NME-Laporan 2 - Kelompok 25

A.
Perhitungan Cp Menggunakan Metode Estimasi
Unsur Δe (J/moloK)_x000D_ (Perry, 1999)

C 10.89
H 7.56
O 13.42
Cl 24.69
Na 26.19
1. Selulosa (C6H10O5)n
4. Na-CMC (C8H11O7Na)n
n = 1000
MR = 162000 g/mol 162 kg/mol
nE ΣnE ΣΔE
C= 6 6000 65340
H= 10 10000 75600
O= 5 5000 67100
208040
CpSelulosa =_x000D_ 208040 J/mol.K 1284.1975 J/kg.K CpNa-CMC =_x000D_
2. Hemiselulosa(C5H8O4)n 5. Na-MCA
n= 175
MR = 23100 g/mol 23.1 kg/mol
nE ΣnE ΣΔE
C= 5 875 9528.75
H= 8 1400 10584
O= 4 700 9394
29506.75
CpHemiselulosa =_x000D_ 29506.75 J/mol.K 1277.3485 J/kg.K CpNa-MCA =_x000D_
6. Na-Glikolat (OHCH2COON
3. Lignin (C9H10O2)n
)
n= 10
MR = 1500 g/mol 1.5 kg/mol
nE ΣnE ΣΔE
C= 9 90 980.1
H= 10 100 756
O= 2 20 268.4
2004.5
Cplignin =_x000D_ 2004.5 J/mol.K 1336.3333 J/kg.K CpNa-Glikolat =_x000D_
Na = 1 0 0 0
4. Na-CMC (C8H11O7Na)n 7. Selulosa-Na ( (C6H9O5Na)n)
n= 1000 n=
MR = 242000 g/mol 242 kg/mol MR =
nE ΣnE ΣΔE
C= 8 8000 87120 C=
H= 11 11000 83160 H=
O= 7 7000 93940 O=
Na = 1 1000 26190 Na =
290410
CpNa-CMC =_x000D_ 290410 J/mol.K 1200.0413 J/kg.K CpSelulosa =_x000D_
ClCH2COONa_x000D_
nE ΣnE ΣΔE
Cl = 1 1 24.69
C= 2 2 21.78
H= 2 2 15.12
61.59
CpNa-MCA =_x000D_ 61.59 J/molK 733.21429 J/kg.K
6. Na-Glikolat (OHCH2COONa
)
nE ΣnE ΣΔE
C= 2 2 21.78
H= 3 3 22.68
O= 3 3 40.26
Na = 1 1 26.19
110.91
CpNa-Glikolat =_x000D_ 110.91 J/molK 1131.7347 J/kg.K
C6H9O5Na)n)
1000
184000 g/mol 184 kg/mol
nE ΣnE ΣΔE
6 6000 65340
9 9000 68040
5 5000 67100
1 1000 26190
200480
200480 J/mol.K 1089.5652 J/kg.K

B. Perhitungan Cp Menggunakan Appendix Yaws
Gas Cp = A+BT+CT2+DT3+ET4_x000D_ (Yaws)

Solid Cp = A+BT+CT 2_x000D_
Liquid Cp = A+BT+CT2+DT3_x000D_
GAS
1. H2O_x000D_
MR = 18 g/mol
T= 298.15 K
A B C D E Cp (J/mol.K)
H2O(g)_x000D_ 33.933 -0.008419 0.000029906 -1.7825E-08 3.6934E-12 9973.677017
SOLID LIQUID
1. NaOH 1. H2O_x000D_
MR = 40 g/mol MR =
T= 298.15 K T=
A B C Cp (J/mol.K) A
NaOH 51.234 0.013088 2.336E-05 16063.501318 H2O(l)_x000D_ 92.053
2. Asam Monokloroasetat (MCA) C2H3ClO2_x000D_ 3. H2O2_x000D_

MR = 94.497 g/mol MR =
T= 298.15 K T=
A B C Cp (J/mol.K) A
MCA -55.75 0.59859 9983.4943871 H2O2_x000D_ -15.248
3. NaCl
MR = 58.5 g/mol
T= 298.15 K
A B C Cp (J/mol.K)
NaCl 41.293 0.033607 -1.393E-05 13682.19015
LIQUID
18 g/mol
298.15 K
B C D Cp (J/mol.K)
-0.039953 -0.000211 5.347E-07 24861.758278
34 g/mol
298.15 K
B C D Cp (J/mol.K)
0.67693 -0.001495 1.202E-06 14709.4417028
Kapasitas Produksi : 6000 ton/tahun
Masa Aktif Produksi : 330 hari
Temperatur Referensi : 25 C_x000D_
o
: 298 K
Basis Perhitungan : kg/jam
Bahan Baku : Bagasse_x000D_
Produk : Carboxymethyl Cellulose (CMC)_x000D_
Kapasitas Perancangan Pabrik CMC

Kapasitas Produksi = 757.5758 kg/jam 757.5757575758
Basis Perancangan = 786.474 kg/jam
26. Rotary Reactor (R-101)

Fungsi : Reaksi karboksimetilasi
Asumsi : 1. Konversi reaksi 80%
2. Basis F36 =_x000D_441.4876
3. Udara keluar F48 membawa 1% produk hasil reaksi_x000D_
4. Rasio Selulosa : MCA adalah 1:1,2
5. Rasio MCA : NaOH adalah 1:1,7
Data aliran 36 F36 =_x000D_ 441.4876 kg/jam

Komponen w F (kg/jam) Mr (kg/kmol) N (kmol)
Selulosa 0.95 419.4132 162000 0.002588971
H2O_x000D_ 0.05 22.0744 18 1.22635449
1.22894346
1.200000 1.7
Tahap 1 : Alkalisasi Selulosa konversi = 0.999

(C6H10O5)1000 + 1000NaOH → (C6H9O5Na)1000
Mula 0.0025889706 + 0.005281500 →
Reaksi 0.000005276 + 0.005276219 → 0.000005276
Sisa 0.0025836944 + 0.000005282 → 0.000005276
Tahap 2 : Eterifikasi konversi = 0.8

ClCH2COOH + NaOH → ClCH2COONa
Mula 0.003106765 + 0.000005282 →
Reaksi 0.000000004 + 0.000004225 → 0.000000004
Sisa 0.0031067605 + 0.000001056 → 0.000000004
konversi = 0.8
ClCH2COONa + (C6H9O5Na)1000 → (C8H11O7Na)1000
Mula 0.000000004 + 0.000005276 →
Reaksi 0.000000003 + 0.000000003 → 0.000000003
Sisa 0.000000001 + 0.000005273 → 0.000000003
Tahap 3 : Reaksi samping 0.8

ClCH2COONa + 1000NaOH → OHCH2COONa
Mula 0.000000001 + 0.00000106 →
Reaksi 0.00000000 + 0.00000085 → 0.000000001
Sisa 0.00000000 + 0.00000021 → 0.000000001
Komponen Mr (kg/kmol) w F (kg/jam) X N (kmol)

Selulosa 162000 0.946 418.55848808 0.002044 0.002584
Selulosa-Na 184000 0.002 0.97020225 0.000004 0.000005
MCA 94.497 0.001 0.29357955 0.002458 0.003107
MCA-Na 84 0.000 0.00000000 0.000000 0.000000
NaOH 40 0.000 0.00000845 0.000000 0.000000
CMC 242000 0.000 0.00081800 0.000000 0.000000
Na-Glikolat 98 0.000 0.00000008 0.000000 0.000000
NaCl 58.5 0.000 0.00024717 0.000003 0.000004
H2O_x000D_ 18 0.051 22.64457340 0.995489 1.258032
1 442 1.000000 1.263732
Masuk
Komponen
F 36
N36
F40
N40
F44
Selulosa 419 0.002589
Selulosa-Na
MCA 0.294 0.003
MCA-Na
NaOH 0.21
CMC
Na-Glikolat
NaCl
H2O_x000D_ 22 1.22635449 0.08 0.004600256 0.39
O2
N2
Total 441 1 0 0 1
27. Heater (E-204)

F masuk F keluar N masuk N keluar
Komponen Mr
46 48 46 48
Selulosa 162000.0 414.3729 414.3729 0.0026 0.0026
Selulosa-Na 184000.0 0.9605 0.9605 0.0000 0.0000
MCA 94.5 0.2906 0.2906 0.0031 0.0031
MCA-Na 84.0 0.0000 0.0000 0.0000 0.0000
NaOH 40.0 0.0000 0.0000 0.0000 0.0000
CMC 242000.0 0.0008 0.0008 0.0000 0.0000
Na-Glikolat 98.0 0.0000 0.0000 0.0000 0.0000
NaCl 58.5 0.0002 0.0002 0.0000 0.0000
H2O_x000D_ 18.0 22.4181 22.4181 1.2455 1.2455
Total 588393.0 438.0432 438.0432 0.0007 0.0007
28. Aging vessel (V-103)

