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Chemistry
Chapter 1. – Periodic Table, Periodic Properties and variations of
Properties
2. What are horizontal rows and vertical columns in a periodic table known as?
Ans: In the periodic table, the horizontal rows are known as periods, while the vertical
columns are known as groups.
10. Name the (i) metals, (ii) metalloids and (iii) non-metals in the first twenty
elements.
Ans: Metals: Lithium, Beryllium, Sodium, Magnesium, Aluminium, Potassium,
Calcium
Metalloids: Boron, Silicon
Non-metals: Hydrogen, Helium, Carbon, Nitrogen, Oxygen, Fluorine, Neon,
Phosphorous, Sulphur, Chlorine, Argon
11. Fluorine, Chlorine and Bromine are put in one group on the basis of their
similar properties.
12. What is the main characteristic of the last element in each period of the
Periodic Table? What is the general name of such elements?
Ans: The last element in each period of the periodic table has the property of being
inert or chemically unreactive. These elements are referred to as "Noble gases" in
general.
13. According to atomic structure, what determines which element will be the
first and which will be the last in a period?
Ans: The quantity of valence electrons defines the first and final element in a period,
according to atomic structure.
18. Name an
A. An alkali metal in period 3 and halogen in period 2
Ans: Na and F
B. The noble gas with 3 shells
Ans: Argon
C. The non-metals present in period 2 and metals in period 3.
Ans: C, N, O and F are non-metals present in period 2 while Na, Mg and Al are metals
in period 3.
D. The element of period 3 with valency 4.
Ans: Silicon
E. The element in period 3 which does not form an oxide.
Ans: Argon
F. The element of lower nuclear charge out of Be and Mg.
Ans: Mg
20. Match the atomic number 19, 15, 8, 4 and 2 with each of the following:
(i) A metal of valency one
Ans: A metal of valency one = 19
(ii) A solid non-metal of period 3
Ans: A solid non-metal of period 3 = 15
(iii) A rare gas
Ans: A rare gas = 2
(iv) A gaseous element with valency 2
Ans: A gaseous element with valency 2 = 8
(v) An element of group 2
Ans: An element of group 2 = 4
Intext Questions
3. Arrange the elements of second and third period in increasing order of their
atomic size. (excluding noble gases).
Ans: Second Period: Fluorine < Oxygen < Nitrogen < Carbon < Boron < Beryllium <
Lithium.
Third Period: Chlorine < Sulphur < Phosphorus < Silicon < Aluminum < Magnesium
< Sodium.
8. A metal M forms an oxide having the formula M 2O3. It belongs to the third
period. Write the atomic number and valency of the metal.
Ans: The metal is from the third period, and it has three shells.
The compound's chemical formula indicates that the metal's valency is +3. It belongs
to the third group since the valence electrons are three.
As a result, the electrical arrangement of the element must be 2, 8, 3.
That indicates there are 13 electrons in all.
Atomic number = 13 Valency = 3 Valency = 3 Valency = 3 Valency = 3 Valency = 3
10. The given table shows elements with same number of electrons in its valence
shell.
Elements A B C
State:
(i) Whether these elements belong to same group or period.
Ans: Yes, these elements are from the same family, but they aren't from the same time
period.
(ii) Arrange them in order of increasing metallic character.
Ans: We know that as we move down the group, m.p. diminishes. As a result of the
aforementioned table, the items can be sorted by period as follows:
Elements B C A
As one travels along the group, the metallic character becomes more prominent. As a
result, the following is the order of the elements with increasing metallic character:
13. The metals of group 2 from top to bottom are Be, Mg, Ca, Sr and Ba.
(i) Which one of these elements will form ions most readily and why?
Ans: The outermost valence electron, which experiences the least force of attraction
by a positively charged nucleus, can quickly be given up to form cations, allowing
barium to form ions.
(ii) State the common feature in their electronic configuration.
Ans: All elements in Group II contain two valence electrons.
19
14. Write the number of protons, neutrons, and electronic configuration of 39K ,
15
31P , Also state their position in periodic table.
Ans:
19
39K
16. The element barium has atomic number 56. Look up its position in the
periodic table and answer the following questions:
(i) Is it a metal or a non-metal?
17. In group I of the periodic table, three elements X,Y and Z have ionic radii
1.33 A0, 0.95 A0 and 0.60 A0, respectively. Giving a reason, arrange them in the
order of increasing atomic numbers in the group.
