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Brillouin function.
c Speed of light; lattice parameter; Elastic moduli.
d Density, distance.
h Planck's
Langevin function.
m Mass; m: Reduced magnetisation
p Pressure.
p Momentum (= mv + qA).
P Power.
q Electric charge; magnetic mass.
S Spin operator (in units of ); oriented surface area; S, Spin quantum number.
t Time.
T Period, temperature; Néel temperature; Curie temperature.
Critical temperature (e.g. superconducting); Compensation temperature.
u Potential difference (voltage); U: Effective potential difference.
Internal energy.
v Velocity.
Magnetic potential.
w Molecular field coefficient.
W Work.
Y Young's modulus.
Compressibility.
Wavelength, spin-orbit coupling parameter; elongation;
Magnetostriction coefficient
Permeance.
Magnetic permeability; Permeability of free space; Relative permeability.
Bohr magneton.
Magnetic flux.
Angular velocity.
Acceleration of gravity, g
Electron rest mass, m
Electron charge (absolute value), e
Bohr magneton,
Flux quantum, h/2e
Avogadro’s number N
Boltzmann’s constant,
APPENDIX 3
In the cells of the table below, for each element, the first line indicates its symbol,
with its atomic number as superscript, the second one its atomic weight, the third
one its spectroscopic ground state in the neutral atomic state, and finally the fourth
one gives the electronic configuration of the external shells, again in the neutral
atomic state.
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APPENDIX 4
MAGNETIC SUSCEPTIBILITIES
There exist several tables of numerical value where engineers can find complementary
information on paramagnetism in solids, e.g. that edited by Landolt et Börnstein [8].
Important comment: some tables still give numerical values in cgs units, and the
reader should thus be careful, and not confuse them with data in which can
be of the same order of magnitude!
Note that a ferromagnetic impurity can strongly disturb the magnetic properties of
very weakly magnetic substances, even for concentrations of the order of a ppm: the
perturbation will generally be temperature dependent, and be larger at low temperature.
On the other hand, special care must be taken in processing materials expected to
exhibit very weak magnetism: brazing or soldering under argon atmosphere is for
instance liable to precipitate a strongly magnetic phase in a weakly magnetic alloy.
Stainless steels that are well known to be very weakly magnetic, are then seen to
become slightly ferromagnetic! Special care is therefore required, and it is important to
check the magnetic properties of an allegedly non magnetic alloy before using it, and
after thermal or mechanical processing. An extremely simple method to check the
magnetism of a metallic part consists in hanging a strong magnet (Nd-Fe-B or
at the end of a 1 metre long thin nylon thread, and bringing it near the part to
be checked: if the slightest attraction is observed, the substance is already slightly
ferromagnetic or at least very strongly paramagnetic.
REFERENCES
[1] Tables de constantes et Données numériques: 7. Constantes sélectionnées: G. FOëX,
Diamagnétisme et paramagnétisme; C.J. GORTER, L.J. SMITS, Relaxation paramagnétique
(1957) Masson & Cie, Paris, 317 p.
[2] C.M. HURD, Cryogenics 6 (1966) 264.
[3] P.T. KEYSER, S.R. KEFFERTS, Rev. Sci. Instrum. 60 (1989) 2711.
[4] PH. LETHUILLIER, private communication.
486 MAGNETISM - MATERIALS AND APPLICATIONS
[5] P. PASCAL, Nouveau traité de chimie minérale, Tome IV (1958) 143, Masson, Paris.
[6] J.G. THOMAS, E. MENDOZA, Phil. Mag. 43 (1952) 900.
[7] Handbook on materials for superconducting machinery, metals and ceramics (1974) Battelle
Information Center, Columbus (Ohio).
[8] LANDöLT, BöRNSTEIN, Zahlenwerte und Funktionen aus Physik. Chemie. Astronomie.
Geophysik. Technik II - 9 - Magnetische Eigenschaften 1, Section 29.1111 (1962) Springer,
Berlin.
