TITLE: Volumetric Analysis (Acid- Base Titration)

AIM: To determine the concentration of a hydrochloric acid solution

APPARATUS: Beakers, Erlenmeyer flask (conical flask) filter funnel, Burette, 25cm3 Pipette,
Dropper, White tile, Distilled water, 0.5M sodium hydroxide, Hydrochloric acid solution,
indicator.

DIAGRAM:

PROCEDURE:

Wash the burette thoroughly with a liquid detergent. Wash it with tap water, then with distilled
water and finally rinse it with the standard sodium hydroxide solution. Fill burette to a
convenient graduation mark with the 0.5M sodium hydroxide. Record this initial burette reading.

Pipette 25.0cm3 of the hydrochloric acid solution into a clean conical flask and 1-2 drops of
indicator. Add the standard sodium hydroxide solution from the burette until the end-point is
reached. Record the burette reading.

Repeat the titration as many times as convenient until consecutive burette readings differ by no
more than +/- 0.20cm3.

Name of indicator used ________________________________________

Colour of indicator change from _____________ (in acidic) to ____________ (in alkaline)
 Data Collected:

Burette Reading / cm3 TITRATION

Volume of 0.5M NaOH used Rough 1 2 3

Final Reading 17.06 20.70 28.20

Initial Reading 10.09 13.20 20.70

Volume of NaOH used/ cm3 6.07 7.50 7.50

Tick the best Titration results

Summary: 25cm3 of hydrochloric acid required on average __0.006 mole (6x10-3)_____ of a

0.5M NaOH for complete neutralization.

(1) Calculate the average volume of NaOH used _________________________________ (1 mark)

(2) Calculate how many moles of NaOH were present in the average volume delivered from the burette
in part (1) above.

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)

(3) Write a balance equation for the reaction (including state symbols) (1 mark)

(4) How many moles of hydrochloric acid was in the 25cm3 originally pipetted and will combine
with the number of moles of sodium hydroxide obtained in (2) above?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)

(i) What is the concentration, in mol/dm3 of the hydrochloric acid solution?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)

(i) What is the concentration, in g/dm3 of the hydrochloric acid solution?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)
 TITLE: Volumetric Analysis (Redox Titration)

AIM: To determine the concentration of a Iron (II) solution

APPARATUS: Beakers, Erlenmeyer flask (conical flask) filter funnel, Burette, 25cm3 Pipette,
Dropper, White tile, Distilled water, 0.02M Potassium permanganate solution (MnO-4), Iron (II)
solution (Fe2+).

DIAGRAM: Draw labeled diagram indicate what reagent was placed where

PROCEDURE:

Wash the burette thoroughly with a liquid detergent. Wash it with tap water, then with distilled
water and finally rinse it with the standard potassium permanganate solution. Fill burette to a
convenient graduation mark with the 0.02M potassium permanganate solution. Record this initial
burette reading.

Pipette 25.0cm3 of the iron (II) solution into a clean conical flask. Add the standard potassium
permanganate solution from the burette until the end-point is reached. Record the burette
reading.

Repeat the titration as many times as convenient until consecutive burette readings differ by no
more than +/- 0.20cm3.

Data Collected:

Burette Reading / cm3 TITRATION

Volume of 0.02M KMnO4 used Rough 1 2 3

Final Reading

Initial Reading

Volume of KMnO4 used / cm3

Tick the best Titration results

Summary: 25cm3 of iron (II) solution required on average _______ of a 0.02M KMnO4 for
complete oxidation.

Why no indicator was used _______________________________________________________

_____________________________________________________________________________

Colour of indicator change from _____________ to ____________

(1) Calculate the average volume of KMnO4 used _________________________________ (1 mark)

(2) Calculate the number of moles of KMnO4 used were present in the average volume delivered from
the burette in part (1) above.

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)

(3) Write a balance equation for the reaction (including state symbols) (1 mark)

(4) How many moles of iron (II) was in the 25cm3 originally pipetted and will combine with the
number of moles of KMnO4 obtained in (2) above?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)

(i) What is the concentration, in mol/dm3 of the iron (II) solution?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)

(i) What is the concentration, in g/dm3 of the iron (II) solution?

______________________________________________________________________________

______________________________________________________________________________

______________________________________________________________________________

(2 mark)