GROUP 16

*
1. Group 16 of the periodic table some times known 12. General electronic Configuration of Group-16
as - elements ?
1) Pnicogens 2) Chalcogens 1) nS2nP3 2) nS2 nP4
2 2
3) Halogen 4) None of these 3) nS nP 4) nS2 nP5
2. Most abundant of all element is 13. The correct order of covalent radius of Group-16
1) Oxygen 2) Sulphur element?
3) Selenium 4) Polonium 1) O > S > Se > Te > Po 2) Te > Po > O > S > Se

Y
3. Oxygen froms by mass of earth crust 3) Po > Te > Se > S > O 4) Po > Te > Se > O > S
1) 20.946% 2) 46.6% 14. Correct order of Ionic Radius Group-16 element ?
3) 0.03-0.1% 4) 3.50% 1) Po > Te > Se > S > O 2) O > S > Se > Te > Po
4. How much percentage of Dry air contain oxygen 3) Po > Te > Se > O > S 4) O > S > Se > Po > Te
volume? 15. Correct order of energy released electron gain
1) 46.6% 2) 20.946% Enthalpy Group-16 element?
3) 30% 4) 40% 1) S> Se > Te > Po > O 2) S > Te > Se > O > Po

I
5. How much percentage of abundane of sulphur in 3) S > Se > Po > Te > O 4) S> Po > Se > Te > O
the crust is? 16. Correct order of >melting TR> PoBoiling
Sex point, > point of
1) 0.1% 2) 0.03% DegH8-
Group-16 element? 0 small

3) 0.03-0.1% 4) 0.4% 1) O > S > Se > Po > Te 2) O > S > Se > Te > Po
sigh
6. Match the Column : 3) O > S > Te > Se >Po decreases
4) None of these
down the

P) Gypsum - - 1) CaSO4.2H2O 17. Correct order of Ionisation energy group

Q) Epsum - 2) MgSO4.7H2O 1) O > S > Se > Te 2) S > O > Se > Po > Te
R) Baryte - 3) BaSO4 3) O > S > Se > Te > Po 4) S > O > Po > Se > Te
S) Galena - 4) Pbs 18. Correct order of electronegativity Group-16
deceases down the
1) P–2, Q–1, R–3, S–4 2) P–1, Q–2, R–4, S–3
- -
element is group
3) P–3, Q–1, R–4, S–2 4) P–1, Q–2, R–3, S–4 1) O> S > Se > Te 2) S > O > Se > Te
- -
->

7. Organic material such as egg, proteins, garlic, 3) O > Se > S > Te 4) O > S > Te > Se
onion,mustard, hair and wool contain? 19. Correct order of electron affinity Group-16
AegH
1) Oxygen 2) Selenium 1) S > Se > Te > O 2) O > S > Se > Te
3) Polonium 4) Sulphur 3) O > Se > S > Te 4) S > O > Te > Se
8. Which element in Group 16 self decay? 20. Oxygen and Sulphur are ?
1) Oxygen 2) Sulphur 1) Metal 2) Non-metal
3) Polonium 4) Tellurium 3) Metalloids 4) Radioactive
9. What is Decay product of Polonium? 21. Selenium & Tellurium are?
1) Thorium 1) Metal 2) Metalloids
2) Livermorium 3) Non-metal 4) Radioactive
3) Thorium & Uranium minerals 22. Stability orders of +6 state top to down in Group-
4) None of these 16 is Higher ON
10. Synthetic Radioactive element in Group-16? 1) Increases 2) Decreases
1) Polonium (Po) 2) Livermorium 3) Neither increases nor decreases
3) Tellurium 4) none of these 4) None of these
11. What is atomic number, Atomic mass & electronic 23. What is the half life period of polonium?
Configuration of Livermorium Respectivelly? 1) 13 days 2) 13.2 days A YAAD
=

1) 116, 292, [Rn] 5f14 6d10 7S2 7P4 3) 13.8 days 4) 14 days
2) 116, 292, [Rn]5f14 6d10 S2 7P3 24. Which of the following hydrides of the oxygen
3) 292, 116, [Rn] 5f14 6d10 7S2 7P4 family shows the lowest boiling point?
BP
4) 116, 292, [Rn] 5f14 6d9 7S2 7P4 1) H2O 2) H 2 S Lowest=

