C HE M IST R Y

BULL’S EYE
CONTENT
CLASSROOM PRACTICE PROBLEMS
Ekalavya & Warrior-2023
Most Important Reagents CPP NO. 34

1.
ST INFORMATIO
X2 / NaOH Or NaOX Converts methyl keto group to carboxylate ion and haloform

 X2 / NaOH Or NaOX Converts amide into amine with one carbon less than amide

3. CHCl3/KOH Converts Phenol to salicyaldehyde

4. CHCl3/KOH Converts primary amine into isocyanides


R  NH 2 CHCl
 
 R  N  C ¯
3 / OH ¯

5. NaOH + CaO Convert carboxylic acid to hydrocarbon with one carbon less

6. H+/KMnO4/ Oxidation of multiple bond to carboxylic acid & ketone



7. Cold dilute KMnO4/OH– Oxidation of multiple bond to syn diols

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8. NaBH4 Reduction of carbonyl compound to alcohol

9. LiAlH4 Reduction of carbonyl compound & carboxylic acid derivatives to alcohol

R  CONH2  LAH
 R  CH2  NH2
R  COOH 
LAH
 R  CH2OH
R  CHO 
LAH
 R  CH2OH
R  COCl 
LAH
 R  CH2OH

10. DIBAL–H Reduction of ester to aldehyde

11. DIBAL–H Reduction of cyanides to aldehyde

12. H2/Pd – BaSO4 Reduction of acid chloride to aldehyde


13. H2/Pd – BaSO4 Reduction of alkene to cis alkene

14. Na/liq. NH3 Reduction of alkyne to trans alkene ]

15. PCC Oxidises alcohol to aldehyde & ketone

R  CH2OH 
PCC
 R  CHO

16. O3/Zn/H2O Reductive ozonolysis of alkene & alkyne to give carbonyl compound.

17. SnCl2/HCl/H3O+ Converts cyanides to aldehyde

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18. Zn(Hg)/HCl converts group to CH2 group

19. NH2–NH2/OH– converts group to CH2 group

20. CrO3/H2SO4 converts primary alcohol to carboxylic acid

21. NaI/acetone Finkelstein reaction

22. AgF/Hg2F2/CoF2/SbF3 Swarts reaction

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