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DEPARTMENT OF GOVERNMENT EXAMINATIONS

N Neet t
HIGHER SECONDARY FIRST YEAR EXAMINATION
N Neet t MAY- 2022

lalai .
i . KEY ANSWER FOR l
CHEMISTRYal i
a .
i .– ENGLISH MEDIUM l a
l i
a
assaa aaddaassa
Maximum
a Marks - 70
a ad da as a
s a
w w. P
. P ww.P P
. 15 x 1 = 15
wwww
Answer all the Questions Part -I
w
www
Q.NO Option A Type Q.NO Option B Type

et
1
N Nett
e
c) C8H18
NN
a) t 1p + 2n
ee t 1

la ai2.i. l a ai .i. c) l a i
a
aa l b) - 2ºC
aa l2
aa l
(1) – (iv), (2) – (iii), (3) – (i), (4) – (ii)

ass 3 a) 3 3
adda
–C(CH ) > -CH(CH ) >-
a ass
CH 3 2 2
ad
a a
d s
a s
– CH > -CH
PP P P

.N
w
3

w . . 3 3 b) NO
ww . .
4 b) www
NO w 4 c) Mass w w
ww/ volume
d) Both assertion and reason
are true but reason is not the
5

NNeett
d) correct explanation of
lai
assertion
N Nee t t 5
CH c) 8 18

l a
l i
a .i. c) l a
l ai .
i . l a
l i
a
assaa ssaa ssaa
6 Mass / volume 6 a) Lithium

a ad d aa
for a system at equilibrium Q
aa d aa
dCH –
ww .
is always less P
. P
than the –C(CH
-CHw
) >
w . P
.
-CH(CHP ) >- 3 3 3 2 2
7 b)
www w
equilibrium constant
7 a)
CH > w
www 3 3
sa
8 c) (1) – (iv), (2) – (iii), (3) – (i), (4) – (ii) 8 c) Stark effect

N Neett NNee t t for a system at equilibrium Q is

l a
l i
a . . a)
9i l a
la i .i. b) always less than the equilibrium lalai
assaa aa aa
Lithium 9
ss s s
da

ad
adaa constant
a ad a
d a
10 b) MgCl 2
w
w . P
. P 10 d) tautomers
ww . P
. P
11 a) ww
1p
w w
+ 2n 11 b) www
MaCl
w 2

12 a) O22– 12 b) - 2oC
Pa

N Neett N Ne
a)ett O
.i. .i.
13 c) Stark effect 13 2-

l a
l i
a l a
lai 2

l a
l i
a
assaa 14 d) d da as
near the hydrogen chloride
aa
aa 14 d) Both
s
a a dd
true but reason is not the aas
assertion and reason are a
s a
bottle
w w .P. P correct
w w . P
.
explanationPof assertion

15 d) www w
tautomers 15 d) w
near w w
thewhydrogen chloride
bottle

N Neett N N e ett
SHANMUGAM S, ST. JOHN’S MAT.HR.SEC.SCHOOL PORUR, CHENNAI – 600116

lalai.i. l a
l ai .i. l a
l i
a
assaa dd aas saa
daassaa
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Part – II

NN ee tt
Answer any SIX Questions and Questions No.24 is Compulsory.
NN e ett 6 X 2 =12

lalai
16.i. Gram equivalent mass is defined as the mass
l a
l i
a .ofi.an element (compound l a
l i
a
assaa or35.5ion)g chlorine. a as agahydrogen or 8 g oxygen or
s
that combines or displaces 1.008
a add aaddaa aa
2ss

w w . P. P
Correct definition ………………………………………………….
ww .P.P
17 w ww
n = 2 represents w
L shell, 2n …………………………………………...
2
ww ww 1
Maximum number of electron in L shell is 2 x 2 = 8 electrons ……..
2 2
1

et
18
N N ett
Types of Covalent (Molecular) hydrides
e N Neett
lalai.i. i) electron precise (CH , C H , SiH , GeH ),la
l i
a .
i . 1
l a
l i
a
assaa ii) electron deficient (B H ) aaddaassaa aa
2
4 2 6 4 4
½
½ d a
d s
a s
2