Ans: The ionic radii will rise as the size of the atom increases in the group. As a
result, the group's growing atomic number order is Z <Y< X.
19. (i) State the number of elements in Period 1, Period 2 and Period 3 of the
periodic table. Name them.
Ans: Period 1:
Number of elements = 2
Hydrogen, helium
Period 2:
Number of elements = 8
Lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine, neon
Period 3:
Number of elements = 8
Sodium, magnesium, aluminium, silicon, phosphorus, sulphur, chlorine, argon
(ii) What is the common feature of the electronic configuration of the elements at
the end of Period 2 and Period 3?
Ans: The atoms have 8 electrons in their outermost shell, which is a common property
of the electronic configuration of the elements near the conclusion of Period 2 and
Period 3.
(iii) If an element is in Group 17, it is likely to be ______ [metallic/non-metallic]
in character, while with one electron in its outermost energy level (shell), then it
is likely to be _______ [metallic/non-metallic].
Ans: non-metallic, metallic.
(iv) In Period 3, the most metallic element is __________
(sodium/magnesium/aluminium).
Ans: Sodium.
Intext Exercise-3
4. Name the elements with highest and lowest ionization energies in first three
periods.
Ans:In the first three periods, helium has the highest ionisation energy of all the
elements, while sodium has the lowest.
7. Electron affinity values generally ----- across the period left to right and ------
down the group top to bottom.
Ans: increase, decrease
11. This question refers to the elements of the periodic table with atomic numbers
from 3 to 18. Some of the elements are shown by letters, but the letters are not the
usual symbols of the elements.
3 4 5 6 7 8 9 10
A B C D E F GH
12. A group of elements in the Periodic Table are given below (boron is the first
member of the group and thallium is the last).
Boron, Aluminium, Gallium, Indium, Thallium
Answer the following questions in relation to the above group of elements:
(a) Which element has the most metallic character?
Ans: Thallium, thallium will have the greatest metallic character because the metallic
character increases down the group.
(b) Which element would be expected to have the highest electronegativity?
Ans: Boron, as the size of the group diminishes, electronegativity falls, and boron will
be the most electronegative atom.
Exercise-1
4. First Ionization enthalpy of two elements X and Y are 500 kJ/mol-1 and 375 kJ
/mol-1 respectively. Comment about their relative position in a group as well in a
period.
Ans: The ionisation energy is the lowest amount of energy required to remove the
outermost electron from a gaseous neutral atom, resulting in the formation of a cation.
Position in a group: Because ionisation energy diminishes as one moves along the
group, X will be placed above Y.
Position in a period: Because ionisation energy grows from left to right, X will be on
the right side of Y.
6. Which element from the following has the highest ionization energy?
(a) P, Na, Cl
Ans: Cl
Metals have a low ionisation energy, while non-metals have a high one. In addition,
ionisation energy tends to rise over time. The third phase includes the elements P, Na,
and Cl. Group 1 is Na, Group 15 is P, and Group 17 is Cl.
(b) F, O, Ne
Ans: Ne
Because of their steady electronic configuration, inert gases have zero electron
affinity.
(c) Ne, He, Ar
Explain your choice.
Ans: He
The ionisation energy drops as the atomic size decreases, i.e. as one progresses down a
group. Inert gases include Ne, He, and Ar. Period 1 is He, Period 2 is Ne, and Period 3
is Ar.
Arrange the elements in the order in which they occur in the periodic table from
left to right.
(The group 1 element first, followed by the group 2 element and so on, up to
group 7).
Ans: Na, Mg, Al, Si, P, S, Cl
8. Choose the word or phrase from the brackets which correctly completes each
of the following statements:
A. The element below sodium in the same group would be expected to have a
............... (lower/higher) electro-negativity than sodium, and the element above
chlorine would be expected to have a (lower/higher) ionisation potential than
chlorine.
Ans: lower, higher.
B. On moving from left to right in a given period, the number of shells .................
(remains the same/increases decreases).
Ans: remains the same.
C. On moving down a group, the number of valence electrons ..................
(remains the same/increases/decreases).
Ans: the same.
D. Metals are good ................. (oxidising agents/reducing agents) because they are
electron ............. (acceptors/donors).
Ans: reducing agents , donors.
9. Parts (a) to (e) refer to change in the properties of elements on moving from
left to right across a period of the periodic table. For each property, choose the
correct answer.
