CHEMISTRY-XI Chapter 8

INTRODUCTION TO CHEMICAL KINETICS

01. The branch of chemistry which deals with the study of rate of reaction and mechanism, called 1
__________.
a) Chemical kinetics b) Chemical reaction
c) Concentration reaction d) None of these A
02. The change in concentration of reactants or products per unit time, is called ______ 2
a) Acceleration b) Rate of reaction
c) Concentration of reaction d) None of these B
04. During the passage of time, concentration of product ________ 3
a) Decreases b) Null
c) Full d) Increases D
06. Physical and ___________ methods are the two main methods for the determination of reaction 4
rate.
a) Historical b) Chemical
c) Tangent d) Velocity B
08. In chemical method, the concentration of reactants or products is measured with the interval of 5
__________
a) Velocity b) Volume
c) Pressure d) Time D
12. The rate of reaction depends upon only one factor that is __________ 6
a) Temperature b) Water
c) Fire d) None of these A
14. The factor affects the rate of chemical reaction is ______________ 7
a) Heat b) Catalyst
c) Energy d) None of these B
15. The rate of chemical reaction is proportional to the molar _____ of reacting substances 8
a) Concentrations b) Molecules
c) Energy d) Volume A
16. A catalyst is a substance which is not consumed in a reaction but ________ the rate of reaction. 9
a) changes b) Homogeneous
c) Greater d) Catalyst A
17. Catalytic reactions are divided into ________ main types. 10
a) Three b) Two
c) Five d) Four B
18. The substance, which slows down a reaction, is called _________ 11
a) Inhibitor b) Reactant
c) Rate of law d) None of these A
19. Potassium is poisoned by ___________ 12
a) Inhibitors b) Zinc
c) Arsenic d) Calories C
02. The change in concentration of reactants or products per unit time is called. 13
a) Reaction rate b) Rate constant
c) Diffusion d) Chemical kinetic A
09. For a reaction system the minimum amount of energy which molecules must have not form an 14
activated complete is called.
a) Activation energy b) Ionization energy
c) Reaction energy d) None of the above A
10. The relation ship between rate of reaction and masses (molar concentration) of reacting substance 15
is summarized as.
a) Law of mass action b) Le-Chatelier principle
c) Charle’s law d) Ideal gas law A
11. The energy of activation is usually expressed in. 16
a) Joules b) Calories.
c) Ergs d) None of the above A
12. When catalyst and reactants are present in same phase, catalyst is called. 17
a) Homogeneous catalyst b) Heterogeneous
c) Organic catalyst d) None of the above A
13. The main function of catalyst is to. 18
a) Lower of activation energy b) Lower temperature
c) Increase in activation energy d) Lower pressure A

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 CHEMISTRY-XI Chapter 8
INTRODUCTION TO CHEMICAL KINETICS
14. Those substance which make catalyst more effective. 19
a) Accelerator b) Inhibitors
c) Promoter d) None of the above C
02. The reaction which may proceed slowly with measurable rate is called. 20
a) Slow reaction b) Fast reaction
c) Moderate reaction d) None of the above C
03. The branch of chemistry which deals with the study of reaction rates is known as. 21
a) Chemical kinetic b) Chemical equilibrium
c) Electro chemistry d) None of the above A
04. The experimental relationship between a reaction rate and the concentration of reactants is 22
called.
a) Order law b) Rate law
c) Moleculirity d) None of the above B
05. The change of concentration of reactants and products in a unit time. 23
a) Rate of reaction b) Order of reaction
c) Moleculirity d) None of the above A
06. The minimum amount of energy required to form an activated complex is called. 24
a) Reaction energy b) Activation energy
c) Deactivation energy d) None of the above B
07. The number of atoms or molecules whose concentration determined the rate of reaction is called. 25
a) Rate of reaction b) Order of reaction
c) Molecularity d) None of the above B
09. The velocity of reaction depends upon which of the following factors. 26
a) Nature of reactants b) Concentration of reactants
c) Temperature at which the reactants is carried out
d) All of the above D
10. If the velocity of reaction is independent of the concentration of the reaction, then it belongs to 27
which category of reactions.
a) Zero order reaction b) First order reaction
c) Second order reaction d) Third order reaction A
13. Ionic reaction are ________ than non ionic reactions. 28
a) Slower b) Moderate
c) Faster d) None of above C
15. I2+H2 → 2HI is ________ order reaction. 29
a) Second b) Zero
c) First d) Third A
17. In the presence of suitable catalyst , the rate of a reaction is. 30
a) Increases b) Decreases
c) Remains constant d) Increases as well as decrease A
20. The substance which decrease the effects of catalysts are. 31
a) Promoters b) Inhibitors
c) Specifity d) None of the above B
25. A chemical substance used to increase the rate of a chemical reaction is called. 32
a) Catalyst b) Catalysis
c) Inhibitors d) Promoters A
26. The reactions which proceed at moderate rates are. 33
a) Very fast b) Very slow
c) Normal d) High C
32. When there is an increase in concentration, the rate of reaction. 34
a) Increases b) Decreases
c) Remain constant d) None of above A
33. Ionic reactions such as neutralization reactions involving H+ and OH ions are usually 35
_________as compared to the molecular reactions.
a) Very fast b) Very slow
c) Sluggish d) None of these A
34. Molecular reactions usually proceed at. 36
a) Very fast rates b) Slow rates
c) Moderate rates d) Ordinary rates C

