Chapter 11

Chemistry: The Central Science, 14e (Brown, et al.
)
Chapter 11 Liquids and Intermolecular Forces
11.1 Multiple-Choice Questions
1) Crystalline solids ________.

A) have their particles arranged randomly
B) have ordered structures
C) are usually very soft
D) exist only at high temperatures
E) exist only at very low temperatures
Answer: B
Diff: 1 Var: 1 Page Ref: Sec. 11.1
LO: 11.1
GO: G2
2) In liquids, the attractive intermolecular forces are ________.

A) very weak compared with kinetic energies of the molecules
B) strong enough to hold molecules relatively close together
C) strong enough to keep the molecules confined to vibrating about their fixed lattice points
D) not strong enough to keep molecules from moving past each other
E) strong enough to hold molecules relatively close together but not strong enough to keep
molecules from moving past each other
Answer: E
LO: 11.1
GO: G2
3) As a gaseous element condenses, the atoms become ________ and they have ________
attraction for one another.
A) more separated, more
B) more separated, less
C) closer together, more
D) closer together, less
E) larger, greater
Answer: C
LO: 11.1
GO: G2
1
Copyright © 2018 Pearson Education, Inc.
4) A gas is ________ and assumes ________ of its container, whereas a liquid is ________ and
assumes ________ of its container.
A) compressible, the volume and shape, not compressible, the shape of a portion
B) compressible, the shape, not compressible, the volume and shape
C) compressible, the volume and shape, compressible, the volume
D) condensed, the volume and shape, condensed, the volume and shape
E) condensed, the shape, compressible, the volume and shape
Answer: A
LO: 11.1
GO: G2
5) Together, liquids and solids constitute ________ phases of matter.

A) the compressible
B) the fluid
C) the condensed
D) all of the
E) the disordered
Answer: C
LO: 11.1
GO: G2
6) Which statement is true about liquids but not true about solids?
A) They flow and are highly ordered.
B) They are highly ordered and not compressible.
C) They flow and are compressible.
D) They assume both the volume and the shape of their containers.
E) They flow and are not compressible.
Answer: E
LO: 11.1
GO: G2
7) The strongest interparticle attractions exist between particles of a ________, and the weakest
interparticle attractions exist between particles of a ________.
A) solid, liquid
B) solid, gas
C) liquid, gas
D) liquid, solid
E) gas, solid
Answer: B
LO: 11.1
GO: G2
2
8) Which species has London dispersion forces as the only intermolecular force?
A) CH3CH2OH
B) Ar
C) NH3
D) HBr
E) H2O
Answer: B
LO: 11.1
GO: G2
9) Which molecule has hydrogen bonding as the predominant intermolecular force?

A) CH4
B) C6H6
C) CH3OH
D) CO2
E) C4H10
Answer: C
LO: 11.1
GO: G2
10) Which species has London dispersion forces as the only intermolecular force?
A) KBr
B) HI
C) CH3OH
D) CH3CH3
E) CH3F
Answer: D
LO: 11.1
GO: G2
11) When KBr dissolves in water, aqueous K+ and Br- ions result. The force of attraction that
exists between K+ and H2O is called a(n) ________ interaction.
A) dipole-dipole
B) ion-dipole
C) ion-ion
D) London dispersion force
E) hydrogen bonding
Answer: B
LO: 11.1
GO: G2
3
12) ________ are particularly polarizable.
A) Small nonpolar molecules
B) Small polar molecules
C) Large nonpolar molecules
D) Large polar molecules
E) Large molecules, regardless of their polarity,
Answer: E
LO: 11.2
GO: G2
13) The ease with which the charge distribution in a molecule can be distorted by an external
electrical field is called the ________.
A) electronegativity
B) hydrogen bonding
C) polarizability
D) volatility
E) viscosity
Answer: C
LO: 11.2
GO: G2
14) The intermolecular force(s) responsible for the fact that CH4 has the lowest boiling point in
the set CH4, CH3CH3, CH3CH2CH3, CH3CH2CH2CH3 is/are ________.
A) hydrogen bonding
B) London dispersion forces
C) mainly hydrogen bonding but also dipole-dipole interactions
D) dipole-dipole interactions
E) mainly London-dispersion forces but also dipole-dipole interactions
Answer: B
LO: 11.1
GO: G2
15) Elemental iodine (I2) is a solid at room temperature. What is the major attractive force that
exists among different I2 molecules in the solid?
A) London dispersion forces
B) dipole-dipole interactions
C) ionic-dipole interactions
D) covalent-ionic interactions
E) dipole-dipole attractions
Answer: A
LO: 11.1
GO: G2
4
16) Hydrogen bonding is a special case of ________.
A) London-dispersion forces
B) ion-dipole attraction
C) dipole-dipole attractions
D) ion-ion interactions
E) none of the above
Answer: C
LO: 11.1
GO: G2
5
17) Which one of the following substances will have hydrogen bonding as one of its
intermolecular forces?
A)
B)
C)
D)
E)
Answer: D
LO: 11.1
GO: G2
6
18) Which one of the following substances will not have hydrogen bonding as one of its
intermolecular forces?
A)
B)
C)
D)
E)
Answer: A
LO: 11.1
GO: G2
7
19) What intermolecular force is responsible for the fact that ice is less dense than liquid water?
B) dipole-dipole forces
C) ion-dipole forces
D) hydrogen bonding
E) ionic bonding
Answer: D
LO: 11.1
GO: G2
20) The predominant intermolecular force in water is ________.

