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4. How can you make a piece of steel soft and then make it hard?
Solution:
By heat treatment ……
Annealing (slow cooling) to soften the steel.
Quenching (fast cooling) to harden the steel.
5. Is the tensile strength of a ceramic material equal to its compressive strength?
Solution:
No. Ceramics normally has a higher compressive strength than tensile strength.
Ceramics are used to resist compressive loads rather than tensile loads.
6. Is a ceramic material a compound between a metallic element and a non-metallic element?
Solution:
Yes. Ceramics are compounds containing at least two elements: one is a metal
and another is a non-metal.
Tutorial 1(I): Materials Categories
7. In a polymer, what kind of primary bond is formed between carbon atoms in
a carbon backbone?
Solution:
Carbon atoms in the backbone are bonded strongly by covalent bond.
Principle:
• Stable atomic configuration: 8 valence electrons.
• If an atom does not have 8 valence electrons, it will try to achieve 8 valence electrons
by accepting, giving up or sharing valence electrons.
Tutorial 1(2): Electron Configuration
Not stable.
The outermost shell only has 2 valence electrons.
It is easy to lose the 2 valence electrons to become a
positive ion, favouring ionic bonding.
Not stable.
The outermost shell has 4 valence electrons.
Favour sharing valence electrons to form covalent bond
Tutorial 1(2): Electron Configuration
Not stable.
The outermost shell has 7 valence electrons.
Favour receiving 1 electron from other atom to form ionic bond
Tutorial 1 (3): Atomic Bonding
1. Explain why some materials (e.g. tungsten) have very high melting temperatures
and some have low melting temperatures (e.g. lead).
2. Why all kind of steels have a similar Young’s modulus?
3. Can you change the Young’s modulus of steel by hardening it?
4. Why different materials have different degree of thermal expansion?
5. What are the three primary bonds?
6. Why many ceramics have ionic bonding?
7. What are some common characteristics of materials with ionic bonding?
8. What is the key feature of covalent bonding?
9. Why can materials with metallic bonding conduct electricity and heat?
Tutorial 1 (3): Atomic Bonding
1. Explain why some materials (e.g. tungsten) have very high melting temperatures
and some have low melting temperatures (e.g. lead).
Solution:
Melting temperature is determined by the
atomic bond energy. The larger the bond energy,
the higher is the melting temperature.
Different materials have different atomic bond
energy, thus they have different melting
temperatures.
Tutorial 1 (3): Atomic Bonding
unstretched length
𝜎 ro
𝐸= r
𝜀
smaller Elastic Modulus
Larger s required
s Smaller s required larger Elastic Modulus
Tutorial 1 (3): Atomic Bonding
∆𝐿
= 𝛼∆𝑇
𝐿𝑜
Larger DT required
Smaller DT required
Tutorial 1 (3): Atomic Bonding
9. Why can materials with metallic bonding conduct electricity and heat?
Solution: because the electrons in the electron cloud can move easily.
Tutorial 1 (4): Crystal Structure
1. Aluminium has an FCC structure. If the atomic radius of aluminium is 0.143 nm,
calculate the volume of its unit cell in cubic meters.
2. Iron has a BCC crystal structure at room temperature and an FCC structure at
950 °C. Compute the theoretical densities of BCC and FCC iron. Given the
atomic radius of iron is 0.124 nm, and the atomic weight of iron is 55.85 g/mol.
Additional questions
1. Compute the theoretical density of tungsten (W) which has a BCC structure. Given
the atomic radius of W is 0.136 nm, and the atomic weight of W is 183.84 g/mol.
2. Compute the theoretical density of magnesium (Mg) which has a HCP structure.
Given the atomic radius of Mg is 0.16 nm, and the atomic weight of Mg is 24.305
g/mol.
Three Common Crystal Structures
2R a
Hexagonal close-packed (hcp)
ENGD2105: Materials Engineering and Processing Crystal Structure
Summary: SC, BCC, FCC, HCP
Structure Coordination # n a (c) Vc APF
SC 6 1 a=2R a3 0.52
4R
BCC 8 2 a= a3 0.68
3
FCC 12 4 a = 2R 2 a3 0.74
1. Aluminium has an FCC structure. If the atomic radius of aluminium is 0.143 nm,
calculate the volume of its unit cell in cubic meters.
Solution: For FCC crystal, the lattice parameter, a, is related to atomic radius
(4R)2 = a2+ a2
𝑎 = 2𝑅 2
1 nm = 10-9 m
Tutorial 1 (4): Crystal Structure
2. Iron has a BCC crystal structure at room temperature and an FCC structure at
950 °C. Compute the theoretical densities of BCC and FCC iron. Given the
atomic radius of iron is 0.124 nm, and the atomic weight of iron is 55.85 g/mol.
Solution: Density computation …… 𝑀𝑎𝑠𝑠 𝑀𝑎𝑠𝑠 𝑜𝑓 𝑎𝑙𝑙 𝑎𝑡𝑜𝑚𝑠 𝑖𝑛 𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙
𝐷𝑒𝑛𝑠𝑖𝑡𝑦 = =
𝑉𝑜𝑙𝑢𝑚𝑒 𝑈𝑛𝑖𝑡 𝑐𝑒𝑙𝑙 𝑣𝑜𝑙𝑢𝑚𝑒
elongation
s e =DL/L0
ex =Dd/d0 u = - ex/e
contraction
s
Tutorial 2 (1): Poisson’s Ratio
∆𝑑
Since 𝜀𝑥 = = −0.0165
𝑑0
Thus reduction in diameter: ∆𝑑 = −0.0165 × 𝑑0 = −0.0165 × 40 = −0.66𝑚𝑚
Tutorial 2 (1): Poisson’s Ratio
3. When a tensile stress is applied along the longitudinal axis of a circular steel bar
(n=0.3) and results in a strain of 0.005.
