11k

, mass increase : , 54g

- 3 . 40 0 . kg 15 h 0 .
14 028 3 =
=

0 . 028
kg 28g / hr = 等
molbh =

the
tlowrate
±÷ 0 . 99 ÷ 0 . 04 = 40 . 1

mollhlmolar d

leed gas )
0 .
04 × (1 -

0 .
9n) = 0 04 × 0 03
.

.
= 0 ,
00 12 = 0 12.

mole % water Vapor

(

the poduce
gas )
in

Caclz 顆粒吸⽔達飽和 y 最終產出氣體⽔蒸氣

之莫耳盼率為 4 0 % .

”;

→鬱
Wo

園器
↑
:00 g
…

— … →

0000 s

blOverall mass balane ;

Fo = W , t W2 t .
. + Wo + Fo (Assume W
=W , =Wi =
" =W0 )
=
IOW + Fo
Mass balance for salt :

F0 -

x0 =
Fo - ⑦ 0= F 00 035 .
= Fi 0 OO 5

For each evaporator ;

Fo =
Fit W 1 ,
F1 =
F 2
+ W2 F2 F3 + Ws , 3 F 4 =
=
tW +
…

Fa FotWio
=

F0 =
F 4 + 4W
Fo = 100

L
0

= 100
.

Fo . 0
. 035 = Fo .
0 . 05 Fo 050 nO 。
=

F0 = COW + F 0 10 W 30, W 3
= =

0 =
+ W 1=
F E
+ω 1+ W 2= B
+W 1+ W 2+ W 3 = Fy+ W 1 tWz+ W 3 l
+ 4
=
F 4+ 4 W =
F4 + 12
F
4
=8
Mass balance for sattrom tirst o he
lourty
0 035 = F x 4 = X 4 = 1000035 → 88 -
0039 . 4 )

14 al Awaterm
3
separate
.

orner % 呦
Nil
inermo
… —
品 % —
→
88 21

riloeHup
12 001%
.
solid
如 %北 →
88 . 0 % H
o

m2

12 .
0% solid
88 0 %
.
HO

From the separate point :

Mt =
m 1 + M2
, Knowing me we need one mone

equation
i solve for miand
to m

=7 has one
degnee of lreedom
bllm lookgt
=
,
me = m . tM 2

Overall mass balanee

4
: Me = m 3 + m 5 = 100 M + M
3 5

Overdll mas balane for solitimeo . 12 =m 50 .

100 0 12 =
,

,
Mσ .

0 .
42 m 5= 100 -
=

28 . 6 kg , M
3 11
=
.
4 kg

{
Mass balance
mstmytn
evaporator , i = 1 4 :
m
.
+m4

:olid
Mass balance for 12 = M 4 0 58
X 0 ×
M,
devaporator .

)1 - 4 + M 0 . 12 = m 4 × .58 m 4 0
=
18 6 kg
.

,
m, =
90 kg
m2 =
100 -

90 = 1 Okq

product :M 5 = 28 . 6
kg
per 1 ookglreshjuice

#
fractionbypass the evaporator 000 10 %
mr
= =
mtmz
:

eakes
It

monetime and energy比 evaporate

Morewater ,
 excess CH 4 ni
18 al,

HCHO nI

ant
omolleed O2 n; variablesive
→ → =
Hw
,

indopendeneive
v

⑤ molls CH 4 0 n4

O excess O2 5
n
equations
omolls
Extents ol ne
tional canbe gien as E
,
E红

Unknowns :
ni ni ni , ni, n5 E Ez
, , , ,

Equations :
ni ni
, ,
n;
,
n 4 n5
,

degree oflreedom = -5 =
7

2#

blSelectivity =

CH 4 + O 2 → HUHO + HW
,
CH 4 + 2 O 2
→ O2 + 2 HW
G 红
ni = 50 -

E - Ez

ni = E 1

n 3 =
Ez
ni = E + 2 E2
1

n5 =
5O -

E1 -

2 Ez
@ 0 855 = 世 =
molkG
) 42 95= =

0
( 1 .5
.
,

50
0 900 hi
ni = 0 -E - mols
2 5 ε= . 25
-

=π=
E
=

Selectivity =☆ ⼆流⼆器 =
19 #
ni =
E1 + 2 E2 =
4 n 25
,

molls ,
n5 = 2 75
.
molls
Output sheam :
5mol /s CH 4

42 75 molls HCHO
.