F in F out N in N out
Komponen Mr
Komponen Mr
48 49 N48 N49
Selulosa 162000.0 414.3729 414.3729 0.0026 0.0026
Selulosa-Na 184000.0 0.9605 0.9605 0.0000 0.0000
MCA 94.5 0.2906 0.2906 0.0031 0.0031
MCA-Na 84.0 0.0000 0.0000 0.0000 0.0000
NaOH 40.0 0.0000 0.0000 0.0000 0.0000
CMC 242000.0 0.0008 0.0008 0.0000 0.0000
Na-Glikolat 98.0 0.0000 0.0000 0.0000 0.0000
NaCl 58.5 0.0002 0.0002 0.0000 0.0000
H2O_x000D_ 18.0 22.4181 22.4181 1.2455 1.2455
Total 588393.0 438.0432 438.0432 0.0007 0.0007
29. Cooler (E-205)

Masuk Keluar Masuk Keluar
Komponen Mr
F49 F50 N49 N50
Selulosa 162000.0 414.373 414.373 0.002557857 0.002557857427
Selulosa-Na 184000.0 0.961 0.961 5.22011E-06 5.220109959E-06
MCA 94.5 0.291 0.291 0.003075693 0.003075692877
MCA-Na 84.0 0.000 0.000 0 0
NaOH 40.0 0.000 0.000 2.09147E-07 2.091474001E-07
CMC 242000.0 0.001 0.001 3.34636E-09 3.346358401E-09
Na-Glikolat 98.0 0.000 0.000 8.3659E-10 8.365896004E-10
NaCl 58.5 0.000 0.000 4.18295E-06 4.182948002E-06
H2O_x000D_ 18.0 22.418 22.418 1.245451537 1.245451537057
Total 588392.997 438.043 438.043 1.251 1.251
30. Cyclone (CY-301)

Masuk Keluar Masuk
Komponen Mr
F47 F51 F52 N47
Selulosa 162000 4.186 0.0419 4.1437 0.000026
Selulosa-Na 184000 0.010 0.0001 0.0096 0.000000
MCA 94.497 0.003 0.0000 0.0029 0.000031
MCA-Na 84 0.000 0.0000 0.0000 0.000000
NaOH 40 0.000 0.0000 0.0000 0.000000
CMC 242000 0.000 0.0000 0.0000 0.000000
Na-Glikolat 98 0.000 0.0000 0.0000 0.000000
NaCl 58.5 0.000 0.0000 0.0000 0.000000
H2O_x000D_ 18 0.226 0.0023 0.2242 0.012580
O2 32 1000.000 1000.0000 31.250000
N2 14 1000.000 1000.0000 71.428571
Total 588439 2004.42 2000.04 4.380 102.69
588439 2004.42 2004.42 102.69

Masuk Keluar Masuk
Komponen Mr
F51 F53
F54
N51
Selulosa 162000 0.0419 0.0004 0.0414 0.0000003
Selulosa-Na 184000 0.0001 0.0000 0.0001 0.0000000
MCA 94.5 0.0000 0.0000 0.0000 0.0000003
MCA-Na 84 0.0000 0.0000 0.0000 0.0000000
NaOH 40 0.0000 0.0000 0.0000 0.0000000
CMC 242000 0.0000 0.0000 0.0000 0.0000000
Na-Glikolat 98 0.0000 0.0000 0.0000 0.0000000
NaCl 58.5 0.0000 0.0000 0.0000 0.0000000
H2O_x000D_ 18 0.0023 0.0000 0.0022 0.0001258
O2 32 1000.0000 1000.0000 31.2500000
N2 14 1000.0000 1000.0000 71.4285714
Total 588438.997 2000.044 2000.000 0.044 102.679
32. Silo (TK-107)

Masuk Keluar
Komponen Mr
F
50
F52 F54
F55
Selulosa 162000 414.3729 4.1437 0.0414 418.5581
Selulosa-Na 184000 0.9605 0.0096 0.0001 0.9702
MCA 94.497 0.2906 0.0029 0.0000 0.2936
MCA-Na 84 0.0000 0.0000 0.0000 0.0000
NaOH 40 0.0000 0.0000 0.0000 0.0000
CMC 242000 0.0008 0.0000 0.0000 0.0008
Na-Glikolat 98 0.0000 0.0000 0.0000 0.0000
NaCl 58.5 0.0002 0.0000 0.0000 0.0002
H2O_x000D_ 18 22.4181 0.2242 0.0022 22.6446
Total 438.0432 4.3804 0.0438 442.4675
442.4675 442.4675
33. Rotary Dryer (RD-301)

Masuk Keluar
Komponen Mr
F55 F57 F58 F59
Selulosa 162000 418.56 418.558
Selulosa-Na 184000 0.97 0.970
MCA 94.497 0.29 0.294
MCA-Na 84 0.00 0.000
NaOH 40 0.00 0.000
CMC 242000 0.00 0.001
Na-Glikolat 98 0.00 0.000
NaCl 58.5 0.00 0.000
H2O_x000D_ 18 22.64 22.192 0.453
O2 32 46.61 46.613
N2 14 76.72 76.717
Total 442 123 145.522 420.276
566 566
34. Heater (E-301)

Komponen Mr F56 F57 N56 N57
Komponen Mr F56 F57 N56 N57
O2 32 46.613 46.613 1.457 1.457
N2 14 76.717 76.717 5.480 5.480
Total 46 123 123 7 7
36. Cooler (E-302)

Komponen Mr
F59 F60 N59 N50
Selulosa 162000 418.558 418.558 0.0026 0.002583691787
Selulosa-Na 184000 0.970 0.970 0.0000 5.272833069E-06
MCA 94.497 0.294 0.294 0.0031 0.003106757375
MCA-Na 84 0.000 0.000 0.0000 0
NaOH 40 0.000 0.000 0.0000 2.112597888E-07
CMC 242000 0.001 0.001 0.0000 3.380156621E-09
Na-Glikolat 98 0.000 0.000 0.0000 8.450391553E-10
NaCl 58.5 0.000 0.000 0.0000 4.225195777E-06
H2O_x000D_ 18 0.453 0.453 0.0252 0.025160611952
Total 588392.997 420.276 420.276 0.03086 0.03086
33. Ball mill (BM-301)

Komponen Mr
F60 F61 N50 N61
Selulosa 162000 418.56 418.56 0.002583692 0.002583691787
Selulosa-Na 184000 0.97 0.97 5.27283E-06 5.272833069E-06
MCA 94.497 0.29 0.29 0.003106757 0.003106757375
MCA-Na 84 0.00 0.00 0 0
NaOH 40 0.00 0.00 2.1126E-07 2.112597888E-07
CMC 242000 0.00 0.00 3.38016E-09 3.380156621E-09
Na-Glikolat 98 0.00 0.00 8.45039E-10 8.450391553E-10
NaCl 58.5 0.00 0.00 4.2252E-06 4.225195777E-06
H2O_x000D_ 18 0.45 0.45 0.025160612 0.025160611952
Total 588392.997 420 420 0.030860775 0.030860774628
37. Product Tank (TK-108)

Komponen Mr
F61 F62 N61 N62
Selulosa 162000 418.56 418.56 0.00258 0.00258
Selulosa-Na 184000 0.97 0.97 0.00001 0.00001
MCA 94.497 0.29 0.29 0.00311 0.00311
MCA-Na 84 0.00 0.00 0.00000 0.00000
NaOH 40 0.00 0.00 0.00000 0.00000
CMC 242000 0.00 0.00 0.00000 0.00000
Na-Glikolat 98 0.00 0.00 0.00000 0.00000
NaCl 58.5 0.00 0.00 0.00000 0.00000
H2O_x000D_ 18 0.45 0.45 0.02516 0.02516
Total 588392.9970 420.2758 420.2758 0.03086 0.03086
1. Roll crusher (RC-101)
Komponen Mr
F1 F2 N1 N2
Selulosa 162000 413.934 413.934 0.002555146 0.002555146199
Hemiselulosa 23100 206.967 206.967 0.008959604 0.008959603554
Lignin 1500 206.967 206.967 0.137977895 0.137977894737
827.867 827.867 0.149492644 0.14949264449
2. Vibrating screen (VS-101)

Masuk Keluar Masuk
Komponen Mr
F2 F3 F4 N2
Selulosa 162000 413.934 20.697 393.237 0.002555146199
Hemiselulosa 23100 206.967 10.348 196.619 0.008959603554
Lignin 1500 206.967 10.348 196.619 0.137977894737
827.867 41.393 786.474 0.14949264449
827.867 827.867 0.14949264449
3. Silo 1 (TK-101)
Komponen Mr
F4 F5 N4 N5
Selulosa 162000 393.237 393.237 0.002427389 0.002427388889
Hemiselulosa 23100 196.619 196.619 0.008511623 0.008511623377
Lignin 1500 196.619 196.619 0.131079 0.131079
786.474 786.474 0.142018012 0.142018012266
4. Steam Explosion Tank (V-101)