. 3) H2Se 4) H2Te

Box Moll Mass

BP x H-BONA ING
 02 PARAMAGNETIC
NE
->

25. Reducing property of dioxide SO2 to TeO2 is 38. Incorrect about dioxygen gas is ↳ a unfaired e
1) Increases 2) Constant 1) It is colourless & odourless
3) Decreases * 4) None of these 2) Its soluble in water
26. Formation of EO2 & EO3 type oxide of sulphur are 3) It liquefies at 90 K and freeze at 55 K
1) Both basic in nature SO2 SO3 4) It is diamagnetic in nature
-
2) Both are acidic in nature 39. Dioxygen reacts directly with
Hide
3) Only basic in nature I) Metal II) Non-metal
4) None of these NCERT 1) I only 2) II only
27. The stability of the halides dereasing order is 3) Both 4) None
1) I– > Cl– > Br– > F– 2) F– > Cl– > Br– > I– 40. Dioxygen reacts with
3) F– > Cl– > I– > Br– 4) Cl– > F– > Br– > I– I) Au II) Pt
28. Hexafluorides & hexaclorides are 1) I only 2) II only
In blw lines
of
NCERT
1) Stable 3) Both 4) None
SFJ- exist-stable -> SHAADAR
2) Unstable does not exist grometry 41. Combination of oxygen is exothermic with
Suz-
3) Both stable & unstable ↳ Sterri I) Metal II) Non-metal
4) None of these 1) I only 2) II only
29. Nature of hexafluorides are 3) Both 4) None
1) Solid SFo(g) 2) Liquid 42. Following reaction catalytic used
V205
3) Gaseous 4) None of these ? =a PROCESS
2SO2 + O2 2SO3 CONTACT

30. What is Nature of SF4, SeF4 & TeF4 respectively?

1) Liquid, gas, solid 2) Solid, liquid, gas ?= b &AECON'S PROCESS
4HCl + O2 allz
2Cl2 + 2H2O
3) Gas, liquid, solid 4) None of these
1) VO & CuCl2 2) V2O5 & CuCl2
4 BP ILP
31. In SF4 Sulphur is +

3) V2O5 & Cu2Cl 4) None of these

1) dsp2-Hybridized sod 2) dsp3 - Hybridized
43. Incorrect about dioxygen is
3) d2sp3-Hybridized 4) sp3d- Hybridized
1) Used in welding
32. The correct order of decreasing stability of
2) Used in manufacturing of steel
Hexaflorides of Group-16 member is
3) Combution of fuel
1) SF6 > SeF6 > TeF6 2) TeF6 > SeF6 > SF6
4) As rocket fuel with ammonia
3) SF6 > TeF6 > SeF6 4) TeF6 > SF6 > SeF6
44. Which form mixed oxide
33. Hydrogen peroxide readily decompose into water
I) Mn II) Pb III) Fe
and dioxygen by
1) I and II 2) II and III
I) Fine metals II) MnO2
st 3) I and III 4) I, II and III
1) I Only 2) IInd Only
45. Which among acidic oxide ?
3) Both 4) None
I) SO2 -> II) Cl2O7->
34. Which method give oxygen gas ?
III) N2O5 -> IV) CO2 ->
I) Heating of silver oxide
1) I, II and III 2) II, III and IV
II) Heating of mercuric oxide
3) I, II and IV 4) I, II, III and IV
III) Heating of lead oxide
46. Which among the following correct is statement
1) ‘I’ and ‘II’ 2) ‘II’ and ‘III’
1) Non-metal oxide are basic in nature I
3) ‘I’ and ‘III’ 4) I, II, III
2) Metallic oxide always acidic in nature F
35. On large scale oxygen can be prepared
3) Semimetal oxides always amphoteric F
1) By heating of KClO3 =>
>

4) None of the above

2) By heating of Ag2O
47. SO2 combined with water gives
3) By decomposition of H2O2
1) H2SO 4 SO2 H,0-s42SO3 2) H2SO 3
+