B) hydrogen bonding
C) ion-dipole forces
D) dipole-dipole forces
E) ionic bonding
Answer: B
LO: 11.1
GO: G2
21) Octane C8H18 molecules are held together by ________.

A) ion-ion interactions
B) hydrogen bonding
C) ion-dipole interactions
D) London dispersion forces
E) dipole-dipole interactions
Answer: D
LO: 11.1
GO: G2
22) Which of the following molecules has hydrogen bonding as its only intermolecular force?
A) HCl
B) NH3
C) H2O
D) CH3OH
E) None, all of the above exhibit dispersion forces.
Answer: E
LO: 11.1
GO: G2
8
23) Which of the following molecules has London Forces as its only intermolecular force?
A) H2O
B) CH3CH2NH2
C) HOCH2CH2OH
D) CH3CH3
E) None, all of the above exhibit dispersion forces.
Answer: D
LO: 11.1
GO: G2
24) What types of intermolecular forces exist between CH3OH and H2O?
A) dipole-dipole and ion-dipole
B) dispersion forces, dipole-dipole, and hydrogen bonding
C) dispersion forces, dipole-dipole, and ion-dipole
D) dispersion forces, hydrogen bonding, dipole-dipole, and ion-dipole
E) dispersion forces and ion-dipole
Answer: B
LO: 11.1
GO: G2
25) What type(s) of intermolecular forces exist between Cl2 and CCl4?
A) dispersion forces and ion-dipole
B) dispersion forces and dipole-dipole
C) dispersion forces
D) dispersion forces, ion-dipole, and dipole-dipole
E) None. Since both are gases at room temperature, they do not interact with each other.
Answer: C
LO: 11.1
GO: G2
26) What type(s) of intermolecular forces exist between NH3 and PO43-?
A) dispersion forces
B) dispersion forces, ion-dipole, and dipole-dipole
C) dispersion forces and dipole-dipole
D) dispersion forces and ion-dipole
E) dispersion forces, ion-dipole, dipole-dipole, and hydrogen bonds
Answer: D
LO: 11.1
GO: G2
9
27) What types of intermolecular forces exist between NH3 and H2O?
A) dispersion forces
B) dispersion forces and hydrogen bonds
C) dispersion forces and ion-dipole forces
D) dispersion forces, dipole-dipole forces, and hydrogen bonds
E) dispersion forces, hydrogen bonds, and ion-dipole forces
Answer: D
LO: 11.1
GO: G2
28) What types of intermolecular forces exist between water and HF?
A) dispersion forces and dipole-dipole forces
B) dispersion forces, dipole-dipole forces, and hydrogen bonds
C) dispersion forces and hydrogen bonds
D) dispersion forces
E) dispersion forces, hydrogen bonds, and ion-dipole forces
Answer: B
LO: 11.1
GO: G2
29) ________ is the energy required to expand the surface area of a liquid by a unit amount of
area.
A) Viscosity
B) Surface tension
C) Volatility
D) Meniscus
E) Capillary action
Answer: B
LO: 11.3
GO: G2
10
30) Which statements about viscosity are true?
(i) Viscosity increases as temperature decreases.