Masuk Keluar Masuk
Komponen Mr
5 6 7 5
Selulosa 162000 393.237 393.237 0.002427388889
Hemi 23100 196.619 58.986 0.008511623377
Hemi aq 23100 137.633
Lignin 1500 196.619 196.619 0.131079
H2O g 18 1258.358
H2O l 18 1572.948 314.590
786.474 1572.948 2359.422 0.142018012266
2359.422 2359.422 87.5280180122655
5. Flash Tank (V-102)

Masuk Keluar
Komponen
7 8 9 Mr 7
Selulosa 393.237 393.237 162000 0.002427388889
Hemi 58.986 58.986 23100 0.002553487013
Hemi aq 137.633 137.633 23100 0.005958136364
Lignin 196.619 196.619 1500 0.131079
H2O g 1258.358 1258.358 18 69.9088
H2O l 314.590 314.590 18 17.4772
2359.422 1101.064 1258.358 87.52801801227
2359.422 2359.422 87.52801801227
6. Heater (E-101)
Masuk Keluar
Komponen
8 10 Mr 8 10
Selulosa 393.237 393.237 162000 0.002427389 0.002427388889
Hemi 58.986 58.986 23100 0.002553487 0.002553487013
Hemi aq 137.633 137.633 23100 0.005958136 0.005958136364
Lignin 196.619 196.619 1500 0.131079 0.131079
H2O l 314.590 314.590 18 17.4772 17.4772
1101.064 1101.064 17.61921801 17.61921801227
7. Mixer (M-101)
Masuk Keluar
Komponen
12 13 14 Mr 12
NaOH 1101.064 1101.064 40 27.52659
H2O 1101.064 3303.191 4404.254 18 61.1702
2202.127 3303.191 5505.318 88.69679
5505.318 5505.318 272.20739
8. Heater (E-102)
Masuk Keluar
Komponen
14 15 Mr 14 15
NaOH 1101.064 1101.064 40 27.52659 27.52659
H2O 4404.254 4404.254 18 244.6808 244.6808
5505.318 5505.318 272.20739 272.20739
9. Delignification Tank (DT-101)

Masuk Keluar
Komponen
8 15 16 Mr 8
Selulosa 393.237 393.237 162000 0.002427388889
Hemi 58.986 23100 0.002553487013
Hemi aq 137.633 196.619 23100 0.005958136364
Lig 196.619 9.831 1500 0.131079
Lig aq 186.788 1500
H2O l 314.590 4404.254 4718.844 18 17.4772
NaOH 1101.064 1101.064 40
1101.064 5505.318 6606.382 17.61921801227
6606.382 6606.382 289.826608012266
10. Expansion Valve (EV-101)
Masuk Keluar
Komponen
16 17 Mr 16 17
Selulosa 393.237 393.237 162000 0.002427389 0.002427388889
Hemi aq 196.619 196.619 23100 0.008511623 0.008511623377
Lig 9.831 9.831 1500 0.00655395 0.00655395
Lig aq 186.788 186.788 1500 0.12452505 0.12452505
H2O l 4718.844 4718.844 18 262.158 262.158
NaOH 1101.064 1101.064 40 27.52659 27.52659
6606.382 6606.382 289.826608 289.8266080123
11. Cooler (E-103)

Masuk Keluar
Komponen
17 18 Mr 17 18
Selulosa 393.237 393.237 162000 0.002427389 0.002427388889
Hemi aq 196.619 196.619 23100 0.008511623 0.008511623377
Lig 9.831 9.831 1500 0.00655395 0.00655395
Lig aq 186.788 186.788 1500 0.12452505 0.12452505
H2O l 4718.844 4718.844 18 262.158 262.158
NaOH 1101.064 1101.064 40 27.52659 27.52659
6606.382 6606.382 289.826608 289.8266080123
12. Heater (E-104)

Masuk Keluar
Komponen
19 20 Mr 19 20
H2O 13212.763 13212.763 18 734.0424 734.0424
13212.763 13212.763
13. Rotary Filter (RF-101)

Masuk Keluar
Komponen
18 20 22 21 Mr
Selulosa 393.237 393.237 162000
Hemi aq 196.619 196.619 23100
Lig 9.831 9.831 1500
Lig aq 186.788 186.788 1500
H2O l 4718.844 13212.763 358.632 17572.975 18
NaOH 1101.064 1101.064 40
6606.382 13212.763 761.700 19057.445
19819.145 19819.145
14. Heater (E-105)

Masuk Keluar
Komponen
23 24 Mr 23 24
H2O2 228.510 228.510 Err:509 Err:509 Err:509
228.510 228.510
15. Heater (E-106)+B140

Masuk Keluar
Komponen
25 26 Mr 23 24
H2O 2466.082 2466.082 18 137.0045419 137.0045418529
2466.082 2466.082
16. Bleaching Tank (BT-101)

Masuk Keluar
Komponen
21 24 26 27 Mr
Selulosa 393.237 393.237 162000
Lig 9.831 1500
Lig aq 9.831 1500
H2O l 358.632 2466.082 2824.714 18
H2O2 228.510 228.510 Err:509
761.700 228.510 2466.082 3456.292
3456.292 3456.292
17. Heater (E-107)

Masuk Keluar
Komponen
28 29 Mr 28 29
H2O 6912.584 6912.584 18 384.032427 384.0324270059
6912.584 6912.584

Masuk Keluar
Komponen
27 29 30 31 Mr
Selulosa 393.237 393.237 162000
Lig aq 9.831 9.831 1500
H2O l 2824.714 6912.584 9542.552 194.746 18
H2O2 228.510 228.510 Err:509
3456.292 6912.584 9780.893 587.983
10368.876 10368.876
19. Heater (E-108)

Masuk Keluar
Komponen
32 33 Mr 32 33
Udara Err:509 Err:509 28.97 Err:509 Err:509
Err:509 Err:509
20. Rotary RD (RD-101)
Masuk Keluar
Komponen
31 33 34 35
Selulosa 419.413 419.413
H2O 194.746 172.672 22.074
Udara Err:509 Err:509 Err:509
614.159 Err:509 Err:509 441.488 Err:509
Err:509 Err:509
21. Cooler (E-109)

Masuk Keluar
Komponen
36 37 Mr 36 37
Selulosa 419.413 419.413 162000 0.002588971 0.002588970589
H2O 22.074 22.074 18 1.22635449 1.226354489693
441.488 441.488 1.22894346 1.228943460283
22. Mixer (M-102)

Komponen Masuk Keluar
38 39 40 mr 38
MCA 0.294 0.294 0 #DIV/0!
H2O 0.002965454 0.079839146 0.083 18 0.000164747444
0.2965453985 0.079839146 0.376 #DIV/0!
0.376 0.376 #DIV/0!
23. Heater (E-110)

Masuk Keluar
Komponen
40 41 Mr 40 41
MCA 0.294 0.294 0 #DIV/0! #DIV/0!
H2O 0.083 0.083 18 0.004600256 0.004600255541
0.376 0.376 #DIV/0! #DIV/0!
24. Mixer (M-103)

Masuk Keluar
Komponen
42 43 44 Mr
NaOH 0.211 0.211 Err:509 40
H2O 0.211 0.18 0.392 Err:509 18
0.4225200002 0.18108 0.60360000026 Err:509
0.604 0.604
25. Heater (E-111)
Masuk Keluar
Komponen
44 45 Mr 44 45
NaOH 0.211 0.211 40 0.0052815 189.340149497
H2O 0.392 0.392 18 0.021796667 0.021796666676
0.604 0.604 0.027078167 189.3619461637
Data Aliran 40 F40 =_x000D_ 0.37638454428 kg/jam
MCA 0.78 0.293579944538 94.497 0.003
H2O_x000D_ 0.22 0.082804599742 18 0.004600256
0.008
0.94139376545
+ 1000H2O
+ 1.252751411911
+ 0.005276219
+ 1.258027630413
+ H2O
1.258027630413
+ 0.000004225
+ 1.258031855613
+ 1000NaCl
+ 0.000003
+ 3.38016E-06
+ 1000NaCl
3.38016E-06
+ 0.000000845
+ 0.0000042
F (kg/jam) N (kmol) F (kg/jam) N (kmol)

414.372903197 0.002557857427 4.185584880777 2.5836944E-05
0.96050023243 5.22010996E-06 0.00970202255 5.2728383E-08
0.29064374982 0.003075692877 0.002935795453 3.1067605E-05
0 0 0 0
8.365896E-06 2.091474E-07 8.450400004E-08 2.1126E-09
0.00080981873 3.3463584E-09 8.179987204E-06 3.38016E-11
8.19857808E-08 8.365896E-10 8.281392004E-10 8.4504E-12
0.00024470246 4.182948E-06 2.471742001E-06 4.2252E-08
22.418127667 1.245451537057 0.22644573401 0.01258031856
438.043238 1.251095 4.424679 0.012637
k Keluar
N 44
F45
N 45
F46
N46
F47
414.372903 0.002558 4.185585
0.960500 0.000005 0.009702
0.290644 0.003076 0.002936
0.000000 0.000000 0.000000
0.005 0.000008 0.000000 0.000000
0.000810 0.000000 0.000008
0.000000 0.000000 0.000000
0.000245 0.000004 0.000002
0.02179666668 22.418128 1.245452 0.226446
1000.00 0 1000.000
1000.00 0 1000.000
0 2000 0 438 1.251 2004
2442.468 1.263729 2442.468
0.000
Fungsi : Meningkatkan suhu keluaran dari rotary reactor

