transport hazard class(es)

UN RTDG
Transport hazard class(es) (UN RTDG) : 3
Danger labels (UN RTDG) : 3

IMDG
Transport hazard class(es) (IMDG) : 3
Danger labels (IMDG) : 3

IATA
Transport hazard class(es) (IATA) : 3
Danger labels (IATA) : 3

14.4. Packing group

Packing group (UN RTDG) : II
Packing group (IMDG) : II
Packing group (IATA) : II

14.5. Environmental hazards

Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available

14.6. Special precautions for user

- UN RTDG
Limited quantities (UN RTDG) : 1L
Excepted quantities (UN RTDG) : E2
Packing instruction (UN RTDG) : P001, IBC02

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Pyrolysis Oil
Safety Data Sheet
According to SS 586 Part 3: 2014

Portable tank and bulk container special : T7

instructions (UN RTDG)
Portable tank and bulk container special : TP1, TP8, TP28
provisions (UN RTDG)
- IMDG
Limited quantities (IMDG) : 1L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1, TP8, TP28
EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS
EmS-No. (Spillage) : S-D - SPILLAGE SCHEDULE Delta - FLAMMABLE LIQUIDS
Stowage category (IMDG) : B
Properties and observations (IMDG) : Immiscible with water.
- IATA
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provisions (IATA) : A3, A224
ERG code (IATA) : 3H

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. National regulations
Regulation Component/Mixture
Fire Safety Act/Fire Safety (Petroleum and Petroleum and Flammable Materials Pyrolysis Oil
Flammable Materials) Regulations

15.2. International Regulations

International agreements : This chemical is subject to the Basel Convention (Hazardous Waste).

15.3 Chemical inventory status

Australia AICS Yes
Canada DSL Yes
Canada NDSL No
China IECSC No
EU EINECS Yes
EU ELINCS No
EU NLP No
Korea ECL No
US TSCA Yes

SECTION 16: Other information

Safety Data Sheet (SDS), Singapore

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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