General Chemistry 2 - CHEM122

WEEK 11
 ASSIGNMENT 008
Question 1
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Calculate the hydroxide ion concentration in a 0.0075 M HClO 4 solution. 
Select one:

a. 6.02 x 10-12 M

b. 0.105 M

c. 0.0075 M

d. 1.33 x 10-12 M

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Question 2
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Calculate the pH of a 1.5 M solution of hypochlorous acid, HClO. The Ka for HClO is 4.5 x 10-4.
Select one:

a. 3.64

b. 2.78

c. 4.12

d. 3.95

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Question 3
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The ion-product constant of water considers that it is capable of autoionization.
Select one:

True
 False

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Question 4
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All Lewis acids are Arrhenius acids.
Select one:

True

False

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Question 5
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The pH scale is a logarithmic scale indicating acid or base strength of substances.
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True

False

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Question 6
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Weak acids dissociate completely in solution.
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True

False

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Question 7
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Acids generally taste sour and bases are bitter.
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True

False

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Question 8
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Determine the pH of a solution prepared by dissolving 2.5 g of NaOH in 750 ml water.
Select one:

a. 10.9

b. 11.6

c. 12.8

d. 12.1
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Question 9
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A 1.0 M solution of a weak base will release 1 mole of OH- per liter of solution. 
Select one:

True

False

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Question 10
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Which of the following is not considered an Arrhenius acid?
Select one:

a. HClO4

b. BF3

c. H3PO4

d. HCl

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 SHORT QUIZ 008

Question 1
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Identify the acid-conjugate base pair in the following reaction.
Ba(OH)2 + HI → H2O + BaI2
Select one:

a. Ba(OH)2 and H2O
b. Ba(OH)2 and I-

c. HI and H2O

d. HI and I-

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Question 2
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A strong conjugate acid donates a proton to form back the original weak base.
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True

False

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Question 3
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Calculate the pH of a 0.95 M solution of propionic acid, CH3CH2COOH, The Ka of benzoic acid is 1.34
x 10-5.
Select one:

a. 1.65

b. 3.75

c. 2.45

d. 4.35

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Question 4
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Calculate the pH of a 0.015 M solution of nitric acid, HNO3. 
Select one:

a. 9.34

b. 6.5
c. 1.82

d. 4.8

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Question 5
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Which of the following is a Lewis base?
Select one:

a. NH3

b. Sr(OH)2

c. KOH

d. Mg(OH)2

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Question 6
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Calculate the pH of a solution of 0.275 M Ca(OH)2.
Select one:

a. 7

b. 0.26

c. 9

d. 13.74

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Question 7
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Determine the hydronium ion concentration in a 50 ml solution containing exactly 6.3 x
1021 molecules of HI.
Select one:

a. 0.63 M

b. 0.21 M
c. 0.84 M

d. 0.42 M

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Question 8
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Calculate the pH of a solution prepared by dissolving 2.5 g of KOH in 100 ml of water.
Select one:

a. 13.14

b. 12.2

c. 12.9

d. 13.65

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Question 9
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The pH of a solution can be used to determine its hydroxide ion concentration.
Select one:

True

False

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Question 10
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What is the pOH of a solution of prepared by adding 50 ml of 1 MNaOH to 50 ml of water?
Select one:

a. 0.30

b. 0.20

c. 0.10
d. 0.40

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 LABORATORY EXAM 008

Question 1
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An equilibrium that strongly favors products has __________.
Select one:

a. a value of K = 0.

b. a value of K << 1.

c. a value of K >> 1.

d. a value of K = 1.

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Question 2
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Which of the following occurs when products are added to a chemical reaction in solution at
equilibrium?
Select one:

a. Q increases, so the equilibrium shifts to produce more products.

b. Entropy increases.

c. Q increases, so the equilibrium shifts to produce more reactants.

d. C: Nothing happens.

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Question 3
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Which of the following occurs when reactants are removed from a chemical reaction at equilibrium?
Select one:

a. Nothing happens.

b. Q increases, so the equilibrium shifts to produce more products.

c. Q increases, so the equilibrium shifts to produce more reactants.

d. Enthalpy increases.

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Question 4
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The rate of this reaction can be measured by experimentally determining the amount of reactants A
or B that is consumed as a function of:
Select one:

a. Pressure

b. Time
c. Color

d. Temperature

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Question 5
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The field of chemistry that is concerned with studies of reaction rates is called:
Select one:

a. stoichiometry

b. chemical kinetics

c. thermodynamics

d. calorimetry

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Question 6
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The powers to which the concentrations in the rate law are raised are called the:
Select one:

a. Order of the knights Templars

b. Order of the day

c. Order of the reaction

d. Order of the phoenix

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Question 7
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Which of the following occurs when reactants are added to a chemical reaction? 
Select one:

a. Q increases, so the equilibrium shifts to produce more products

b. Q increases, so the equilibrium shifts to produce more reactants

c. Nothing happens

d. Enthalpy increases.

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Question 8
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If a reaction is first order, a plot of ln [C] vs time gives:
Select one:

a. a dashed line

b. a straight line

c. a dotted line

d. a curved line

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Question 9
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If a reaction is first order, a plot of 1/[C] vs time gives:
Select one:

a. a curved line

b. a dotted line

c. a straight line

d. a dashed line

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Question 10
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Quantitative studies lead to very important predictions not only about how fast a reaction proceeds
and how much of a product will form after a certain time.
Select one:
a. Cannot tell the meaning of the sentence.

b. The statement is true.

c. The statement is false.

d. The statement is neither true nor false.