Asumsi : 1. Tidak terjadi perubahan massa
Fungsi : Pematangan produk

Kondisi : T = 55 o
C_x000D_ kg/jam
t= 8 jam
Fungsi : Menurunkan suhu dari aging vessel

Keluar Fungsi : Memisahkan produk dari udara

N51 N52 Asumsi : 1. 1% produk terbawa udara
0.000000 0.000026
0.000000 0.000000
0.000000 0.000031
0.000000 0.000000
0.000000 0.000000
0.000000 0.000000
0.000000 0.000000
0.000000 0.000000
0.000126 0.012455
31.250000
71.428571
102.68 0.013
102.69
N53
N54
Asumsi : 1. 1% produk terbawa udara
0.0000000 0.0000003
0.0000000 0.0000000
0.0000000 0.0000003
0.0000000 0.0000000
0.0000000 0.0000000
0.0000000 0.0000000
0.0000000 0.0000000
0.0000000 0.0000000
0.0000013 0.0001245
31.2500000
71.4285714 0.0000000
102.679 0.000
N50 N52 N54 N55

0.00255785743 2.55785743E-05 2.557857427E-07 0.00258369179
5.22010996E-06 5.22010996E-08 5.220109959E-10 5.2728331E-06
0.00307569288 3.07569288E-05 3.075692877E-07 0.00310675738
0 0 0 0
2.091474E-07 2.091474E-09 2.091474001E-11 2.1125979E-07
3.3463584E-09 3.3463584E-11 3.346358401E-13 3.3801566E-09
8.365896E-10 8.365896E-12 8.365896004E-14 8.4503916E-10
4.182948E-06 4.182948E-08 4.182948002E-10 4.2251958E-06
1.24545153706 0.012454515371 0.000124545154 1.25803059758
1.25109470375 0.012510947037 0.00012510947 1.2637307603
1.263731 1.2637307603
N Fungsi : Mengurangi kadar air

55 57 58 59 Asumsi : 1. Efisiensi 95%
0.00258369179 0.00258369179
5.27283307E-06 5.2728331E-06
0.00310675738 0.00310675738
0 0
2.11259789E-07 2.1125979E-07
3.38015662E-09 3.3801566E-09
8.45039155E-10 8.4503916E-10
4.22519578E-06 4.2251958E-06
1.25803059758 1.232869985629 0.02516061195
1.456653645861 1.456653645861
5.47979228681 5.47979228681
1.26373076026 6.936445932671 8.169315918301 0.03086077463
8.20017669292855 8.20017669292855
Fungsi : Memperkecilkan ukuran prduk
Asumsi : tidak teriadi perubahan massa
0.00019463359
Fungsi : Mencacah Bagasse menjadi 2 mm
Asumsi : 1. Efisiensi Roll crusher 95%
2. Aliran F3 dimasukkan kembali kedalam roll crusher
asumsi F1 = 827.867
Feed = 786.474 kg bagasse
Keluar Fungsi : Untuk Screening bagasse yang memenuhi ukuran

N3 N4 Asumsi : 1. Aliran 3 adalah 5% dari aliran 2
0.00012775731 0.002427388889
0.00044798018 0.008511623377
0.00689889474 0.131079
0.00747463222 0.142018012266
0.149492644490013
Fungsi : Untuk menyimpan bagasse sementara

Asumsi : tidak ada perubahan massa
Masuk Keluar Fungsi : Melunakan serta mengurangi ukuran partikel dan kandungan hemise
6 7 Asumsi : 1. Aliran keluar tangki dalam keadaan saturated pada tekanan atmos
0.002427388889 2. Adiabatic expansion process
0.002553487013 3. 70% hemiselulosa terpisahkan dari bagasse
0.005958136364 4. Rasio saturated steam terhadap bagasse 1:2
0.131079
69.9088 y= 0.8000
87.386 17.4772 x= 0.2000
87.386 87.52801801227
87.5280180122655 87.52801801227
Fungsi : Untuk melepaskan uap air sisa steam explotion tank

8 9 Asumsi : 1. semua uap terlepas ke aliran 9
0.00242738889
0.00255348701
0.00595813636
0.131079
69.9088
17.4772
17.6192180123 69.9088
87.5280180122655
Fungsi : Untuk meningkatkan suhu keluaran dari flash tank (V-102) dari 100C menjadi 150C
Asumsi : 1. Menggunakan steam suhu
karena tidak ada perubahan massa masuk dan keluar maka nilai F8 = F10
Fungsi : Untuk mengencerkan NaOH 50% menjadi 20%

13 14 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 :
27.52659 F11= 1101.275
183.5106 244.6808 1101.275
183.5106 272.20739 2202.550
272.20739
Fungsi : Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)

Fungsi : Untuk memecahkan ikatan lignin

15 16 T= 150
0.002427388889 P= 7
Asumsi : 1. rasio bagasse : cairan NaOH adalah 1:5
0.008511623377 2. menghilangkan lignin sebesar 95%
0.00655395 3. melarutkan hemiselulosa yang masih tersisa dari dalam bagasse
0.12452505
244.6808 262.158
27.52659 27.52659
272.20739 289.8266080123
289.826608012266 289.8266080123
Fungsi : Untuk menurunkan tekanan keluaran dari tangki delignifikasi (DT-101)
Asumsi: 1. Tidak ada perubahan masa
2. Tekanan diturunkan dari 7 menjadi 1 bar
Fungsi : Untuk mendinginkan keluaran dari tangki delignifikasi

Asumsi: 1. tidak ada perubahan massa
2. medinginkan dari suhu 150 ke suhu 80
Fungsi : Untuk meningkatkam suhu air pencucian yang akan masuk kedalam rotary filter 1
Asumsi: 1. Tidak ada perubahan massa
2. Meningkatkan suhu air dari 30 menjadi 80
3. Rasio air yang digunakan untuk pencucian 2 : 1
Fungsi : Untuk memisahkan selulosa dari sisa b

18 20 22 21 Asumsi : 1. Efisiensi rotary filter 98%
0.00242738889 0.002427388889 2. Rasio Air pencucian dan pulp 2 : 1
0.00851162338 0.00851162338
0.00655395 0.00655395
0.12452505 0.12452505
262.158 734.0424 19.924008 976.276392
27.52659 27.52659
289.826608012 734.0424 19.93298933889 1003.9360187
1023.86900801227 1023.86900801227
Fungsi : Untuk meningkatkan suhu H2O2 yang akan masuk kedalam tangki bleaching
Asumsi : 1. Tidak ada perubahan massa
2. Suhu dinaikkan dari 30 menjadi 80
3. H2O2 yang akan digunakan adalah 30% dari aliran 21
Fungsi : Untuk meningkatkan suhu air yang akan digunakan pada proses bleaching
Asumsi : 1. Tidal terjadi perubahan massa
Fungsi : Untuk menghilangkan sisa lignin dan si

21 24 26 27 Asumsi : 1. Melarutkan sisa lignin yang ada
0.00242738889 0 0 0.00242738889 2. Air yang digunakan untuk konsistens
0.00655395 0 0 0
0 0 0 0.00655395
19.924008 0 137.0045418529 156.928549853
Err:509 Err:509 Err:509 Err:509
Err:509 Err:509 Err:509 Err:509
Err:509 Err:509
Fungsi : Untuk meningkatkan suhu air pencucian yang akan digunakan pada rotary filter 2
Asumsi : 1. Tidal terjadi perubahan massa
Fungsi : Untuk memisahkan selulosa dari sisa li

27 29 30 31 Asumsi : 1. Rasio Air pencucian dan pulp 2 : 1
0.00242738889 196.6185 355.868141331
0.00655395 0.00655395
156.928549853 384.0324270059 530.1417573216 97.3729758346
Err:509 Err:509
Err:509 384.0324270059 Err:509 293.99147583
Err:509 Err:509
Fungsi : Untuk meningkatkan suhu udara pengering

Fungsi :
Mr 31 33 34 35 Asumsi :
162000 0.002588970589 0 0 0.002588971
18 10.81921953718 0 9.59286504748 1.22635449
28.97 0 Err:509 Err:509 0
10.82180850777 Err:509 Err:509 1.22894346
Err:509 Err:509
Fungsi : Untuk menurunkan suhu selulosa keluaran rotary dryer (RD-101)

