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RSAINS S

PT

Ditulis dan disusun oleh


Guru Berprestasi Tinggi
Sektor Pembelajaran
Jabatan Pendidikan Negeri Selangor
CHAPTER 4 Rate of Reaction
Kadar Tindak Balas
Video PdPR

Paper 1 4 Excess zinc reacts with dilute sulphuric acid. After


a while, the reaction gradually become slower and
1 Which of the following is an example of slow finally stops.
reaction? Which of the following statement best explains why
Antara berikut, yang manakah merupakan contoh tindak this happens?
balas perlahan? Zink berlebihan bertindak balas dengan asid sulfurik cair.
A Burning of fireworks. Selepas seketika, tindak balas menjadi semakin perlahan dan
akhirnya berhenti.
Pembakaran bunga api.
Antara pernyataan berikut, yang manakah paling tepat
B Reaction of sodium with water.
menjelaskan kejadian ini?
Tindak balas natrium dengan air.
A The zinc is used up.
C The process of photosynthesis performed by
Zink habis digunakan.
plants.
B The sulphuric acid is used up.
Proses fotosintesis yang dijalankan oleh tumbuhan.
Asid sulfurik habis digunakan.
D Burning of a piece of paper.
C The insoluble zinc sulphate is formed.
Pembakaran kertas.
Zink sulfat yang tidak larut dihasilkan.
D The hydrogen gas covers the zinc metal.
2 Which of the following statement is correct about
Gas hidrogen menutupi logam zink.
fast reaction?

tindak balas cepat?


A

The rate of reaction is zero.
Kadar tindak balas adalah sifar.
S
Antara pernyataan berikut, yang manakah betul tentang 5 Diagram 1 shows the graph of volume of hydrogen
gas against time.
Rajah 1 menunjukkan graf isi padu gas hidrogen melawan
masa.
R
B The rate of reaction is slow. Volume of hydrogen gas (cm3)
Kadar tindak balas adalah perlahan. Isi padu gas hidrogen (cm3 )

C Takes a shorter time to complete the reaction.


Memerlukan masa yang singkat untuk melengkapkan 35.0
tindak balas. 30.0
D Takes a longer time to complete the reaction.
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25.0
Mengambil masa yang lebih lama untuk melengkapkan
tindak balas. 20.0

15.0
3 Choose the following reaction with the lowest rate
10.0
of reaction.
Antara berikut, pilih tindak balas yang mempunyai kadar 5.0
tindak balas paling rendah. 0 Time (s)
Masa (s)
A Fermentation process of glucose to ethanol. 60 120 180 240 300 360
Proses penapaian glukosa kepada etanol. Diagram 1/ Rajah 1
B Neutralisation reaction between hydrochloric
acid and sodium carbonate solution. Calculate the average rate of reaction for the first
Tindak balas peneutralan antara asid hidroklorik dan 3 minutes.
larutan natrium karbonat. Hitung kadar tindak balas purata pada 3 minit yang
pertama.
C Displacement reaction of copper(II) sulphate
solution by zinc metal. A 0.097 cm3 s-1 C 0.194 cm3 s-1
Tindak balas penyesaran antara larutan kuprum(II)
B 0.146 cm3 s-1 D 1.167 cm3 s-1
sulfat dengan logam zink. 6 0.7 g of magnesium powder reacts completely with
D Precipitation of silver chloride by adding silver excess dilute hydrochloric acid in 45 seconds.
nitrate solution into sodium chloride solution. Calculate the rate of reaction of this reaction.
Tindak balas pemendakan argentum klorida dengan 0.7 g serbuk magnesium bertindak balas dengan asid
menambahkan larutan argentum nitrat ke dalam hidroklorik cair berlebihan sehingga lengkap dalam masa
larutan natrium klorida. 45 saat. Hitung kadar tindak balas bagi tindak balas ini.
A 0.0133 g s-1 C 0.0175 g s-1
B 0.0156 g s-1 D 0.0214 g s-1