APPENDIX 5
FERROMAGNETIC MATERIALS
The aim of this Appendix is to illustrate, through figures, the economic impact of the
major applications covered in this book, without in any way claiming to offer an
exhaustive account of the global economic facts pertaining to the magnetic material
market, the importance of which is generally underestimated. Information comes
from diverse sources and, at times, it is difficult to separate out the turnover relevant
to raw material from that of processed material, or from a system that has reached
the market.
1. INTRODUCTION
In order to grasp the reality behind the figures below, we shall give here some essential
facts. The various materials produced represent an annual turnover for the firms that
produce them: this is this figure which is estimated here. These materials are
incorporated into systems, devices, etc., which have a value higher than that of the
material itself, frequently an order of magnitude higher. However, without the material,
nothing would exist. It is estimated that the component amounts to 5-10% of the total
cost.
Magnetic materials are key components of our everyday lives, in traditional domestic
applications as well as in rapidly growing technologies such as information and
telecommunications. Constant research leads both to improvements in existing
materials and to the discovery of others, thus raising the performance of current
products and enabling the creation of new ones. In the field of energy, the principal
market for magnetic materials, raising the efficiency of electric motors with medium
power from 90 to 92%, corresponds, on the world scale, to the electricity output of a
nuclear power plant.
First we shall consider the three principal markets. These are:
the hard materials,
the soft materials for electrical engineering and electronics, and
the materials for magnetic recording.
We then discuss, more briefly, some other magnetic materials.
490 MAGNETISM - MATERIALS AND APPLICATIONS
3. SOFT MATERIALS
The soft magnetic material market is essentially that for electrical engineering,
dominated by ferromagnetic alloys. In electronics, where the operating frequency lies
in the radio and microwave ranges, insulators or semi-conductors such as ferro- or
ferrimagnetic oxides are used. In the intermediate frequency range, special alloys are
used.
In 2001 the turnover in materials used for magnetic recording represented more than
47 billion euros globally: 40 for hard disk drives, 5 for tape drives, 2 for floppy drives.
This industry, which is in constant technical evolution, has as its primary objective the
enhancement of storage capacity per unit area; for example, the demand for computers
is rising at 60% per annum, half of which is for hard disks, and this trend is expected
to continue for at least ten years. In 2001 the most common density stood at 1.5 to
(see fig. 1.8). The technologies permitting to be attained
are known and will be implemented rapidly, making them available to the market early
in the new millennium. The substitution of longitudinal recording by a perpendicular
method should allow surface densities of 15 to to be reached, with
reading heads made of giant magneto-resistance transducers.
5.2. FERROFLUIDS
Here too, the quantities of material involved are very modest, and most of the
applications envisaged –described in chapter 22– are only at the experimental stage.
As yet few companies commercialise this product: to take one example, Ferrofluidics
in the USA both produces ferrofluids and sells the applications for these materials; a
company such as Advanced Fluid Systems in Great Britain also sells applications.