2. Suhu diturunkan dari 90 menjadi 35
Fungsi : Untuk mengencerkan MCA 99% menjadi 78%

39 40 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 :
#DIV/0! F40 = 0.37638454428
0.0044355081 0.004600255541
0.0044355081 #DIV/0!
#DIV/0! #DIV/0!
Fungsi : Untuk meningkatkan suhu MCA


42 43 44 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Ba
0.0052815 0.005281500002 F41 = 0.6036 kg/jam
0.01173666667 0.010060000004 0.021796666676
0.01701816667 0.010060000004 0.027078166678
0.0270781666783505 0.027078166678
Fungsi : Untuk meningkatkan suhu NaOH
Data Aliran 44 F44 =_x000D_ 0.6036000002604 kg
NaOH 0.35 0.21126 40 0.005
H2O_x000D_ 0.65 0.39234 18 0.0217966667
0.027
N47
0.000026
0.000000
0.000031
0.000000
0.000000
0.000000
0.000000
0.000000
0.012580
0.000000
0.000
0.013
1.263732
gurangi kadar air
menuhi ukuran
n partikel dan kandungan hemiselulosa bagasse

an saturated pada tekanan atmosfer
m explotion tank
a delignifikasi : Bagasse adalah 5 : 1
asih tersisa dari dalam bagasse

k memisahkan selulosa dari sisa black liquor
siensi rotary filter 98%
sio Air pencucian dan pulp 2 : 1
k menghilangkan sisa lignin dan sisa blackliquor
elarutkan sisa lignin yang ada
yang digunakan untuk konsistensi pulp 15% 0.1138
0.0028
0.8173
0.0661
1
k memisahkan selulosa dari sisa lignin dan bleaching agent

sio Air pencucian dan pulp 2 : 1
Untuk mengurangi kadar air
1. Efisiensi rotary dryer 95%
2. Rasio Air pencucian dan pulp 2 : 1
a delignifikasi : Bagasse adalah 5 : 1
an NaOH 50% menjadi 35%

digunakan pada delignifikasi : Bagasse adalah 5 : 1
Masuk
Komponen
x 36_x000D_
N36_x000D_
x 40_x000D_
Selulosa 0.00 0.0026
MCA 0.4031084
NaOH
Na-Glikolat
CMC
NaCl
H2O_x000D_ 1.00 1.2264 0.60
Total 1.0000 1.2289 1.0000

1
Masuk Keluar
N
40_x000D_
x44_x000D_ N44_x000D_
x 45_x000D_
N
45_x000D_
x
46_x000D_
N46_x000D_
x47 N47
0.0020 0.0025579 0.0020 2.584E-05
0.003 0.0025 0.0030757 0.0025 3.107E-05
0.0000 2.091E-07 0.0000 2.113E-09

0.20 0.0053 0.0000 8.366E-10 0.0000 8.45E-12
0.0000 3.346E-09 0.0000 3.38E-11
0.0000 4.183E-06 0.0000 4.225E-08
0.0046 0.80 0.0217967 0.9955 1.2454515 0.9955 0.0125803
0 0.0000 0
0.0077 1.0000 0.0271 0.0000 0.000 1.0000 1.2511 1.0000 0.01
1 1
0
Reaksi Alkalisasi (C_6 H_10 O_5 )n+NaOH →(C_6 H_10 O_5 Na)+H_2 O
Reaksi Eterifikasi ClCH_2 COOH+NaOH →ClCH_2 COONa+H_2 O
(C_6 H_10 O_5 Na)+ClCH_2 COONa →C_5 H_7 O_4 CH_2 OCH_2 COONa+NaCl
Reaksi Samping ClCH_2 COONa+NaOH →OHCH_2 COONa+NaCl
Neraca Energi Total : Qumpan + Qreaksi = Qproduk + Qloss
a. Panas Umpan
T36 = 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
H2O 92.053 -0.039953 -0.00021103 0.00000053469
T44 = 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
NaOH 51.234 0.013088 0.000023359
H2O 92.053 -0.039953 -0.00021103 0.00000053469
Qumpan = 6338.180658695 + 147.3914273716 N O2
b. Panas Reaksi Standar

Reaksi beroperasi pada 35oC
Data ΔHf0 masing komponen pada 25oC (298 K) :
Komponen ΔHf (kj/mol) ΔHf (kj/kmol)

Selulosa -74.764 -74764
Selulosa-Na -161.075 -161075
MCA -435.2025997143 -435202.5997143
MCA-Na -59.888 -59888
NaOH -147.456 -147456
CMC -198.038 -198038
Na-Glikolat -30.954 -30954
NaCl -250.267 -250267
H2O -285 -285000
Tahap 1 : Alkalisasi Selulosa

(C_6 H_10 O_5 )+NaOH →(C_6 H_9 O_5 Na)+ H_2 O
T = 308.15 Tref = 298.15
Komponen Mr (kg/kmol) N (kmol) F (kg) A
Selulosa 162000 0 419.4132354751
Selulosa-Na 94.497 5.276218502E-06 0.00049858682
NaOH 40 0.005281500002 0.211260000091 51.234
H2O 18 1.258027630413 22.64449734743 92.053
ΔHR0 = Σ ΔHf produk - Σ ΔHf reaktan ΔHR =

ΔHR0 = -223.855 kJ/mol ΔHR =
ΔHR = 0
-223855 kJ/kmol ΔHR =
Tahap 2 : Eterifikasi
ClCH_2 COOH+NaOH →ClCH_2 COONa+ H_2 O
T = 308.15 Tref = 298.15

MCA 94.497 0 0.293579944538 -55.75
MCA-Na 84 4.225200002E-09 3.549168E-07
NaOH 40 5.281500002E-06 0.00021126 51.234
H2O 18 1.258031855613 22.64457340103 92.053

ΔHR0 = 237770.5997143 kJ/kmol ΔHR =
ΔHR =
ClCH_2 COONa+(C_6 H_9 O_5 Na) →(C_8 H_11 O_7 Na)+ NaCl
T = 308.15 Tref = 298.15
Selulosa-Na 184000 0 0.970824204419
MCA-Na 84 4.225200002E-09 3.549168E-07
CMC 242000 3.380160001E-09 0.00081799872
NaCl 58.5 3.380160001E-06 0.00019773936 41.293

ΔHR0 = -227342 kJ/kmol ΔHR =
ΔHR =
Tahap 3 : Reaksi samping

ClCH_2 COONa+NaOH →OHCH_2 COONa+NaCl
T = 308.15 Tref = 298.15
Komponen Mr (kg/mol) N (mol) F (kg) A
MCA-Na 84 8.450400004E-10 7.098336E-08
Na-Glikolat 98 8.450400004E-10 8.281392E-08
NaOH 40 1.0563E-06 4.2252E-05 51.234
NaCl 58.5 4.225200002E-06 0.0002471742 41.293

ΔHR0 = -73877 kj/jam ΔHR =
ΔHR =
c. Q Produk
(ΔH47)
T= 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
CMC
Na-Glikolat
H2O 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
NaCl 41.293 0.033607 -0.000013927
Q produk = 5961.536763511 + 60.21754306577 +
d. Qloss
0,25 dari Qudara di aliran 48
Qloss = 0.25 X ( 147.3914273716
Qloss = 36.84785684289 N O2 + 36.341979849
Qumpan = 6338.180658695 + 147.3914273716 N O2

Qreaksi = -273388.7205882
Qproduk = 5961.536763511 + 60.21754306577 +
Qloss = 36.84785684289 N O2 + 136.715067051
Qumpan + Qreaksi = Qproduk + Qloss

6338.18065869489 + 147.3914273716 N O2 +
6338.180658695 +
-485436.124055924 = -485436.1240559
-485436.124055924 = -485436.1240559
Qloss = -54596.39603159 kJ/jam

Qudara 46 = -2.18E+05 kJ/jam
Qudara 48 = -436861.4823309 kJ/jam
Masuk
Komponen
36 40 44 45
Selulosa 5386.094414089
Selulosa-Na
MCA 4
MCA-Na
NaOH 3.028861670404
Na-Glikolat
CMC
NaCl
H2O_x000D_ 925.236347386 3 16.44472983142
O2 -46363.8233322
N2 -172022
Total 6311.330761475 7.376305718326 19.47359150183 -218385.584126
Reaksi -273388.720588247
Qloss
-485436.1
Heater (E-204)
(ΔH46)
T= 35 C = 308.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
CMC
Na-Glikolat
H2O 92.053 -0.039953 -0.00021103 0.00000053469
NaOH 51.234 0.013088 0.000023359
NaCl 41.293 0.033607 -0.000013927
Aging Vessel (V-103)
T= 55 C = 328.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Cooler (E-205)
T= 55 C = 328.15 K
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Cyclone (CY-101)
Tref = 25 C = 298.15 K
T48 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Cyclone (CY-102)
Tref = 25 C = 298.15 K
T52 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Silo (TK-107)
Tref = 25 C = 298.15 K
T51 = 35 C = 308.15 K
T53 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Rotary Dryer (RD-102)