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7 Table 1 shows the result obtained from the Which of the following gas is collected in the gas
decomposition of hydrogen peroxide. syringe?
Jadual 1 menunjukkan keputusan yang diperoleh daripada Antara berikut, gas yang manakah terkumpul di dalam
penguraian hidrogen peroksida. picagari gas?
A Chlorine
Time (min) Volume of O2 (cm3) Klorin
Masa (min) Isi padu O2 (cm3) B Carbon dioxide
Karbon dioksida
0 0 C Oxygen
1 4 Oksigen
D Hydrogen
2 8 Hidrogen
3 11
10 Which of the following produces the highest rate of
4 12 reaction?
5 12 Antara berikut, yang manakah menghasilkan kadar tindak
balas paling tinggi?
6 12 A 20 cm3 of 0.18 mol dm-3 sodium thiosulphate
solution and 5 cm3 of 1.0 mol dm-3 sulphuric acid.
Table 1/ Jadual 1 20 cm3 larutan natrium tiosulfat 0.18 mol dm-3 dan
Calculate the average rate of reaction of 5 cm3 asid sulfurik 1.0 mol dm-3.
decomposition of hydrogen peroxide. B 20 cm3 of 0.16 mol dm-3 sodium thiosulphate
Hitung kadar tindak balas purata bagi penguraian hidrogen solution and 5 cm3 of 1.0 mol dm-3 sulphuric acid .
peroksida.
A
B
C
2.0 cm min
3

3.0 cm3 min-1


6.0 cm3 min-1
-1

S 20 cm3 larutan natrium tiosulfat 0.16 mol dm-3 dan


5 cm3 asid sulfurik 1.0 mol dm-3.
C 20 cm3 of 0.08 mol dm-3 sodium thiosulphate
solution and 5 cm3 of 1.0 mol dm-3 sulphuric acid.
R
D 12.0 cm3 min-1 20 cm3 larutan natrium tiosulfat 0.08 mol dm-3 dan
5 cm3 asid sulfurik 1.0 mol dm-3.
8 Which of the following factors does not affect the D 20 cm3 of 0.20 mol dm-3 sodium thiosulphate
rate of reaction for the reaction between zinc and solution and 5 cm3 of 1.0 mol dm-3 sulphuric acid.
dilute hydrochloric acid? 20 cm3 larutan natrium tiosulfat 0.20 mol dm-3 dan
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Antara faktor berikut, yang manakah tidak mempengaruhi 5 cm3 asid sulfurik 1.0 mol dm-3.

FORM 5
kadar tindak balas bagi tindak balas antara zink dengan asid
hidroklorik cair? 11 Diagram 3 shows the graph of volume of hydrogen
A Pressure of the reaction gas produced against time when excess zinc reacts
Tekanan tindak balas with dilute hydrochloric acid.
B Temperature of the hydrochloric acid Rajah 3 menunjukkan graf isi padu gas hidrogen yang terhasil
Suhu asid hidroklorik melawan masa apabila zink berlebihan bertindak balas
C Presence of copper(II) sulphate as catalyst dengan asid hidroklorik cair.
Kehadiran kuprum(II) sulfat sebagai mangkin
Total volume of hydrogen gas (cm3)
D Size of zinc Jumlah isi padu gas hidrogen (cm3)
Saiz zink

9 Diagram 2 shows the reaction between zinc and


P Q
dilute hydrochloric acid.
Rajah 2 menunjukkan tindak balas antara zink dengan asid
hidroklorik cair.

Gas syringe Time (min)


Picagari gas Masa (min)
Diagram 3/ Rajah 3
Dilute hydrochloric acid
Zinc Asid hidroklorik cair Which of the following statement is correct about
Zink section PQ?
Diagram 2/ Rajah 2 Antara berikut, pernyataan yang manakah betul mengenai
bahagian PQ?

