Professional Documents
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Fuel Energy
Production Conversion
Woody biomasses :
Fuel wood,
Woody residues: Whole trees and stemwood, Bark and
stumps, Pile of bark chips
Other woody biomasses :
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sewage sludge
other municipal biowaste
woody waste from gardens and park
de-inking sludge
papermaking sludge
meat and bone meat
chicken litter
leather waste, etc.
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Produced by gasification
◦ Synthesis gas (mainly H2 and CO) at high
temperatures (>1000K):
CO + 2H2 CH3OH +heat
◦ Excess hydrogen (with catalyst):
3H2 + CO2 CH3OH + H2O
Methanol is used as
◦ a fuel as such
◦ reacted with isobutylene methyl tertiary butyl
ether (MTBE) for blending with gasoline.
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condensed to bio-oil.
Chemically complex
Heating value 14-18 MJ/kg
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Expensive
Transportation
Low heating values
Decaying
Quality variations
Some negative environmental impacts
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Quantity
Quantity
Quality
Biodiversity Quality
Biodiversity
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Technology Options
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•Treatment of Waste
• Energy production
• Valuable Products
F:Fuel F:Fertilizer
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Temperature:
Mesophilic (30-44oC) and thermophilic (45- 60oC) temperature for optimum biogas
production compare to psychrophilic (<30oC).
Constant temperature is important for preventing negative effects on biogas production.
pH: Optimal pH range from 6.5 to 8.5.
Solid Concentration:
Normally 7-9% solid concentration is best suited.
The Volatile Solid (VS) should be 90 % of the Total Solid (TS) and we can maintain the TS
of the feedstock by addition of water.
TS vary with the types of feedstock and digesters.
Mixing: Mixing doesn’t always take place continuously because excessive mixing can
reduce biogas production.
It is reported that slow mixing allow the digester to better absorb the disturbance of shock
loading than high mixing of the reactor contents.
Excessive mixing can disrupt the granules (microbial biomass) structure; reduce the rate of
oxidation of fatty acids which can lead to digester instability .
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C:N ratio:
High level of nitrogen as undissociate ammonia with low C/N ratio can cause toxicity, and
low level of nitrogen with high C/N ratio can inhibit the rate of digestion.
It was investigated that during biomethanation process microorganisms utilize carbon 25-30
times more than nitrogen .
Fatty Acids:
Fatty acids are a key intermediate in biomethanation process which is also capable of
inhibiting methanogensis in high concentrations.
Hydraulic Retention Time (HRT):
Number of days the materials stays in the digester is called the Hydraulic Retention Time
or HRT .
In tropical countries like India, HRT varies from 30-50 days or vary according to weather
changes
HRT is important since it establishes the quantity of time available for bacterial growth and
subsequent conversion of the organic material to gas.
Materials Total Solid content (%) Water content (%) C/N Ratio
Green grass 24 76 37
Human excreta 20 80 8
Pig excreta 18 82 18
Cattle excrement 17 83 24
Poultry waste 47 53 10
Water hyacinth 18 82 25
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Indian Agricultural Research Institute (IARI) and Khadi & Village Industries Commission
(KVIC) type design for family, community, institutional and industrial biogas plants.
Advantages:
Constant gas pressure and higher gas production.
No problem of gas leakage.
Scum problem is less.
No danger of mixing between biogas and external air.
Disadvantages:
Higher initial and maintenance cost.
The outlet pipe should be flexible, requires rwgular attention.
Heat is lost through gas holder.
Advantages:
Disadvantages:
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This mainly consists of a digester or pit for fermentation and a floating drum for the
collection of gas.
The gas generation takes place slowly and in two stages. In the first stage, the complex,
organic substances contained in the waste are acted upon by a certain kind of bacteria,
called acid formers and broken up into small-chain simple acids. In the second stage, these
acids are acted upon by another kind of bacteria, called methane formers and produce
methane and carbon dioxide.