(ii) Viscosity increases as molecular weight increases.
(iii) Viscosity increases as intermolecular forces increase.
A) (i) only
B) (ii) and (iii)
C) (i) and (iii)
D) none
E) all
Answer: E
LO: 11.3
GO: G2
31) The shape of a liquid's meniscus is determined by ________.

A) the viscosity of the liquid
B) the type of material the container is made of
C) the relative magnitudes of cohesive forces in the liquid and adhesive forces between the liquid
and its container
D) the amount of hydrogen bonding in the liquid
E) the volume of the liquid
Answer: C
LO: 11.3
GO: G2
32) Viscosity is ________.

A) the "skin" on a liquid surface caused by intermolecular attraction
B) the resistance to flow
C) the same as density
D) inversely proportional to molar mass
E) unaffected by temperature
Answer: B
LO: 11.3
GO: G2
11
33) How high a liquid will rise up a narrow tube as a result of capillary action depends on
________.
A) the magnitudes of cohesive forces in the liquid and adhesive forces between the liquid and the
tube, and gravity
B) gravity alone
C) only the magnitude of adhesive forces between the liquid and the tube
D) the viscosity of the liquid
E) only the magnitude of cohesive forces in the liquid
Answer: A
LO: 11.3
GO: G2
34) The property responsible for the "beading up" of water is ________.
A) density
B) viscosity
C) vapor pressure
D) surface tension
E) hydrogen bonding
Answer: D
LO: 11.3
GO: G2
35) Heat of sublimation can be approximated by adding together ________ and ________.
A) heat of fusion, heat of condensation
B) heat of fusion, heat of vaporization
C) heat of freezing (solidification), heat of condensation
D) heat of freezing (solidification), heat of vaporization
E) heat of deposition, heat of vaporization
Answer: B
LO: 11.4
GO: G2
12
36) Which of the following statements is false?
A) The absolute value of the heat of sublimation is equal to the absolute value of the heat of
deposition.
B) The heat of sublimation is equal to the sum of the heat of vaporization and the heat of
deposition.
C) The heat of sublimation is equal to the sum of the heat of vaporization and the heat of
freezing.
D) The absolute value of the heat of sublimation is equal to the absolute value of the sum of the
heat of condensation and the heat of freezing.
E) The absolute value of the heat of deposition is equal to sum of the absolute value of the heat
of vaporization and the absolute value of the heat of freezing.
Answer: C
LO: 11.4
GO: G2
37) The ________ (is)are associated with the heat energy being used up to increase distances
between molecules.
A) phase change B → C
B) phase changes B → C and D → E
C) phase change D → E
D) phase change B → E
E) phase change C → E
Answer: B
LO: 11.5
GO: G3
13
38) Based on the following information, which compound has the strongest intermolecular
forces?
Substance ΔHvap (kJ/mol)

Argon (Ar) 6.3
Benzene (C6H6) 31.0
Ethanol (C2H5OH) 39.3
Water (H2O) 40.8
Methane (CH4) 9.2
A) Argon
B) Benzene
C) Ethanol
D) Water
E) Methane
Answer: D
LO: 11.4
GO: G3
39) Which compound has the strongest intermolecular forces?

A) CCl4
B) CI4
C) CH4
D) H2
E) O2
Answer: B
LO: 11.4
GO: G2
40) Large intermolecular forces in a substance are manifested by ________.

A) low vapor pressure
B) high boiling point
C) high heats of fusion and vaporization
D) high critical temperatures and pressures
E) all of the above
Answer: E
LO: 11.4
GO: G2
14
41) A supercritical fluid can expand like a ________ to fill a container and has a density similar
to that of a ________ so can behave as a solvent.
A) gas, plasma
B) gas, solid
C) solid, gas
D) liquid, gas
E) gas, liquid
Answer: E
LO: 11.4
GO: G2
42) The critical temperature and pressure of CS2 are 279 °C and 78 atm, respectively. A
supercritical fluid can only exist at a temperature ________ 279 °C and pressure ________ 78
atm.
A) exactly, exactly
B) above, below
C) above, above
D) below, above
E) below, below
Answer: C
LO: 11.4
GO: G2
43) The substance with the largest heat of vaporization is ________.