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I No more hydrogen gas is being produced. I Oil acts as catalyst.
Tiada lagi gas hidrogen dihasilkan. Minyak bertindak sebagai mangkin.
II All the hydrochloric acid has reacted. II Oil breaks down the protein in the meat.
Semua asid hidroklorik telah bertindak balas. Minyak menguraikan protein dalam daging.
III The rate of reaction is decreasing. III The temperature of oil is higher than water.
Kadar tindak balas berkurang. Suhu minyak lebih tinggi daripada air.
IV The rate of reaction is increasing. IV Sliced meat has a greater surface area than chunk
Kadar tindak balas bertambah. meat.
A I and II C III and IV Hirisan daging mempunyai luas permukaan yang lebih
I dan II III dan IV besar daripada ketulan daging.
B II and III D I, II and III A I and III C II and IV
II dan III I, II dan III I dan III II dan IV
B II and III D III and IV
12 How to increase the time reaction between a magnesium II dan III III dan IV
ribbon and 25 cm3 of 2.0 mol dm-3 nitric acid?
Bagaimanakah masa tindak balas antara jalur magnesium 15 Which of the following process is used to produced
dan 25 cm3 asid nitrik 2.0 mol dm-3 dapat dipanjangkan? sulphuric acid?
A Heat the acid solution. Antara proses berikut, yang manakah digunakan untuk
Panaskan larutan asid. menghasilkan asid sulfurik?
B Add distilled water into the acid solution. A Haber Process
Tambahkan air suling ke dalam larutan asid. Proses Haber
C Add copper(II) sulphate into the mixture. B Contact Process
Tambahkan kuprum(II) sulfat ke dalam larutan. Proses Sentuh
D Add a few drops of concentrated hydrochloric
acid into the mixture.

S
Tambahkan beberapa titis asid hidroklorik pekat ke
dalam campuran.
C Photosynthesis process
Proses fotosintesis
D Neutralisation process
Proses peneutralan
R
13 Why the rate of reaction for gas reactant is affected 16 Which of the following increases the production of
by pressure? ammonia?
Mengapakah kadar tindak balas bagi bahan tindak balas Antara yang berikut, yang manakah meningkatkan
berkeadaan gas dipengaruhi oleh tekanan? penghasilan ammonia?
A Pressure affects the size of gas particles to A 200 atm, 450 °C and the presence of iron filings.
PT
increase the frequency of effective collisions. 200 atm, 450 °C dan kehadiran serbuk ferum.
Tekanan mempengaruhi saiz zarah gas bagi B 400 atm, 450 °C and the presence of iron filings.
meningkatkan frekuensi perlanggaran berkesan. 400 atm, 450 °C dan kehadiran serbuk ferum
B Pressure affects the distance between gas C 1 atm, 450 °C and the presence of iron filings.
particles to increase the frequency of collisions 1 atm, 450 °C dan kehadiran serbuk ferum.
between gas particles. D 200 atm, 450 °C and the presence of vanadium(V)
Tekanan mempengaruhi jarak antara zarah gas untuk oxide.
meningkatkan frekuensi perlanggaran antara zarah- 200 atm, 450 °C dan kehadiran vanadium(V) oksida.
zarah gas.
C Pressure converts gas particles into solid. 17 The chemical equation below shows the reaction
Tekanan menukarkan zarah gas menjadi pepejal. between nitrogen and hydrogen gas to form ammonia.
D Pressure converts gas particles into liquid. Persamaan kimia di bawah menunjukkan tindak balas antara
Tekanan menukarkan zarah gas menjadi cecair. gas nitrogen dan hidrogen untuk menghasilkan ammonia.
Iron filings
14 Understand the statement below. N2(g) + 3H2(g) 2NH3(g)
Serbuk ferum
Fahami pernyataan di bawah.
Why iron filings is used in this reaction?
• Meat cooks faster in hot oil than hot water. Mengapakah serbuk ferum digunakan dalam tindak balas
Daging lebih cepat masak di dalam minyak panas ini?
berbanding dengan air panas. A Increase the kinetic energy of nitrogen and
• Sliced meat cooks faster than chunk meat. hydrogen molecules.
Hirisan daging masak lebih cepat berbanding dengan Meningkatkan tenaga kinetik molekul nitrogen dan
ketulan daging. hidrogen.
B Increase the concentration of nitrogen and
Choose the correct statements. hydrogen gas.
Pilih pernyataan yang betul. Meningkatkan kepekatan gas hidrogen dan nitrogen.

