Chapter e Mixtures of Gases + Gases cnch @ Conclensesle Vepours [Text: pe. 642-697] Universal Gos oo, fe = BBG ee ae For ole Gas Constant: [i s Vee ok Mie. a “ Ba volume, OG is fa Ne 2) 7 OF Vprixe = Von + Vide VS PC Caig, Tarte) he. Mi vhure Velanme = Sum of eorhed volumes SS ve : fo 1 chee [amamed Mace, lect pve n RT ~5 ye okt Nye _ 1, REE 1 pt SEE x Lee zac, —o te mule Frain mK Nai he Tvnix if Pallows : Xo, Fou. TY In ogreral Verms | (Eo = S v, = > V5 7 4 ae at ae my Mwy ayes ni je m M v an Ry Sr ; — GAN The mass Rrochion a | Prmig Moni —> sec aFurther mixture mies» &) Rin = 2 ay hy Unie 7795 wy Conn F463 aa = EWC ZAG; Pressure of Moe Components Gas pressure results Fron te collision of excited pole with a sucFace. Each comoorent rralees a contrition be mixture Pressure! a — ee oo Pe x A, + Po, | Resch) mix Le. Mix wre pressure = Sum a part iol pressures, > Var (mix) = 9.79 bar (,) + 9.21 bor (92) Tn Qeneral . _ — Prin = > PA where 0; = FT, Yai ee to Mie: ee nN. fee : =f, RT ve — o ie = a Vorwi x, RTL it Cee tot fee = Dean = ox = A Rie Mmik [.é. i — Ca MoleewWar Mass, " ob a Mixture: Hes NM ee = aes miy =Exon le3l For O.5le) Met O.2 leo On whot is Myil © O.B+0% _ Ik M= oe ae 72872 Vind 2g aan Brenyale 3:2 Fino Sp of O2leg Hy #1. Shy Me oe 2733 Xx Ce mix * ¥ 435 See 1.3+0.2 ee a) Ha Ma Mixtares of Gases ¢ Conclensible Vopouts. A Poon 3x 20x 2Om (oon) Is Filled a soburedecd water vapour e aie at poiskee ¢ 25°C. Colenlate (> Py, Fae, My b mops Steam telale Ae oo an ieee eo tte eS ole ei oe Vee [foo 0" i Me es = E47 ie Meier Fa se : VWesat 43. ey J IBiXlo° IB00. Tis) V, seu) T O-TixXlo%} a STEMI 26 Whoarb if the else. mixkure was on the room © const. pressure fo S57 fe ole @ oe consk. Suppose that my also shows the some = Py Mm 2 ce cy = “Ay nic a he. for a ene , Com,be reek L ah oe ie &) Raf soturabion @ressure i A water vapour ak Tuy Typical ce typresll parkial pressure oF wodler vapour in aie at Trniy 16, Superhestedl Soturahion Line, ee Tf mixhace ie codeck at conch pressure laslow 25°c, Vepesr will condense, Le. my y reclucg For CXanrle, ak CoG = a ‘are Fee Ro. : ‘ex a> om, = kee = 3th) 57.8 > ALB -B1.5 = lob ley will conclemse of of air. StadyoP Mesh Ain > Poachroneten. LL ot Reba; TONS ES Mons | Cowl use 4. 4. _ Ma my For atmospheric mixtures, My Ts small, Se we use fee ne TP lsat carn he resp. eck ae perfect Aases » oe Vie) Me 7 y Pao, V/CRT) Si fw fo Ge ee BLUE r5.029 For previous examele x 2°65 ee [ So Z166 4 Ma” 2.96 Lorz-aozb6 © | >. 98) zos2>So Veporn Jain mixtures, the c= ratio ® Is callech the Kaeidiby rohle om speci Me humicliy , a Cor 69 in harblocles Ak 25°C 9% = o.52 is the sod. or maximum value, For dner abmospheres: 969 < 9.02 Lnvoajint ehanet i co = Blew, anchan abmoscher, oF NAe/Ne: Ab -tove, Cyboa = 2 998 tear 5 From belles ~2%C, + oe (oc Gg ie eo) oy 7 ff A fe i ee 4 o : sot Olds) a Pee Se ee 1.6. Sy CAN he = (ole viously gpan't be >!) ee oe Se 2 ee esr =o '513-2.05974 _7) ie. ‘ i. Tesat F when af mosphere, cs lotte . We Wee a ce measure by Com pate 4, a y ee ee a Want, yok By sah A = Frat V RT) eo Relakive Harsichi by: 2 oy Dz EC Rag TedRelekionehie between Ql ep: 68) +2 My PGat « $2 Ry p- beat Biot (14 ayy) Lyon ple 22 a £Mg> At B2°c, dete R= Lod hear, Pr sab = 0.9 1 Shoor,| ly a O.TX 2.0415 = hamiodity akio A to.62) =O.024I > : 1-213-9.7X 0.0475 J specitic hum. What is We ee fee ey ae R Cerf my, Ae = ee - eo contiions, Reg: Py sak = O.TK 0.9415 +0.085he Few peink teme is the sohetion fernpereature Corre Sending te Prec 083 har, From satrroted weder Propeckicg telsle, We Can inter folate Py sokler)o.9216F Co.oasy 2: 23363 Gc) 7S. Tere 26 TE we cole the mintire te 20’, haw muel eo to lo ee AL 20°C, Oy gah * ©. 