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WEEK 12
 ASSIGNMENT 009
Question 1
Correct

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The conversion of X molecules to Y molecules follows first order kinetics. If concentration of X is
increased 3 times, what will happen to the rate of formation of Y?
Select one:
a. Increase 6 times

b. Increase 3 times

c. Decrease 3 times

d. Increase 6 times

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Question 2
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All incident collisions lead to formation of products.
Select one:

True

False

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Question 3
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Exothermic reactions will have higher reaction rates because they are always favored.
Select one:

True

False

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Question 4
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The activation energy for chemical reactions must be overcome by the kinetic energy reactants for
the products to be formed.
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True

False

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Question 5
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Which of the following will lead to increase in rate of reaction?
Select one:

a. A decrease in temperature

b. Addition of a catalyst

c. An increase in frequency of collisions

d. A decrease in frequency of collisions

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Question 6
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Question text
The reaction N2 + 3H2→ 2NH3 is first order with respect to N2 and H2. What will be the rate of reaction
if the concentration of N2 is multiplied by 3?
Select one:

a. Double

b. 1/3 of the rate

c. Triple

d. 1/2 of the rate

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Question 7
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In the theoretical reaction A + 2B → C + 2D, which of the substances has the greater rate of
disappearance? 
Select one:

a. C

b. A

c. B

d. D
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Question 8
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The following reaction occurs in a closed container: 2A ®B
It is monitoredand the following data were recorded:

Time, seconds [A], mol/L [B], mol/L

0 2.00 0
30 1.00 0.50
60 0.5 0.75
What will be the concentration of A and B after 90 seconds?
Select one:

a. [A] = 0.375; [B] = 0.90

b. [A] = 0.20; [B] = 0.80

c. [A] = 0.125; [B] = 0.1

d. [A] = 0.25; [B] = 0.875

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Question 9
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The reaction N2 + 3H2→ 2NH3 is first order with respect to N2 and H2. If the concentration of N2 is
doubled and the concentration of H2 is halved, the rate of reaction would be
Select one:

a. 2 times the original

b. 1/4 of the original

c. 1/2 of the original

d. 4 times the original

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Question 10
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If the rate law for a reaction is k[A][B]2, what is the overall order of the reaction?
Select one:
a. Second order

b. First order

c. Third order

d. Fourth order

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 SHORT QUIZ 009

Question 1
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In the following combustion reaction:
CH4 + O2→ CO2 + 2H2O
Which has the greatest rate of formation? 
Select one:

a. O2
b. CO2

c. H2O

d. CH4

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Question 2
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For a reaction that has the following rate law:
rate = k[A]2[B]
The total order of the reaction is third order.
Select one:

True

False

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Question 3
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In the theoretical reaction A + 2B → C + 2D, what is the instantaneous rate of formation of C in
terms of A?
Select one:

a. 

b. 

c. 

d. 

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Question 4
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The rate constant is proportional to the order of reaction with respect to reactants.
Select one:
 True

False

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Question 5
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For the reaction N2 + 3H2→ 2NH3: if the rate of production of ammonia is 0.444 M/s, what is the rate
of consumption of N2?
Select one:

a. - 0.444 M/s

b. - 0.333 M/s

c. - 0.111 M/s

d. - 0.222 M/s

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Question 6
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For the reaction 2CH4 + Cl2→ 2CH3Cl: if the rate law is Rate = k[CH4]2[Cl2]; doubling the concentration
of CH4 will result in a reaction rate that is
Select one:

a. The same

b. Quadruple

c. Triple

d. Double

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Question 7
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Increasing the concentration of reactants speeds up the reaction because
Select one:

a. It lowers the order of reaction

b. It serves as a catalyst

c. It increases the activation energy

d. It increases the number of molecular collisions

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Question 8
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The following reaction occurs in a closed container: CS2 → CS + S
It is monitored and the following data were recorded:

Time, seconds [CS ], mol/L

2 [S], mol/L
0 3.00 0
20 1.50 0.25
40 0.75 0.50
What will be the concentration of CS2 and S after 80 seconds?
Select one:

a. [CS2] = 0.10; [S] = 0.88

b. [CS2] = 0.1875; [S] = 1.0

c. [CS2] = 0.09; [S] = 1.0

d. [CS2] = 0.35; [S] = 0.75

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Question 9
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The energy required for reactants to proceed to product formation is called
Select one:

a. Kinetic energy

b. Potential energy

c. Activation energy

d. Thermal energy

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Question 10
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The combustion of methane is
CH4 + 2O2→ CO2 + 2H2O
Which of the following is correct?
Select one:

a. The rate of consumption of oxygen is twice as the rate of production of H 2O

b. The rate of formation of CO2 is equal to that of H2O

c. The rate of formation of H2O is equal to rate of consumption of CH4

d. The rate of formation of CO2 is equal to the rate of consumption of CH4

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 LABORATORY EXAM 009

{same with Laboratory Exam 008}
WEEK 13
 LONG QUIZ 003
Question 1
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Substances that can accept or donate a proton are called ____.
Select one:

a. prokaryotic

b. ambivalent

c. amphoteric

d. monoprotic

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Question 2
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 Flag question

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For the reaction 2 HCl → H2+ Cl2, the instantaneous rate with respect to HCl may be. 
Select one:

a. 

b. 

c. 

d. 

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Question 3
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What is the pH of a 0.0125 M HNO3solution?
Select one:

a. 1.2
b. 2.5

c. 2.1

d. 1.9

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Question 4
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A chemical reaction that favors formation of products is a reaction with ____
Select one:

a. Q > K

b. Q = K

c. Q = 1

d. K < Q

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Question 5
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Determine the hydronium ion concentration in a 100 mlsolution containing exactly 1.25 x
1020molecules of HBr.
Select one:

a. 0.013

b. 0.016

c. 0.002 M

d. 0.006

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Question 6
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Which of the following is true for a reaction at equilibrium?
Select one:
a. only the backward reaction is occurring

b. the rate constant of the forward reaction is doubled

c. the rates of the forward and backward reactions are equal

d. only the forward reaction is occurring

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Question 7
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A precipitation reaction that is exothermic in nature will be favored by putting the reaction vessel in
an ice bath.
Select one:

True

False

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Question 8
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What is the equilibrium constant expression for the following reaction?
NH4CO2NH2(s) ⇌ 2 NH3(g) + CO2(g)
Select one:

a. 

b. 

c. 

d. 