2 25 molls O 2
.

47 25 molls H
.

2 75. molls O2
2巧
a
( C4H . 0
+ 53
O → 4ω + HW
2 2

"
" =1
0 → →0
,
以

0
ninr % 3

□
,

ng Yω 3
YNz ,
2 = 0
z
,

YHw 3

φ 0 21
,
=
02 2
YN 3
.

, 2
,

Yo 2 3 ,

unknouns atomic balanceslor ,H 0 Ngives lour

8

, C , ,

indopendent equations specilication onthe

The .

onversion od butane
airthe
excess yive two more

independentequations. Mole fractionsof allhe

species in
1 00 the
roduce must addo
gas .

gives
another independent eauation .

Degree od lreedom : - - -
8
4
2

1
=1 #

bl 100 %conversion ,
no excess air : For 100 mol butane
basis

0
10 □
0 →=
nn

,
oms
→③
星 -
0 21 n 2 = 100 1 00 × 6 5
-

→
,

.
.

n9 Yω 3
YNz ,
2
= 0 .
z
, n 2= 3095 mol
YHw 3

Yoz O 21
product gas × 9 + 3095
,
100
=
2 :
YN 3
.

, 2
,
0 n9
φ02 , =
.

⼆ 33 molso
Y ωz
,
3 =
××=
100 0 119 .

[4
R H 10 + BO 45→ 2 +
2 HW
W
335
lOO × 5
YHe 3 =
—
= 0
149
,
335
.

φNz 3 =| ,
-

θ 119
-

0 .
149 = 0 .
732

iil (0 excess air 100 %

%

,
onversion n, = 100 :
,

□②→
" "
①→
1
= “
⼆
③
minr
,

, 3 : 0 0 2/ n2 100 × 6 5 × 1 2
yu
.
=
.

0 ns Yω 3
3714 mol
= z
z ,
,
φHw 3 n2 =

Y0 0 21
,
=
2
z
YNr ,
.

Y02 3 ,

n 100 × 9 3 n 14 0 99 6 3964 mol

= 0
+ × + 0 2 × 5x
=
3 .

excess airCOz
=□
× 4 0
φω z 3 = 0 101
3964
, .

Y+ z 0 3 =⑩
5964 0 .6
,
=
99 × 3714 3964 32= = . 74
2 0 -
= 3
.

Yω , YN , O

.
2
2

YOz ,
3 =| -
0 101
.
-

0 26 .
-

0 n 40 ,
= 0 .
033

jiin w % excess air, 90 conversion

%
,
n ,
= ( 00 :

100
, = θ21n . 2× 6 .5 X 10
①→
*

" 2 1

,
=
n
"
m
③m h2 =
3 ⽉ 14 mol
□②→ ym
, r =
o. Yoz
YHw
,
3
3
90 %conversion )
=

Yoz 0.2 ombustion poducts 岁

1000
,
=
=
2
, Ywr 3 ,
g
φ02 3
810 mol
,
=
 h 3 = 810 + 0 9 × 3714 + n
0 . ×6 , 2
52. 100 + 6 -

.
5× 0 1 × 100 + O
.

.
1 ×100 = 3949 mol

0 1
.
× 100 =
3949 φ ,
3
= φb , 3
=
0 00253
.

C balance ;

100 × 4 =
3949 yoz ,
3
t 3949 .

4 000253
,

Yω 2
,
3
=
Q 0912

balance
H :

3949 00253 + 3949 YH ω 32 )

100 × 10 = 10 0 =
YHw 3 0 114
.

=
-

,
.

, ,

N balancei
99 × 2 = 3949 Yn, 3 n 43
Yπ 3 ×2
= 0
3114 × 0 .
× z
,
,

φ02 3
=
1 -

000253 - 0

. 0912 - 0

. 114 0 743
-

.
= 0 .
0493
,