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Paper Scheme:
1. The question paper consists of 3 subjects (Subject I: Physics, Subject II: Chemistry, Subject III : Mathematics).
Each subject has three sections (Section 1, Section 2 & Section 3).
Type A contains 6 Multiple Correct Answers Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONE OR MORE THAN ONE CHOICE is correct.
Type B contains 2 Paragraphs containing 2 Questions on each paragraph. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE CHOICE is correct.
3. Section 2 contains 2 Match the Columns Type Questions. Each question contains statements given in
two columns. Statements in column I have to be matched with statements in column II. The answers to these
questions have to be appropriately bubbled in the answer sheet.
4. Section 3 contains 6 Numerical Value Type Questions. The answer to each of the question is a numerical value
type, ranging from 0 to 999 (both inclusive). There are no decimal values.
5. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your Test Code,
Roll No. and Group properly in the space given in the ANSWER SHEET.
Marking Scheme:
1. Section – 1:
For Type A, 4 marks for all correct answers, +1 for partially correct answer and – 1 (Negative Marking) for
incorrect answer. Zero marks if none of the bubbles are darkened.
For Type B, 4 marks for correct answer and – 1 (Negative Marking) for incorrect answer. Zero marks if none of
the bubbles is darkened.
SECTION 1 | Type A
MULTIPLE CORRECT ANSWERS TYPE
This section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:
3r 4r gr gr
(A) (B) (C) 2 (D) 2
T cos T cos sin 2 sin 2
3. Mass of A = m1 , Mass of B = m2
100 gR
(A) Acceleration of the topmost point on the solid sphere when it is at B is , in the
7 r(R r)
vertical upward direction
100 gR (2r R )
(B) Acceleration of the topmost point on the solid sphere when it is at B is , in the
7 r (R r)
vertical upward direction
(C) Maximum height achieved by the solid sphere after leaving Q is less than 10R + r
(D) Maximum height achieved by the solid sphere after leaving Q is equal to 10R + r
SPACE FOR ROUGH WORK
SECTION 1 | Type B
LINK COMPREHENSION TYPE
This section contains two paragraphs containing 2 Questions each. Each question has four choices A, B, C
and D out of which ONLY ONE choice is correct.
9. Moment of inertia of the solid sphere about an axis passing through its centre of mass is:
4 8 4 2
(A) 0 R5 (B) 0 R 5 (C) 0 R5 (D) 0 R5
3 15 9 9
10. Moment of inertia of the solid sphere about an axis which is tangent to the solid sphere is:
7 23 13 11
(A) 0 R5 (B) 0 R 5 (C) 0 R5 (D) 0 R5
3 15 9 9
SECTION 2
MATRIX MATCH TYPE
This section contains 2 questions. Each question contains statements given in two columns which have to be
matched. Statements in Column I are labeled as A, B, C & D whereas statements in Column II are labeled as
p, q, r, s & t. The answers to these questions have to be appropriately bubbled.
Column I Column II
Ball will swing completely around the circle centered along
(A) 60, d 0.6 l (p)
the nail
Ball will not be able to swing the complete circle centered
(B) 53, d 0.6 l (q)
along the nail.
41
(C) 60, d l (r) Tension in string just after it touches the nail is 3.5mg
50
41
(D) 53, d l (s) Tension in string just after it touches the nail is 3mg
50
Column I Column II
Magnitude of angular impulse exerted by object on the rod mul
(A) (p)
about centre of mass of the rod 5
Magnitude of angular impulse exerted by hinge on the rod 3
(B) (q) mul
about centre of mass of the rod 5
Magnitude of angular momentum of rod about P after 2mul
(C) (r)
collision 5
Magnitude of angular momentum of object about P after 4mul
(D) (s)
collision 5
SECTION 3
NUMERICAL VALUE TYPE QUESTIONS
This section contains 6 Numerical Value Type Questions. For each question, enter the correct numerical
value. The answer to each of these questions ranges from 0 to 999. THERE ARE NO DECIMAL VALUES.
Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
3. A mass m tied to a string of length l and is rotated in a vertical circle with centre at the other end of the
string. Mass is given a velocity 3gl at the bottom of the vertical circle. Tension in the string when
the string becomes horizontal is kmg. Find k.
SPACE FOR ROUGH WORK
4. Hundreds of athletes compete in a race to climb a hill to height = 300 m. The winning time is about 10
minutes. Assuming mass of an average runner = 80kg, the average power the winner exerts is k 50W .