A) H2
B) Cl2
C) I2
D) N2
E) O2
Answer: C
LO: 11.4
GO: G2
44) Of the following, ________ is an exothermic process.

A) melting
B) subliming
C) freezing
D) boiling
E) All of the above are exothermic.
Answer: C
LO: 11.4
GO: G2
15
45) Of the following, ________ should have the highest critical temperature.
A) CBr4
B) CCl4
C) CF4
D) CH4
E) H2
Answer: A
LO: 11.6
GO: G2
46) A volatile liquid is one that ________.

A) is highly flammable
B) is highly viscous
C) is highly hydrogen-bonded
D) is highly cohesive
E) readily evaporates
Answer: E
LO: 11.6
GO: G2
47) In general, the vapor pressure of a substance increases as ________ increases.

A) surface tension
B) molecular weight
C) hydrogen bonding
D) viscosity
E) temperature
Answer: E
LO: 11.6
GO: G2
48) The vapor pressure of any substance at its normal boiling point is ________.
A) 1 Pa
B) 1 torr
C) 1 atm
D) equal to atmospheric pressure
E) equal to the vapor pressure of water
Answer: C
LO: 11.6
GO: G2
16
49) Volatility and vapor pressure are ________.
A) inversely proportional to one another
B) directly proportional to one another
C) not related
D) the same thing
E) both independent of temperature
Answer: B
LO: 11.6
GO: G2
50) Some things take longer to cook at high altitudes than at low altitudes because ________.
A) water boils at a lower temperature at high altitude than at low altitude
B) water boils at a higher temperature at high altitude than at low altitude
C) heat isn't conducted as well in low density air
D) natural gas flames don't burn as hot at high altitudes
E) there is a higher moisture content in the air at high altitude
Answer: A
LO: 11.6
GO: G2
51) The vapor pressure of a liquid ________.

A) increases linearly with increasing temperature
B) increases nonlinearly with increasing temperature
C) decreases linearly with increasing temperature
D) decreases nonlinearly with increasing temperature
E) is totally unrelated to its molecular structure
Answer: B
LO: 11.6
GO: G2
52) - is the slope of a plot of the natural log of the vapor pressure of a substance versus
________.
A) -1/T
B) -T
C) 1/T
D) T
E) 2T
Answer: C
LO: 11.6
GO: G2
17
53) On a phase diagram, the critical pressure is ________.
A) the pressure required to melt a solid
B) the pressure below which a substance is a solid at all temperatures
C) the pressure above which a substance is a liquid at all temperatures
D) the pressure at which a liquid changes to a gas
E) the pressure required to liquefy a gas at its critical temperature
Answer: E
LO: 11.6
GO: G2
54) On a phase diagram, the critical temperature is ________.

A) the temperature below which a gas cannot be liquefied
B) the temperature above which a gas cannot be liquefied
C) the temperature at which all three states are in equilibrium
D) the temperature required to melt a solid
E) the temperature required to cause sublimation of a solid
Answer: B
LO: 11.6
GO: G2
55) On a phase diagram, the melting point is the same as ________.

A) the triple point
B) the critical point
C) the freezing point
D) the boiling point
E) the vapor-pressure curve
Answer: C
LO: 11.6
GO: G2
56) When the phase diagram for a substance has a solid-liquid phase boundary line that has a
________ slope, the substance can go from solid to liquid, within a small temperature range, via
the application of pressure.
A) positive
B) zero
C) y = 1
D) negative
E) y = 0
Answer: D
LO: 11.7
GO: G2
18
57) The predominant intramolecular force in CaBr2 is ________.
B) ion-dipole forces
C) ionic bonding
D) dipole-dipole forces
E) hydrogen bonding
Answer: C
LO: 11.8
GO: G2
58) Which of the following is most likely to exhibit liquid-crystalline behavior?

