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Chapter 5 Homework 3

Matching
Column A Column B
f 1. Effusion a. The volume of a fixed mass of gas is
directly proportional to the Kelvin
temperature if the pressure is kept constant.
e 2. Boyle’s law b. At constant volume and temperature, the
total pressure exerted by a mixture of gases is
equal to the sum of the partial pressures of the
component gases.
b 3. Dalton’s law of partial pressures c. A gas tends to move to an area of lower
concentration until the concentration is
uniform throughout.
d 4. ideal gas law d. P × V = n × R × T
a 5. Charles’s law e. For a given mass of gas at constant
temperature, the volume of gas varies
inversely with the pressure.
c 6. diffusion f. the escape of a gas through a tiny hole in a
container of gas

Multiple Choice
1. “The rate of effusion of a gas is inversely proportional to the square root of its molar mass” is a
statement of ______________________ Law.
A) Charles's B) Graham's C) Dalton's D) Avogadro's E) Boyle's

2. A compound composed of carbon, hydrogen, and chlorine effuses through a pinhole 0.411 times
as fast as neon. Select the correct molecular formula for the compound.
A) CHCl3 B) CH2Cl2 C) C2H2Cl2 D) C2H3Cl E) CCl4

3. At what temperature in kelvin is the root mean square speed of helium atoms (atomic weight =
4.00) equal to that of oxygen molecules (molecular weight = 32.00) at 300. K?
A) 37.5 K B) 75 K C) 106 K D) 292 K E) 2400. K

4. Select the gas with the highest average kinetic energy per mole at 298 K.
A) O2 B) CO2 C) H2O D) H2 E) All have the same average kinetic energy.

5. The ideal gas law tends to become inaccurate when

A. the pressure is lowered and molecular interactions become significant.
B. the pressure is raised and the temperature is lowered.
C. the temperature is raised above the temperature of STP.
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D. large gas samples are involved.

E. the volume expands beyond the standard molar volume.

6. A 2 L sample of N2(g) and a 1 L sample of Ar(g), each originally at 1 atm and 0°C, are
combined in a 1 L tank. If the temperature is held constant, what is the total pressure of the gases
in the tank?
(A) 1 atm (B) 2 atm (C) 3 atm (D) 4 atm (E) 5atm

7. Under which of the following conditions of temperature and pressure will H 2 gas be expected to
behave most like an ideal gas?
(A)  50 K and 0.10 atm (B)  50 K and 5.0 atm
(C) 500 K and 0.10 atm (D) 500 K and 50 atm

8. The gas particles in vessel 3 at 27°C are represented in the diagram above. The lengthsof the
arrows represent the speeds of the particles. Which of the following diagrams best represents the
particles when vessel 3 is heated to 127°C? A

9.

(1).In which flask do the molecules have the greatest average speed? B
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(2).Which flask contains the smallest number of moles of gas? B

(3).Which flask contains the sample with the greatest density? C