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 University of Dhaka
Department of Chemistry
1" Year B. S. (Hons.) Minor Examination 2020
Subject: Chemistry
Course No.: CMG 100 (4 credits); Course title: Fundamentals of Chemistry
Full Marks: 70
Time: 2 h

Answer to question No. I and any hvo questions from the rest

1. Answer all ofthe following questions. Atsa aO THT S8Y Hmsi 7x2
(a) What are the conjugate acids ofthe bases SO«and HCO ?

(6) Why entropy of water vapor is higher than liquid water?

(c) What are the geometrical isomers of 1,2-dichloroehtene?

d) Phenols are acidic in nature-Explain.

RRJNT
(e) Write down the nuclear reaction for the bombardment reaction:

N(d,n) Os
What type of intemolecular force of attraction might exist between the following pairs of
(
compounds:

() HCl and H20 and (ii) k and H0

ground state electronic configuration of [Xe]444sd"6s6p?.
How many
(e) Pb atom has the
unpaired clectrons does it have?

2. (a) What are the four quantum numbers? Describe the importance of these quantum numbers. 8

a transition of an electron 4
b) What is the wavelength of a photon (in nanometers) emitted during
from the - 4 state to the ne=3 state? Given that RH =2.18 x 10-3 J.

TI AS TE, RA =2.18 x 108J

(c) Balance the following reaction by considering acidic medium.

Fe+Mn04 > Fet +Mn2*

(d) What does VSEPR stand for? Draw the geometry and mention the number of electron-pairs 8
and bond angle of CH4, NH; and H20 according to VSEPR theory
VSEPR CE TT VSEPR T T CH4, NH H0 9 AT o RAFR

(e) Define electronegativity and electron affinity. 4

3. (a) (i) Calculate the root mean square velocities of O gas at 25 and 50 °C. (ii) Graphically show5 4+3
and explain the distribution of molecular velocities of O2 gas at these two temperatures.

(b) i) Draw the phase diagram of water indicating all phases, the riple point, and the critical point. 4+4 4+3

ii)How does the freezing tempearture of water change when sugar is added to it?

1/2
o-H*
 2+
(o) What are colligatlve propertlen? Why they are called so?

minutes. (i) Calculate the rate constant of thís reactíon

(d) Half-l1fe ofa fMrst order reactlon ln 40 reaction.
and () Caleulate the tlme required to complcte 60% ofthis

IMIG
() Which fhetors nfloct the chemleal cqullibrlum'?

4. (a) Give the lUPAC names ofthe following compounds

(i) CHC(CHi)CH(CH1)NO and (ii) CH(CH3)»C(CIMCH)CH2COOH 6

and (ii) HsC-CH-CH?
(b) What are the hybrlid orbitals of the C atoms present in (i) CH3-H;
Explain with necessary drawing.
«ff01 aCKcu? azATatu f6ra 145
li) CH-CH (11) HsC-CH-CH onu mfu 119a fa f aKvfHE

(c) How can you diflerentiate between 1-propanol and 2-propanol?

whereas C-O bond undergo 6

(d) Why does CC bond undergoes electrophilic addition reaction,
nucleophilic addition reaction?

(c) Complete the following reactions by naming each species involved:

i)HCHO+RMgX-?
i)HCCH=CH2 +?> HCCOOH

? +NaNH2 ?
ii) H2CBr-CH2Br +alcoholic KOH ->

Write down short note on any four from the followings: IfAcza a oITAT 8T DTT N 4x7
5.
(a) Diagonal relationship f l
(b) Born-Haber cycle M-RAR BIE I|
(c) Natural and synthetic organic polymers (argibe 7 u ATRi

(d) Collision theory of reaction rate IAfI KICAM Tevd wg il

(e) Friedel-Crafts alkylation and acylation lcuM-MT TPt s Uetr il
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