Professional Documents
Culture Documents
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Feb 28_2023
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Ramananda Chakrabarti / Attreyee Ghosh
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Center for Earth Sciences
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UENG 103
Introduction to Earth and its Environment
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Feb 28_2023
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2 exams
2 quizzes
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Feb 28_2023
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How to build a habitable planet (Langmuir and Broecker)
Intro to global geophysics (Fowler)
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Image from NASA's Voyager 1 spacecraft
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“There is perhaps no better demonstration of the folly of human conceits than this
distant image of our tiny world. To me, it underscores our responsibility to deal more
kindly with one another and to preserve and cherish the pale blue dot, the only
home we've ever known”. - Carl Sagan
Pale blue dot
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Image from NASA's Voyager 1 spacecraft
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Earth science deals with understanding the origin of this planet, its evolution,
and its future
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Earth science deals with understanding the origin of this planet, its evolution,
and its FUTURE
~4.56 Ga history of the Earth in 12 hours
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Earth Science: diverse (interacting) domains
Physics, Chemistry, Math, Biology, Engineering and GEOLOGY
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Planetary Science
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Climate, natural disasters, Seismology
Water, soil, …
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Geobiology Geodynamics/
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Earth Science structural geology
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Energy/natur
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Petrology
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Geochemistry
Geomagnetism …..
EES major/minor
revamped
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• 18 credits of core courses (3 in Earth Science,
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3 in Env. Sc.)
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• 18 credits of courses offered in CEaS, CAOS,
Civil, CST
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• 16 project credits
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Earth Science: what do we study?
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Meteorites – oldest solids in the Solar System
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Impact craters
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Earth Science: what do we study?
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Molten material from the deep Earth
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Sediments deposited from 2.5 billion years old oceans!
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Earth Science: what do we study?
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Globigerinoides ruber
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Ancient life-forms (macro and micro)
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Earth Science: what do we study?
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Globigerinoides ruber
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Paleoclimate reconstruction
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Earth Science: what do we study?
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Extreme climatic events, pollution, natural resources
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Earth Science: what do we study?
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Computational studies: Geoid anomaly, dipolar magnetic fields
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Earliest history of the Solar System:
rocks from space
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ISRO, NASA, ESA, JAXA…
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Internships…
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Evolution of other planetary bodies
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Lunar rocks collected from the Apollo Perseverance and InSight – probing
missions have provided insights into for life on Mars and studying its
the formation of the Moon interior structure
Occurrence of earthquakes and
volcanism
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USGS data
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Submarine volcanism:
origin of life, mineral deposits
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Atmospheric CO2 Concentration
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Atmospheric CO2 Concentration
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Paleoclimate reconstruction
Drilling the ocean floor
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Some basic questions
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• What are planets made up of?
• What is the Earth made up of?
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• What is the Sun made up of?
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• Starting composition?
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• What are planets made up of?
• What is the Earth made up of?
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• What is the Sun made up of?
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• Starting composition?
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Z = atomic number (number of protons, proton number)
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N = number of neutrons
A = mass number (A = Z +N) = mass of an atom
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General notation for a nuclide: AZC
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Isotope = same Z, different A due to difference in N
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•solid squares = stable nuclides (264 stable nuclides out of ~1700 nuclides – define the central
path of stability)
•open squares = unstable nuclides
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Atomic # Neutron # Mass #
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Parent Z N Z+N = A
Daughter Z+1 N-1 Z+1+N-1 = A
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Daughter is an isobar
10 + b- + n +Q (1.4 Ga)
40 K 40
20Ca
Atomic number (Z)
19
Stable
daughter Q = max. decay energy = 1.312 MeV
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Z+2, N-2
Unstable 87 Rb 87 Sr + b- (49 Ga)
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37 38
daughter
Z+1, N-1
Parent
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Z,N
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Atomic # Neutron # Mass #
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Parent Z N Z+N = A
Daughter Z-1 N+1 Z-1+N+1 = A
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Parent
Daughter is an isobar
Z,N
10 + b+ + n +Q
18 F 18 O
Atomic number (Z)
9 8
Unstable
daughter Q = max. decay energy = 1.655 MeV
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Z-1, N+1
Stable
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daughter
Z-2, N+2
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Atomic # Neutron # Mass #
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Parent Z N Z+N = A
Daughter Z-1 N+1 Z-1+N+1 = A
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Parent
Daughter is an isobar
Z,N
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40 K + e- 40 Ar (12 Ga)
Atomic number (Z)
Unstable 19 18
daughter
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Z-1, N+1
Stable
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daughter
Z-2, N+2
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Atomic # Neutron # Mass #
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Parent Z N Z+N = A
Daughter Z-2 N-2 Z+N-4 = A-4
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particle has 2p and 2n and hence
a charge of +2
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Atomic number (Z)
Parent
Z,N Daughter is not an isobar
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147 Sm 143 Nd + (106 Ga)
62 60
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Z-2, N-2
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• Occurs when a nucleus is in an excited state with too much energy
• Typically happens after a beta or alpha decay
• No particles are ejected from the nucleus
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• High photon energy/ short wavelength EM radiation
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Examples of nuclear reactions in the chart of
the nuclides
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Examples of nuclear reactions in the chart of
the nuclides
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Nuclear Binding Energy (EB)
•Energy required to split the nucleus of an atom into neutrons and protons (nucleons). It explains the overall
trends in a nuclear reaction.
