Professional Documents
Culture Documents
Feedstock in the form of large coal particles are loaded into the top of the refractory-lined gasifier vessel
and move slowly downward through the bed, while reacting with high oxygen content gas introduced at
the bottom of the gasifier that is flowing counter-currently upward in the gasifier.
• Most coals are suitable for this type of gasifier because of the high
operating temperatures and because the coal particles are well
separated from one another.
• High conversion
• Entrained-flow gasifiers operate at high temperature and pressure— and extremely turbulent flow—which causes
rapid feed conversion and allows high throughput.
• The gasification reactions occur at a very high rate (typical residence time is on the order of few seconds), with high
carbon conversion efficiencies (98-99.5%). The tar, oil, phenols, and other liquids produced from devolatization of coal
inside the gasifier are decomposed into hydrogen (H2), carbon monoxide (CO) and small amounts of light
hydrocarbon gases.
• Entrained-flow gasifiers have the ability to handle practically any coal feedstock and produce a clean, tar-free syngas.
Given the high operating temperatures, gasifiers of this type melt the coal ash into inert slag.
Fluidized bed gasifiers
commercialized in 1926
Coal is ground to 0- 8 mm
major issue with this gasifier is that the entrained ash contains a significant quantity of unreacted carbon.
Operating Temperature: 800 - 1100 0C
Operating Pressure : Atmospheric
Well suited for synthesis of Hydrogen, Ammonia or Methanol.
Fluidized bed gasifiers Operation
• Fluidized-bed gasifiers suspend feedstock particles in an oxygen-rich gas so the resulting bed within the
gasifier acts as a fluid. These gasifiers employ back-mixing, and efficiently mix feed coal particles with coal
particles already undergoing gasification.
• To sustain fluidization, or suspension of coal particles within the gasifier, coal of small particles sizes (<6mm) is
commonly used.
• Coal enters at the side of the reactor, while steam and oxidant enter near the bottom with enough velocity to
fully suspend or fluidize the reactor bed. Due to the thorough mixing within the gasifier, a constant temperature
is sustained in the reactor bed. The gasifiers normally operate at moderately high temperature to achieve an
acceptable carbon conversion rate (e.g., 90-95%) and to decompose most of the tar, oils, phenols, and other
liquid byproducts.
• However, the operating temperatures are usually less than the ash fusion temperature so as to avoid clinker
formation.
• Some char particles are entrained in the raw syngas as its leaves the top of the gasifier, but are recovered and
recycled back to the reactor via a cyclone. Ash particles, removed below the bed, give up heat to the incoming
steam and oxygen gas. At startup, the bed is heated externally before the feedstock is introduced.
Conclusions
• Gasification is the cleanest, most flexible and reliable way of using fossil-fuels. It can convert low-
value residuals into high value products, such as chemicals and fertilizers, substitute natural gas,
transportation fuels, electric power, steam, and hydrogen.