Find k. Take g 10 m / s 2
SECTION 1 | Type A
MULTIPLE CORRECT ANSWERS TYPE
This section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:
(A) Addition of noble gas in chamber (I) causes cooling in chamber (II)
(B) On withdrawing NO2 from chamber (II), cooling in chamber (I) is observed
(C) By increasing temperature in chamber (I) by mini explosion, Kc of equilibrium in chamber (II)
decreases.
(D) By increasing temperature in chamber (II) by mini explosion, Kc of equilibrium in chamber (II)
decreases.
2. An ideal gas is taken from state A (Pressure-P0, Volume-V0) to the state B (Pressure- P0/2, Volume-2V0)
along a straight-line path in PV diagram as shown in the figure.
Select the correct statement(s) among the following:
(A) The work done by gas in the process A to B
exceeds the work that would be done by it if the
system was taken from A to B along the isotherm.
(B) In the T – V diagram, the path AB is a part of
straight line.
(C) In the P – T diagram, the path AB is a part of
straight line.
(D) In going from A to B, the temperature T of the gas
first increases to a maximum value and then
decreases.
SPACE FOR ROUGH WORK
3. The normal boiling point of liquid ‘A’ is 350 K, ΔHvap at normal boiling point is 35 kJ/mole. Pick out
the correct statement(s). (Assume ΔHvap to be independent of pressure).
(A) ΔSvaporization > 100 J/K mole at 350 K and 0.5 atm
(B) ΔSvaporization < 100 J/K mole at 350 K and 0.5 atm
(C) ΔSvaporization < 100 J/K mole at 350 K and 2 atm
(D) ΔSvaporization > 100 J/K mole at 350 K and 2 atm
4. All the tubes are of equal and uniform area of cross section
5. At 25°C and 1 atm pressure PCl5(g) dissociates into PCl3 (g) and Cl2 (g) . If it is 30% dissociated at
given conditions. Mark the correct options.
9
(A) Value of K p
91
(B) 8.95 ml of mixture will be diffused in the same time 20 ml of O2 is diffused
(Under similar conditions)
27
(C) Value of K p
81
(D) (Molecular mass)mix 160
6. On the recently discovered 10th planet it has been found that the gases
follow the relationship PeV/2 = nCT where C is constant and other
notations are as usual (V in litres, P in atm and T in Kelvin). A curve is
plotted between P and V at 500 K & 2 moles of gas as shown in figure. If
a closed container of volume 200 lit. of O2 gas (ideal gas) at 1 atm & 200
K is taken to planet. Find the pressure of oxygen gas at the planet at 821 K
in same container.
10 20
(A) 100
(B) (C) 1 atm (D) 2 atm
e e50
SECTION 1 | Type B
LINK COMPREHENSION TYPE
This section contains two paragraphs containing 2 Questions each. Each question has four choices A, B, C and
D out of which ONLY ONE choice is correct.
Paragraph for Q-7 to Q-8
The industrial preparation of a polymer PTFE is based on the synthesis of the monomer CF2 = CF2, which is
produced according to reaction (i) below.
2CHCIF2 (g)
CF2 CF2 (g) 2HCl (g) ….. (i)
8. What is the average C – X bond energies for the species CX4(g), where X = F and Cl respectively?
(A) 329.5 kJ/mol, 426.75 kJ/mol (B) 426.75 kJ/mol, 329.5 kJ/mol
(C) 248 kJ/mol, 365 kJ/mol (D) 405 kJ/mol, 623 kJ/mol
SPACE FOR ROUGH WORK
SECTION 2
MATRIX MATCH TYPE
This section contains 2 questions. Each question contains statements given in two columns which have to be
matched. Statements in Column I are labeled as A, B, C & D whereas statements in Column II are labeled as
p, q, r, s & t. The answers to these questions have to be appropriately bubbled.
2NO(g); H ve
(B) N 2 (g) O 2 (g) (q) K decreases with increase in temperature
SECTION 3
NUMERICAL VALUE TYPE QUESTIONS
This section contains 6 Numerical Value Type Questions. For each question, enter the correct numerical
value. The answer to each of these questions ranges from 0 to 999. THERE ARE NO DECIMAL VALUES.
Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
1. Two moles of an ideal gas is changed from their initial state (16 atm, 6L) to final state (4 atm, 15L) in
such a way that this change can be represented by a straight line in P–V curve. Let ‘y’ L atm be the
maximum average translational kinetic energy possessed by the gas sample during the above change.
1
Report your answer as y/2. (Take R L atm K–1 mol–1)
12
2. A flask has 10 gas particles out of which four particles are moving at 7 ms 1 and the remaining are
moving at the same speed of ‘X’ ms 1 . If the r.m.s. of the gas is 5 ms 1 , what is the value of X?