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Question 9
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Determine the pH of a solution resulting from mixing of 100 ml of 0.75 M HClO4and 200 ml of 0.50 M
NaOH.
Select one:
a. 13.7

b. 14

c. 13.2

d. 13.9

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Question 10
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In a reaction where Q = K, the reaction is at equilibrium and both forward and backward reactions
occur at the same rates.
Select one:

True

False

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Question 11
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Which of the following is the strongest acid?
Select one:

a. HCIO3

b. HCIO4

c. HCIO2

d. HCIO

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Question 12
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Enzymes perform better than metal catalysts.
Select one:

True
 False

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Question 13
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For a given reaction:
                A(s) + B(l) ⇌ C(g) + D(l)
What can be done to lower the concentration of C in the system?
Select one:

a. increase the pressure

b. evaporate D from the system

c. add additional A to the system

d. increase the volume

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Question 14
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What is the concentration of hydroxide in a 0.85 M NaOH solution?
Select one:

a. 0.85

b. >0.85

c. 1.7

d. <0.85

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Question 15
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Determine the pH of a solution prepared by dissolving 4.5 g of KOH in 800 ml water? 
Select one:

a. 13.1
b. 13.4

c. 12.4

d. 12.8

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Question 16
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Increase in frequency of collisions increases reaction rates.
Select one:

True

False

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Question 17
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 Flag question

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Increasing the temperature of an exothermic reaction will result in _____.
Select one:

a. less products and more reactants

b. less products and reactants

c. more products and reactants

d. more products and less reactants

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Question 18
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A decrease in pressure will shift the equilibrium favoring the side with less gaseous molecules.
Select one:

True

False
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Question 19
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For the reaction CH4 + O2 → CO2 + 2 H2O: if the reaction is first order with respect to CH4, doubling
the concentration of methane will lead to _____.
Select one:

a. doubling of rate

b. quadrupling of rate

c. rate is halved

d. rate is decreased by 4 times

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Question 20
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Question text
If the rate of a chemical reaction doubles with a 10⁰C increase in temperature, what will be the rate
of the reaction that was subjected to 30⁰C increase?
Select one:

a. increase twice

b. increase 6 times

c. increase 8 times

d. increase 4 times

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Question 21
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Consider the theoretical reaction that follows first order kinetics
         A + 2B→C + 2D
If the concentration of A is doubled, what will be the rate of formation of C?
Select one:

a. halved
b. doubled

c. quadrupled

d. remain as is

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Question 22
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Determine the pH of a solution containing 2.45x 1018hydroxide ions.
Select one:

a. 7.85

b. 8.23

c. 8.79

d. 8.61

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Question 23
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Strong acids form weak conjugate bases in solutions.
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True

False

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Question 24
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An increase in temperature slows down reaction rates because the energy is used to increase the
temperature.
Select one:

True

False
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Question 25
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The activation energy is the energy released by a reaction.
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True

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Question 26
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Adding an extra mole of one of the products in a reaction will result in ____
Select one:

a. formation of more products

b. formation of equal amounts of products and reactants

c. formation of more reactants

d. formation of 2 moles of products

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Question 27
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Arrhenius acids release electrons in solutions.
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True

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Question 28
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Consider the theoretical reaction
           A + 2B→C + 2D 
If the reaction is first order with respect to A and second with respect to B, what is the total order of
the reaction?
 
Select one:

a. second

b. first

c. third

d. fourth

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Question 29
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For a theoretical reaction A+B→C, the rate of formation of C is twice the rate of disappearance of A. 
Select one:

True

False

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Question 30
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Which of the following is true about a chemical system at equilibrium?
Select one:

a. the volume of products is equal to the volume of reactants 

b. the ion product constant is equal to the equilibrium constant

c. the numberof moles of products is equal to the number of moles of reactants

d. the concentrations of products is equal to the concentrations of reactants

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WEEK 14
 ASSIGNMENT 010
Question 1
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An open system can exchange matter but not energy with its surroundings.
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True

False

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Question 2
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 Flag question

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A reaction inside a coffee-cup calorimeter. 
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True

False

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Question 3
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An endothermic process involves increase in temperature of the surroundings.
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True

False

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Question 4
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A closed system does not exchange matter with its surroundings.
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Question 5
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What is the specific heat of an unknown substance if 1.50 g sample releases 17 calories as its
temperature changes from 35°C to 20°C?
Select one:

a. 0.76 cal/g⁰C
b. 0.89 cal/g⁰C

c. 0.67 cal/g⁰C

d. 0.53 cal/g⁰C

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Question 6
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What is the final temperature after 840 Joules is absorbed by 10.0g of water at 25.0⁰C? The specific
heat of water is 4.179 J/g⁰C.
Select one:

a. 38.9 ⁰C

b. 33.3 ⁰C

c. 45.1 ⁰C

d. 51.2 ⁰C

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Question 7
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Substances with high thermal energy will have higher kinetic energy.
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Question 8
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Heat may be transferred through convection.
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True

False
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Question 9
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Higher temperature of substances results in lower thermal energy due to higher kinetic energy.
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Question text
How much heat is released by a 100 g coffee solution at 96°C cools to 35°C? The specific heat of
water is 1 cal/g°C. Assume that coffee will have the same specific heat as that of water.
Select one:

a. 6100 cal

b. 5750 cal

c. 6210 cal

d. 5945 cal

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 SHORT QUIZ 010

Question 1
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The temperature of a sample of water increases from 27°C to 56°C as it absorbs 3500 calories of
heat. What is the mass of the sample? (Specific heat of water is 1.0 cal/g °C)
Select one:

a. 13.4 g

b. 11.6 g

c. 12.1 g

d. 10.8 g

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Question 2
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Energy may be transferred as work or heat.
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True

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Question 3
Correct

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In a coffee-cup calorimeter, 50.0 g of H2O and 50.0 mL of HCl are mixed. The initial temperature of
HCl was 43⁰C and that of water was 22⁰C. The final temperature was observed to 32⁰C. Calculate
the heat lost or gained during the reaction. (Specific heat of water is 1.0 cal/g °C)
Select one:

a. 2750 cal

b. 1950 cal

c. 2100 cal

d. 2340 cal

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Question 4
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A 155 g sample of an unknown substance was heated from 15°C to 37°C. In the process, the
substance absorbed 350 calories of energy. What is the specific heat of the substance?
Select one:
a. 0.197 cal/g⁰C

b. 0.096 cal/g⁰C

c. 0.244 cal/g⁰C

d. 0.102 cal/g⁰C

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Question 5
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The heat capacity of a substance is an extensive property.
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True