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 CHEMISTRY-XI Chapter 8
INTRODUCTION TO CHEMICAL KINETICS
38. With the increase in temperature, the rate of reaction. 37
a) Increases greatly b) Does not increase
c) Increases a little d) None of above A
39. The decrease in the catalytic property of catalyst is called the. 38
a) Poisoning of a catalyst b) Limit of a catalyst
c) Specifity of a catalyst d) None of the above A
40. The average rate of reaction between two intervals is _______ to the reaction rate at any moment. 39
a) Equal b) Not equal
c) Balanced d) Higher
B
41. The p H of water is greater at temperature of. 40
a) 140C b) 150C
c) 18 C 0
d) 250C A
42. Water at 250C is. 41
a) Neutral b) Acid
c) Basic d) None of the above A
43. Mercury is the best liquid for barometer, because. 42
a) Its high density keep the instrument small
b) It does not evaporate rapidly
c) It is unfairly reactive
d) All the above D
45. In a reaction A+ 2B  product, the molecularity of the reaction is given by 43
a) 3 b) 2
c) 1 d) 0 A
46. For a reaction 2A+B  product, the active mass of B is kept constant and that of A is doubled. 44
The rate of reaction will then.
a) Increases 2 times b) Increases 4 times
c) Decreases 2 times d) Decreases 4 times B
47. The rate law of for a chemical reaction N2O5 2NO2+1/2 O2 is shown as Rate=K[N2O5] identity 45
the order of the reaction.
a) First order b) Second order
c) Third order d) Zero order A
48. The rate law of chemical reaction 2NO2(g)  2NO(g)+O2(g) is represented by experience rate = 46
K[NO2]2 the order of reaction is.
a) First order b) Second order
c) Third order d) Zero order B
50. Consider the reaction H2 (g) +1(g)  2HI (g) the order of reaction for this is. 47
a) 1 b) 2
c) 3 d) 2.5 B
51. Reactions with high activation energy are. 48
a) Slow b) Fast
c) Moderate d) does not take place A
53. Use of catalyst in a reaction changes. 49
a) Enthalpy b) Entropy
c) Internal energy d) Activation energy D
57. A chemical reaction is characterized by. 50
a) Concentration b) Temperature
c) Catalyst d) All the above D
59. Kinetic energy is given by the. 51
a) K.E=1/2(mass of object) ¿ (velocity of object)2
b) K.E=(mass of object) ¿ (velocity of object)2
c) K.E=1/2(mass of object) ¿ (velocity of object)
d) K.E=1/2(mass of object)2 ¿ (velocity of object) A
66. In the chemical reaction XClO2+Y  X Cl+O2+Y, which of the substance is a catalyst? 52
a) XCIO2 b) Y
c) XCl d) O2 B
687. The rate reaction depends up. 53
a) Concentration b) Temperature
c) Catalyst d) All of these D

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 CHEMISTRY-XI Chapter 8
INTRODUCTION TO CHEMICAL KINETICS
689. The rate of reaction is expressed in units of 54
a) Mol dm-3s-1 b) Mol dm-3s
c) Mol dm s 3
d) Mol-1 dm3s-1 A
690. Rate of a reaction can be determined by 55
a) Physical method b) Chemical method
c) Both methods d) None of these C
691. The number of atoms or molecules whose concentrations determine the rate of the reaction is 56
called
a) Molecularity b) Order
c) Rate of reaction d) Rate constant B
693. The rate constant depends on 57
a) Solvent b) Pressure
c) Temperature d) All these D
694. The rate of reaction depends on 58
a) Catalyst b) Concentration
c) Temperature d) All these D
696. According to Bronsted concept, the strength of an acid is measured from its tendency to donate 59
a) Electron b) Neutron
c) Proton d) Positron C
697. The order of decreasing strength of halogen acids is 60
a) HI > HCl > HBr b) HBr >HCl > HI
c) HI > HBr >HCl d) HCl > HI> HBr C
698. Phenalphthalein is an example of 61
a) Redox indicator b) Acid-base indicator
c) Precipitation indicator d) None of these B
699. The colour of phenolphthalein in acidic medium is 62
a) Red b) Yellow
c) Orange d) Colourless D
700. The colour of methyl orange in alkaline medium is 63
a) Red b) Yellow
c) Blue d) Colourless B
704. When ice melts, then it takes place 64
a) Physical change b) Chemical change
c) No change d) All possible A
705. Total number of atoms or molecules taking part in a chemical reaction is known as 65
a) order b) Molecularity
c) rate constant d) rate of reactions B
706. The rate of reaction depends upon 66
a) initial concentration of reactants b) extent of reaction
c) temperature d) time of reaction C
707. Which of the following factors does not influenced the rate of reaction? 67
a) concentration of the reactants b) nature of the reactants
c) molecularity of the reaction d) temperature C
708. The activation energy of a reaction may be lowered 68
a) by raising the temperature b) by lowering the temperature
c) by removing the products d) by adding a catalyst D
709. If the rate of reaction is independent of the concentration of the reactant, the reaction is of 69
a) zero order b) first order
c) second order d) third order A
716. Those substances which slow down a reaction are called 70
a) catalysts b) promoters
c) inhibitors d) none of these C
718. Which of the following act as inhibitor? 71
a) As b) pyridine
c) quinoline d) all these D
719. The specific rate constant of a first order reaction depends on the: 72
a) Concentration of reactant b) Concentration of product
c) Time d) Temperature D

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 CHEMISTRY-XI Chapter 8
INTRODUCTION TO CHEMICAL KINETICS
720. A zero order reaction is one: 73
a) In which reactants do not react b) In which one of the reactant is in large excess
c) Whose rate is not affected by concentration
d) Whose rate is independent of temperature D
724. For the single step reaction 2A + B ------------> A2B, Rate =? 74
a) K [A] [B] b) K [A] [B]2
c) K [A] [B]
2
d) K [A]2 [B]2 C

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