(1) What is the strain induced in the transverse direction? (answer: -0.0015)
(2) Is the diameter of the bar increased or decreased? Explain.
(3) If the original cross-section diameter of the bar is 10 mm, what is the final
diameter? (answer: 9.985 mm)
𝐸 = 2𝐺(1 + 𝜈)
Young’s modulus
𝐸
𝐺=
2(1 + 𝜈)
110
= = 42 𝐺𝑃𝑎
2(1 + 0.31)
Tutorial 2 (2): Hooke’s Law
2. A certain material has a Young’s modulus of 310 GN m-2 and shear modulus of
130 GNm-2. What is its Poisson’s ratio?
Shear modulus
Use ….. Poisson’s ratio
𝐸 = 2𝐺(1 + 𝜈)
Young’s modulus
𝐸
𝜈= −1
2𝐺
310
= − 1 = 0.192
2 × 130
Tutorial 2 (2): Hooke’s Law
3. A piece of steel of 400 mm long is pull elastically to 402 mm. What is the stress
in the steel? The Young’s modulus of steel is 200 GN m-2 (GPa).
Hooke’s Law: 𝜎 = 𝐸𝜀
𝐸 = 200 × 109 𝑁/𝑚2
402−400
𝜀= = 0.005
400
𝜎 15.28 × 106
𝐸= = = 764 × 106 𝑁𝑚−2 = 764𝑀𝑁𝑚−2
𝜀 0.02
Tutorial 2 (2): Hooke’s Law
𝜎 100𝑥106 𝑁𝑚−2
𝜀= = = 0.00143
𝐸 70𝑥109 𝑁𝑚−2
7. A 100 mm long rubber having a cross sectional area of 100 mm2 has to be stretched to a length of
130 mm. What is the stress required? What is the force required? The Young’s modulus of rubber
is 2 MPa.
130𝑚𝑚 − 100𝑚𝑚
𝜀= = 0.3
100𝑚𝑚
𝜎 = 𝐸𝜀 = 2 𝑀𝑃𝑎𝑥0.3 = 0.6𝑀𝑃𝑎
𝐹 100𝑥103 𝑁
(1) 𝜎= =
𝐴 2 = 1273𝑥106 𝑁𝑚−2 = 1273 𝑀𝑁𝑚−2 = 1273 𝑀𝑃𝑎
10𝑥10−3 𝑚
𝜋
2
𝐿𝑓 − 𝐿0 50.3 − 50
(2) 𝜀= = = 0.006
𝐿0 50
Tutorial 2 (2): Hooke’s Law
(3) Elastic, because the stress (1273 MPa) is smaller than the yield strength (1500 MPa)
𝜎 1273 × 106
(4) 𝐸= = = 212167 × 106 𝑁𝑚−2 = 212.2 𝐺𝑃𝑎
𝜀 0.006
𝜀𝑥
(5) 𝜐=−
𝜀
Δ𝑑 = 𝑑0 𝜀𝑥 = (10𝑚𝑚)𝑥(−0.0018) = −0.018 𝑚𝑚
Tutorial 3 (I): Tensile Properties
1. The yield strength of aluminium alloy is 200 MN m-2. Which of the following applied stresses
can cause plastic deformation to this alloy? Which can only cause elastic deformation?
50 MN m-2, 420 MN m-2, 150 MN m-2, 250 MN m-2
Stress, s (MPa)
(2) From line a (with 0.002 strain offset), 800
sy=775 MPa
600
(3) From line b, and line c, b
a
eT=0.024, eP=0.0175 400
1 c
eE=eT-eP=0.0065
(4) Lf=(1+eP)L0 200
=(1+0.0175)200=203.5 mm
eP eT
0
0 0.01 0.02 0.03
0.002
Strain, e
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Stress (MPa)
250
350
300
• Use Hooke’s law: s = Ee
Stress (MPa)
250
50
= 26.3 GPa
Strain = 0.0057
0
0 0.01 0.02 0.03 0.04 0.05 0.06
Strain
How to find yield strength at 0.002 strain offset?
• Find the 0.002 strain point at the Strain axis
• Draw a straight line from this point parallel to the linear part
of the Stress-Strain curve
400
350
Yield
Strength
300
=320 MPa
• Find the intercept point
Stress (MPa)
250
• The stress at this intercept point
200
is the yield strength
150
100
50
0
0 0.01 0.02 0.03 0.04 0.05 0.06
Strain
How to find the Tensile Strength?
• Find the peak point on the curve
• The stress at this point is the Tensile Strength.
400
TS=
365 MPa 350
300
Stress (MPa)
250
200
150
100
50
0
0 0.01 0.02 0.03 0.04 0.05 0.06
Strain
How to find final length after a force of 10,000 N
is applied and then released?