4) By decomposition of water
3) H2SO 5 SOz 420- 42SOy 4) No reaction proceed
+

36. On electrolysis of water at cathode and anode

liberate respectively 48. Some metal in high oxidation state +5
which
+7
character is introduced Mnz07 V205
1) H2, SO2 2) H2, O2
1) Basic 2) Acidic
3) O2, H2 4) SO2, H2
3) Neutral 4) None of these
37. Which of the following isotopes is present in
largest amount ? 49. Al2O3 which type of oxide
1) O16 2) O17 1) Acidic 2) Basic
3) O 18
4) All in equal amounts . 3) Ampheteric 4) Neutral
 x
50. Al2O3(S) + 6HCl (aq) + 9H2O(l) ? + 6Cl–(aq) 63. Two oxygen-oxygen bond length & bond angle are
+3
1) 2[Al(H2O)6] (aq) 2) [Al(H2O)5]+3(aq) in ozone
3) [Al(H2O)6]+3(aq) 4) 2[Al(H2O)6]+3(aq) 1) 128 pm, 116o 2) 128 pm, 117o
51. CO, NO & N2O which type of oxide 3) 117 pm, 118o 4) 125 pm, 119o
1) Acidic 2) Basic 64. Most important allotropes of sulphur is
3) Neutral 4) None of these 1) Plastic sulphur
52. Ozone is ___ 2) -sulphur
1) An isobar of oxygen 3) -sulphur & -sulphur
2) An isotopes of oxygen 4) None of these
3) an polymer of oxygen 65. Transition temp of sulphur is
4) An Allotrop of oxygen 1) 300 K 2) 269 K
N
53. Ozone gas which nature found 3) 369 K 4) 370 K
77369
1) Diamagnetic 2) Ferrimagnetic 66. At allotropic equillibrium sulphur temp
<369
3) paramagnetic 4) ferromagnetic is greater than 369K then reaction goes
electric discharg e -7305
54. 3O2 ? Product 1) Back ward directin
203 2) Forward direction
1) O2 2) O
3) At equilibrium maintain
3) 2O3 4) None of these
4) None of these
55. Ozone formation process is Ozone-unstable
ENDO THERMIC
67. In nature of sulphur found in which form?
1) Exothermic 2) Endothermic
1) S 2 2) S 6
3) Isothermic 4) None of these
3) S 8 4) S
56. Pure ozone is found in which colour ?
68. S8 Shape and Hybridisatoin of each sulphur is
-- -

1) Voilet-black 2) Dark-blue
1) crown shape and Sp
3) Pale-blue 4) None of these
2) crown shape and Sp2
57. Liquid & solid ozone found in which colour ?
3) crown shape andSp3
1) Voilet-black & pale-blue
4) None of these
2) Pale-blue & dark blue
69. If T > 1000K then sulphur converted
3) Dark blue & violet black
1) S 6 2) S 8
4) None of these
3) S 2 4) S
58. Breathing of ozone becomes ___
70. Nature of S2 is O2-Para
1) Fever 2) Nausea Para
1) Paramagnetic Se
->
2) Diamagnetic
3) Headache & nausea 4) None of these
3) Ferromagnetic 4) none of these
59. Nascent oxygen acts as ____

ex
71. When sulphur burn in air or in O2 percentage of
1) Reducing agent 03-ox+
4 SO3 form with SO2 is
2) Oxidising agent oidisingagent 1) 1 to 2% 2) 3 to 5%
3) Neither oxidising nor reducing
3) 6 to 8% 4) 9 to 11%
4) None of these
72. In laboratory SO2 can form by
60. In the reaction I2
1) Combustion of sulphur
O3 + 2I– + H2O 2OH– + X + O2,
2) Oxidation of iron pyrite
The compound X is ___
3) With dil. Sulphuric acid react with sulphite
1) I2 2) IO3–
–
4) All of the above
3) IO4 4) I2O5
73. Incorrect about SO2
61. Estimation of ozone can be made quantitatively
1) Highly soluble in water
by ____
2) Pungent smell
1) Decomposition into O2 & absorption O2 into
pyrogallol 3) Colourless gas
2) Volume metric method using KI & titration of 4) Boils above room temperature

I
the liberated iodine using hypo solution 74. SO2 liquiefy at room temperature under pressure
3) Oxidative ozonolysis method 1) 1 atm 2) 2 atm
4) All methods given above 3) 3 atm 4) 100 atm
62. NO(g) + O3 NO2(g) + X 75. When excess of SO2 react with NaOH form
1) O2 2) N2O 1) Na2SO 3 2) NaHSO3
3) O3 4) NO .
⑲ . 3) Na2SO 4 4) NaHSO4
76. When SO2 react with chlorine form sulphuryl 87. When SO32 gas from catalytic converter absorbed
chloride in presence of catalyst in H2SO4 form H2SO4 SO2 +
H2S201
-

