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    Shreetama Bhattacharya
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    This document describes a line compound in a phase diagram for a binary system. The diagram shows the two-phase equilibria between the liquid phase and either the Cd or Zn solid phases are unchanged by the compound. It also notes that the solubility limits in the Cd and Zn phases decrease due to the new stable compound phase. The eutectic points form where the liquid+Cd or liquid+Zn two-phase regions meet the liquid+compound two-phase regions.

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    This document describes a line compound in a phase diagram for a binary system. The diagram shows the two-phase equilibria between the liquid phase and either the Cd or Zn solid phases are unchanged by the compound. It also notes that the solubility limits in the Cd and Zn phases decrease due to the new stable compound phase. The eutectic points form where the liquid+Cd or liquid+Zn two-phase regions meet the liquid+compound two-phase regions.

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    © All Rights Reserved
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    17 views7 pages

    E2 Ans

    Uploaded by

    Shreetama Bhattacharya
    This document describes a line compound in a phase diagram for a binary system. The diagram shows the two-phase equilibria between the liquid phase and either the Cd or Zn solid phases are unchanged by the compound. It also notes that the solubility limits in the Cd and Zn phases decrease due to the new stable compound phase. The eutectic points form where the liquid+Cd or liquid+Zn two-phase regions meet the liquid+compound two-phase regions.

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    © All Rights Reserved
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    of 7

    Problem 4:

    b'
    b

    a'
    a

    e f

    The compound is drawn as a line compound for simplicity, though a compound


    with off-stoichiometry can also be drawn. Some particular features to look for:

    lines a, a’, b, b’: These represent the two-phase equilibria between the liquid and
    either the Cd or Zn phase. Nothing is changed to these equilibria as one
    introduces the compound. This can be easily seen by drawing the free energy
    curves for the system, with and without the compound.

    Cd
    Zn

    Compound

    Cd+L L+Zn

    L L
    XZn
    lines e and f: When a new stable appears the solubility limits in the adjoining
    phases decrease. Again, draw free energy curves to see this.

    points c and d: The eutectics are formed when the Cd+L (or Zn+L) two-phase
    region meets the Li+compound two-phase region.

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