• Compute stress at this force: s =
F 10000 N
=
Need to find A for a A A
circular cross section of 400
10 mm diameter
350
2
d
A= 300
2
Stress (MPa)
250
10 x10 m
−3 2 200 • Find the point with s=127.4 MPa
= 150 on the curve
2 100
• It is on the linear part elastic
= 7.85 x10 −5 m 2 50
• Recovery after force is released
Thus, s = 127.4 MN/m2 0
0 0.01 0.02 0.03 0.04 0.05 0.06
= 127.4 MPa Strain
350
Thus, s = 344 MN/m2
300
= 344 MPa
Stress (MPa)
250
• Find the point with • Draw a line from this point
s=344 MPa on the curve 200 parallel to the linear part
Partial recovery
50
ep =0.007
0
Solution:
List the given values: L0=50 mm; A0 = 200 mm2 = 2x10-4 m2
L f − L0 50.23mm − 50mm
Thus, strain: e = = = 0.0046 490 MPa
L0 50mm
Slope of the straight line:
This strain must be offset by the 0.002 strain at yield
490 MPa
point to find the elastic strain: E=
0.0046 − 0.002
ee = e – 0.002 = 0.0026
s 490 MPa
Young’s modulus: E = y = = 188,462 MPa = 188.5 GPa
ee 0.0026
0.002 0.0046
Maximum Load 168,000 N
(c) Tensile strength: TS = = = 840 x10 N / m = 840 MPa
6 2
A0 2 x10 −4 m 2
L f − L0 74.3mm − 50mm
(d) Final length at fracture: Lf=74.3 mm EL% = x100 = x100 = 48.6
L0 50mm
A0 − A f 200mm 2 − 92mm 2
(e) Final neck area at fracture: Af = 92 mm2 RA% = x100 = 2
x100 = 54
A0 200mm
Tutorial 3 (II): Tensile Properties
3. A cylindrical specimen of a hypothetical metal alloy is stressed in compression. If its original and
final diameters are 30.00 and 30.04 mm respectively, and its final length is 105.20 mm, compute its
original length if the deformation is totally elastic. The elastic and the shear moduli of this alloy are
65.5 and 25.4 GPa respectively. (answer: 105.69 mm)
Solution: ➢ Use E = 2G(1+n) to find the Poisson’s ratio:
List given data for the compression test: E 65.5 GPa
Original diameter: d0 = 30.00 mm n= −1 = − 1 = 0.29
2G 2 x 25.4 GPa
Final diameter: df = 30.04 mm ➢ Find strain ex due to increase in diameter:
Final length: Lf = 105.20 mm
d f − d0 30.04mm − 30mm
E = 65.5 GPa ex = = = 0.00133
G = 25.4 GPa d0 30mm
To find: original length of the specimen, L0 ➢ Find strain e along the length direction:
e e 0.00133
(note: this must be longer than the final n =− x e =− x =− = −0.0046
length since it is a compression test). e n 0.29
➢ Find original length: L0
Lf 105.20 mm
Lf = (1+e)L0; L0 = = = 105.69 mm
1+ e 1 + (−0.0046)
Tutorial 3 (III): Tensile Properties
1. Young’s modulus is a measure of
(a) material’s resistance to plastic deformation
(b) material’s resistance to fracture
(c) material’s ductility
(d) material’s resistance to elastic deformation
3. The Young’s modulus of aluminium, steel and polystyrene is 70 GN/m2, 200 GN/m2
and 1.2 GN/m2, respectively. If a stress of 20 MN/m2 is applied to these three
materials, which will experience the largest elastic deformation?
(a) aluminium
(b) steel
(c) polystyrene
6. The yield strength and tensile strength of a material are 200 MN/m2 and
320 MN/m2 respectively. If a tensile stress of 250 MN/m2 is applied, the
material will
(a) deform elastically
(b) fracture
(c) deform only plastically
(d) deform both elastically and plastically
Tutorial 3 (III): Tensile Properties
8. The yield strength and tensile strength of a material are 200 MN/m2 and
320 MN/m2 respectively. A tensile stress of 250 MN/m2 is applied to
the material and then removed. If the same specimen is stressed again,
its new yield strength is
(a) 200 MN/m2
(b) 320 MN/m2
(c) 250 MN/m2
(d) 450 MN/m2
Tutorial 3 (III): Tensile Properties
9. It took a 100 N force to bend a piece of steel wire, 120 N to unbend it, and
140 N to re-bend it back to the same angle. This is because
(a) the diameter of the steel wire was increased
(b) the steel wire was shortened
(c) the steel wire was strain hardened
(d) the steel wire was hardened due to the heat generated
11.A cylindrical bar having a cross sectional area of 50 mm2 is pulled by a tensile
force of 7,500 N. The resultant tensile stress is
(a) 150 MN/m2
(b) 150,000 MN/m2
(c) 3750 MN/m2
(d) 75 MN/m2
14.An aluminium bar having a cross sectional area of 100 mm2 is pulled by a
force of 12,000N. If the yield strength of aluminium is 85 MN/m2, it will
deform
(a) elastically
(b) plastically
Tutorial 3 (III): Tensile Properties
15.The yield strength and Young’s modulus of a titanium alloy are 1500 MN/m2
and 150 GN/m2 respectively. If a bar of this alloy of 200 mm long is pulled by
a stress of 1200 MN/m2, what is the final length of the bar after the stress is
completely removed?
