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SAINT MARY’S UNIVERSITY

3700 BAYOMBONG, NUEVA VIZCAYA


SCHOOL OF HEALTH AND NATURAL SCIENCES
PHARMACY DEPARTMENT

Alkanes
Prepared by: Brent Jericko P. Narciso, RPh.
What are Alkanes?

→ The simplest type of organic compounds.


→ Alkanes are members of a larger class of
organic compounds called hydrocarbons.

Hydrocarbon
→ is a compound composed of only carbon
and hydrogen.
The 4 classes of Hydrocarbons.
Alkanes
▪ Alkanes are saturated hydrocarbons. *
▪ Saturated in this context means that each carbon in the
hydrocarbon has the maximum number of hydrogens
bonded to it.
▪ A hydrocarbon that contains one or more carbon–carbon
double bonds, triple bonds, or benzene rings is
classified as an Unsaturated hydrocarbon.
Alkanes

▪ We often refer to alkanes as aliphatic hydrocarbons because the


physical properties of the higher members of this class resemble those
of the long carbon-chain molecules. *
Alkanes
• All alkanes fit the general molecular
formula CnH2n + 2 , where n is the
number of carbon atoms. *
• Each member of this series differs
from the next higher and the next
lower member by a (-CH2) group
(methylene group).
• A series of compounds in which the
members are built up in a regular,
repetitive way like this is called a
homologous series. *
How Do We Write Structural Formulas of Alkanes?
The Structures of Alkanes
• Methane, CH4, and ethane, C2H6, are the first two members of the alkane
family. *
• The shape of methane is tetrahedral, and all H-C-H bond angles are 109.5°.
• Each carbon atom in ethane is also tetrahedral, and the bond angles in it are
all approximately 109.5° as well.
The Structures of Alkanes
Practice Problem 1:
1. Give an IUPAC name for the following compounds:

d. e.
Practice Problem 2:
What is the molecular formula of an alkane with:
1. 12 carbon atoms
2. 8 carbon atoms
3. 3 carbon atoms
4. 5 carbon atoms
5. 7 carbon atoms
THANK YOU.
• Aiko Narciso

• bjnarciso@smu.edu.ph

• bjnarciso@smu.edu.ph

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SAINT MARY’S UNIVERSITY
3700 BAYOMBONG, NUEVA VIZCAYA
SCHOOL OF HEALTH AND NATURAL SCIENCES
PHARMACY DEPARTMENT

(C) All rights reserved. No part of this lecture may be reproduced, distributed, or
transmitted in any form or by any means, including photocopying, recording, or
other electronic or mechanical methods including information storage and retrieval
systems, without the prior written permission of the publisher, in writing form the
author, except by reviewers who may quote brief passages in a review.
Sources:
▪ Introduction to General, Organic and Biochemistry
▪ Basic Organic Chemistry for the Life Sciences
▪ Foundations of Organic Chemistry by John McMurry

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