A) CH3CH2-C(CH3)2-CH2CH3
B) CH3CH2CH2CH2CH2CH2CH2CH3
C) CH3CH2CH2CH2CH2-
D)
E)
Answer: E
LO: 11.8
GO: G2
59) All of the following are characteristics of liquid crystal behavior except ________.
A) long axial structure
B) carbon-carbon single bonds
C) double bonding
D) ionic configuration
E) polar groups
Answer: D
LO: 11.8
GO: G2
19
60) In the ________ liquid-crystalline phase,the molecules are arranged in sheets, with their long
axes parallel and their ends aligned as well.
A) smectic B
B) smectic C
C) smectic A
D) smectic E
E) smectic D
Answer: C
LO: 11.8
GO: G2
61) In the ________ liquid crystalline phase, the component molecules exhibit ________
dimensional ordering.
A) nematic, one
B) smectic A, one
C) nematic, two
D) nematic, three
E) smectic B, one
Answer: A
LO: 11.8
GO: G2
62) What are the common types of smectic liquid-crystalline phases?

A) A, C, and D
B) A only
C) A and C
D) A and D
E) C and D
Answer: C
LO: 11.8
GO: G2
63) ________ liquid crystals are colored because the molecular layers are arranged in slightly
twisted planes with respect to one another.
A) smectic B
B) cholesteric
C) smectic A
D) smectic C
E) smectic D
Answer: B
LO: 11.8
GO: G2
20
64) Molecules with ________ do not generally exhibit liquid-crystalline properties because they
lack the rigidity necessary for alignment.
A) both single and double bonds
B) double or triple bonds
C) single, double, and triple bonds
D) only single bonds
E) only single and double bonds
Answer: D
LO: 11.8
GO: G2
65) For a given substance that exhibits liquid-crystalline properties, the transition from solid to
liquid-crystal state occurs ________.
A) over a range of temperatures between the melting point of the solid and the boiling point of
the liquid
B) at the melting point of the solid
C) over a range of temperatures that includes the melting point of the solid
D) at a well-defined temperature above the melting point of the solid
E) at a well-defined temperature below the melting point of the solid
Answer: B
LO: 11.8
GO: G2
66) There are ________ types of smectic liquid-crystalline phases.

A) 6
B) 5
C) 2
D) 3
E) 4
Answer: D
LO: 11.8
GO: G2
21
11.2 Bimodal Questions
1) Based on molecular mass and dipole moment of the five compounds in the table below, which
should have the highest boiling point?
A) CH3CH2CH3
B) CH3OCH3
C) CH3Cl
D) CH3CHO
E) CH3CN
Answer: E
LO: 11.1
GO: G3
22
2) The heating curve shown was generated by measuring the heat flow and temperature for a
solid as it was heated. The slope of the ________ segment corresponds to the heat capacity of the
liquid of the substance.
A) AB
B) BC
C) CD
D) DE
E) EF
Answer: C
LO: 11.5
GO: G3
solid as it was heated. The slope of the ________ segment corresponds to the heat capacity of the
solid.
A) AB
B) BC
C) CD
D) DE
E) EF
Answer: A
LO: 11.5
GO: G3
23
solid as it was heated. The slope of the E-F segment corresponds to the heat capacity of the
________.
A) liquid-gas
B) solid-gas
C) gas
D) solid
E) liquid
Answer: C
LO: 11.5
GO: G3
5) The heating curve shown was generated by measuring the heat flow and temperature of a solid
as it was heated. The heat flow into the sample in the segment D-E will yield the value of the
________ of this substance.
A) ΔHsub
B) ΔHvap
C) ΔHmelting
D) ΔHfusion
E) ΔHrxn
Answer: B
LO: 11.5
GO: G3
6) The heating curve shown was generated by measuring the heat flow and temperature of a solid
as it was heated. The heat flow into the sample in the segment ________ will yield the value of
the ΔHfusion of this substance.
A) AB
B) BC
C) CD
D) DE
E) EF
Answer: B
LO: 11.5
GO: G3
24
7) On the phase diagram shown above, segment ________ corresponds to the conditions of
temperature and pressure under which the solid and the gas of the substance are in equilibrium.
A) AB
B) AC
C) AD
D) CD
E) BC
Answer: B
LO: 11.7
GO: G3
8) On the phase diagram shown above, the coordinates of point B corresponds to the ________.
A) critical temperature and pressure
B) critical pressure
C) critical temperature
D) boiling point
E) triple point
Answer: A
LO: 11.7
GO: G3
25
9) On the phase diagram shown above, the coordinates of point ________ correspond to the
triple point.
A) A
B) B
C) C
D) D
E) E
Answer: A
LO: 11.7
GO: G3
10) The phase diagram of a substance is given above. The region that corresponds to the solid
phase is ________.
A) w
B) x
C) y
D) z
E) x and y
Answer: A
LO: 11.7
GO: G3
26
11) According to the phase diagram shown above, what is the normal boiling point (°C)?
A) 10
B) 20
C) 30
D) 40
E) 50
Answer: D
LO: 11.7
GO: G3
12) According to the phase diagram shown above, what is the normal melting point (°C)?
A) 15
B) 25
C) 35
D) 45
E) 55
Answer: A
LO: 11.7
GO: G3
27
13) The phase diagram of a substance is shown above. The area labeled ________ indicates the
gas phase for the substance.
A) w
B) x
C) y
D) z
E) y and z
Answer: C
LO: 11.7
GO: G3
solid phase for the substance.
A) w
B) x
C) y
D) z
E) y and z
Answer: A
LO: 11.7
GO: G3
liquid phase for the substance.
A) w
B) x
C) y
D) z
E) y and z
Answer: B
LO: 11.7
GO: G3
28
16) According to the phase diagram shown above, what is the normal boiling point (°C)?
A) 10
B) -3
C) 38
D) 29
E) 0
Answer: D
LO: 11.7
GO: G3
17) According to the phase diagram shown above, what is the normal melting point (°C)?
A) -13
B) 0
C) 38
D) 10
E) 29
Answer: B
LO: 11.7
GO: G3
18) A ________ liquid crystal has the least order and is the most liquid-like.
A) nematic
B) smectic
C) cholesteric
D) smectic C
E) smectic B
Answer: A
LO: 11.8
GO: G2
19) ________ liquid crystals are colored and change color with temperature changes.
A) Smectic A
B) Nematic
C) Cholesteric
D) Smectic B
E) Smectic C
Answer: C
LO: 11.8
GO: G2
29
11.3 Algorithmic Questions
1) As a gaseous element condenses, the atoms become ________ and they have ________
attraction for one another.
A) less separated, more
B) less separated, less
C) more separated, more
D) more separated, less
E) smaller, lesser
Answer: A
LO: 11.1
GO: G2
2) What is the predominant intramolecular force in NaNO3?