1) MnO2 2) CuCl2 1) H2SO 5 2) H2SO 3 dum -

3) V2O 5 4) Charcoal D 3) H2S2O7 4) H2S2O8

77. SO2 can reduce 88. SO3 + X H2S2O7 (oleum) X is
->
1) Fe2+ ion 2) MnO–4 1) H2SO 5 reson 2) H2SO 4
3) H 2 S 4) All of above 3) SO 3 4) SO 4
78. SO2 shape is 89. How much percentage of purity obtained
1) Angular ·xo 2) Sea-saw sulphuric acid in contact process is
3) Linear 4) Triangular planar 1) 92.96% 2) 93%
79. SO2 can use in 3) 96-98% 4) 100%
I) Refining of petrol and sugar T 90. Impurities of arsenic purified by ___ during
II) As a permanent bleaching agent F contact process.
III) As a disinfectant and preservative T 1) V2O 5 2) Ferrous oxide
1) I and II 2) II and III 3) Ferric oxide 4) All of the above
3) I and III 4) I, II and III 91. Incorrect about H2SO4
80. Out of HUs--
S O , H2S4O6, H2SO5 and H2S2O8 proxy
2 2 3 Bleaching
1) It is colourless liquid
H202
acid are: ↳ oxidation 2) Specific gravity 1.84 at 25oC
1) H2S2O3, H2S4O6↳ Prmanent
2) H2S4O6, H2SO5 3) Dissolve in water heat absorb
3)
SO2
Blacking
H2SO5, H2S2O8 4) H2S2O3, H2S2O8 4) Low volatile
agent
81. S–O–S linkage possible in 92. Low volatile nature of H2SO4 is due to
↳ reduction
1) ↳H2SO 5 2) H2S2O8 1) Hydrogen bonding 2) Vander waals force
3) H2S2Temporary
O7 4) H2S2O4 3) Strong bonds 4) None of these
82. Oleum formula 93. Correct about H2SO4
1) H2S2O7 42S207 2) H2S2O3 I) Highly volatile
3) H2S2O8 4) H2SO 5 II) Strong oxidizing agent
83. In contact process SO2 form by burning of III) High affinity for water
1) Sulphur 2) Sulphide 1) I and II 2) II and III
3) (1) and (2) Both 4) None 3) I and III 4) I, II, III
84. In the oxidation of SO2 by air in presence of V2O5 94. NaCl and NaNO3 react with conc. H2SO4 gives
favours formation of SO3 when&5002 5, sus 1) Cl2, NO 2) Cl2, NO2
P4
3
=
Pt molest
=>

1) Volume increase 2) Temperature increase 3) HCl, HNO3 4) HCl, NO2

3) Pressure increase 4) All of the above 95. When Cu and Carbon react with conc. H 2SO4
85. In contact process in oxidation of SO2 temperature gases liberate
should be 1) SO2 only 2) CO2 only
1) Very low 2) Low 3) Both (1) & (2) 4) CO2 & SO3
3) High 4) Very high 96. H2SO4 used in
86. Optimum pressure and temperature of contact I) Petrol refining II) In storage battery
NICERT
process is => III) Detergent formation IV) Rocket thurst
1) 1 bar and 500 K 2) 2 bar and 500 K 1) I, II, III 2) II, III, IV
3) 1 bar and 700 K 4) 2 bar and 700 K 3) I, III, IV 4) I, II, III, IV
↓
*

Ans er key
1. 2 11. 1 21. 2 31. 4 41. 3 51. 3 61. 2 71. 3 81. 3 91. 3
2. 1 12. 2 22. 2 32. 1 42. 2 52. 4 62. 1 72. 3 82. 1 92. 1
3. 2 13. 3 23. 2 33. 3 43. 4 53. 1 63. 2 73. 4 83. 3 93. 2
RCC * * RCC * *

4. 2 14. 1 24. 2 34. 4 44. 4 54. 3 64. 3 74. 2 84. 3 94. 3

5. 3 15. 1 25. 3 35. 4 45. 4 55. 2 65. 2 75. 2 85. 2 95. 3
6. 4 16. 4 26. 2 36. 2 46. 4 56. 3 66. 2 76. 4 86. 4 96. 1
7. 4 17. 3 27. 2 37. 3 47. 2 57. 3 67. 3 77. 2 87. 3
8. 3 18. 1 28. 3 38. 4 48. 2 58. 3 68. 3 78. 1 88. 2
9. 3 19. 1 29. 3 39. 3 49. 3 59. 2 69. 3 79. 3 89. 3
10. 2 20. 2 30. 3 40. 4 50. 1 70. 1 80. 3 90. 3
4 60. 1