(a) 200.01 mm
(b) 202 mm
(c) 200 mm
(d) 201.6 mm
19. Plastic deformation is useful in engineering, because (may be more than one)
(a) it allows for the forming of the material into shapes by deformation
(b) the material can resist high loads without deformation
(c) it gives warning before the component fractures
(d) it absorbs more energy before the component fractures.
Tutorial 3 (III): Tensile Properties
21. Two grades of steel, AISI 1020 and AISI 1045, both in the annealed
condition, were tensile-tested. Which of the following figure correctly shows
(schematically) the stress-strain curves for these two materials?
Stress
Stress
AISI 1020 AISI 1020 AISI 1020
22. Two AISI 1045 steel specimens, one annealed and the other quench-hardened,
were tensile-tested. Which of the following figure correctly shows
(schematically) the stress-strain curves for these two specimens?
Hardened
Hardened Hardened
Stress
Stress
Stress
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Shear
stress
Shear
stress
Dislocation Theory
Permanent
deformation
Stress
Plastic deformation Materials
becomes more difficult become stronger
Strengthening principle: Strain
Large Small
grains grains
Slip
Grain boundary Yield strength of a material increases with
plane decreasing grain size – due to increased
grain boundary areas … which are barriers
to dislocation motion
Slip
plane
Grain B
Grain A
Strengthening by Grain refinement
Hall-Petch Equation
Yield Constants
strength
ky
y = 0 +
d
Grain
diameter
Tutorial 4 (I): Grain refinement and Hall-Petch equation
1. Estimate the yield strengths of an alloy when its average grain sizes are 0.1 mm and
0.02 mm respectively, if 0=100 MPa and ky = 20 MPa mm in the Hall-Petch equation
ky
y =0 +
d
20
y = 100 +
d
20
for d = 0.1 mm: y = 100 + = 163 .2 MPa
0.1
20
for d = 0.02 mm: y = 100 + = 241 .4 MPa
0.02
Tutorial 4 (I): Grain refinement and Hall-Petch equation
2. The strength of a copper alloy is 100 MPa when its average grain size is 0.05 mm.
Estimate the strength of the same alloy when the grain size is reduced to 0.01 mm.
Assume value of 0 for the alloy is 30 MPa.
ky
(a) Since 0=30 MPa, the Hall-Petch equation can be rewritten as follows: y = 30 +
d
(b) To compute y for any given grain size (d) value, the value of constant ky must
be known first. The value of ky can be determined because
when d = 0.05 mm, y = 100 MPa, i.e. in the Hall-Petch form
ky
100 = 30 + k y = (100 − 30) 0.05 = 15.65 (MPa mm )
0.05
(c) Now, since the values of the constants, 0 and ky, are known, the Hall-Petch
equation becomes 15 .65
y = 30 +
d
15 .65
(d) For d = 0.01 mm y = 30 + = 186 .5 MPa
0.01
Tutorial 4 (I): Grain refinement and Hall-Petch equation
3.The strength of a nickel alloy is 500 MN/m2 when its average grain size is 0.16 mm. The strength is
increased to 750 MN/m2 by reducing the average grain size to 0.04 mm. Estimate the strength of the
same alloy when the grain size is further reduced to 0.01 mm.
(a)The two constants, 0 and ky, in the Hall-Petch equation must be known.
(b) The 0 and ky values can be determined because
ky
When d = 0.16 mm, y = 500 MPa, i.e. 500 = 0 +
0.16
ky
When d = 0.04 mm, y = 750 MPa, i.e. 750 = 0 +
0.04
(c) Solve the above two simultaneous equations, to find the values of 0 and ky
ky = 100 (MPa mm ) 0 = 250 (MPa)
100
(d) Now, the Hall-Petch equation for this alloy becomes y = 250 +
100 d
(e) For d = 0.01 mm y = 250 + = 1250 MPa
0.01
Tutorial 4 (I): Grain refinement and Hall-Petch equation
4. The following figure shows the relationship between yield strength (y) and average
grain size (d) experimentally measured for a metallic alloy. Determine
i) the values of the constants, 0 and ky, in the Hall-Petch equation:
ii) the yield strength of this alloy when its average grain size is 0.005 mm.
ky
y =0 +
600
d 500
5. The yield strength for an iron that has an average grain diameter of 5x10-2 mm is
135 MPa. At a grain diameter of 8x10-3 mm, the yield point increases to 260 MPa.
At what grain diameter will the yield point be 205 MPa? (Answer: 1.48x10-2 mm)
Lattice strain
Theory of Strain Hardening
When a metal is plastically deformed it becomes stronger with increasing
amount of deformation – strain (cold work) hardening
Strain-hardening
Why?
Stress
Dislocation interactions;
Dislocation density increases; s=Ken
Dislocations entangling
Yielding: dislocation start to move
A0 – Ad
%CW = ( A )x100
0
1. Rank the strength and ductility of the following silver alloy in decreasing orders
and explain your ranking:
(a) silver alloyed with 5 wt% copper
(b) pure silver
(c) silver alloyed with 2.5 wt% copper
Solution:
Rectangular:
A0 − Ad (125 175 − 75 200
%CW = x100 = 100 = 31 .43
A0 125 175
Solution:
Calculate recrystallization temperature:
Lead:
Trec = 0.5(327 + 273 ) = 300 K = 300 − 273 = 27 o C
Tin:
𝑇𝑟𝑒𝑐 = 0.5(232 + 273) = 252.5𝐾 = 252.5 − 273 = −20. 5𝑜 𝐶
A0 − Ad 12 2 − R 2
Case 2: %CW = x100 = 100 = 52 .73; Thus, R = 8.25 mm
A0 12
2
Tutorial 4 (II): Solid Solution and Strain Hardening
6. Describe in your own words the three strengthening mechanisms (i.e. grain size
reduction, solid solution strengthening, and strain hardening). Be sure to explain
how dislocations are involved in each of the strengthening techniques.