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G bala Chander, Namita Khanna, Debrata Das. Chapter 6, Biohydrogen Production From Organic Waste , Elseivier Publication , June 2013
Dr.Richa Kothari, Central
University of Jammu, J&K 7/18/2020 53
Parameters Concentrations
25% 50% 75% 100%
Initial Final R* Initial Final R* Initial Final R* Initial Final R*
Richa Kothari, Virendra Kumar, S.K.Tyagi, Dual benefits from dairy wastewater using Dr.Richa Kothari,
E.aerogens Centralreduction and biohydrogen production: a
in pollutant
cost-effective approach, International Journal of Applied Energy , 2015 (Submitted) University of Jammu, J&K 7/18/2020 54
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Disadvantages
Sugar industry •The yield of H2 from any other processes is low for
commercial application.
•Lack of the appropriate bioreactor design for H2
production, interspecies H2 transfer in non sterile
conditions and separation/purification of H2
• Insufficient knowledge on the metabolism of H2
producing bacteria and the levels of H2 concentration
tolerance of these bacteria.
•A lack of understanding on the improvement of
economics of the process by integration of H2 production
Dr.Richa Kothari, Central
with other processes
University of Jammu, J&K 7/18/2020 55
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Algal biofuel production and mitigation potential in India H. N. Chanakya & Durga Madhab Mahapatra & R. Sarada
& R. Abith, Mitig Adapt Strateg Glob Change (2013) 18:113–136 Dr.Richa Kothari, Central
University of Jammu, J&K 7/18/2020 61
(40%) (60%)
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.
https://www.downtoearth.org.in/blog/agriculture/india-s-city-compost-policy-needs-
overhauling-63248
https://twitter.com/swachhhyd/status/94878899561
Dr.Richa Kothari, Central
University of Jammu, J&K 7/18/2020 66
3376512
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The advertisements and punch line ‘Compost Banao, Compost Apnao’ (Make
compost, use compost) did catch on but the lack of an appropriate market and
ineffective implementation didn’t give this much-needed practice the desired
popularity.
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Environmental issues
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[http://www.greenhouse.gov.au] 74
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Reducing the
emissions of
greenhouse gases into
the atmosphere by:
◦ Using renewable energy
sources instead of fossil
fuels
Solar power & heat
Wind power
◦ Capture and store
greenhouse gases from
fossil fuels
Planting more forests
Saving electricity
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NOx
SOx
Solid ash and soot particles
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Emissions
Energy crops
◦ agricultural problems
Construction
◦ environmental impacts typical of any engineering
project of similar scale
Nutrient loss and erosion in forests
The energy strategy of country aims to chart the way forward to meet the
Government’s recent ambitious announcements in the energy domain such as
*electrification of all census villages by 2019,
*24x7 electricity & 175 GW of renewable energy capacity by 2022,
*reduction in energy emissions intensity by 33%- 35% by 2030 and
*share of non-fossil fuel based capacity in the electricity mix is aimed at
above 40% by 2030.
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(E) Creating suitable environment for biofuels and its integration with
the main fuels.
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1. Convenience: Garbage and wastewater problems that people face are usually not related to
health risks but a nuisance from filthy surroundings, rats, flies and bad odor. To motivate
people to address this situation, it is important to understand the factors or benefits that they
would value from a change in the situation rather than those that are important according to
health experts.
2. Understanding: Health experts tend to focus on concepts such as germs and transmission
routes, and disease prevention. However, health education that aims at understanding builds
on local knowledge and uses health-related beliefs and reasoning of the people themselves.
3. Prestige and Approval: People tend to adopt practices that are associated with approval from
people they respect or help them to gain prestige. A community may also institute rewards for
compliance or fines for noncompliance. However, convenience and understanding are found
to be linked to more sustainable adoption than approval or prestige alone.
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Thank You
Dr.Richa Kothari, Central
University of Jammu, J&K 7/18/2020 92
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