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 Flag question

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Work done by or on the system is a state function.
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Question 7
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What will be the final temperature when 100 g of granite brick at 100°C comes in contact with 75 g
another brick at 75°C? Specific heat capacity of granite is 0.1 cal/gºC.
Select one:

a. 67.2 ⁰C

b. 78.4 ⁰C

c. 89.3 ⁰C

d. 93.5 ⁰C
 Check

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Question 8
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Two pieces of a metal with specific heat of 0.105 J/g⁰C and both weighing 2.5 g were placed in
separate containers. One was heated to 85⁰C and the other was cooled to 4⁰C. What will be the
final temperature when they placed in contact with each other?
Select one:

a. 41.7 ⁰C

b. 59.2 ⁰C

c. 36.8 ⁰C

d. 44.5 ⁰C

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Question 9
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 Flag question

Question text
How much work is done on a system when a pressure of 1.7 atm is applied to cause the volume to
change from 7.2 L to 4.3 L?
Select one:

a. 6.12 L atm

b. 4.93 L atm

c. 3.57 L atm

d. 2.75 L atm

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Question 10
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Water contained in a thermos bottle is an example of an isolated system.
Select one:

True

False
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 LABORATORY EXAM 010

Question 1
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What is an exothermic reaction?
Select one:

a. When liver melts

b. When the thermometer gets broken by the reaction

c. When there is effervescence.

d. When heat is formed and released by the reaction

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Question 2
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What is an endothermic reaction?
Select one:

a. When liver melts

b. When there is effervescence

c. When the thermometer gets broken by the reaction

d. When heat is absorbed by the reaction

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Question 3
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What kind of reaction took place in glass A?
Select one:

a. The thermometer is broken

b. endothermic

c. nothing happened

d. exothermic

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Question 4
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Did the temperature in glass A decrease or increase?
Select one:

a. The thermometer is broken

b. decrease

c. increase

d. nothing happened

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Question 5
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__________ is heat transfer by waves.
Select one:

a. Addition

b. Division

c. Radiation

d. Subtraction

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Question 6
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Question text
Did the temperature in glass B decrease or increase?
Select one:

a. increase

b. decrease

c. The thermometer is broken

d. nothing happened

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Question 7
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What kind of reaction took place in glass B?
Select one:

a. exothermic

b. endothermic

c. nothing happened

d. The thermometer is broken

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Question 8
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_______ is the amount of heat transfer that will change the temperature of 1kg of a material by 1°C.
Select one:

a. specific enthalpy

b. specific gravity

c. specific temperature change

d. specific heat capacity

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Question 9
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Question text
Which one is a type of hear transfer?
Select one:

a. induction

b. reduction

c. convection

d. addition

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Question 10
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_____ is produced in an exothermic reaction, while it is absorbed in an endothermic reaction.
Select one:

a. Coldwave

b. Coldness

c. Heat

d. Electric current

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WEEK 15
 ASSIGNMENT 011
Question 1
Correct

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Question text
Determine the enthalpy change for the following reaction:
2Al(s) + Fe2O3(s) → Al2O3(s) + 2Fe(s)
Use the enthalpy values in the table provided with the module or use the information
here: https://www.chegg.com/homework-help/questions-and-answers/using-enthalpies-formation-
appendix-c-scroll-calculate-h-following-reaction-25-c-also-calc-q2442091  
Select one:

a. 213 kJ/mol

b. 198 kJ/mol

c. - 920.4 kJ/mol

d. - 850.2 kJ/mol

 Check

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Question 2
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Given the following reactions:
4C(s) + 5H2(g) + ½ O2(g) → C4H10O(l)            
ΔH = - 335 kJ/mol
4C(s) + 4H2(g) → C4H8(g) ΔH = -17 kJ/mol
H2(g) + ½ O2(g) → H2O(g) ΔH = -242 kJ/mol
 
Calculate the production of C4H8 from C4H10O.
Select one:

a. 78 kJ/mol

b. 81 kJ/mol

c. 47 kJ/mol

d. 53 kJ/mol

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Question 3
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Only exothermic thermochemical equations may be reversed.
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True

False

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Question 4
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Which of the following is an endothermic process?
Select one:

a. Freezing

b. Deposition
c. Sublimation

d. Condensation

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Question 5
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The melting process is an endothermic reaction because the heat gained is used for breaking
intermolecular forces between molecules.
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True

False

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Question 6
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 Flag question

Question text
Determine the enthalpy change for the following reaction:
C2H4(g) + O2(g) → 2CO2(g) + H2O(g)
 
Use the enthalpy values in the table provided with the module or use the information
here:  https://www.chegg.com/homework-help/questions-and-answers/using-enthalpies-formation-
appendix-c-scroll-calculate-h-following-reaction-25-c-also-calc-q2442091
Select one:

a. - 1367.56 kJ/mol

b. - 1081.27 kJ/mol

c. - 1534.8 kJ/mol

d. - 1274.9 kJ/mol

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Question 7
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The sign of enthalpy change for evaporation is positive.
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 True

False

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Question 8
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The theoretical reaction A + B → C will have a negative enthalpy change because two molecules
formed one molecule of product. 
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True

False

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 Flag question

Question text
Determine the enthalpy change when 3 moles of Ba is used up in the following reaction:
Ba(s) + Cl2(g) → BaCl2(s)  ΔH = - 858.6 kJ
Select one:

a. - 2675.8 kJ

b. - 2145 kJ

c. - 1395.1 kJ

d. - 1986 kJ

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Question text
Hess’s law of summation is a way of determining the enthalpy of a reaction from the sum of
enthalpies of each step of the reaction.
Select one:

True
 False

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 SHORT QUIZ 011

Question 1
Correct

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The magnitude of enthalpy change for a reaction. 
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True

False

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Question 2
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Calculate the enthalpy of combustion of diborane (B2H6) given the following:
2B(s) + 3H2(g) → B2H6(g) ΔH = 36 kJ/mol
 H2(g) + ½O2(g) → H2O(l) ΔH = −286 kJ/mol
 2B(s) + 1½O2(g) → B2O3(s) ΔH = −1274 kJ/mol
Select one:

a. - 1596 kJ/mol

b. - 1861 kJ/mol

c. - 1265 kJ/mol

d. - 1378 kJ/mol

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Question 3
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Question text
Determine the enthalpy change associated with formation of 20.2 g KCl based on the following
reaction:
K(s) + ½Cl2(g) → KCl(s) ΔH = –437 kJ/mol
Select one:

a. - 256.9 kJ/mol

b. - 291.4 kJ/mol

c. - 118.4 kJ/mol

d. - 362.2 kJ/mol

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Question 4
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Enthalpy is a state function and depends only on the final and initial states.
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True

False

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Question 5
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Determine the enthalpy change for the following reaction when 5.5 g of OF 2 is consumed?
OF2(g) + H2O(l) → O2(g) + 2HF(g)  ΔH = -277 kJ
Select one:

a. - 25.6 kJ

b. - 23.8 kJ

c. - 22.9 kJ

d. - 28.2 kJ

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Question text
Bond breaking is an endothermic process.
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True

False

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Question 7
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Use the following enthalpy changes:
 KClO3(s) + 3Mg(s) → KClO3(s) + 3MgO(s) ΔH = –1852 kJ/mol
 K(s) + ½Cl2(g) → KCl(s) ΔH = –437 kJ/mol
 Mg(s) + ½O2(g) → MgO(s) ΔH = –602 kJ/mol
to calculate the enthalpy change in kJ/mol, for the reaction:
 K(s) + ½Cl2(g) + 1½O2(g) → KClO3(s)
Select one:

a. - 512 kJ/mol

b. - 367 kJ/mol

c. - 452 kJ/mol

d. - 391 kJ/mol

 Check

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Question 8
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Calculate the enthalpy change when 4.53 x 1023 molecules of CaO is used up in the following
reaction:
CaO(s) + 2H+(aq) → Ca2+(aq) + H2O(l)  ΔH = - 193 kJ
Select one:

a. - 168 kJ

b. - 123 kJ

c. - 159 kJ

d. - 145 kJ

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Question 9
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 Flag question

Question text
The reverse of a reaction will have the same magnitude and sign as the original reaction.
Select one:

True

False

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Question 10
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Question text
Calculate the enthalpy change when 2 moles of NaOH is used up in the following reaction:
2NaOH + CO2 → Na2CO + H2O ΔH = - 109 kJ
Select one:

a. - 109 kJ

b. - 155 kJ

c. -176 kJ

d. - 208 kJ
 Check

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 LABORATORY EXAM 011

Question 1
Correct

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Question text
Which has more entropy: ice or liquid water at room temperature?
Select one:

a. Both "Ice and Water" are correct.

b. None of the choices

c. Ice

d. Water

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Question 2
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Entropy _______ when heat is added to a system.
Select one:

a. does not change

b. cannot tell what is happening

c. increases

d. decreases

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Question 3
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Sugars are non-electrolytes and form non-ionic solutions. Can you predict what happens to sugar
when dissolved in water?
Select one:
a. They undergo chemical change.

b. They remain sugars.

c. Nothing happens

d. They undergo sublimation

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Question 4
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Absolute zero (0K, -273°C, and -459°F) is the temperature at which molecular kinetic energy is zero.
At this temperature, molecules are ______.
Select one:

a. moving slowly.

b. not moving.

c. moving but not visibly so.

d. moving fast.

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Question 5
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On the other hand, cooling reactions are needed to preserve meat. What type of reactions are
usually utilized in these situations?
Select one:

a. Endothermic

b. Neutralization

c. Naturalization

d. Exothermic

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Question 6
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Question text
Entropy ________ when heat is removed.
Select one:

a. cannot tell what is happening

b. decreases

c. increases

d. does not change

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Question 7
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What happened to the temperature when candies were added to water?
Select one:

a. increase

b. decreased

c. The thermometer is broken

d. nothing happened

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Question 8
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What happened to the temperature when Alka-Seltzer were added to water?
Select one:

a. The thermometer is broken

b. increase

c. decrease

d. nothing happened

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Question 9
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Question text
Alka-Seltzer is used to neutralize acidic stomach. Can you predict the product of its reaction with
acid?
Select one:

a. bile

b. water

c. ammonia

d. vinegar

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Question 10
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In theory, when a compound produces gas, they can be used to power motors. When reactions
produce CO2 most likely, the reaction is:
Select one:

a. acidic

b. neutral

c. exothermic

d. endothermic
 Check

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WEEK 16
 ASSIGNMENT 012
Question 1
Correct

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Which of the following will have the lowest molar entropy?
Select one:

a. Na(s)

b. Cl2(g)

c. CCl4(l)

d. HCN(l)

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Question 2
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Calculate the entropy change for the following reaction. Use the table of enthalpy, entropy, and
Gibbs energy that was provided with the module.
C2H6O (g) + ½ O2(g) ⇌ 2CO(g) + 3H2(g)
Use the values in the table provided with the module or use the information
here:  https://www.chegg.com/homework-help/questions-and-answers/using-enthalpies-formation-
appendix-c-scroll-calculate-h-following-reaction-25-c-also-calc-q2442091
Select one:

a. 365.5 J/molK

b. 298.1 J/molK

c. 378.4 J/molK

d. 401.7 J/molK

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Question 3
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 Flag question

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Gibbs free energy is a state function.
Select one:

True

False

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Question 4
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Which of the following will have the highest entropy?
Select one:

a. H2O

b. CH3OH

c. CH3CH2CH2OH

d. CH3CH2CH2CH2OH
 Check

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Question 5
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Entropy of gases is always higher than liquids.
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True