0250 boar - — =: o6ai 2:02 Slr - Ole a a. Ww _ TT fa v \; > lee 25 c v ot RB - 2.022cS) Rue as ms \ Ney ~ wee 2.22 icoy Ae - M20 5 . : Bt Zo. YU 5 22'S a My = 291 Slesy Me ee jto = 9-P2\— 9.915 = 2.904 lecy. Ceo We ee ol precesses where air 1S conmpresseck se Cooled, ie. iscthermelly compressed’ _> Ce Corms as air is cole trod nt be Removed \ Flow Processes with Moist Mic ® Rie Cond: Kieninoy ne 1 Qua 7 a — oo Ly 62» ae ae ee ze a : Lo, ean 7 7 7 Cee. a Mass (ILA : Moar My 7% ye in : : SFEE gives ° Me G8 BSA he mahsatmy by, 2 Quy eee te or ‘ 2 Qot / = thy: hart Ube why Hala hist Syehve Qox or ot _ 6 7 , ey Be 7H CegT-B) ba, harchal)- alba hedExample 20 ioe) ee Bleayls Flow of moist air a) ab S6c with Pebor, codedk fo25%e with Prove PR; mix =] ot, Oy = 2.60 GF o.62 2EX920NT = oa BoP Prva 1.913 - 0.6% 0.0544] A = 9.62) eeseh — geen 2 9.920) vz 1.068 -1K9-0 3167 EntheleieS? Toe chy: Kens, 2 25671 Ye, T225°C Wes hemor 2547.2 Yor heat Wp 5104.61 “Sees o. “+ Yosh = 9.95 (36-25) 4 9.0227 2567. [-104.89) —-__-~--=E__ xz iloe je’ poe = 746 aN aw Tey Air Ate Cookin coe Cac ieOy + Cordlensabion ed ® Coline, Towers A wares, very moist am ioe. 5 Mary TS Coa moderately meish aie Fo. ; . Mass Bolance (1.9). oe co . PV AM OEP, fy, 2% 9,- (yy,é SFEE: Fog Bayt hes Hip ha = Big hg tava + (iy, Pry thy.) hy _ Cog hit yhys 7 Te has : Coy a cboe + (Cs La Sot hen = ae , ane haa hea)s rag (TED) Al hvam ga) ai no mn ceca water vagone is lest the cool ine Coe . : ™M, Crags eve = Myer my, or 2a cae This tho loSs ts compensatah eo. buy = vecter’ Adiaketic Sobrretion a 224 _, ot. A Air > > [ TA aye Pe (= loon Por lang duh) f oe Incominn STream gp: Stoke oo ralens ole ee Shobe of woter VOpowr 1h exits ar Pr Note Bc ps & Tad. Mass Balance (HD): mM er My,2 As v1 Energy Balance: Cegtt9,, (hy rhy ) = Spats +92 Chy,e- he )what we're inferestedd in: ® Tr? -5 neeck ayeh yor Bi? —> neck Te T2 Example 3.5, IP Tz 25’ ¢G760¥% Ter 7 Assuming Daw.) as a FC py Tmid, Te is hicklen in amt 1G. fe ae so Gol. ee Wask ios ce 2 Ect) Tterahive ol . reach! O Seleck o 1 Finck Fy acset) , caleulate a ; yah & Suh hasnt ints ene rey ee calcukeke fo Ot 2. R° , this cerred or @ IF oot, bru AQAA with ri The Reuchronettic Chart This cho conveniently plots Ay AS % Ranckion of ay Q. a also ase rb to rench okt Tole fee ve hk fdr a iver mix tace Shale. 7 : < - En. % otf P2597 + 30"C 7g ea chowk | oO oleTHis michine were Coleck, troce The pracess S | & Finck the dewyoint : | oo. Ad tolselte Sobral Ton | - At an intermed cake. &, 7 /% . 1 LO p Con be Func... §, 1027,, a Exome 36 , ® For @ 2 25Y. oe \. eS Find a a Usiney Oreck: le 22 Ta at = ferme ncasureh ky the rine meter hel) TA mix bare a ele ee Fens meesitec fovy he te Covered un woler~ scale! wicle held rm MIxkre cy aolichatte saturation temp for o Ylven fp. Excrnele 27 For Tict hel = IFC Toy toa bs = Z2TC, QD-7 Fron Chart DPeaw2y, The Enthel By Scale For acl. sat. [PRESSES enthelyay const ok For~ cooling [heating : Y= h, to Thas oY can aasilv bse Foun fron electBxoneple 38 65). For previon . | OF PrEVISCUS Ceol incy examale * 4, tte a ye For QO Coe 1 arph qives : h, = 975.5 Ta dry ae Be pe Se eee ? eyreph Aives | he? TET ee ong. Vouk F US.5-14.7 = 1&.§ S/n