P
6

P P Paa

.N
w w .
iii) electron-rich hydrides .
(NH , H O). 3 2
w w. .
19 The spontaneity www w of any process depends on three differentw w
ww ½
factors.
i) If the enthalpy change of a process is negative, then the process is
exothermic (ΔH is negative)

NNii)e
tthet entropy change of a process is positive, (ΔS
Ife lai NN e
ise
tt ½

l a
l i
a .i. iii) The Gibbs free energy which is the combination
l a
l i
a .i. of the above two
positive)
2
l a
l i
a
assaa (ΔH -TΔS) should be negativeaafordda assaa
a reaction to occur spontaneously
1
aaddaassaa
ΔH -TΔS < 0 w w . PP
. (OR) w
w . P
. P
www w wwww
sa
i) ΔH < 0 ii) ΔS > 0 iii) ΔG < 0
20 Sign convention of heat

N e t t e t t
i) If heat flows into the system from the surrounding, energy of a system
e
increases. Hence it is taken to be positive (+q).i.N
N N e
1

l a
l i
a .
i . l a
la i . l a
l i
a
assaa ii)system asurrounding,
a aa
2
If heat flows out of the system into s s ss
da

decreases. Hence, ita d

isa daa the energy of the
1
aaddaa
w +w
. PP
. (Correct balanced equation )…………………..
taken to be negative (–q).
w
w . P
. P
21 4NO + 6H O ⇌ 4NH
2
wwww 3 5O 2
w
www 2 2
(unbalanced equation ………………………………………….. 1M)

Isotonic solutions
Pa

22
N Ne
Two etsolutions
t having same osmotic pressure at aNgiven Neettemperature
t are
l a
l i
a .
i . l a
lai.i. 2 2
l a
l i
a
assaa (Correct definition) aaddaassaa aa
called isotonic solutions.

d a
d s
a s
. P
. P . P
. Paa
w w
23 Conversion of ethyl chloride
w
into ethane:
w w w
www www 2 2

N Neett
Explanation only ……………………………………………………… 1 M
N N e ett
lalai.i. l a
l ai .i. l a
l i
a
assaa dd aas saa
daassaa
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24 Compulsory questions:

NN eett N Neet t 1

lalai .i. i) l a
l i
a .
i . l a
l i
a
assaa aa aa
2
ddaass 1addaass
. P
. Paa .P.P a
ii)
wwww wwww
ww ww
SHANMUGAM S, ST. JOHN’S MAT.HR.SEC.SCHOOL PORUR, CHENNAI – 600116

Part – III

et
e e tt
Answer any SIX Questions and Questions No.33 is Compulsory.
N N N Ne ett 6 X 3 =18

lalai.i. ii) H SO la l i
a .i. l a
l i
a
assaa xx += 24 (– 2) = 0 s saa ssaa
25 i) CO 2 2 4 1½

a ad d a2a(+ 1) + x + 4 (– 2) = 0
ad
a aa
d3
PP P P

.N
w w. . 2 + x – 8 = 0 x = + 6
w
w . . 1½

ww
26 i) It is defined w
as w
the amount of energy released (required in thew w
wwnoble 2
case
gases) when an electron is added to the valence shell of an isolated neutral
gaseous atom in its ground state to form its anion. 3

NNii)e
tt
Ite lai N Neett 1

l a
l i
a .i. John Dalton stated that
is expressed in kJ mol -1

l a
l a .i.
A + e- → A + EA ……………………
i
-

l a
l i
a
assaa “ the total pressure of a mixture ssaa ssaa
27

aad daa
of non-reacting gases is the sum of
aaddaa
w . P
P
the.gases present in the mixture”.
w w w. P
. P 3

www w
partial pressures of
wwww 3
sa
Correct statement……………………………..
28
2

N Ne ett N Ne ett
l a
l i
a .
i . l al
The molar mass of the solute (M ) can be calculated
ai .
i . using the known values
3
l a
l i
a
assaa of w , w , M and the measured alowering
a of vapour pressure. aa
B

s s 1
ss
da

A B A
a ad da a
relative
aaddaa
29 Electronic configuration.of
w w P
. Phydrogen atom is 1s 1

ww . PP
. ½½

w w w w
Valence shell electronic configuration of fluorine atom 2
: 2s 2
2px
w,2
ww
2pyw,12pz
3
When half filled 1s orbital of hydrogen linearly overlaps with a half filled 2pz
2
orbital of fluorine, a σ-covalent bond is formed between hydrogen and
Pa