A) ionic bonding
C) dipole-dipole attraction
D) hydrogen bonding
E) London-dispersion forces
Answer: A
LO: 11.1
GO: G2
3) With what compound will NH3 experience only dispersion intermolecular forces?
A) BF3
B) LiF
C) CH3I
D) CH3OH
E) HCN
Answer: A
Diff: 2 Var: 50+ Page Ref: Sec. 11.2
LO: 11.1
GO: G2
30
4) With what compound will NH3 experience only ion-dipole intermolecular forces?
A) LiCl
B) SiH4
C) CH3I
D) C3H7OH
E) OCl2
Answer: A
LO: 11.1
GO: G2
5) Which one of the following exhibits dipole-dipole attraction between molecules?

A) HCl
B) CF4
C) CS2
D) F2
E) BI3
Answer: A
LO: 11.1
GO: G2
6) Which one of the following exhibits dipole-dipole attraction between molecules?

A) NH3
B) CF4
C) C10H22
D) O2
E) SF6
Answer: A
LO: 11.1
GO: G2
31
7) Of the following substances, only ________ has London dispersion forces as its only
intermolecular force.
A) CCl4
B) SnF3
C) CH3OH
D) HI
E) H2O
Answer: A
LO: 11.1
GO: G2
8) Which of the following has London dispersion forces as its only intermolecular force?
A) NBr3
B) CH3COOH
C) SiCl4
D) HBr
E) Cl2O
Answer: C
LO: 11.1
GO: G2
9) Which molecule has the lowest boiling point?

A) CH3CH2CH2CH3
B) CH3CH2CH3
C) CH3CH3
D) CH4
E) H2O
Answer: D
LO: 11.1
GO: G2
10) Which one of the following should have the lowest boiling point?
A) CH4
B) PCl3
C) C2H5COOH
D) LiCl
E) Cl2S
Answer: A
LO: 11.1
32
GO: G2
11) Of the following substances, ________ has the highest boiling point.
A) H2O
B) SiH4
C) Ar
D) Cl2
E) BF3
Answer: A
LO: 11.1
GO: G2
A) HOCH2CH2CH2OH
B) CH3CH2OH
C) C4H10
D) N2
E) Cl2
Answer: A
LO: 11.1
GO: G2
A) Br2
B) N2
C) Cl2
D) O2
E) H2
Answer: A
LO: 11.1
GO: G2
33
14) Which one of the following derivatives of methane has the highest boiling point?
A) CI4
B) CBr4
C) CCl4
D) CF4
E) CH4
Answer: A
LO: 11.1
GO: G2
15) What is the predominant intermolecular force in CH4?