False

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Question 6
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For the following reaction, what is the sign of ΔS?
H2(g) + I2(g) ⇌ 2 HI(g)
Select one:

a. negative

b. positive

c. equal to zero

d. cannot be determined

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Question 7
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Temperature does not affect the entropy of a system.
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True

False

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Question 8
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Hydrogen reacts with nitrogen to form ammonia (NH3) according to the reaction
3H2(g) + N2(g) ⇌ 2NH3(g)
Given: ΔH° is –92.38 kJ/mol; ΔS° = –198.2 J/mol · K. Determine ΔG° at 25°C.
Select one:

a. - 168.5 kJ/mol

b. - 148.1 kJ/mol

c. - 151.4 kJ/mol

d. - 138.6 kJ/mol

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Question 9
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Question text
The dissolution of NaCl in water results in increase in entropy.
Select one:

True

False

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Question 10
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Which of the following will have the highest entropy?
Select one:

a. 1 mole NaOH

b. 1 mole Zn

c. 1 mole SiCl4

d. 1 mole HF

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  SHORT QUIZ 012
Question 1
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Rust formation from the reaction of iron and oxygen will have a ____ entropy change.
Select one:

a. cannot be determined

b. zero

c. negative

d. positive

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Question 2
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 Flag question

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Nonspontaneous reactions may occur after an increase in heat.
Select one:

True

False

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Question 3
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Pure crystalline compounds will have entropy of zero at absolute zero temperature.
Select one:

True

False

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Question 4
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Calculate the Gibbs free energy change for the following reaction. Use the table of enthalpy, entropy,
and Gibbs energy that was provided with the module.
C2H6O(g) + 3O2(g) → 2CO2(g) + 3H2O(g)
Select one:

a. - 987 kJ/mol

b. - 685.8 kJ/mol

c. - 788.8 kJ/mol

d. - 1279 kJ/mol

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Question 5
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Question text
Calculate the entropy change for the following reaction. Use the table of enthalpy, entropy, and
Gibbs energy that was provided with the module.
Mg(s) + ½ O2(g) → MgO(s)
Select one:

a. - 601.2 kJ/mol

b. - 924.7 kJ/mol

c. - 568.9 kJ/mol

d. - 681.5 kJ/mol

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Question 6
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A positive entropy change for a system will always result in spontaneous reactions.
Select one:

True

False

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Question 7
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What is the sign of entropy change for the following reaction?
4HCN(l) + 5O2(g) → 2H2O(g) + 4CO2(g) + 2N2(g)
Select one:

a. Cannot be determined

b. Negative

c. Positive

d. Zero

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Question 8
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Given the following data, determine the molar free energy of combustion for propane gas, C 3H8.
 ΔG(C3H8, g) = –23.5 kJ/mol
 ΔG(CO2, g) = –394.4 kJ/mol
 ΔG(H2O, g) = –105.6 kJ/mol
Select one:

a. - 1582.1 kJ/mol

b. - 1183.2 kJ/mol

c. - 759.8 kJ/mol

d. - 422.4 kJ/mol

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Question 9
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Which of the following will lead to an increase in entropy?
Select one:

a. gas escaping from LPG container

b. baking of cake

c. water forming on the surface of icy glass

d. ice forming in the freezer

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Question 10
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Higher number of microstates lead to higher entropy of a system.
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True

False

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 LABORATORY EXAM 012

Question 1
Correct
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________ is temperature that flows from cold objects to hot objects.
Select one:

a. Kinetic energy

b. Total energy

c. Heat

d. Potential energy

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Question 2
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The more technical name for this type of calorimetry is:
Select one:

a. isomerism
b. isobaric

c. isolated

d. isometric

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Question 3
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Entropy tends to _______ over time.
Select one:

a. vanish

b. decrease

c. not change

d. increase

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Question 4
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A heat engine is device that converts electrical energy into _______ energy.
Select one:

a. Kinetic

b. Potential

c. Extraterrestrial

d. Thermal

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Question 5
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Temperature is the _____ molecular kinetic energy of a system.
Select one:
a. Thermo potential

b. Partial

c. Total

d. Sum

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Question 6
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A coffee cup calorimeter is a _________. 
Select one:

a. constant pressure calorimeter

b. constant voltage

c. constant craving

d. constant temperature calorimeter

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Question 7
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Since this measurement is at constant pressure (isobaric), the heat is equal to the change in:
Select one:

a. enigma

b. entropy

c. energetics

d. enthalpy

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Question 8
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Entropy is a measure of the amount of _____ in a system.
Select one:

a. border

b. newer energy

c. order

d. older energy

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Question 9
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A decrease in temperature means the reaction was "endothermic" and ΔH is:
Select one:

a. zero

b. no change

c. negative

d. positive

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Question 9
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Question text
A decrease in temperature means the reaction was "endothermic" and ΔH is:
Select one:

a. zero

b. no change

c. negative

d. positive

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Question text
An increase in temperature means the reaction was "exothermic" and ΔH is:
Select one:

a. zero

b. no change

c. positive

d. negative

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WEEK 17 - 18
 ASSIGNMENT 013
Question 1
Correct

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Question text
A galvanic cell is constructed from a spontaneous redox reaction.
Select one:

True

False

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Question 2
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Calculate the overall cell potential for the cell in Problem #7. Use the table of reduction potentials
provided with the module or use the value here:
https://chem.libretexts.org/Ancillary_Materials/ Reference/Reference_Tables/Electrochemistry_
Tables/P1%3A_Standard_Reduction_ Potentials_by_Element
Select one:

a. 0.93 V

b. 0.76 V

c. 0.59 V

d. 0.88 V

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Question 3
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Electrolytic cells require an input equal to or higher than its cell potential for the reaction to occur.
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True

False

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Question 4
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Salt bridges may be composed of solid substances.
Select one:
 True

False

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Question 5
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For the following cell:
Pb │ Pb(NO3)2 (1.0 M) || AgNO3 (1.0 M) │ Ag
Which is the reducing agent?
Select one:

a. Ag

b. AgNO3

c. Pb

d. Pb(NO3)2

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Question 6
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The flow of electrons in electrochemical cells is from the cathode to the anode. 
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True