Tref = 25 C = 298.15 K
T57 = 35 C = 308.15 K
T59 = 150 C = 423.15 K
T60 = 100 C = 373.15 K
a. menentukan % relative humidity
T udara awal = 30 C
P= 1 atm
PA = 2.97 kPa
P uap air = 4.246 kPa (Appendix A.2-9 Geankoplis 1993:857)
100 𝑥 𝑃𝐴/(𝑃𝑢𝑎𝑝 𝑎𝑖𝑟)

HR = = 69.9481865285
H= 0.019 kg uap air/kg udara kering (perry's 7th ed gambar 12-3 hal 12-6)
H2 = 0.019 (diasumsi kan tidak berubah)
b. Menentukan wet bulb (Tw)
Ww = 0.0646
Wg = 0.019
tw = 123.8 F = 51
0.0456 = 0.00023 196.2
0.0456 = 0.04563
c. Menentukan suhu udara keluar (TG1)
exp(1,5) = 150-51
4.48169 = 99
99 = 4.48169
99 = 4.48169
327.56614 = 4.48169
TG1 = 73.1
= 346.2
d. Menentukan panas umpan masuk (Q57)
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
e. menentukan panas produk keluar (Q60 dan Q61)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
O2 29.526 -0.0088999 0.000038083 -3.2629E-08
N2 29.342 -0.0035395 0.000010076 -4.3116E-09
4460.390785463 + 294.93738 N O2
f. Qloss
Qloss = 0,25 x Panas udara masuk
Qloss = 0.25 x ( 3737.70020
Qloss = 934.4250489227 N O2 + 912.0466488625
Panas masuk = Panas keluar

Q55 + Q57 = Q58 + Q59 + Qloss
6339.33933 + 3737.70020 N O2 +
6339.33933 + 3737.70020 N O2 +
6339.339 +
17461.83072 N O2 -
31775.1787110264 31775.17871103
Q55 = 6339.34 31775.18

Q57= 25435.83938378 kj/jam 31775.18
Q58 = 6483.37753 kj/jam
Qloss = 6358.959845945 kj/jam
Masuk Keluar
Komponen
55 57 58 59
Selulosa 5375.11239 18812.89
Selulosa-Na 10.57098 37.00
MCA 3.90558 14.48
MCA-Na 0.00000 0.00
NaOH 0.61352 2.15
CMC 0.00000 0.03
Na-Glikolat 0.00000 0.00
NaCl 0.00212 0.01
H2O_x000D_ 949.13473 4460.39079 66.28
O2 5444.535 429.62162
N2 19991.305 1593.365
6339.339 25435.839 6483.378 18932.841
Qloss 6358.95985
Total 31775.179 31775.179
Heater (E-301)
Tref = 25 C = 298.15 K
Komponen A B C D
O2 29.526 -0.0088999 0.000038083 -3.2629E-08

N2 29.342 -0.0035395 0.000010076 -4.3116E-09
Masuk Keluar
Komponen
58 59
Udara 1011.284 25435.839
Qsteam 24424.555
25435.839 25435.839
Cooler (E-302)
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Masuk Keluar
Komponen
59 60
Selulosa 18812.893 5375.112
Selulosa-Na 36.998 325.745
MCA 14.483 3.906
MCA-Na 0.000 0.000
NaOH 0.000 0.000
CMC 0.034 0.302
Na-Glikolat 0.000 0.000
NaCl 0.007 0.002
H2O_x000D_ 66.277 18.983
18930.694 5724.050
Qsteam -13206.644
total 5724.050 5724.050
Ball Mill (BM-301)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Selulosa-Na
MCA -55.75 0.59859
MCA-Na
NaOH 51.234 0.013088 0.000023359
CMC
Na-Glikolat
NaCl 41.293 0.033607 -0.000013927
H2O_x000D_ 92.053 -0.039953 -0.00021103 0.00000053469
Roll Crusher (RC-101)

Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Komponen Cp (kj/kg) 1 2
N (kmol) NCpdT N (kmol)
Selulosa 1040200 0.002555146199 2657.863076023 0.002555146199
Hemiselulosa 147533.75 0.008959603554 1321.843910885 0.008959603554
Lignin 10022.5 0.137977894737 1382.88345 0.137977894737
5362.590436909
Vibrating Screen (VS-101)

Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Selulosa 1040200 0.002555146199 2657.863076023 0.00012775731
Hemiselulosa 147533.75 0.008959603554 1321.843910885 0.000447980178
Lignin 10022.5 0.137977894737 1382.88345 0.006898894737
5362.590436909
5362.590436909
Silo 1 (TK-101)
Tref = 25 C = 298.15 K T57 = 30 C = 303.15
Masuk Keluar
Selulosa 1040200 0.002427388889 2524.969922222 0.002427388889
Hemiselulosa 147533.75 0.008511623377 1255.751715341 0.008511623377
Lignin 10022.5 0.131079 1313.7392775 0.131079
5094.460915063
Steam Explosion Tank (V-101)

Data Steam
P= 1002.7 kPa P=
T =_x000D_
6
453.15 K T =_x000D_
7
Vspecific =_x000D_ 193.8 cm3/g Vspecific =_x000D_

Hvap = 2776.3 kj/kg Hvap =
Hliq = 763.1 kj/kg Hliq =
Q= 0 diasumikan proses adibatik
r= 0 diasumsikan tidak ada panas tergenerasi
T =_x000D_
5
303.15 K
T6=_x000D_ 453.15 K
T7=_x000D_ 373.15 diasumsikan aliran keluar proses dalam keadaan setimbang pada tekanan atmos
Tref= _x000D_ 298.15 K
1. Menghitung Usaha (W)

𝑊=−∫_(𝑣_1^𝑡)^(
𝑣_2^𝑡)▒ 〖𝑃 P1.3 hal 9 van ness et al (2005) introduction of chemical engineering thermody
𝑑𝑉 ^𝑡 〗
Adiabatic expansion process berlaku persamaan 𝑃𝑉^𝛾=𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
γ= 1.32
Vin = 2631.542004 m3/jam
Vout = 304.8373224 m3/jam
K = 3313500.572382 kJ/m3
W= -827438.6720435 kj/jam
2. Menghitung Entalpi Aliran Input
Komponen Cp m N.Cp.dT
Selulosa 6.420987654321 393.237 2524.97

Hemiselulosa 6.386742424242 196.6185 1255.75
Lignin 6.681666666667 196.6185 1313.7393
H2O 4366976
4372069.993
W+ 〖∆ H 〗 _input− 〖∆ H 〗 _output =0
W+ 〖∆ H 〗 _input−( 〖∆ H 〗 _Selulosa+ 〖∆ H 〗 _Hemiselulosa+ 〖∆ H 〗 _Hemiselulosa(aq) +
〖∆ 〖
W+ H〗∆ H_Lignin+ 〖∆〖
〗 _input−( H∆〗H_(H_2 O(g) )+ 〖〖
〗 _Selulosa+ ∆∆HH〗〗_(H_2 O(l))) =0
_Hemiselulosa+
〖∆ H 〗 _(Hemiselulosa(aq))+ 〖∆ H 〗 _Lignin) = 〖∆ H 〗 _(H_2 O)
∆H2O = 2204.9 kj/jam
4. Menghitung fraksi uap dan cair dari steam
y= fraksi uap
P6.73a hal 219 van ness et al (2005) introdu
y= 0.7913
1-y= 0.2087
3367367.0784 kj/jam
131844.50136 kj/jam
Masuk Keluar
Komponen 5 6 7
Q Q Q
Selulosa 2524.9699 37874.5488
Hemiselulosa 1255.7517 5650.8827
Hemiselulosa (aq) 13185.3930
Lignin 1313.7393 19706.0892
H2O (g) 4366975.5324 3367367.0784
H2O (l) 131844.50136
5094 4366975.5 3575628
W -827438.672043464
3544631.32 3575628.49
Cp (kj/kg)
Flash Tank (V-102)
Tref = 25 C = 298.15 K
T7 = 100 C = 373.15 K
T8= 100 C = 373.15 K
T9 = 100 C = 373.15 K
Masuk Keluar
Komponen 7 8
m (kg) mCpdT m (kg) mCpdT
Selulosa 393.237 37874.5488 393.237 37874.5488
Hemiselulosa 58.98555 5650.8827 58.98555 5650.8827
Hemiselulosa (aq) 137.63295 13185.3930 137.63295 13185.3930
Lignin 196.6185 19706.0892 196.6185 19706.0892
H2O (g) 1258.3584 3367367.078
H2O (l) 314.5896 131844.5014 314.5896 131844.5014
3575628.4935 208261.4151
3575628.4935
Heater (E-101)
Tref = 25 C = 298.15 K
T8 = 100 C = 373.15 K
T10= 150 C = 423.15 K
Masuk Keluar
Komponen 8 10
m (kg) mCpdT Cp (kj/kg K) m (kg)
Selulosa 393.237 37874.5488 160.524691358 393.237
Hemiselulosa 58.98555 5650.8827 159.6685606061 58.98555
Hemiselulosa (aq) 137.63295 13185.3930 159.6685606061 137.63295
Lignin 196.6185 19706.0892 167.0416666667 196.6185
H2O 314.5896 131844.5014 Err:509 314.5896
208261.4151 Err:509
Qsteam Err:509
Err:509
Mixer (M-101)
Tref = 25 C = 298.15 K
T12 = 100 C = 373.15 K
T13= 100 C = 373.15 K
T14= 100 C = 373.15 K
Komponen A B C D
NaOH Err:509 Err:509 Err:509