(a) The non-metallic character of the elements:
(i) Decreases
10. The elements of one short period of the periodic table are given below in
order from left to right:
Li Be B C O F Ne
(a) To which period do these elements belong?
Ans: Period 2
(b) One element of this period is missing. Which is the missing element and where
should it be placed?
Ans: Nitrogen (N), between carbon and oxygen
(c) Place the three elements: Fluorine, Beryllium and nitrogen in the order of
increasing electronegativity.
Ans: Be< N< F
(d) Which one of the above element belongs to the halogen series?
Ans: Fluorine
11. With reference to the variation of properties in the Periodic table, which of
the following is generally true?
A. Atomic size increases from left to right across a period.
B. Ionization potential increases from left to right across a period.
C. Electron affinity increases going down a group.
D. Electro-negativity increases going down a group.
Ans: B. Electrons are added to the same valence shell as we move from left to right in
a period. As a result, atomic size shrinks and nuclear charge rises. The energy required
to remove an electron grows as nuclear charge increases, and hence the ionisation
potential increases over time.
13. (a) Formula of ion of A is A2+. Element A probably belongs to …….. Group.
Ans: Second
(b) In a period, increase in electron affinity increases …………
(oxidation/reduction).
Ans: reduction
(c) On descending a group,……… (increase/decrease) in ionization potential as
well as electron affinity …….. (increase/decrease) oxidizing capacity.
Ans: increase, decreases
2009
In the table below, H does not represent hydrogen. Some elements are given in
their own symbol and position in the periodic table while others are shown with a
letter.
1. (a) Among Period 2 elements A, B, C and D, the one which has high electron
affinity is
A. Lithium
B. Carbon
C. Fluorine
D. Neon
Ans: The electron affinity of lithium diminishes as the non-metallic character grows
from left to right.
(b)
IA IIA IIIA IVA VA VIA VIIA O
1 2 13 14 15 16 17 18
Li D O J Ne
A Mg E Si H K
2010
2011
(a) Give reasons - The oxidising power of elements increases from left to right
along a period.
Ans: The oxidising power of elements is determined by their tendency to acquire
electrons, which rises from left to right over time as nuclear pull increases.
(b) Select the correct answer:
(i) Across a period, the ionisation potential ………… [increases, decreases,
remains same]
Ans: increases.
(ii) Down the group, electron affinity ………… [increases, decreases, remains
same]
Ans: decreases.
(c) Choose the correct answer from the choice given:
(i) In the periodic table, alkali metals are placed in the group
2012
(a) Choose the correct answer from the option: An element in Period 3 whose
electron affinity is zero.
A. Neon
B. Sulphur
C. Sodium
D. Argon
Ans: The correct option is (D).
(b) Give reason:
(i) Ionisation potential of the element increases across a period from left to right.
2013
(a) Among the Period 2 elements, the element which has high electron affinity is
A. Lithium
B. Carbon
C. Chlorine
D. Fluorine
Ans: The correct option is (D).
(b) In the table below, H does not represent hydrogen. Some elements are given
in their own symbol and position in the periodic table while others are shown
with a letter.
2014
2015
(a) Among the elements given below, the element with the least electronegativity
is:
(i) Lithium
(ii) Carbon
(iii) Boron
(iv) Fluorine
Ans: Lithium, From left to right, electronegativity rises. Lithium is the least
electronegative element because it is found on the left side of the periodic table.
(b) The metals of Group 2 from top to bottom are Be, Mg, Ca, Sr and Ba.
(i) Which of these elements will form ions most readily and why?
Ans: Because the ionisation energy lowers as the group size grows, Ba metal quickly
forms ions.
(ii) State the common feature in the electronic configuration of all these elements.
Ans: The number of electrons in the outermost shell, i.e. valence electrons, remains
constant as you move down the group. As a result, the valency of a group remains
constant, i.e. 2.
(a) In Period 3 of the Periodic table, element B is placed to the left of element A.
On the basis of this information, choose the correct word from the brackets to
complete the following statements:
(i) The element B would have (lower /higher) metallic character than A.
Ans: The element B would have a higher metallic character than A.
(ii) The element A would probably have (lesser / higher) electron affinity than B.
Ans: The element A would probably have higher electron affinity than B.
(iii) The element A would have (greater /smaller) atomic size than B. Ans: The
element A would have a smaller atomic size than B.
2019
Study the extract of the periodic table given below and answer the questions that
follow. Give the letter corresponding to the element in question. DO NOT repeat
an element.