Solution: Plastic deformation in metals is due to dislocation motion.
Grain reduction technique: grains boundaries are obstacles to dislocation motion.
The smaller the grain sizes, the more grain boundaries, thus the stronger is the
material.
Solid solution hardening: the solid solute atoms induce lattice strain surrounding
each atom. The lattice strain can impede dislocation motion and thus harden the
material.
Strain hardening: when metals are plastic deformed, dislocations move around in
the metal and at the same time more dislocations are created which can impede
one another, thus resulting in increased strength.
Tutorial 5 (I): Binary phase diagrams
Tutorial 5 (I): Binary phase diagrams
1. Using the binary Pb-Sn phase diagram, determine (1) the phases present, (2) phase compositions, and (3)
relative amount of the phases for the 30 wt% Sn-70 wt% Pb alloy at three different temperatures:
100°C, 200 °C and 300 °C.
Invariant point @ 61.9%Sn & 183oC
Three phases co-exist: Liquid, a & b
Eutectic reaction:
183℃
𝐿(61.9𝑆𝑛) 𝛼(18.3𝑆𝑛) + 𝛽(97.8𝑆𝑛)
R S Lever Rule:
𝑆 97.8 − 61.9
𝑊𝛼 = = = 0.45
𝑅 + 𝑆 97.8 − 18.3
𝑅 61.9 − 18.3
𝑊𝛽 = = = 0.55
𝑅 + 𝑆 97.8 − 18.3
Tutorial 5 (I): Binary phase diagrams
𝑅 𝐶0 − 𝐶𝛼 30 − 17
𝑊𝐿 = = = = 0.33 Ca CL
𝑅 + 𝑆 𝐶𝐿 − 𝐶𝛼 56 − 17
C0
𝑊𝛼 + 𝑊𝐿 = 1
Tutorial 5 (I): Binary phase diagrams
C0
Tutorial 5 (I): Binary phase diagrams
2. A 65 wt% Ni- 35 wt% Cu alloy is heated to a temperature within the alpha+liquid phase region.
If the composition of the alpha phase is 70 wt% Ni, determine
(a) the temperature of the alloy.
(b) the composition of the liquid phase.
(c) the mass fractions of both the phases.
Solution:
(a) Temperature: 1345 °C T
(b) Composition of liquid phase:
CL = 59 wt% Ni
(c) Mass fraction of each phase:
𝐶0 − 𝐶𝐿 65 − 59
𝑊𝑎 = = = 0.55
𝐶𝛼 − 𝐶𝐿 70 − 59
𝐶𝛼 − 𝐶0 70 − 65 CL C0 Ca
𝑊𝐿 = = = 0.45
𝐶𝛼 − 𝐶𝐿 70 − 59
Tutorial 5 (II): F-C System
Use the Fe-C phase diagram shown below, calculate the relative amount of phases at 720 °C:
(1) the relative amount of ferrite (a) and cementite (Fe3C) in steels containing 0.2%C, 0.4%C and 0.6%C.
(2) the relative amount of pre-eutectoid ferrite and pearlite in 0.5%C steel.
(3) the relative amount of pre-eutectoid cementite and pearlite in 1.2%C steel
Solution:
Ca = 0.022 (ferrite)
@ 720 °C:
Cm = 6.70 (cementite)
(1) Mass fraction of ferrite and cementite:
𝐶𝑚 − 𝐶0 𝐶0 − 𝐶𝛼
𝑊𝑎 = 𝑊𝑚 =
𝐶𝑚 − 𝐶𝛼 𝐶𝑚 − 𝐶𝛼
Solution:
Ca = 0.022 (ferrite)
@ 720 °C:
CP = 0.76 (pearlite)
(2) Mass fraction of pre-eutectoid ferrite
and pearlite:
𝐶𝑃 − 𝐶0 0.76 − 𝐶0
𝑊𝑎′ = =
𝐶𝑃 − 𝐶𝛼 0.76 − 0.022
𝐶0 − 𝐶𝛼 𝐶0 − 0.022
𝑊𝑃 = = C0
𝐶𝑃 − 𝐶𝛼 0.76 − 0.022
For C0=0.5%C:
Wa’=0.35, WP=0.65 P(0.76C)
Tutorial 5 (II): F-C System
Proeutectoid a’+pearlite
P (a+cementite)
a’
Tutorial 5 (II): F-C System
Use the Fe-C phase diagram shown below, calculate the relative amount of phases at 720 °C:
(1) the relative amount of ferrite (a) and cementite (Fe3C) in steels containing 0.2%C, 0.4%C and 0.6%C.
(2) the relative amount of pre-eutectoid ferrite and pearlite in 0.5%C steel.