N Neett
fluorine. (OR)
N N eett
l a
l i
a .i. l a
lai.i. l a
l i
a
assaa aaddaasaa
s
ad
a a
d s
a aa
s
Optical Isomerismw w.P. P w
w. P
. P
30
Compoundsw
w
wwsame physical and chemical property but differ
having wwonlyw
w
3
in the rotation of plane of the polarized light are known as optical isomers and

NN ee tt
the phenomenon is known as optical isomerism
N N e ett
lalai.i. Correct statement……………………………..lalai.i. l a
l i
a
assaa dd aas saa
daassaa
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31 S.NO Nucleophiles Electrophiles

N N
1
eet t N Ne et t
Nucleophiles are reagents that Electrophiles are reagents that are 1

lalai .
i . has high affinity for electro
positive centre. ora
l l i
a . .
attracted towards
i
electron
negative charge
rich centre.
l a
l i
a
assaa 2 AllactLewis bases
as nucleophiles. d
aa d a s
a aaAll Lewis acids
s act as electrophiles
a1d
a a
d3assaa
w w . P
. P Ex: Neutral electrophiles : w . . P
P
3
NHw ,w
w
Ex: Neutral
w Nucleophiles:
H O, R-OH, R-O-R’
3 2 CO , AlCl , BF , FeCl
2 3 3
www
ww:CCl 3 2

-Ve charged nucleophiles +Ve charged Electrophiles:

X- (Cl-, Br -, I - ) H+, X +, O+ , N+ 1

et
N Ne ett RCOO-, RO-, OH- , CN –
N e ett
( any one example )
N
lalai.i. (any one example)
l a
l ai .i. l a
l i
a
assaa 32 Alkenes react with Baeyer’s areagent
ad da as
tosaa
form vicinal diols. The purple solution
ad
a a
d s
a aa
s
PP P P

.N
7+
.
ww.
(Mn ) becomes dark green (Mn ), and 6+
then produces a dark brown
w w . .
precipitate (Mn w
)w w
ww 4+ (OR)
www
3

N Neett lai N Neett

l a
l i
a .i. l a
l i
a .i. l a
l i
a
assaa 33 Compulsory questions: aaddaassaa aaddaassaa
w w . P
. P w
w . PP
. 1
w
www w
www
sa
3
1

N Neett N Neett
l a
l i
a .i. l a
l ai .
i . 1
l a
l i
a
assaa ssaa saa
s
da

ad
adaa aaddaa
w w. P
. P Part – IV
w
w . P
. P
wwww
Answer all the Questions w
www 5 x 5 = 25
34 a) i) n = 4 l = 0, 1, 2, 3 four sub-shells ⇒ s, p, d, f ½
Pa

N Neett l=0 ml = 0 ;
N Nee t t4s orbital.
one

l a
l i
a .i. l a
lai.i. ½
l a
l i
a
assaa l=1 m = –1, 0, +1 ; ss
l

aa d da a aa three 4p orbitals.
a
½
d
a a
d s
a
3
aa
s
l=2 w
w .=P
. P
–2, –1, 0, +1, +2 ; five 4d orbitals. ww.P
. P½
½

wwww wwww
m l

l=3 ml = -3, –2, –1, 0, +1, +2 , +3; seven 4f orbitals

N Neett e ett
Over all (16)Sixteen orbital
N N
½

lalai.i. l a
l ai .i. l a
l i
a
assaa dd aas saa
daassaa
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N N ett N N ett
ii) Electronic configuration of N atom is 1s2 2s2 2p3
e e
lalai .i. l a
l i
a .i. l a
l i
a
assaa s aa s aa
2

ddaa s 1
d a
d a s
. P
. Paa .P Pa
. 1a
www w w
w
www (OR) www
b) Pauling Method :

et
NNett
e N Nee t
d = rC+ + rA- ------------------ (1) t 1

lalai.i. r , r l a
l i
a
are the radius of the cation and anion .
i .
respectively.
l a
l i
a
assaa aa aa
C+ A-

d da ass d a
d s
a s
PP aa P Paa1

.N
w w . . ww. .
www w w
www 1

N Neett lai N Neett

Where Zeff is the effective nuclear charge and Zeff = Z - S
1

l a
l i
a .i. l a
l i
a .i.
Dividing the equation 2 by 3
l a
l i
a
assaa aaddaasaa
s
aad a
d s
5s
a aa
w w. P
. P w w. PP
. 1
w w
www1) and (4) the values of r and r can be calculated
www
sa
On solving equation( C+ A-