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C The activation energy of the reaction is lowered. 19 Iron filings is used as a catalyst in Haber Process.
Tenaga pengaktifan tindak balas direndahkan. Which of the following statements are correct about
D Helps in producing more ammonia gas. iron filings?
Membantu menghasilkan gas ammonia yang banyak. Serbuk ferum digunakan sebagai mangkin dalam Proses
Haber. Antara pernyataan berikut yang manakah betul
18 Which of the following will not affect the rate of mengenai serbuk ferum?
reaction between nitrogen and hydrogen gas to form I Increases the production of ammonia.
ammonia in Haber Process? Meningkatkan penghasilan ammonia.
Antara berikut, yang manakah tidak mempengaruhi II Increases the rate of formation of ammonia.
kadar tindak balas antara gas nitrogen dan hidrogen bagi Meningkatkan kadar pembentukan ammonia.
menghasilkan ammonia dalam Proses Haber? III The iron filings is a more effective catalyst than
A Volume of the gases iron plate.
Serbuk ferum ialah pemangkin yang lebih berkesan
Isi padu gas
berbanding dengan kepingan ferum.
B Pressure of the reactant IV The mass of iron filings remain unchange after
Tekanan terhadap bahan tindak balas the reaction.
C Presence of iron filings Jisim serbuk ferum tidak berubah selepas tindak balas.
Kehadiran serbuk ferum A I, II and III C II, III and IV
D Concentration of the gases I, II dan III II, III dan IV
Kepekatan gas B I, III and IV D I, II, III and IV
I, III dan IV I, II, III dan IV

Paper 2 (a) Complete Table 1 by calculating the value of 1


Section A
1 Diagram 1 shows an experiment conducted by a
group of students to study the effect of temperature
S for the reaction at 45 °C.
Lengkapkan Jadual 1 dengan menghitung nilai
time

1
masa
R bagi tindak balas pada suhu 45 °C.
of reactant on rate of reaction between sodium [1 mark/markah]
thiosulfate solution and sulphuric acid.
Rajah 1 menunjukkan eksperimen yang dijalankan oleh (b) Based on the data in Table 1, plot a graph of
sekumpulan murid untuk mengkaji kesan suhu bahan
tindak balas terhadap kadar tindak balas antara larutan temperature against 1 on the graph paper.
natrium tiosulfat dengan asid sulfurik.
time
PT
Berdasarkan data dalam Jadual 1, plotkan satu graf
Sodium thiosulphate

FORM 5
solution + sulphuric acid suhu melawan 1 pada kertas graf.
Larutan natrium tiosulfat masa
+ asid sulfurik

Beginning of the experiment End of the experiment


Awal eksperimen Akhir eksperimen
Diagram 1/ Rajah 1

Table 1 shows the results of the experiment.


Jadual 1 menunjukkan keputusan eksperimen tersebut.

Reactant Time taken for ‘×’ mark 1


temperature to disappear from view Time
Suhu bahan Masa yang diambil untuk 1
tindak balas tanda ‘×’ hilang dari Masa
(°C) pandangan (s) (s-1)
28.0 42 0.024 [2 marks/markah]

35.0 26 0.038 (c) State one observation from this experiment.


40.0 21 0.047 Nyatakan satu pemerhatian daripada eksperimen
ini.
45.0 19
Table 1/ Jadual 1 [1 mark/markah]

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(d) State the relationship between the temperature (b) Predict what is metal Q.
and the rate of reaction for this experiment. Tick (3) to the correct answer.
Nyatakan hubungan antara suhu dengan kadar tindak Ramalkan apakah logam Q.
balas bagi eksperimen ini. Tandakan (3) pada jawapan yang betul.

[1 mark/markah] Sodium/ Natrium


(e) Predict the time for ‘×’ mark to disappear from Calcium/ Kalsium
view if the temperature is increased to 50.0°C.
Ramalkan masa untuk tanda ‘×’ hilang dari pandangan Zinc/Zink
jika suhu tindak balas ditingkatkan kepada 50.0 °C. [1 mark/markah]

(c) State one constant variable.


[1 mark/markah]
Nyatakan satu pemboleh ubah dimalarkan.
2 Diagram 2.1 and Diagram 2.2 shows the volume
of gas accumulated in the measuring cylinder after [1 mark/markah]
10 minutes when magnesium and metal Q were
(d) Based on this experiment, state the operational
reacting with dilute hydrochloric acid respectively.
definition of rate of reaction.
Rajah 2.1 dan Rajah 2.2 menunjukkan isi padu gas yang
Berdasarkan eksperimen ini, nyatakan definisi secara
terkumpul di dalam silinder penyukat selepas 10 minit
operasi bagi kadar tindak balas.
apabila magnesium dan logam Q masing-masing bertindak
balas dengan asid hidroklorik cair.
Dilute hydrochloric Measuring cylinder [1 mark/markah]
Silinder penyukat
acid
Asid hidroklorik cair