(3) the relative amount of pre-eutectoid cementite and pearlite in 1.2%C steel
Solution:
Cm = 6.7 (cementite)
@ 720 °C:
CP = 0.76 (pearlite)
(3) Mass fraction of pre-eutectoid cementite
and pearlite:
𝐶0 − 𝐶𝑃 𝐶0 − 0.76
𝑊𝑚′ = =
𝐶𝑚 − 𝐶𝑃 6.7 − 0.76
𝐶𝑚 − 𝐶0 6.7 − 𝐶0
𝑊𝑃 = =
𝐶𝑚 − 𝐶𝑃 6.7 − 0.76 C0
For C0=1.2%C:
Wm’=0.07, WP=0.93 P(0.76C)
Tutorial 5 (II): F-C System
Pre-eutectoid Fe3C’+pearlite
Tutorial 5 (II): F-C System
Calculate the relative amount of ferrite, cementite and pearlite for the carbon steels tested
in the Hardness Testing lab:
0.18 wt% C, 0.35 wt% C, 0.60 wt% C, 0.90 wt% C, 1.20 wt% C
6.7 − 𝐶0
𝑊𝛼 =
6.7 − 0.022
𝐶0 − 0.022
𝑊𝑐𝑚 =
6.7 − 0.022
C0
Tutorial 5 (II): F-C System
Calculate the relative amount of ferrite, cementite and pearlite for the carbon steels tested
in the Hardness Testing lab:
0.18 wt% C, 0.35 wt% C, 0.60 wt% C, 0.90 wt% C, 1.20 wt% C
WP: 0.18% C , 0.35%C, 0.60%C … Hypoeutectoid
𝐶0 − 0.022
𝑊𝑃 =
0.76 − 0.022
C0
Tutorial 6 (I): Steels and Heat Treatments
1. Which two of the following alloys are ferrous alloys?
(a) steels; (b) aluminium alloys; (c) cast irons; (d) titanium alloys
2. The range of carbon content in steels is
(a) 2.1% to 4.5%; (b) 0.02% to 2.0%; (c) 0.5% to 1.0%; (d) 4.5% to 6.7%
3. The carbon content in AISI 1060 steel is
(a) 60%; (b) 6%; (c) 0.6%; (d) 1%
4. The crystal structure of iron at room temperature is called
(a) ferrite; (b) austenite; (c) pearlite; (d) cementite
5. The crystal structure of iron at 1000°C is called
(a) ferrite; (b) austenite; (c) pearlite; (d) cementite
6. Pearlite in steel is
(a) a mixture of austenite and cementite; (b) a mixture of ferrite and austenite
(c) a mixture of ferrite and cementite; (d) carbon in steel
Tutorial 6 (I): Steels and Heat Treatments
7. At equilibrium, steel containing less than 0.8% C has a structure of
(a) a mixture of pearlite and cementite; (b) a mixture of ferrite and pearlite;
(c) a mixture of cementite and austenite
8. The process of heating a steel to a high temperature and then cooling it slowly in
furnace is called
(a) normalising; (b) tempering; (c) hardening; (d) annealing
9. The process of heating a steel to a high temperature and then cooling it in air
is called
(a) normalising; (b) tempering; (c) hardening; (d) annealing
10. The process of heating a steel to a high temperature and then cooling it
rapidly is called
(a) normalising; (b) tempering; (c) hardening; (d) annealing
Tutorial 6 (I): Steels and Heat Treatments
11. The structure produced in steel by quenching is called
(a) martensite; (b) cementite; (c) austenite; (d) pearlite
12. A quenched steel should always be
(a) tempered; (b) annealed; (c) normalised; (d) quenched again
13. Which of the following are the effects of tempering (maybe more than one)
(a) increasing hardness; (b) increasing toughness;
(c) reducing toughness; (d) reducing residual stresses
14. Tempering also reduces the hardness of alloyed high carbon tool steels
irrespective of tempering temperature.
(a)True, or (b) False.
15. Secondary hardening occurs in tool steels at which tempering temperature range?
(a) 200 – 300°C; (b) 350 – 440°C; (c) 450-600°C; (d) 600 – 700°C.
Tutorial 6 (I): Steels and Heat Treatments
16. Secondary hardening is due to
(a) second quenching; (b) formation of fine carbides dispersed in the matrix;
(c) formation of austenite; (d) formation of harder martensite.
17. Which of the following heat treatment procedure can be used to harden a
0.4%C steel?
(a) heating the steel to 900oC to form a fully austenitic structure, soaking at that
temperature for some time, then cooling the steel rapidly in water down to room
temperature.
(b) heating the steel to 500oC for recrystallisation, then cooling rapidly in water.
(c) heating the steel to 900oC to form a fully austenitic structure, soaking at that
temperature for some time, then cooling the steel slowly in furnace down to
room temperature.
Tutorial 6 (I): Steels and Heat Treatments
18. Some alloy steels can be hardened by cooling from austenite (high
temperature) just in air, because
(a) the alloying elements harden the steel
(b) it is not necessary to form martensite
(c) the alloy steels have very good hardenability and can form martensite by
air-cooling.
(d) the steels have been hardened previously.
19. The major purpose of adding alloying elements to steel is
(a) to make the steel look better; (b) to increase the hardenability of steel;
(c) to increase the ductility of steel; (d) to increase the conductivity of steel.