False

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Question 7
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The oxidation state of C in C(graphite) is higher than in C(diamond).
Select one:

True

False
 Check

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Question 8
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The ║notation in electrochemical cells represent ___.
Select one:

a. A gaseous component

b. The salt bridge

c. A phase difference

d. An electrode

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Question 9
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 Flag question

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A substance that gains electrons in a reaction is an oxidizing agent.
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True

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Question 10
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The oxidation state of Cl in Cl2 is ___.
Select one:

a. -1

b. 0

c. 2

d. +1
 Check

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 SHORT QUIZ 013

Question 1
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Sacrificial coating is composed of metals that are readily oxidized compared to the material being
protected.
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True

False

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Question 2
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The oxidation state of N in NH4+ is ___.
Select one:

a. - 1

b. + 4

c. + 3

d. - 3

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Question 3
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Electrolysis is a spontaneous chemical reaction.
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 True

False

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Question 4
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Galvanic cells produce a positive overall cell potential.
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True

False

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Question 5
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 Flag question

Question text
Balance the following reaction in acidic medium:
HCOOH + MnO4- → CO2 + Mn2+
Select one:

a. HCOOH + 3H+ + MnO4-→ CO2 + Mn2+ + 2H2O

b. HCOOH + MnO4-→ CO2 + Mn2+ + 3OH-

c. 2HCOOH + 2MnO4-→ 2CO2 + 2Mn2+ + 2e-

d. 5HCOOH + 6H+ + 2MnO4-→ 5CO2 + 2Mn2+ + 8H2O

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Question 6
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Question text
Given the following reduction potential, which is the better reducing agent?
Ag+  + e- → Ag              E°red = 0.799 V
Sn2+ + 2e- → Sn            E°red = - 0.136 V
Select one:
a. Ag

b. Sn2+

c. Ag+

d. Sn

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Question 7
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In the following reaction, which is the reducing agent?
PbO2 + Pb + H2SO4 → PbSO4 + H2O
Select one:

a. H2SO4

b. Pb

c. PbO2

d. PbSO4

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Question 8
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For the following reaction, write the notation for the galvanic cell if all solutions have a concentration
of 0.1M.
Pd2+ + Cu(s) → Pd(s) + Cu2+  E°cell = + 0.609 V
Select one:

a. Cu(s) │Cu2+ (aq, 0. 1M) ║ Pd2+(aq,0. 1M)│Pd(s)

b. Pd2+(aq,0. 1M)│Pd(s)║ Cu(s) │Cu2+ (aq, 0. 1M)

c. Pd(s) │Pd2+ (aq, 0. 1M) ║ Cu2+(aq,0. 1M)│Cu(s)

d. Cu(s) │ Pd2+(aq,0. 1M)║ Cu2+ (aq, 0. 1M)│Pd(s)

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Question text
The oxidation number of Fe in Fe2O3 is ___.
Select one:

a. + 3

b. - 3

c. - 2

d. + 2

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Question 10
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Reduction reactions may occur independently of oxidation reactions.
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True

False

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  LABORATORY EXAM 013
Question 1
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Question text
Which one of the following items does not characterize an oxidizing agent?
Select one:

a. An oxidizing agent is an essential part of a battery.

b. An oxidizing agent causes another species to be oxidized

c. An oxidizing agent gains electron.

d. An oxidizing agent loses electrons.

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Question 2
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 Flag question

Question text
Cobalt is one of many metals that can be oxidized by nitric acid. Cobalt can be a good ____ in a
voltaic cell with nitric acid.
Select one:

a. either cathode or anode

b. anode

c. cannot be used in a voltaic cell

d. cathode

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Question 3
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Electrons flow from:
Select one:

a. from the middle to the sides

b. from the sides to the middle

c. anode to cathode

d. cathode to anode

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Question 4
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Negative end of the battery is called:
Select one:

a. cathode

b. anode

c. dogiode

d. erode

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Question 5
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 Flag question

Question text
Positive end of the battery is called:
Select one:

a. cathode

b. erode

c. dogiode

d. anode

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Question 6
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Which of the following is a metal and can be used as a conductor of electricity?
Select one:

a. sucrose

b. mercury
c. adamantium

d. aluminum

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Question 7
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Metal atoms are held together by electrical attractions between the nuclei and:
Select one:

a. dogoins

b. protons

c. cations

d. electrons

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Question 8
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Which statement about a voltaic cell is correct?
Select one:

a. Reduction occurs at the cathode.

b. Reduction involves losing weight.

c. Reduction occurs at the anode.

d. Reduction is not necessary in a galvanic cell.

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Question 9
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The best conductor of electricity is:
Select one:

a. electrolytes
b. mercury

c. electrolote

d. adamantium

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Question 10
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Which statement is true?
Select one:

a. Usually the cathode is a carbon strip.

b. Usually the cathode is a ceramic strip.

c. Usually the cathode is a metal strip.

d. Usually the cathode is a plastic strip.

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WEEK 19
 LONG QUIZ 004
Question 1
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Two identical rods weighing 350 g were placed at different temperatures of 100⁰C and 4⁰C.
Determine the final temperature when these two rods are placed in contact with each other. Specific
heat of copper is 0.092 cal/g°C.
Select one:

a. 56.6 ⁰C

b. 61.7 ⁰C

c. 48.5 ⁰C

d. 53.2 ⁰C

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Question 2
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Which of the following will have the lowest entropy?
Select one:

a. diamond

b. baking powder

c. sugar

d. cola

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Question 3
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Energy may be released as work or heat.
Select one:
 True

False

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Question 4
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Which of the following will lead to a decrease in entropy?
Select one:

a. baking of cake

b. melting of ice

c. tumbling of dominoes

d. dry ice left at room temperature

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Question 5
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Increase in the number of atoms in a molecule also increases molar entropy.
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True