H2O Err:509 Err:509 Err:509
Heater (E-102)
Tref = 25 C = 298.15 K
T14 = 30 C = 303.15 K
T15= 150 C = 423.15 K
Komponen A B C D
NaOH Err:509 Err:509 194800

Qsteam
Delignification Tank (DT-101)

Tref = 25 C = 298.15 K
T10 = 150 C = 423.15 K
T15= 150 C = 423.15 K
T16= 150 C = 423.15 K
Komponen A B C D
Selulosa
Hemi
Hemi aq
Lig
Lig aq
H2O l Err:509 Err:509 Err:509
NaOH Err:509 Err:509 194800
Expansion Valve (EV-101)

Tref = 25 C = 298.15 K
T16 = 150 C = 423.15 K
T17 = 150 C = 423.15 K
Komponen A B C D
Selulosa
Hemi aq
Lig
Lig aq
NaOH Err:509 Err:509 194800
Cooler (E-103)
Tref = 25 C = 298.15 K
T17 = 150 C = 423.15 K
T8 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Hemi aq
Lig
Lig aq
NaOH Err:509 Err:509 194800
Qcw
Heater (E-104)
Tref = 25 C = 298.15 K
T19 = 30 C = 303.15 K
T20 = 80 C = 353.15 K
Komponen A B C D

Qsteam
Rotary Filter (RF-101)

Tref = 25 C = 298.15 K
T18 = 80 C = 353.15 K
T20 = 80 C = 353.15 K
T21 = 80 C = 353.15 K
T22 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Hemiselulosa(aq)
Lgnin
Lignin (aq)
NaOH Err:509 Err:509 194800
Heater (E-105)
Tref = 25 C = 298.15 K
T23 = 30 C = 303.15 K
T24 = 80 C = 353.15 K
Masuk Keluar
Komponen 23 24
Cp (kJ/kg) m (kg) mCpdT Cp (kJ/kg)
H2O2 Err:509 228.5100207 Err:509 Err:509
Qsteam Err:509
Err:509
Bleaching Tank (BT-101)

Tref = 25 C = 298.15 K
T21 = 80 C = 353.15 K
T24 = 80 C = 353.15 K
T26 = 80 C = 353.15 K
T27 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Lig
Lig aq
H2O2
Heater (E-106)
Tref = 25 C = 298.15 K
T25 = 30 C = 303.15 K
T26 = 80 C = 353.15 K
Komponen A B C D
Qsteam
Heater (E-107)
Tref = 25 C = 298.15 K
T28 = 30 C = 303.15 K
T29 = 80 C = 353.15 K
Komponen A B C D
Qsteam
Rotary Filter (RF-102)

Tref = 25 C = 298.15 K
T27 = 80 C = 353.15 K
T29 = 80 C = 353.15 K
T30 = 80 C = 353.15 K
T31 = 80 C = 353.15 K
Komponen A B C D
Selulosa
Lignin (aq)
H2O (l) Err:509 Err:509 Err:509
H2O2
Rotary Dryer (RD-101)
Tref = 25 C = 298.15 K
T31 = 80 C = 353.15 K
T33 = 200 C = 473.15 K
T35 = 90 C = 363.15 K
a. menentukan % relative humidity
T udara awal = 30 C
P= 1 atm
PA = 2.97 kPa
P uap air = 4.246 kPa (Appendix A.2-9 Geankoplis 1993:857)
100 𝑥 𝑃𝐴/(𝑃𝑢𝑎𝑝 𝑎𝑖𝑟)

HR = = 69.9481865285
H= 0.019 kg uap air/kg udara kering (perry's 7th ed gambar 12-3 hal 12-6)
H2 = 0.019 (diasumsi kan tidak berubah)
b. Menentukan wet bulb (Tw)
Ww = 0.0646
Wg = 0.019
tw = 123.8 F = 51
0.0456 = 0.00023 196.2
0.0456 = 0.04563
c. Menentukan suhu udara keluar (TG1)
exp(1,5) = 200-51
4.48169 = 149
149 = 4.48169
149 = 4.48169
377.56614 = 4.48169
TG1 = 84.2
= 357.4
d. Menentukan panas umpan masuk (Q57)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Udara 29.342 -0.0035395 -4.3116E-09
e. menentukan panas produk keluar (Q60 dan Q61)

Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Udara 29.342 -0.0035395 -4.3116E-09
Q34=
f. Qloss
Qloss = 0,25 x Panas udara masuk
Qloss = 0.25 x 0.16900 m
Qloss = 0.042250375987 m
Panas masuk = Panas keluar

Q57 + Q59 = Q60 Q61 + Qloss
Err:509 + 0.16900 m =
0.06912 m =
m =
Q59= Err:509 kj/jam

Q60= Err:509 kj/jam
Qloss = Err:509 kj/jam
Tref = 25 C = 298.15 K
Komponen A B C D
Selulosa
Udara 29.342 -0.0035395 -4.3116E-09
Masuk Keluar
Komponen
31 33 34 35
Selulosa 29623.51928 35009.61369
Udara Err:509 Err:509
Qloss Err:509
Total Err:509 Err:509
Heater (E-108)
Tref = 25 C = 298.15 K
T32 = 30 C = 303.15 K
T33 = 200 C = 473.15 K
Komponen A B C D
Qsteam
Cooler (E-109)
Tref = 25 C = 298.15 K
T36 = 90 C = 363.15 K
T37 = 35 C = 308.15 K
Komponen A B C D
Selulosa
Qcw
Heater (E-110)
Tref = 25 C = 298.15 K
T32 = 30 C = 303.15 K
T33 = 35 C = 308.15 K
Komponen A B C D
MCA
Qcw
heater (E-111)
Tref = 25 C = 298.15 K
T44 = 30 C = 303.15 K
T45 = 35 C = 308.15 K
Komponen A B C D
NaOH Err:509 Err:509 194800

Qcw
Mixer (M-102)
Tref = 25 C = 298.15 K
T37 = 30 C = 303.15 K
T38= 30 C = 303.15 K
T39= 30 C = 303.15 K
Komponen A B C D
MCA
Mixer (103)
Tref = 25 C = 298.15 K
T41 = 30 C = 303.15 K
T42= 30 C = 303.15 K
T43= 30 C = 303.15 K
Komponen A B C D
NaOH Err:509 Err:509 194800

O
_2 OCH_2 COONa+NaCl
T40 =
Tref =
Cp (J/mol ) N (kmol) Q (kj/jam) Komponen
2080400 0.00259 5386.09441408872 MCA
754.460765759055 1 925.236347386016 H2O
6311.33076147473
T45 =
Tref =
Cp (J/mol ) N (kmol) Q (kj/jam) Komponen
573.485121480108 0.0052815000023 3.0288616704041 O2
754.460765759055 0.0217966666761 16.4447298314238 N2
19.4735915018279
+ 145.36792 N N2
B C D Cp (kJ/kmol) ΔH (kj/jam)
2080400 5386.0944140887
2004800 10.577762853364
0.013088 0.000023359 573.48512148011 3.0288616704041
-0.039953 -0.00021103 0.00000053469 754.46076575906 949.13248938728
ΔHR0 + [ΔH produk - ΔH reaktan]

-223855 + -75419.024355721
-299274.02435572
0.59859 1257.125585 3.9055934000249
61.59 2.602300681E-06
0.013088 0.000023359 573.48512148011 0.0030288616704
-0.039953 -0.00021103 0.00000053469 754.46076575906 949.13567713491

237770.599714255 + -1014.5599407211
236756.039773534
200480 10.577762853364
61.59 2.602300681E-06
290410 0.0098163226602
0.033607 -0.000013927 502.00955771009 0.0016968726273

-227342 + 90370.4195577101
-136971.58044229
B C D Cp (J/kg) ΔH (kj/jam)
61.59 5.204601362E-07
110.91 9.372338644E-07
0.013088 0.000023359 573.48512148011 0.0006057723341
0.033607 -0.000013927 502.00955771009 0.0021210907842