GENERAL REFERENCES
Gd-Co I - 423
I - 438
Gd-Fe I - 423
I - 426
I - 267
I - 451
I - 113
I - 346
GdTbFe I - 438
GdZn I - 101
GGG see
Goethite II - 395
Greigite II - 395-396, 428
Haemoglobin II - 427
Haemosiderin II - 427
Hard ferrite II - 19, 48
Hematite see
Heusler alloy I - 423
Hexaferrite II - 49, 193, 197, 493
II - 251
High superconductor II - 251
Ho I - 269
I - 139
Ilmenite II - 397
Interstitial compound II - 63
Invar I - 352 II - 213-215
Iron I - 165-166, 195, 224, 366, 373, 377, 384, 438, 475-476 II - 145, 162, 395, 487-488, 492
Iron based amorphous alloy I - 369, 372 II - 118, 145
Iron-cobalt alloy II - 111
II - 251
I - 318
I -318
Lodestone see magnetite
I - 136
Maghemite see
Magnetite see
Manganese-zinc ferrite see
Manganite I - 451, 454
Metglas II - 226, 227, 494
II - 393
I- 181
MnO I - 10
II - 112, 162
II - 251
II - 251, 459
NbTi II - 251, 459
Nd I - 316
I - 285, 475-476 II - 41, 43, 51, 63, 68, 487-488
Nd-Fe-B I - 13, 186, 242 II - 17, 19, 491
500 MAGNETISM - MATERIALS AND APPLICATIONS
I - 422, 438
II - 63
I - 267
Ni I - 215, 301, 351-352, 359, 374, 377, 380, 422, 438, 475-476 II - 215, 217, 487-488
II - 275
Nickel-zinc ferrite see
I - 267
I - 267
I - 314, 475-476 II - 217, 487-488
NiMnSb I - 423, 438
NiO I - 180
II - 112, 162
Olivine II - 397
Oxyhydroxides II - 393, 396
PdMnSb I - 423
Permalloy I - 385 II - 110, 217
Permanent magnet II - 3
Permendur II - 217
Phosphates II - 393
Phyllosilicates II - 397
PtMnSb I - 423, 438, 450
PtMnSn I - 423
Pyrite II - 396
Pyroxene II - 397
Pyrrhotite II - 395-396
Quartz II - 393
R often stands for a rare earth element
I - 268
I - 279 II - 55, 59
II - 61
R-Co I - 422, 438
I - 268
I - 423
II - 63
II - 63
II - 63
II - 62
I - 279 II - 55
II - 63
I - 268, 421 II - 318, 493
R-Fe I - 308, 422, 438
R-FeCo amorphous alloy II - 317
I - 268
Rare earth garnet see
RIG see
Siderite II - 397
Silicates II - 393, 397
Silicate glass I - 421
I - 186, 234, 285, 475-476 II - 19, 41, 43, 51, 63, 68, 487-488
INDEX BY MATERIAL 501
I - 243
I - 475-476 II - 19, 43, 63, 68, 72, 487-488
Sm-Co II - 17, 491
Sm-Co phase diagram II - 58
II - 63
II - 63
II - 63
Soft ferrite II - 112
Spinel II - 191, 193, 197
II - 43, 48
Sulphates II - 393
Sulphides II - 396
Tanol suberate II - 425
Tb I - 269
II - 60
TbFe I - 423, 438
I - 438
TbFeCo I - 423, 438
I - 431
I - 100
I - 267
TbIG see
Terfenol II - 217
Terfenol-D I - 390 II - 216, 219, 221, 494
Tetrathiafulvalene II - 426
II - 63
I - 360
Titanohematite II - 395
Titanomagnetite II - 395
II - 251
Tm I - 269
I - 267
Transition metals I - 422
Troilite II - 396
I - 360
II - 251
II - 60
I - 85
I - 85
I - 184, 266, 361, 363-365, 430, 475-476 II - 183, 190, 344, 487
Y-Co/Gd-Co/Y-Co II - 276
I - 422, 438
YIG see
Yttrium-iron garnet. see
I - 284-285
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INDEX BY SUBJECT
Electromotive field I - 48
Electromotive force I - 47
Electron interference holography I - 174
Electron microscopy I - 174
Elinvar I - 352 II - 213
Ellipticity I - 419
Energy see Free energy
Energy dissipation see Losses
Energy product II - 8, 11
EPI see Echo Planar Imaging
Epitaxy II - 256, 262, 265
Epstein permeameter II - 126, 444
Exchange coefficient I - 145
Exchange energy I - 117
Exchange integral I - 312
Exchange interactions I - 116, 143-144, 311
Exchange length I - 146 II - 257
Exchange magnetostriction I - 101, 351, 359
External field I - 37, 183
External susceptibility I - 40 II - 159, 309
Faraday effect I - 163, 169, 400, 407, 415, 421 II - 199
Faraday’s experiment I - 48
Fermi level II - 264, 281, 286
Fermi surface II - 280
Fermi velocity II - 279