3. The pressure of the liquid is linear function of volume. The pressure and internal energy of the fluid is
given by P a bV , U 34 3PV
1 q U 3 3
Calculate w for the change in state from (100 Pa, 3m ) to (400 Pa, 6m )
3 10 100
BEs s
4. Calculate bond enthalpy of from the given data.
46
H Formation C2 H5 S C2 H5(g) 147 kJ
H Formation C2 H5 S S C2 H5 (g) 201 kJ
H Formation S(g) 222 kJ
5. What is the modulus of net work done (in calories) by 1 mole of monoatomic ideal gas in a process
described by 1, 2, 3, 4 is given V – T graph.
Use : R = 2cal/mole K
ln 2 = 0.7
SECTION 1 | Type A
MULTIPLE CORRECT ANSWERS TYPE
This section contains 6 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:
1. Let a, b, c, d be non-zero distinct digits. The number of 4-digit numbers. abcd such that ab + cd is even is
divisible by :
(A) 3 (B) 4 (C) 7 (D) 11
(D) If the first term of the GP g1 , g 2 ..... is unity, then the value of common ratio of the progression
such that (4 g 2 5 g3 ) is minimum equals 0.4.
3. The possible values of r for which the region represented by the set { c | 4 2i | r} is a subset of
the region represented by the set { c | z 1| | z i |} are :
7 13 11 5
(A) 2 (B) (C) (D) 2
2 2 2 2 2 2
4. The number of ways of selecting 2 unit squares from 64 unit square of a chess board such that they have
exactly one common corner is less than:
(A) 97 (B) 98 (C) 99 (D) 100
5. Let N be the maximum number of elements of a subset L of {1,2,3…1999} such that difference of any
two distinct elements of L is not equal to 4. The value of N is less than:
(A) 999 (B) 1002 (C) 1001 (D) 2000
SECTION 1 | Type B
LINK COMPREHENSION TYPE
This section contains two paragraphs containing 2 Questions each. Each question has four choices A, B, C and
D out of which ONLY ONE choice is correct.
Paragraph for Q-7 to Q-8
Let z1 and z2 be complex numbers, such that z12 4 z2 16 20i. Also suppose that roots & of equation
t 2 z1t z2 m 0 for some complex number. m satisfy the relation 2 7 .
7. The greatest value of |m| is:
(A) 5 21 (B) 5 23 (C) 7 43 (D) 7 41
22 32 42
10. The sum of series ....... is :
1! 2! 3!
(A) 4e – 1 (B) 5e (C) 5e – 1 (D) 4e
SECTION 2
MATRIX MATCH TYPE
This section contains 2 questions. Each question contains statements given in two columns which have to be
matched. Statements in Column I are labeled as A, B, C & D whereas statements in Column II are labeled as
p, q, r, s & t. The answers to these questions have to be appropriately bubbled.
1. Match the following Column-I and Column-II
Column I Column II
2z 1
Arg where z is a complex number then
(B) 1 z 3 (q) Circle
the path of z is
SECTION 3
NUMERICAL VALUE TYPE QUESTIONS
This section contains 6 Numerical Value Type Questions. For each question, enter the correct numerical
value. The answer to each of these questions ranges from 0 to 999. THERE ARE NO DECIMAL VALUES.
Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
2 20
i
1. If e 7 and f ( x ) a0 ak x k then the value of f ( x ) f (x) ....... f ( 6 x) is na0. Then n =
k 1
______ given that a0 0 .
4
2. Let z1, z2 , z3 & z4 be the roots of the equation z 4 z 3 2 0 , the value of (2zr 1) is equal to____.
r 1
4. 17 coupons are numbered from 1 – 17. 6 coupons are selected at random one by one with replacement. If
the possible ways such that the largest number appeared on selected coupons is 5 is represented by p.
p
Find the value of [x] denotes integral part of x.
1500
5. Consider 2 numbers 6 and 54. 10AMs, 10GMs and 10 HMs are inserted between them.
10 10 10
1
Let Ai p, Gi q, H i r. Then the value of r (q )1/5 pr 3r is…{A denotes AM, G
i 1 i 1 i 1
6. An intelligence agency forms a code of two distinct digits selected from 0, 1, 2, …. 9 such that the first
digit of the code is non-zero. The code hand written on a slip, can however potentially create confusion,
when read upside down for example, the code 91 may appear as 16. Let N be the number of codes for
which no such confusion can arise. Find sum of digits of N.
SPACE FOR ROUGH WORK