•Specific binding energy is the binding energy per nucleon (EB/A)
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•Highest binding energy is 8.8 MeV for 6228Ni followed by 5826Fe and 5626Fe
•Nuclei can lower their total energy by moving towards the Fe-Ni region either by fusion (light nuclei), emission
of alpha particles or fission (for heavy nuclei)
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•Binding energy per nucleon of most nuclei is close to 8 MeV
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Nuclear Binding Energy (EB)
•Light nuclei have smaller binding energy per
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nucleon i.e. each nucleon experiences attraction
from a small number of other nucleons e.g. 2H
(1.1 MeV per nucleon)
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•Exception is the doubly magic 42He (7.07 MeV)
•Also 84Be (7.07 MeV) – however it is extremely
unstable – dissociates into 2 alpha particles as
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the alpha particles are a bit more tightly bound
– this is an exception to the rule that light nuclei
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prefer to fusion to heavier nuclei
•NOTE: Without 84Be, there would be no life on
Earth; Big Bang nucleosynthesis produced no
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elements heavier than Be (that too in trace
amounts) – C formed in the interior of aging
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Binding energy of 126C is 7.68 MeV per nucleon which is greater than that of alpha particles
Magic number
Z N A = Z+N #stable
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nuclides
Even Even Even 157
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Even Odd Odd 53
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Odd Odd Even 4
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G 264
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•Magic number is a number of protons or neutrons (nucleons) or both such that they are
arranged into complete shells within the atomic nucleus
•Nuclides with magic numbers of Z or N or both are more stable e.g., Ca (Z = 20) isotopes
with A = 40, 42, 43, 44, 46, 48; 4020Ca is doubly magic
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•Magic number for Z and N are 2, 8, 10, 20, 28, 50, 82, and 126
•N:Z increases from 1 to 3 with increasing A
Solar System (cosmic) abundances of elements
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•A realistic model for the nucleosynthesis of the elements must be based on
empirical data for the ‘cosmic abundance’
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•True cosmic abundance can be derived from stellar spectroscopy or by
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chemical analysis of galactic cosmic rays
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•However, such data are difficult to measure at high precision, so cosmic
abundances are normally approximated by Solar System abundances
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•These can be determined by solar sprectroscopy or by direct analysis of the
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•A comparison of elemental
concentrations from solar
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spectroscopy and direct analysis
of carbonaceous chondrites
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demonstrates good agreement
for most elements
the stars
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Abundance of elements in the solar nebula
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After Anders and Ebihara, 1982
Data listed in Faure, Table 2.2
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•H and He are the most abundant elements
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•Anomalously high abundance of Fe (Z = 26) – possibly due to maximum in the binding energy
curve at A = 56
•Abundance pattern is primarily a result of nuclear reactions
Abundance of nuclei in the solar nebula as a
function of atomic number Z
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Origin of elements
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•Nucleosynthesis is the study of the nuclear
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processes responsible for the formation of
elements which constitute the baryonic matter of
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the Universe
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•Production of nuclides (elements/isotopes or
groups of elements) are associated with specific
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astrophysical settings:
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WHERE?