C) ionic bonding
D) dipole-dipole attraction
E) hydrogen bonding
Answer: A
LO: 11.1
GO: G2
16) What is the predominant intermolecular force in H2NNH2?

A) hydrogen bonding
C) ionic bonding
D) dipole-dipole attraction
E) London-dispersion forces
Answer: A
LO: 11.1
GO: G2
17) What is the predominant intermolecular force in HCN?

A) dipole-dipole attraction
C) ionic bonding
D) hydrogen bonding
E) London dispersion forces
Answer: A
LO: 11.1
GO: G2
34
18) Ethanol melts at -114 °C and boils at 78 °C at a constant pressure of 1 atm. What state of
matter must a sample of ethanol be in at 0°C and 1 atm?
A) liquid
B) gas
C) solid
D) solid and liquid in equilibrium
E) liquid and gas in equilibrium
Answer: A
LO: 11.4
GO: G2
19) At 1 atm, an unknown sample melts at 49.9 °C and boils at 209.5 °C. If the temperature is
0°C, what is the state of matter for the sample?
A) solid and liquid in equilibrium
B) liquid
C) gas
D) solid
E) liquid and gas in equilibrium
Answer: D
LO: 11.4
GO: G2
20) The enthalpy change for converting 1.00 mol of ice at -25.0 °C to water at 50.0 °C is
The specific heats of ice, water, and steam are and
respectively. For O, Δ = 6.01 kJ/mol, and .
A) 12.28
B) 6.27
C) 10.71
D) 4709
E) 8.83
Answer: C
LO: 11.5
GO: G4
35
21) The enthalpy change for converting 10.0 g of ice at -50.0 °C to water at 50.0 °C is ________
kJ. The specific heats of ice, water, and steam are and
respectively. For O, Δ = 6.01 kJ/mol, and .
A) 12.28
B) 4.38
C) 3138
D) 6.47
E) 9.15
Answer: D
LO: 11.5
GO: G4
22) The heat of fusion of water is 6.01 kJ/mol. The heat capacity of liquid water is 75.3 J/mol ∙
K. The conversion of of ice at 0.00 °C to liquid water at 0.00°C requires ________ kJ of
heat.
A) 6.01
B) 16.7
C) 75.3
D) 17.2
E) Insufficient data are given.
Answer: B
LO: 11.5
GO: G4
23) Calculate the enthalpy change (in kJ) associated with the conversion of 25.0 grams of ice at -
4.00 °C to water vapor at 109.0 °C. The specific heats of ice, water, and steam are 2.09 J/g-K,
4.18 J/g-K, and 1.84 J/g-K, respectively. For H2O, Δ = 6.01 kJ/mol and Δ = 40.67
kJ/mol.
A) 64.8
B) 75.9
C) 11100
D) 12000
E) 112
Answer: B
LO: 11.5
GO: G4
36
24) Ethanol ( OH) melts at -114 °C. The enthalpy of fusion is 5.02 kJ/mol. The specific
heats of solid and liquid ethanol are 0.97 J/g-K and 2.3 J/g-K, respectively. How much heat (kJ)
is needed to convert 25.0 g of solid ethanol at -135 °C to liquid ethanol at -60 °C?
A) 207.3
B) -13.3
C) 6.34
D) 3617
E) 8.63
Answer: C
LO: 11.5
GO: G4
25) Of the following, ________ is the most volatile.

A) C2H6
B) C2I6
C) C2Br6
D) C2Cl6
E) C2F6
Answer: A
LO: 11.6
GO: G2
26) Which molecule is the least volatile?