NN eett
a) i) Reason for the anomalous behaviour of beryllium
N
Neett
l a
l i
a .i.1) Its small size and high polarising power lalai.i.
35
1
l a
l i
a
assaa 2)members s saa enthalpy as compared to other aassaa
da

a a dda a
Relatively high electronegativity and ionisation
aad d
w w . PP
. in its valence shell w w . P
. P 1

w w w
3) Absence of vacantw d-orbitals
ww w w 1
ii) Comparison of Properties of Beryllium with other elements of the group
Beryllium Other elements of the family
Pa

NN e et tcovalent compounds
Forms
NN e e
form ionic tcompounds
t
l a
l i
a .i. High melting and boiling point l a
la i.i.melting and boiling point 5
l a
l i
a
assaa Does not react with water even aa React with water aa
Low

dda as s d a s
a s
aa aa2d
at elevated
temperature
w w .P. P ww . P
. P
w
wwwdirectly with hydrogen Combine directly with
Does not combine w w
wwhydrogen
Does not combine directly with halogens. Combine directly with halogens

N Neett
Halides are covalent

N N ett
Halides are electrovalent.
e
lalai.i. (Correct two points)
l a
l ai .i. l a
l i
a
assaa dd aas saa
daassaa
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(OR)
b) Characteristics of internal energy (U):

NN eetinternal
t energy of a system is an extensiveNNproperty.
e et t It depends on 1
lalai .i.the amount of the substances present in thelasystem.
i) The
l i
a .i. If the amount is doubled, l a
l i
a
assaa the internal energy is also doubled.a d
a daa s saa
aaddaas aa
s
. PP .
ii) The internal energy of.a system is a state function. It depends only upon
w w ww P P
. 1
w
www(T, P, V, n) of the system. The change in internal
the state variables
w w
wwenergy 5
does not depend on the path by which the final state is reached.

et
N N e et t N Ne et
iii) The change in internal energy of a system is expressed as ΔU= Uf – Ui
t ½

lalai.i. l a
l ai .
i .
iv) In a cyclic process, there is no internal energy change. ΔU(cyclic) = 0
½
l a
l i
a
assaa v)vi) ΔU= U − U = − ve (U < U )
f i f

ΔU=Uf − Ui = + ve (U > Ua )adda

i
assaa
ad
a
1
1d
aassaa
PP P P

.N
w w .f
. mass of solute from elevation of boiling
i

w w. .
ww
36 a) Determination
If the solution
ww
is prepared by dissolving w g of solute in w g of w
of molar
B A ww w point
solvent,
then the molality is,

N Neett lai N Neett

l a
l i
a .i. l a
l i
a .
i . 1
l a
l i
a
assaa aaddaa ssaa
a1d
a daassaa
w
w . P
. P w
w . P
. P
w
wwmass of the solute Therefore,
Where, M =w
w
www
sa
molar
B

N Neett N Neet t 1

l a
l i
a .i. l a
lai .
i . l a
l i
a
assaa ssaa saa
s
da

ad
adaa a1d
a daa
ww. P
. P w
w . P
. P
w
www w
www
Pa

N N e et t N N e et t 1

l a
l i
a .
i . (OR)
l a
lai.i. l a
l i
a
assaa The distance between the nuclei s saa saa
s
b) i) Bond length

aadd
ofa a
the two covalently bonded atoms is called
aad
1d
aa
w
w .P. P ww . P
. P
bond length.
www
ii) Bond angle
w wwww
Covalent bonds are directional in nature and are oriented in specific directions

N Neet t N N e et t
in space. This directional nature creates a fixed angle between two covalent
2

lalai.i.bonds in a molecule and this angle is termed as .