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Dark (night) Sky Paradox
Proposed by Heinrich Olbers in 1826
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And for light from other galaxies the dark bands occurred in the same pattern,
but shifted towards the red: “the red shift” (objects moving away –
wavelengths stretched towards longer wavelength)
Red Shift: Olbers Paradox RESOLVED
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• All galaxies are moving away from us
• The universe is expanding
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Spectral fingerprinting of a star
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• A hot, dense object (star) will emit a continuous spectrum (loose electrons) of
radiation of different wavelengths
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• The cooler gas in the outer atmosphere absorbs photons with the characteristic
wavelengths corresponding to the transitions between different energy levels of
the atoms in the gas (line spectrum, bound electrons).
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• This leads to dark lines in the spectrum
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Elements in a star’s outer layer will absorb light, each element with its own spectral
fingerprint
Red Shift and distance
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Hubble discovered in 1929
that measurements of
velocity by the red shift
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correlated with
measurements of distance.
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Straight line means everything started at one place at one time (1/H o = age of
Universe)
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Straight line means everything started at one place at one time (1/H o = age of
Universe) – ~14 billion years ago
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processes responsible for the formation of
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elements which constitute the baryonic matter of
the Universe
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•Production of nuclides (elements/isotopes or
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groups of elements) are associated with specific
astrophysical settings:
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(iii)Supernovae
Immediately after the Big Bang
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Planck epoch (10-43 seconds) - Very
high T – all four forces unified
Grand unification epoch (till 10-36
seconds) - Expansion, cooling, phase
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transitions, Gravity separates from
other forces
Inflationary epoch (started after 10-
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32 secs
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weak force
………
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Photon epoch (10 sec to 380K years)
– universe is dominated by photons;
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Single electron
Proton (+)
cloud (-)
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Soon after Big Bang, matter was largely in the form of neutrons
Free neutrons collided with protons (hydrogen ions) to form 2 1H (deuterium); other
collisions resulted in formation of 3He and 4He along with Deuterium fusion to form
4 He (high nuclear binding energy)
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No stable nucleus of mass 5 or 8
“mass traps”
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•A helium nucleus colliding
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with protons or neutrons
produce no reaction
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No stable nucleus of mass 5 or 8
“mass traps”
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•Rare reactions produce
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masses 6, 7, 8 e.g. triple
collision of a p, n and 4He
nucleus (statistically rare,
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hence low abundance)
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No stable nucleus of mass 5 or 8
“mass traps”
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•A helium nucleus colliding with protons or
neutrons produce no reaction
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•Rare reactions produce masses 6, 7, 8 e.g.
triple collision of a p, n and 4He nucleus
(statistically rare, hence low abundance)
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•Big Bang nucleosynthesis produced no
elements heavier than Be (that too in trace
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amounts)
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FORCE STRENGTH OVER IS
WHICH IT IMPORTANT
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OPERATES
STRONG FORCE 1 10-15 m In the atomic
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FORCE
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E= MC 2
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•If there is a loss of mass, then energy is released.
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•If there is a gain in mass, energy needs to be added to make the reaction happen.
10 Important Concepts:
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•Nuclear Fusion happens as long as mass of the product nucleus is lower than the
reacting nuclei
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•AND, nuclear fusion requires the nuclei to “touch” so the strong force can operate, and
this requires very high temperatures. A confined environment helps.
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Big Bang nucleosynthesis – fusion and energy
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Mass of 4 hydrogen atoms: 6.696 *10-24 gm
Mass of 1 helium atom: 6.648 * 10-24 gm
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Mass LOSS of 0.048 *10-24 gm during conversion of hydrogen atom to helium atom
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Converting one gram of hydrogen to helium releases enough energy to boil 4.4 million
pounds of water
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BUT, temperatures (energy) of 10 million degrees are required for the protons to be
forced together
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During the Big Bang, the universe is rapidly expanding so temperatures decline
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very rapidly. There is a very short time window in which nuclear reactions can
occur.
