Lesson 2

Chapter 18: Temperature, heat, and the first law of thermodynamics

18.4: Heats of transformation

Specific Heat: Heat required to change the temperature of the material or sample.
Q = cm ∆T

Latent Heat: Heat required to change the state of the material.

Latent Heat of Fusion Latent Heat of Vaporization

Solid --------------------Liquid Liquid --------------------Vapor
Liquid-------------------Solid Vapor-------------------Liquid

Q = mL
 Lesson 2
Chapter 18: Temperature, heat, and the first law of thermodynamics

18.4: Heats of transformation

When energy is absorbed as heat by a solid or liquid, the temperature of the sample does not
necessarily rise. Instead, the sample may change from one phase (or state) to another.
The amount of energy required per unit mass to change the state (at constant temperature) of a
particular material is its heat of transformation L.
Thus, when a sample of mass m completely undergoes a phase change, the total energy transferred is
Q = mL
Heat of Vaporization
The heat of vaporization LV is the amount of energy per unit mass that must be added to vaporize a
liquid or that must be removed to condense a gas. For water at its normal boiling or condensation
temperature, Q = m Lv [LV = 539 cal/g = 40.7 kJ/mol = 2256 kJ/kg]
Heat of Fusion
The heat of fusion Lf is the amount of energy per unit mass that must be added to melt a solid or that
must be removed to freeze a liquid. For water at its normal freezing or melting temperature,
Q = m Lf [Lf = 79.5 cal/g = 6.01 kJ/mol = 333 kJ/kg]
18.5: A closer look at heat and work

 Let us take as our system a gas confined to a cylinder with a movable piston, as in Fig. The
upward force on the piston due to the pressure of the confined gas is equal to the weight of lead
shot loaded onto the top of the piston.
 The walls of the cylinder are made of insulating material that does not allow any transfer of energy
as heat. The bottom of the cylinder rests on a reservoir for thermal energy, a thermal
reservoir(perhaps a hot plate) whose temperature T you can control by turning a knob.
 The system (the gas) starts from an initial state i, described by a pressure pi , a volume Vi and a
temperature Ti . You want to change the system to a final state f, described by a pressure pf ,a
volume Vf ,and a temperature Tf .The procedure by which you change the system from its initial
state to its final state is called a thermodynamic process.
 During such a process, energy may be transferred into the system from the thermal reservoir
(positive heat) or vice versa (negative heat).
 Also, work can be done by the system to raise the loaded piston (positive work) or lower it
(negative work).
 Suppose that we remove a few lead shot from the piston of Fig , allowing the
gas to push the piston and remaining shot upward through a differential
displacement d𝑠 with an upward force 𝐹.
 Since the displacement is tiny, we can assume that 𝐹 is constant during the
displacement. Then 𝐹 has a magnitude that is equal to pA, where p is the
pressure of the gas and A is the face area of the piston. [p = F/A]

 The differential work dW done by the gas during the displacement is

Work is done by the system (gas) on the environment (piston)
dW = 𝐹.𝑑 𝑠 = Fdscos00= Fds(+1)=(pA)ds = p(Ads)= + pdV
[p=F/A or F=pA]
Work is done on the system (gas) by the environment (piston)
dW = 𝐹.𝑑 𝑠 = Fdscos1800= Fds(-1)= -(pA)ds = -p(Ads)= - pdV
in which dV is the differential change in the volume of the gas due to the
movement of the piston. When you have removed enough shot to allow the
gas to change its volume from Vi to Vf , the total work done by the gas is
V
W = 𝑑𝑊 = V f 𝑝 𝑑𝑉 [any gas]
i
Problem 27 : Calculate the minimum amount of energy, in joules, required to
completely melt 130 g of silver initially at 15.0° C.

Solution: Here, c = 236 J/kg-K m = 130 g = 0.130 kg

The melting point of silver is 1235 K
Ti =15.0°C = (273+15)K = 288 K Tf = 1235 K
∆𝑇 = (1235 − 288)𝐾 = 947 K
Now, specific heat
Q1 = cm∆𝑻 = 236(0.130)947 = 2.91×104 J

Again for the state change [ Solid to Liquid]

Latent heat of fusion,
Q2 = mLf = (0.130) (105 × 103) = 1.36×104 J [Lf = 105×103 J/kg]

The total heat required, Q = Q1 +Q2 = (2.91×104 + 1.36×104 ) J = 4.27×104 J

Problem 28 : How much water remains unfrozen after 50.2 kJ is transferred as heat from 260 g
of liquid water initially at its freezing point?

Solution:
Q = 50.2 kJ = 50.2 × 103 J
Lf = 333 kJ/kg = 333 × 103 J/kg

Mass of frozen water (ice), m =?

Q = mLf
𝑄 50.2×103
m= = = 0.151 kg
Lf 333×103

Liquid water, m1 = 260 g = 0.260 kg

The amount of water that remains unfrozen (liquid water) = m1 – m

= (0.260 – 0.151) kg = 0.109 kg = 109 g