l a
l ai i .
bond angle.
l a
l i
a
assaa d da a s saa
d aassaa
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N N e t t enthalpy is defined as the minimum amount

iii) Bond enthalpy
e N Nee tenergy
t required to
lalai .i.The bond
l a
l ai .i. of
l a
l i
a
assaa break one mole of a particular bond ins
a ad a
. d
a saa in their gaseous state. The 2 aassaa
molecules
aadd
w P
. P
unit of bond enthalpy is kJ mol
.
-1

character in a covalent bond can be related to thew

w w . P
. P
w
wwwto the bonded atoms. In a typical polar molecule,
37 a) The extent of ionic
negativity difference wwww electro
A B , δ—2 δ+

the electronegativity difference (χA - χB) can be used to predict the percentage of

et
N N e e tt
ionic character as follows.
N Neett
lalai.i.If the electronegativity difference (χ - χ
l al
),
ai
is .
i . 5
l a
l i
a
assaa i)ii)equal aaionic character aa
A B

to 1.7, then the bond A-B hass s s s

1

if it is greater than 1.7, P a ad da a50%

aaddaa
P P P

.N
w w . . the bond A-B has less than 50% ionicw
then the bond A-B has more than 50% ionic
. .
character,
w w
1

www w
iii) if it is lesser than 1.7, then
w w w
character.
1
(OR)
b) i) 2-bromo-3-methylbutane 1

N Ne e t t
ii) methoxymethane
lai N Neet t 1

l a
l i
a .
i . iii) 2-hydroxybutanal
l a
l i
a .
i . 1
l a
l i
a
assaa iv) buta-1,3-diene
v) 4-chloropent-2-yne Pa
d
a a
d s
a aa
s
a
1
addaas
5s
aa
ww . . P w
w . P
. P 1

w w ww w
w w
w
sa
38 a) i) nitrobenzene
Nitration:

N ee
When
N tbenzene
t is heated at 330K with a nitrating mixture N Ne et(Con.
t HNO + Con.
l a
l i
a .i.H SO ), nitro benzene is formed by replacinglalone
ai .ihydrogen
.
3

l a
l i
a
assaa ion(electrophile) ConcentratedaaHdd aasissaadded
a to produce nitronium ion NO aa
2 4 atom by nitronium 2
ss
da

SO 2 4
aadd
+
2aa
ww . P
. P w w . P
. P
www w w
www
Pa

NN e ett N Nee tt
l a
l i
a .i.ii) benzene sulphonic acid l a
lai .i. l a
l i
a
assaa Sulphonation: Benzene reacts a ad a as saa
with fuming sulphuric acid (Con H SO + SO ) d
d aa a
d s
a aa
s
w w .P P
. acid. The electrophile SO is a molecule.
2

ww
4

. P
. P 2
3

ww w
and gives benzene wsulphonic 3
w w w wAlthough
5
it does not have positive charge, it is a strong electrophile. This is because the
octet of electron around the sulphur atom is not reached. The reaction is

N e et t and desulphonation occurs readily in aqueous

reversible
N N N e etmedium.
t
lalai.i. l a
l ai .i. l a
l i
a
assaa dd aas saa
daassaa
PP
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N Neett N Ne ett
lalai .i. l a
l i
a .i. l a
l i
a
assaa aadd aassaa
aaddaassaa
w
w . P
. P w w . P
.P
w
iii) BHC : Benzene www
2
w
wwwreacts with three molecules of Cl in the presence of sun
light or UV light to yield Benzene Hexachloride (BHC) C6H6Cl6. This is known as

et
N N tt
e N N ett
gammaxane or Lindane which is a powerful insecticide.
e e
lalai.i. l a
l i
a .i. l a
l i
a
assaa aa aa
(or)

ddaass 1
ddaass
PPaa P Paa

.N
w
w . . ww. .
w
www w
www

N Neett lai NNe tt

e
l a
l i
a .i. (OR) ai.i.
l l a l a
l i
a
assaa aa daas saa
aa1daassaa
b) 1. Ethene reacts with HCl to give Chloroethane CH3 - CH2Cl as (B) by addition
d d
.P P .P P
reaction.

ww .
= CH + HCl → CH - CH Cl ww .
wwww wwww
CH 2 2 3 2
sa
2. Chloroethane reacts with ammonia to give Ethylamine CH3 -CH2NH2 as (C). It is a
primary amine and Carbylamine test is the characteristic test for 1° amine.

N Neett N N e et t
CH3 - CH2Cl + NH3 → CH3 -CH2NH2 + HCl 1

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