Big Bang Nucleosynthesis
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•The process of light element formation in the early universe is called “Big Bang nucleosynthesis”
•The early Universe was a very hot place; one second after the Big Bang, the temperature of the
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universe was roughly 10 billion degrees and was filled with a sea of neutrons, protons, electrons, anti-
electrons (positrons), photons and neutrinos
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•As the universe cooled, the neutrons either decayed into protons and electrons or combined with
protons to make deuterium
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•During the first three minutes of the universe, most of the deuterium combined to make helium; trace
amounts of lithium were also produced at this time
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•It is believed that 30 minutes after the Big Bang, the matter of the universe (in the form of protons and
neutrons) consisted mostly of 1H and 22-28% by mass of 4He, along with traces of 2H and 3He
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•Hydrogen is by far the most abundant element in the universe (88.6% of all nuclei) and with He, makes
up 98% of its mass
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element distribution would be uniform – which is NOT the case
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spectroscopically
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Stellar evolution (H-R diagram)
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The length of the life-history of some typical
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stars depends directly on the stellar mass,
and can be traced on a plot of absolute
magnitude (brightness/luminosity) versus
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spectral type (color) or classifications and
effective temperatures, referred to as the
Hertzsprung-Russell or H-R diagram
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Stellar nucleosynthesis
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•stellar nucleosynthesis is linked to different stages of stellar evolution
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also return heavy element enriched matter to the interstellar gas from which
new stars are formed
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•Heavy elements comprise ~1.8% of the mass of our Solar System; stars forming
today in our galaxy can be enriched 2-3 times in heavier elements
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•3 dominant sites of nucleosynthesis of heavy elements: (i) intermediate mass
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stars (M/M0 = 1-10), (ii) massive stars (M/M0 > 10) and associated type II
supernovae, and (iii) type Ia supernovae
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Star formation and the solar nebula
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•Galaxy = stars + stellar remnants + ISM (H, He and dust)
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•Stars form in higher density regions of the ISM – interstellar
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clouds
•Clouds with optimal density and size have molecular hydrogen
(H2) – hence molecular clouds – other areas have ionized gas
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Stars form by gravitational collapse of dense regions of molecular clouds
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As the cloud contracts, all its energy is confined to a smaller volume and it heats up
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It keeps contracting and keeps heating up until some force operates to offset the
gravitational contraction.
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That force is the heat generated by nuclear fusion.
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The bigger the star, the stronger the gravity, and the more heat is required to keep
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it from contracting
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Stellar evolution (H-R diagram)
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The length of the life-history of some typical
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stars depends directly on the stellar mass,
and can be traced on a plot of absolute
magnitude (brightness/luminosity) versus
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spectral type (color) or classifications and
effective temperatures, referred to as the
Hertzsprung-Russell or H-R diagram
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Stellar Nucleosynthesis
•Present day models of stellar nucleosynthesis are based heavily on a classic review paper by
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Burbidge et al., 1957 in which 8 element building processes were identified (hydrogen
burning, He burning, alpha, e, s, r, x*, and p) to explain the abundance pattern of different
groups of elements
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(i)Hydrogen burning – powers stars for 90% of their lifetimes
(ii)Helium burning – responsible for production of the two most abundant elements after H
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and He – 12C and 16O
(iii)alpha-process – combination of carbon, neon and oxygen burning
(iv)Equilibrium (e) process – silicon burning proceeds to the formation of a nuclear statistical
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equilibrium abundance peak centered on A = 56 (Fe)
(v)Slow (s) and rapid (r) processes (neutron irradiation) – mechanisms of neutron capture for
synthesis of the heaviest elements (A > 60-70); in s-process, neutron addition is slow while in
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r-process, neutron addition is rapid – compared to b-decay; r-process occurs only in
supernovae
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Hydrogen burning
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•Fusion of 4 protons (?) to form one 4He nucleus (+ energy) – p-p reaction
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•Strongly exothermic
•Long t1/2 explains long duration of H-burning (Main sequence) stage for small stars
•Consumption of 2D and 3He explains their lower abundance than 4He
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Hydrogen burning - CNO cycle
more important in large stars
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•If heavier elements are present in a star
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•CNO reactions contribute less than 10% of H-burning reactions in small starts like our
Sun but is the dominant reaction of Hydrogen burning in large stars (>10 ME)
Stellar nucleosynthesis
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Helium burning
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T1/2 of 8Be is <10-15 sec but critical for a 3-particle collision to form 12C
Decay of C* to ground state C is exothermic – drives the equilibria to the right
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•Li, Be, B have low nuclear binding energy – unstable at T>107 K (star core) – hence
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Allow further reactions that fill gaps between masses 12 and 24
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Alpha process
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When small star reaches max. core T of 109K
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Overall reaction has a positive energy budget
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•Similar to helium burning but different source of 4He
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O, Si burning
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Stellar nucleosynthesis
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Stellar nucleosynthesis
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Nuclear fusion can continue only up to 56Fe
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Once 56Fe is produced, no further heat production is possible through fusion
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Creating elements heavier than Fe:
Neutron capture
Can occur at room T! (no charge, can freely enter a nucleus)
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•Occurs during supernova
•Inside a close-packed exploding star, neutrons
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encounter a nucleus (many with Fe nuclei) long
before undergoing spontaneous decay to a p+e-
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•Rapid addition of neutrons (“r”) – no time for decay
•A nucleus gets heavier until it cannot accept any
more neutrons
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•During this brief pause, neutrons undergo beta
decay by emitting an e-
•Can go past U and Th – when nuclei become very
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big, neutron impacts cause them to fission
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•Supernova explosions are not the only way
of adding free neutrons to nuclei
•During last few million years of a Red Giant’s
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life, nuclear reactions can release free
neutrons
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•Capture of these neutrons is a slow (“s”) process
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to Pb, Tl
Neutron capture
Neutron capture cross section (nccs) – how readily a nuclide can absorb neutrons
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•Nuclides with N = 50, 82, 126, 184 have very small •Why does the r-process path have less zig-zags?