Tutorial 6 (I): Steels and Heat Treatments
Short Questions:
1. Briefly describe a heat treatment process that can be used to harden the 0.55%C steel.
Steel can be hardened by quenching, which involves heating to a high temperature,
normally between 800oC and 1100oC to form an austenite structure, followed by
rapid cooling to form a marteniste structure. Martensite is a hard structure in steel.
Rapid cooling (quenching) is required to avoid the formation of equilibrium
structure, i.e. pearlite, ferrite and cementite.
2. A piece of steel is too hard to be machined. Can you soften it for machining? How?
Yes, by annealing: involves heating to a high temperature, normally between
800oC and 1100oC to form an austenite structure, followed by slow furnace
cooling to form the equilibrium structure, i.e. pearlite, ferrite and cementite.
Tutorial 6 (II): Engineering Materials
Steels and Cast Irons:
1. Which of the following materials is most suitable for making the body of a car?
(a) low carbon steel
(b) medium carbon steel
(c) high carbon steel
(d) pure aluminium
2. Which of the following materials is most suitable for making a coldworking die?
(a) low carbon steel
(b) medium carbon steel
(c) high carbon steel
(d) cast iron
3. Which of the following materials is most suitable for making a power transmission shaft?
(a) low carbon steel
(b) medium carbon steel
(c) high carbon steel
(d) aluminium
Tutorial 6 (II): Engineering Materials
4. Which of the following are characteristics of cast irons?
(a) high carbon content
(b) brittle
(c) cheap
(d) good damping ability
(e) all of the above
5. Which of the following materials is most suitable for making the base of a power saw machine?
(a) low carbon steel
(b) medium carbon steel
(c) high carbon steel
(d) cast iron
9. Many stainless steel articles carry a symbol “18-8”. This symbol means that the stainless steel contains
(a) 18% Cr + 8% Ni
(b) 18% Fe + 8% Cr
(c) 18% C + 8% Cr
(d) 18% Cr + 8% C
Tutorial 6 (II): Engineering Materials
Non-ferrous Alloys:
10.Aluminium alloys can be strengthened by quenching to form a martensite structure.
(a) true, or
(b) false
11. The two most important requirements for achieving precipitation hardening are
(a) proper size and number of the precipitate particles
(b) grain size of the matrix phase
(c) uniform distribution of the precipitate particles
(d) melting temperature of the matrix phase
12.The three heat treatment stages to achieve precipitation hardening in an aluminium alloy are
(a) annealing
(b) solution treatment
(c) rapid cooling
(d) hardening
(e) aging
Tutorial 6 (II): Engineering Materials
Non-ferrous Alloys:
13.Aluminium alloys are widely used, because
(a) they are light
(b) they have good strength-to-density ratio
(c) they have pleasant appearance
(d) they have good corrosion resistance
(e) all of the above
25.Polystyrene (PS) is polymeric material used to make CD cases. It has a semicrystalline structure. Is PS
recyclable? Why?
(a) Yes
(b) No
Your reasoning:
Because it has some crystallinity, it must be a thermoplastic and thermoplastics are recyclable.
Tutorial 6 (II): Engineering Materials
Short Questions:
26. Briefly describe the properties and typical applications of low carbon steels, medium carbon steels,
and high carbon steels.
Solution:
Please refer to the lecture notes
27. Briefly explain why stainless steels are ‘stainless’.
Solution:
Due to the formation of a chromium rich oxide film of a few nanometer thick on the surface. The
film is dense, adherent and insoluble.
28. How does titanium compare to steel for the shaft on a golf club?
Solution:
Titanium is as strong as steel, but has a lower Yong’s modulus (130 GPa for Ti vs 210 GPa for steel).
Thus the shaft made of Ti will be more flexible and deflect more elastically. This helps to drive the ball
further with the same amount of force.
Tutorial 6 (II): Engineering Materials
Short Questions:
29. Explain why the compressive strength of ceramics is usually much greater than its tensile strength.
Solution:
This is because ceramics are normally fabricated by powder processing and there are many pores and
voids inside ceramics. The pores and voids can serve as cracks which open easily under tension, but may
close under compression.
30. Explain why it is difficult to measure the stress-strain behaviour of brittle ceramics by a tensile test.
Solution:
Three reasons:
(1) Difficult to make a dog-bone like sample for tensile testing
(2) Difficult to clamp the sample for tensile testing
(3) Difficult to align the sample along the loading direction
Ceramics are normally tested by bending, which can alleviate the above problems
(1) No need to machine a dog-bone like sample. Any rectangular or circular sample will do.
(2) No need to clamp the sample
(3) No need to align the sample
Tutorial 6 (II): Engineering Materials
Short Questions:
31. Discuss the differences between thermoplastic polymers and thermosetting polymers, in terms of molecular
structure, strength, response to heating and recycling.
Solution:
Thermoplastic
Properties: no crosslinking, mostly semi-crystalline, low strength, low resistant to heat
Heating/recycling: re-melt upon heat and hardened upon cooling. Recyclable.
Thermosets
Properties: Crosslinking structure, amorphous, higher strength, resist higher temperature
Heating/recycling: only melt once. Once set, cannot be re-melt upon heating, but burn and tar.
Not recyclable.
Tutorial 7 (I): Ductile & Brittle Fracture and Stress Concentration
1. Describe the mechanism of crack propagation for both ductile and brittle
modes of fracture.