Fermi wavelength II - 257
Fermi’s golden rule II - 281, 292
Ferrimagnetic macroscopic order II - 276
Ferrimagnetism I - 10, 83, 127
Ferrimagnets I - 385
Ferrite magnet II - 25
Ferritin II - 427, 429
Ferrofluid I - 168 II - 337
Ferromagnetic materials I - 475 II - 487
Ferromagnetism I - 82, 118
Fibrin II - 428
Field coefficient I - 24
Field detector I - 427
Field gradient II - 366
Field sensor I - 430 II - 298
Fluctuation after-effect I - 98, 236-237
Flux channeling II - 464
Flux conservation I - 23
Flux gate II - 392
Flux gate magnetometer II - 432, 470
Flux leakage coefficient II - 6
Flux quantization II - 238
Flux quantum II - 238
Fluxmeter II - 444
508 MAGNETISM - MATERIALS AND APPLICATIONS
Load line II - 6
Local density of states I - 302
Localized electron model I - 262, 414
Lodestone see Magnetite
Longitudinal recording II - 307
Lorentz field I - 46
Lorentz force I - 46
Lorentz microscopy I - 174
Losses II - 92-93
Loudspeaker II - 29, 77
Low Energy Electron Diffraction (LEED) II - 263
Lubrication II - 345
Maghemite I - 4, 85, 266 II - 314, 347, 394-395
Magic cylinder I - 70 II - 34, 468
Magnetic after-effect I - 98, 236
Magnetic anisotropy I - 89
Magnetic charge I - 27-28, 32, 149
Magnetic circuit I - 42 II - 5
Magnetic dichroism I - 172
Magnetic dipole I - 27
Magnetic domain I - 87, 173, 147 II - 102, 349
Magnetic domain imaging I - 168, 426
Magnetic field I - 22, 32
Magnetic force I - 29
Magnetic Force Microscopy (MFM) I- 175
Magnetic head II - 319
Magnetic image I - 64
Magnetic induction I - 20
Magnetic marking II - 432
Magnetic mass see magnetic charge
Magnetic moment I - 27
Magnetic polarization I - 32
Magnetic quantum number I - 252
Magnetic Random Access Memory (MRAM) II - 299
Magnetic recording I - 14 II - 305
Magnetic Resonance Imaging (MRI) II - 355, 362
Magnetic semiconductor I - 451
Magnetic separation II - 399, 433
Magnetic structure I - 138
Magnetic susceptibilities I - 39 II - 483
Magnetic torque I - 29
Magnetic valence I - 307-308
Magnetic X-ray diffraction I - 404
Magnetite I - 3-4, 266, 475-476 II - 191, 217, 339, 394, 428, 487-488
Magnetization I - 30, 339
Magnetization curling I - 165, 205
Magnetization curve I - 38
Magnetization loop II - 4
Magnetization processes I - 183, 211
INDEX BY SUBJECT 511
Superexchange I - 313
Superimposed susceptibility I- 198
Superlattice II - 256
Superparamagnetic limit II - 295
Superparamagnetics II - 374
Superparamagnetism I - 115 II - 315, 340
Surface anisotropy II - 270
Surface magnetism II - 265
Susceptibility I - 471 II - 374, 390
Synchrotron radiation I - 171, 404, 428, 437 II - 412
T (twin) domains I - 180
contrast II - 371
contrast II - 371
Technical magnetization II - 166
Tectonics II - 419
Tectonic drift II - 417
Telegraphone II - 306
Terfenol-D II - 216
Term I - 258
Thermal activation I - 209
Thermal expansion I - 101 II - 213
Thermodynamics I - 321
Thermoremanent Magnetization (TRM) II - 404
Thin film I - 157 II - 230-231, 255
Threshold field I - 191
Tight-binding approximation I - 295
Time reversal I - 328
Torque I - 45, 57
Torquemeter II - 228
Total field I - 32
Transformer II - 123
Transition metal I - 295
Transition metal magnet II - 48
Transport II - 278
Trilayer II - 275-276
TRM see Thermoremanent Magnetization
Tunnel magnetoresistance II - 292
Two current model II - 281
Type-I superconductor II - 246
Type-II superconductor II - 246
Ultrathin films II - 265
Undulator II - 35
Uniform magnetostatic resonances II - 185
Unpinning I - 218
Van der Waals force II - 339
Van Vleck’s paramagnetism I - 81
Vector potential I - 23
Very weak ferromagnet I - 285
VGP see Virtual Geomagnetic Pole
INDEX BY SUBJECT 517