NCCS – magic neutron numbers •How do nuclides climb up the r-process path at magic numbers?
•This results in local abundance peaks at masses (A) 90, •r-process nuclides have lower (8-12) particles than s-process
138, 208 nuclides
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Intermediate stars Massive stars (SN II) Binary stars (SN Ia)
•Most time spent in the •Increased core P and •Half of all stars in
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main sequence during higher core T our galaxy are binary
H-burning •C, Ne, O, Si burning stars
•After H-He burning, all possible •Can end as white
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stars have a C-O rich •Collapse of Fe-core dwarf, neutron star
core •Type II supernova and or black hole
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•T not high enough for C formation of neutron star •Accretion onto C-O
burning or black hole remnant white dwarfs allow
•Lots of elements •SN-II is the major source growth of the core to
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produced during AGB of elements heavier than the Chandrasekhar
stage H, He limit (1.44 M0) –
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constitute the baryonic matter of the Universe
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•Big Bang nucleosynthesis produced the lightest elements: 1H, 2H, 3He, 4He and 7Li – primordial
composition of both galaxies and the stars formed therein
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•If nucleosynthesis of heavy elements had occurred in the Big Bang then the element distribution would be
uniform – which is not the case
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•Elements from C to U are all synthesized in stars and supernovae; supernovae also return heavy element
enriched matter to the interstellar gas from which new stars are formed
•Heavy elements comprise ~1.8% of the mass of our Solar System; stars forming today in our galaxy can be
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enriched 2-3 times in heavier elements
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•3 dominant sites of nucleosynthesis of heavy elements: (i) intermediate mass stars (M/M0 = 1-10), (ii)
massive stars (M/M0 > 10) and associated type II supernovae, and (iii) type Ia supernovae
•Stars of different ages have different compositions which can be detected spectroscopically; stellar
nucleosynthesis is linked to different stages of stellar evolution and masses of stars
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Stellar Nucleosynthesis
•Present day models of stellar nucleosynthesis are based heavily on a classic review paper by
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Burbidge et al., 1957 in which 8 element building processes were identified (hydrogen
burning, He burning, alpha, e, s, r, x*, and p) to explain the abundance pattern of different
groups of elements
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(i)Hydrogen burning – powers stars for 90% of their lifetimes
(ii)Helium burning – responsible for production of the two most abundant elements after H
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and He – 12C and 16O
(iii)alpha-process – combination of carbon, neon and oxygen burning
(iv)Equilibrium (e) process – silicon burning proceeds to the formation of a nuclear statistical
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equilibrium abundance peak centered on A = 56 (Fe)
(v)Slow (s) and rapid (r) processes (neutron irradiation) – mechanisms of neutron capture for
synthesis of the heaviest elements (A > 60-70); in s-process, neutron addition is slow while in
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r-process, neutron addition is rapid – compared to b-decay; r-process occurs only in
supernovae
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•In the minutes before explosion, when T > 3 x 109 K, very rapid nuclear
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reactions occur
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neutrons synthesizing elements life Fe by the so-called e process
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•The supernovae explosion itself lasts only a few seconds but is characterized
by colossal neutron fluxes
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•These very rapidly synthesize heavier elements, terminating a 254Cf, which
undergoes spontaneous fission
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•Products of the supernova explosions are distributed through space and later
incorporated in a new generation of stars
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