Magnesium
Magnesium
300
400

S Section B
3 Diagram 3 shows the graph of volume of hydrogen
R
gas produced against time.
Reaction X/ Tindak balas X Rajah 3 menunjukkan graf isi padu gas hidrogen yang
Diagram 2.1/ Rajah 2.1 terhasil melawan masa.
Dilute hydrochloric Measuring cylinder 3
Volume of hydrogen gas (cm )
acid Silinder penyukat 3
Isi padu gas hidrogen (cm )
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Asid hidroklorik cair 0
100
200
35
Metal Q 300
400
Logam Q 30

25
Reaction Y/ Tindak balas Y
Diagram 2.2/ Rajah 2.2 20

(a) (i) Write one observation that can be made 15


based on Diagram 2.1 and Diagram 2.2.
Tuliskan satu pemerhatian yang boleh dibuat 10
berdasarkan Rajah 2.1 dan Rajah 2.2.
5

Time(s)
10 20 30 40 50 60 70 Masa(s)

Diagram 3/ Rajah 3

(a) What is the volume of gas released in 20 seconds?


[1 mark/markah]
Berapakah isi padu gas yang terhasil pada masa
(ii) Write one inference based on your answer 20 saat?
in 2(a)(i).
Tuliskan satu inferens berdasarkan jawapan anda
di 2(a)(i). [1 mark/markah]

[1 mark/markah]

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(b) Calculate the average rate of reaction: Aminah found that uncut potatoes take longer time
Hitung kadar tindak balas purata: to cook than the small cut potatoes. Duration for the
(i) for the first 30 seconds. potatoes to cook refers to the reaction rate.
untuk 30 saat yang pertama. Aminah mendapati bahawa kentang yang tidak dipotong
mengambil masa yang lebih lama untuk dimasak
berbanding dengan kentang yang dipotong kecil. Tempoh
untuk kentang masak merujuk kepada kadar tindak balas.
(a) State one problem statement from the above
[2 marks/markah] information.
(ii) for the whole reaction. Nyatakan satu pernyataan masalah daripada maklumat
untuk keseluruhan tindak balas. di atas.
[1 mark/markah]

(b) Suggest one hypothesis to investigate the above


statement.
Cadangkan satu hipotesis untuk menyiasat pernyataan
[2 marks/markah]
di atas.
(c) Give one example of a reaction that releases [1 mark/markah]
hydrogen gas. (c) Based on the given statement, design a laboratory
Berikan satu contoh tindak balas yang membebaskan experiment to test your hypothesis using small
gas hidrogen.
and large marble chips, dilute hydrochloric
acid, water, conical flask, measuring cylinder,
[1 mark/markah] rubber stopper with delivery tube, burette, basin,

Senaraikan dua faktor yang mempengaruhi kadar


tindak balas.
S
(d) List two factors that affect the rate of reaction. electronic balance and retort stand with clamps.
Berdasarkan pernyataan yang diberi, reka bentuk
satu eksperimen makmal untuk menguji hipotesis
anda dengan menggunakan ketulan marmar kecil dan
R
• besar, asid hidroklorik cair, air, kelalang kon, silinder
penyukat, penyumbat getah dengan salur penghantar,

buret, besen, penimbang elektronik dan kaki retort
[2 marks/markah]
dengan pengapit.

Section C Your description should include the following


PT
criteria:

FORM 5
4 Aminah was asked to prepare dinner. She boiled
Huraian anda harus mengandungi aspek berikut:
uncut potatoes in pot K and small cut potatoes in pot L.
(i) Aim of the experiment.
Aminah diminta untuk menyediakan makan malam. Dia
Tujuan eksperimen.
telah merebus kentang yang tidak dipotong di dalam periuk [1 mark/markah]
K dan kentang yang dipotong kecil di dalam periuk L.
(ii) Identification of variables.
Mengenal pasti pemboleh ubah.
[2 marks/markah]
(iii) Procedure or method.
Prosedur atau kaedah.
[4 marks/markah]
(iv) Tabulation of data.
Penjadualan data.
K [1 mark/markah]

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