False

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Question 6
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Balance the following in acidic medium:
Cr2O72¯ + Fe2+ → Cr3+ + Fe3+
Select one:

a. Cr2O72¯ +14OH- + 6Fe2+ → 2Cr3+ + Fe3+ + 6H2O

b. Cr2O72¯ + 6Fe2+ → 2Cr3+ + Fe3+ + 3H2O

c. Cr2O72¯ +14H+ + 3Fe2+ → 2Cr3+ + 3Fe3+ + 5H2O

d. Cr2O72¯ +14H+ + 6Fe2+ → 2Cr3+ + 6Fe3+ + 7H2O

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Question 7
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Gases have lower molar entropy compared to liquids.
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True

False

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Question 8
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Question text
The enthalpy change for the backward reaction is half in magnitude of the value for the forward
reaction.
Select one:

True

False

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Question 9
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Calculate the enthalpy change when 5.4 g of KCl is used up in the reaction:
KCl (s) + 3MgO(s) → KClO3(s) + 3Mg(s) ΔH = 1852 kJ/mol
Select one:

a. 134 kJ

b. 139 kJ

c. 148 kJ

d. 126 kJ

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Question 10
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Coffee-cup calorimeter is an example of an open system.
Select one:

True

False

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Question 11
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Determine the enthalpy change when 2.4 moles of BaCl2 decomposes according to the following
reaction:
BaCl2(s) → Ba(s) + Cl2(g)  ΔH =  858.6 kJ
Select one:
a. + 2060.6 kJ

b. + 3021.9 kJ

c. + 1050.1 kJ

d. + 1890.7 kJ

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Question 12
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The oxidation state of C in C2O42- is ____
Select one:

a. -2

b. -3

c. +2

d. +3

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Question 13
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Determine the enthalpy change when 2L of HF behaving as ideal gas is produced by the following
reaction:
OF2(g) + H2O(l) → O2(g) + 2HF(g)    ΔH = -277 kJ
Select one:

a. - 554 kJ

b. + 714 kJ

c. - 612 kJ

d. + 387 kJ

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Question 14
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Question text
Determine the enthalpy change when 2L of HF behaving as ideal gas is produced by the following
reaction:
OF2(g) + H2O(l) → O2(g) + 2HF(g)    ΔH = -277 kJ
Select one:

a. - 554 kJ

b. - 612 kJ

c. + 714 kJ

d. + 387 kJ

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Question 15
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Heat capacity is an intensive property.
Select one:

True

False

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Question 16
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Calculate the enthalpy change when 4.7 g of Ba is formed from the reaction:
BaCl2(s) → Ba(s) + Cl2(g)  ΔH =  858.6 kJ
Select one:

a. + 29.3 kJ

b. + 36.4 kJ

c. + 34.7 kJ

d. + 41.8 kJ

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Question 17
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Question text
Determine the mass of a water sample that absorbed 2750 calories of heat to change temperature
from 21⁰C to 41⁰C. (Specific heat of water is 1.0 cal/g °C)
Select one:

a. 127.3 g

b. 126.4 g

c. 137.5 g

d. 148.9 g

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Question 18
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In the reaction in Cr2O72¯ + Fe2+ → Cr3+ + Fe3+, what is the reducing agent?
Select one:

a. Fe3+

b. Cr3+

c. Fe2+

d. Cr2O72¯
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Question 19
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In the reaction in H2C2O4 + MnO4¯  → CO2 + Mn2+, what is the oxidizing agent?
Select one:

a. Mn2+

b. CO2

c. H2C2O4

d. MnO4-

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Question 20
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Calculate the heat released by a 200 ml milk solution when it cools down from 88⁰C to freezing point
of water. Assume that the solution will have same specific heat as that of water, 1 cal/g°C.
Select one:

a. - 18965 cal

b. - 18300 cal

c. - 17600 cal

d. - 16790 cal

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Question 21
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A pure crystalline compound will have lower entropy as temperature is decreasing towards its
freezing point.
Select one:

True
 False

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Question 22
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State functions are only affected by the final states of reactions.
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True

False

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Question 23
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Question text
Determine the heat taken up by a substance weighing 145 g and the observed temperature change
was from 15⁰C to 33⁰C. Assume that the specific heat of the substance is 0.15 cal/g⁰C.
Select one:

a. 478.5 cal

b. 391.5 cal

c. 402.1 cal

d. 428.4 cal

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Question 24
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Equilibrium reactions will have Gibbs free energy values equal to zero.
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True

False

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Question 25
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Enthalpy change for sublimation reaction is positive.
Select one:

True

False

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Question 26
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Determine the specific heat of a substance weighing 2.3 g and is able to absorb 28 calories of heat
as it changes temperature from 23⁰C to 37⁰C.
Select one:

a. 0.33 cal/g⁰C
b. 0.57 cal/g⁰C

c. 0.45 cal/g⁰C

d. 0.28 cal/g⁰C

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Question 27
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Determine the enthalpy change when 2.3 moles of B is deposited from the following reaction:
2B(s) + 3H2(g) → B2H6(g) ΔH = 36 kJ/mol
Select one:

a. + 112.4 kJ

b. - 82.8 kJ

c. - 94.7 kJ

d. + 105.7 kJ

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Question 28
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The oxidation state of O in S2O32- is ____
Select one:

a. -4

b. -2

c. +4

d. +2

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Question 29
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Balance the following reaction in acidic medium:
H2C2O4 + MnO4¯  → CO2 + Mn2+
Select one:

a. 4H2C2O4 + 3H+  + 2MnO4¯  → 8CO2 + 2Mn2+ + 4H2O

b. 5H2C2O4 + 6H+  + 2MnO4¯  → 10CO2 + 2Mn2+ + 8H2O

c. 5H2C2O4 + 6H+  + 2MnO4¯  → 5CO2 + 2Mn2+ + 8OH-

d. 5H2C2O4 + 4OH-  + 3MnO4¯  → 10CO2 + 3Mn2+ + 8H2O

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Question 30
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Which of the following will have positive sign of ΔS?
Select one:

a. freezing

b. condensation

c. precipitation

d. sublimation

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WEEK 20
 SECOND QUARTER EXAM