Solution:
Ductile: propagate slowly, accompanied with plastic deformation, requires
more energy
Brittle: propagate rapidly, without plastic deformation, requires less energy
2. Explain why ductile fracture is more desirable than brittle fracture.
Solution:
(1) Ductile fracture is accompanied with plastic deformation. This gives
warning and avoids catastrophe
(2) Ductile fracture requires more energy
Tutorial 7 (I): Ductile & Brittle Fracture and Stress Concentration
3. What is the magnitude of the maximum stress that exists at the tip of an internal
crack having a radius of curvature of 2.5x10-4 mm and a crack length of 2.5x10-2
mm when a tensile stress of 170 MPa is applied? (Answer: smax = 2574 MPa)
s m =s 2 x a +1 =1035 (MPa) 2 x 0.5 mm
+ 1
= 2.17 x 10 4
MPa =21.7 GPa
o t −3
5 x10 mm
Tutorial 7 (I): Ductile & Brittle Fracture and Stress Concentration
Summary
• Fracture Mechanics equation:
K = Y a Y=1 a Y=1.1
K ≥ KIc
• Condition for safe use (no fracture):
K < KIc
Tutorial 7 (II): Fracture Mechanics
Q1: An airplane component made of an aluminium alloy having a plain strain fracture
toughness of 30MPa m is known to have an internal crack of 4 mm long. Is it safe to
use the component if the maximum applied stress is 300 MPa? Assume Y = 1.1.
Solution:
Calculate K value: note 2a = 4 mm; a = 2x10-3 m; KIC = 30 MPa m
Solution:
Case 1: Fracture occurs when = 112 MPa, 2a = 8.6 mm Case 2: If 2a = 6 mm, c = ???
𝐾 = 𝐾𝐼𝐶 = 𝑌𝜎 𝜋𝑎 𝑌 = 2.0 is the same for both cases
8.6 × 10−3 𝑚
26 𝑀𝑃𝑎 𝑚 = 𝑌 × 112𝑀𝑃𝑎 × 𝜋 𝐾 = 𝐾𝐼𝐶 = 𝑌𝜎 𝜋𝑎
2
26 6 × 10−3
𝑌= = 2.0 26 = 2.0 × 𝜎𝑐 × 𝜋
−3
2
8.6 × 10
112 × 𝜋 26
2
𝜎𝑐 = = 134 𝑀𝑃𝑎
6× 10−3
2× 𝜋
2
Tutorial 7 (II): Fracture Mechanics
Q5. A large plate is fabricated from a steel alloy that has a plane strain fracture toughness of 32.4 MPa 𝑚.
(a) If, during service use, the plate is exposed to a tensile stress of 500 MPa, determine the minimum
length of a surface crack that will lead to fracture. Assume a value of 1.0 for Y.
(b) The following table shows the detection limits (hypothetical) of several NDT techniques
available on the market. Which one would you suggest to use for NDT of such components?
Technique Microsco Dye Ultrasonic Magnetic Eddy current
pic penetrant particle
Minimum
detectable 1.5 mm 1.8 mm 2.0 mm 1.1 mm 1.0 mm
crack size
Solution:
(a) Use ….. 𝐾 = 𝐾𝐼𝐶 = 𝑌𝜎 𝜋𝑎
2 2
1 𝐾𝐼𝐶 1 32.4
𝑎𝑐 = = = 1.34 × 10−3 𝑚 = 1.34 𝑚𝑚
𝜋 𝑌𝜎 𝜋 1.0 × 500
Surface crack length = a = 1.34 mm (Note: Internal crack length = 2a)
s s
sc 𝐾 = 𝐾𝐼𝐶 Fracture sc 𝐾 = 𝐾𝐼𝐶 Fracture
sapplied
2a
sapplied 𝐾 < 𝐾𝐼𝐶 No fracture
Time Time
s
S-N Curves
s max − s min
2
Fatigue
limit
If stress is
below this
limit, the
Material will
last forever
At this stress, the material can last 105 cycles,
i.e. the material has a fatigue life of 105 cycles
Fatigue Failure Processes
(2) Crack Propagation:
Beach marks (clamshell pattern) & striations.
•Macroscopic •Microscopic
dimensions dimensions
•Caused by • formed by
interruptions crack advance
of operation during a single
load cycle
There may be thousands of striations within one
beachmark
The presence of beachmarks and striations on a fracture
surface confirms that the cause of failure was fatigue
Fatigue Failure Processes
(2) Crack Propagation:
Beach marks (clamshell pattern) & striations.
3. Briefly explain the difference between fatigue striations and beachmarks both in
terms of (a) size and (b) origin.
Solution:
Feature Size Origin
macroscopic, may be interrupion in stress
Beachmarks observed with naked eye cycles or operation
microscopic, observed Fatigue crack growth
Striations under electron microscopy during each load cycle
4. List four measures that may be taken to increase the resistance to fatigue of a
metal alloy.
Solution:
Proper design to avoid stress concentration, smoothen the surface by lapping
or polishing, introduce compressive residual stresses by shot peening,
surface hardening by carburizing and nitriding
Tutorial 8 (I): Fatigue Failure
5. Briefly explain (1) What causes fatigue; (2) Why fatigue happens; (3) How fatigue
failure can be identified.
Solution:
(1) Due to cyclic stress
(2) Crack growth after each stress cycle
(3) By looking for beachmarks and striations