A) CH3Cl
B) CH3I
C) CH3F
D) CH4
E) CH3Br
Answer: B
LO: 11.6
GO: G2
37
27) Based on the figure above, the boiling point of diethyl ether under an external pressure of
is ________ °C.
A) 40
B) 10
C) 30
D) 20
E) 0
Answer: D
LO: 11.6
GO: G3
28) Based on the figure above, the boiling point of ethyl alcohol under an external pressure of
is
A) 20
B) 40
C) 60
D) 80
E) 70
Answer: E
LO: 11.6
GO: G3
38
29) Based on the figure above, what is the boiling point (°C) of water under an external pressure
of .
A) 40
B) 60
C) 70
D) 90
E) 80
Answer: D
LO: 11.6
GO: G3
30) The phase diagram of a substance is given above. This substance is a ________ at 30 °C and
0.5 atm.
A) liquid
B) gas
C) solid
D) supercritical fluid
E) crystal
Answer: B
LO: 11.7
GO: G3
39
11.4 Short Answer Questions
1) In general, intramolecular forces determine the ________ properties of a substance and

intermolecular forces determine its ________ properties.
Answer: chemical, physical
LO: 11.1
GO: G2
2) London Dispersion Forces tend to ________ in strength with increasing molecular weight.
Answer: increase
LO: 11.1
GO: G2
3) The conversion of a solid to a liquid is called ________.

Answer: melting
LO: 11.4
GO: G2
4) The initial discovery of a liquid crystal resulted from studies of a ________ derivative.
Answer: cholesterol
LO: 11.8
GO: G2
11.5 True/False Questions
1) The principal source of the difference in the normal boiling points of ICl (97 °C; molecular
mass and Br2 (59 °C; molecular mass 160 amu) is both dipole-dipole interactions and
London dispersion forces.
Answer: FALSE
LO: 11.1
GO: G2
2) The boiling points of normal hydrocarbons are higher than those of branched hydrocarbons of
similar molecular weight because the London-dispersion forces between normal hydrocarbons
are greater than those between branched hydrocarbons.
Answer: TRUE
LO: 11.1
GO: G2
40
3) Heats of vaporization are greater than heats of fusion.
Answer: TRUE
LO: 11.4
GO: G2
4) Under ordinary conditions, a substance will sublime rather than melt if its triple point occurs
at a pressure above atmospheric pressure.
Answer: TRUE
LO: 11.6
GO: G2
5) Molecules containing many double bonds do not exhibit liquid-crystal behavior because free
rotation can occur only around single bonds making these molecules rigid.
Answer: FALSE
LO: 11.8
GO: G2
41

Chapter 11

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Chapter 11

Uploaded by

Copyright:

Available Formats

Chemistry: The Central Science, 14e (Brown, et al.

11.1 Multiple-Choice Questions

1) Crystalline solids ________.

2) In liquids, the attractive intermolecular forces are ________.

5) Together, liquids and solids constitute ________ phases of matter.

9) Which molecule has hydrogen bonding as the predominant intermolecular force?

20) The predominant intermolecular force in water is ________.

21) Octane C8H18 molecules are held together by ________.

(i) Viscosity increases as temperature decreases.

31) The shape of a liquid's meniscus is determined by ________.

32) Viscosity is ________.

Substance ΔHvap (kJ/mol)

39) Which compound has the strongest intermolecular forces?

40) Large intermolecular forces in a substance are manifested by ________.

43) The substance with the largest heat of vaporization is ________.

44) Of the following, ________ is an exothermic process.

46) A volatile liquid is one that ________.

47) In general, the vapor pressure of a substance increases as ________ increases.

51) The vapor pressure of a liquid ________.

54) On a phase diagram, the critical temperature is ________.

55) On a phase diagram, the melting point is the same as ________.

58) Which of the following is most likely to exhibit liquid-crystalline behavior?

62) What are the common types of smectic liquid-crystalline phases?

66) There are ________ types of smectic liquid-crystalline phases.

2) What is the predominant intramolecular force in NaNO3?

5) Which one of the following exhibits dipole-dipole attraction between molecules?

6) Which one of the following exhibits dipole-dipole attraction between molecules?

9) Which molecule has the lowest boiling point?

15) What is the predominant intermolecular force in CH4?

16) What is the predominant intermolecular force in H2NNH2?

17) What is the predominant intermolecular force in HCN?

25) Of the following, ________ is the most volatile.

26) Which molecule is the least volatile?

1) In general, intramolecular forces determine the ________ properties of a substance and

3) The conversion of a solid to a liquid is called ________.

11.5 True/False Questions

You might also like