-73877 + -22.155563770017
-73899.15556377
(ΔH48)
T=
Tref =
Cp (J/kg) N (kmol) Q (kj/jam) Komponen
208040 0.002558 5321.36659142542 Selulosa
200480 0.000005 10.4652764455073 Selulosa-Na
1257.125585 0.003076 3.8665322075337 MCA
61.59 0.000000 0 MCA-Na
290410 0.000000 0.60738496460203 CMC
110.91 0.000000 3.711446103E-06 Na-Glikolat
754.460765759055 0.000000 6.3117403051E-07 H2O
573.485121480108 0.000004 0.00239885844296 NaOH
502.009557710092 1.245452 625.228575267168 NaCl
5961.53676351129 O2
N2
294.937383716924 N O2 + 290.77108187013 N N2
N O2 + 145.36792 N N2 )
N N2
+ 546.86026820407 N O2
294.937383716924 N O2 + 1093.8531175115 N O2
N O2
546.860268204066 N O2 + -273388.72058825 =
694.251695575628 N O2 + -273388.72058825 =
-267050.53992955 + 694.251695575628 N O2 =
694.251695575628 N O2 =
-868.10172954666 N O2 =
N O2 =
F O2 =
F O2 =
N N2 =
F N2 =
F N2 =
Udara =
=
Keluar
46 47
5321.36659142542 53.751177691166
10.4652764455073 0.1057098630859
3.8665322075337 0.0390558808842
0 0
0.60738496460203 0.0061352016626
3.711446103E-06 3.748935458E-08
6.3117403051E-07 6.375495258E-09
0.00239885844296 2.423089336E-05
625.228575267168 6.3154401542138
-92776.25569257
-344085.2266383
5961.53676351129 -436801.2647878
-54596.3960315928
-485436.124
(ΔH48)
T=
Tref =
Cp (J/mol.K) N (kmol) Q (kj/jam) Komponen
2080400 0.00 5321.37 Selulosa
2004800 0.00 10.47 Selulosa-Na
1257.13 0.00 3.87 MCA
615.90 0.00 0.00 MCA-Na
2904100 0.00 0.61 CMC
1109.10 0.00 0.00 Na-Glikolat
754.46 0.00 0.00 H2O
573.49 0.00 0.00 NaOH
502.01 1.25 625.23 NaCl
5961.54
T=
Tref =
Cp N (kmol) Q (kj/jam) Komponen
6241200 0.0026 15964.1 Selulosa
6014400 0.0000 31.4 Selulosa-Na
3950.9538 0.0031 12.2 MCA
1847.7000 0.0000 0.0 MCA-Na
1728.7473 0.0000 0.0 NaOH
8712300 0.0000 0.0 CMC
3327.3000 0.0000 0.0 Na-Glikolat
1513.5080 0.0000 0.0 NaCl
2258.6647 1.2455 2813.1 H2O_x000D_
18820.741
T=
Tref =
Cp (J/kg K) N (kmol) Q (kj/jam) Komponen
6241200 0.0025578574271 15964.0997742762 Selulosa
6014400 5.220109959E-06 31.3958293365218 Selulosa-Na
3950.9538 0.0030756928772 12.1519203224105 MCA
1847.7 0 0 MCA-Na
1728.7473 2.091474001E-07 0.00036156300905 NaOH
8712300 3.346358401E-09 0.0291544783009 CMC
3327.3 8.365896004E-10 2.7835845773E-06 Na-Glikolat
1513.5080 4.182948002E-06 0.00633092508068 NaCl
2258.6647 1.2454515370567 2813.05739062638 H2O_x000D_
18820.7408
T52 = 35 C =
T53 = 35 C =
47 51
E
Cp N (kmol) Q (kj/jam) Cp
2080400 2.5836943709E-05 53.751177691166 2080400
2004800 5.2728383423E-08 0.1057098630859 2004800
1257.125585 3.106760482E-05 0.0390558808842 1257.125585
615.9 0 0 615.9
573.48512148011 2.1126000009E-09 1.2115446682E-06 573.48512148011
2904100 3.3801600015E-11 9.8163226602E-05 2904100
1109.1 8.4504000036E-12 9.372338644E-09 1109.1
502.00955771009 4.2252000018E-08 2.1210907842E-05 502.00955771009
754.46076575906 0.01258031855613 9.4913567713491 754.46076575906
8.8607E-12 294.93738371693 31.25 9216.7932411539 294.93738371693
2.5935E-13 290.77108187013 71.4285714285714 20769.362990724 290.77108187013
30049.543652679
30049.543652679
T54 = 35 C =
T55 = 35 C =
51 53
E
2080400 2.5836943709E-07 0.5375118 2080400.00
2004800 5.2728383423E-10 0.0010571 2004800.00
1257.125585 3.106760482E-07 0.0003906 1257.13
615.9 0 0.0000000 615.90
573.48512148011 2.1126000009E-11 0.0000000 573.49
2904100 3.3801600015E-13 0.0000010 2904100.00
1109.1 8.4504000036E-14 0.0000000 1109.10
502.00955771009 4.2252000018E-10 0.0000002 502.01
754.46076575906 0.00012580318556 0.0949136 754.46
8.8607E-12 294.93738371693 31.25 9216.793 294.94
2.5935E-13 290.77108187013 71.4285714285714 20769.363 290.77
29986.79
29986.79
T55 = 35 C = 308.15
T56 = 35 C = 308.15
50 52
Cp N (kmol) Q (kj/jam) Cp N (kmol)
2080400 0.003 5321.367 2080400.00 0.00003
2004800 0.000 10.465 2004800.00 0.00000
1257.125585 0.003 3.867 1257.13 0.00003
615.9 0.000 0.000 615.90 0.00000
573.485121480108 0.000 0.000 573.49 0.00000
2904100 0.000 0.010 2904100.00 0.00000
1109.1 0.000 0.000 1109.10 0.00000
502.009557710092 0.000 0.002 502.01 0.00000
754.460765759055 1.245 939.644 754.46 0.01245
6275.355
oplis 1993:857)
y's 7th ed gambar 12-3 hal 12-6)
C = 324.15 K
/ TG1 - 51
/ TG1 - 51
(TG1- 51)
TG1 - 228.566142587241
TG1
C
K
T57 = 35 C = 308.15 K T59 = 150C =
55 57
E
Cp (kj/kg) N (kmol) Q (kj/jam) Cp (kj/kg)
2080400 0.00258 5375.11 26005000
2004800 0.00001 10.57 25060000
1257.12559 0.00311 3.91 20016.43544
615.90 0.00000 0.00 7698.75000
2904100 0.00000 0.61 36301250
1109.10 0.00000 0.00 36301250.00
1109.10000 0.00000 0.00 13863.75000
502.00956 0.00000 0.00 6447.97094
754.46077 1.25803 949.13 9469.49572
8.8607E-12 3737.70020
2.5935E-13 3648.18660
6339.34
T60=73,1C = 346.25 K T61 = 60 C =

58 59
E
Cp (kj/kg) N (kmol) Q (kj/jam) Cp (kj/kg)
7281400
7016800
4661.82267
2155.65000
10164350
10164350
3881.85000
1767.92043
3617.89227 1.23286998562932 4460.3907854632 2634.16638
8.8607E-12 294.93738 ? ?
2.5935E-13 290.77108 ? ?
+ 290.77108 N N2
N O2 + 3648.18660 N N2 )
N N2
3648.18660 N N2 = 4460.3907854632 +
13724.13053 N O2 = 4460.3907854632 +
17461.831 N O2 = 5754.248 N O2
5754.248 N O2 = 23393.232 -
11707.583 N O2 = 17053.893
N O2 = 1.457 kmol/jam
F O2 = 46.613 kg/jam
F O2 = 0.047 ton/jam
N N2 = 5.480 kmol/jam
F N2 = 76.717 kg/jam
F N2 = 0.077 ton/jam
Udara = 123.330 kg/jam

udara = 0.123 ton/jam
T56 = 30 C = 303.15 K T57 = 150C =

56 57
E
8.8607E-12 147.39142737156 1.45665364586099 214.69826004944 3737.7001956907
2.5935E-13 145.36791939602 5.47979228681038 796.58600345597 3648.18659545
1011.28426
T59 = 60 C = 333.15 K T60 = 35C = 308.15
59 60
Cp (J/mol.K) N (kmol) Q (kj/jam) Cp (kj/kg) N (kg)
7281400 0.00258 18812.89338 2080400 0.00258
7016800 0.00001 36.99842 61777912 0.00001
4661.82267 0.00311 14.48315 1257.12559 0.00311
2155.65 0.00000 0.00000 18978.96 0.00000
2019.32444 0.00000 0.00043 573.48512 0.00000
10164350 0.00000 0.03436 89489842 0.00000
3881.85 0.00000 0.00000 34176.92 0.00000
1767.92043 0.00000 0.00747 502.00956 0.00000
2634.16638 0.02516 66.27724 754.46077 0.02516
18930.69
T60 = 60 C = 308.15 K T61 = 35C = 308.15

59 60
Cp (J/mol.K) N (kmol) Q (kj/jam) Cp (kj/kg) N (kg)
2080400 0.00258 5375.11239 2080400 0.00258
2004800 0.00001 10.57098 2004800 0.00001
1257.12559 0.00311 3.90558 1257.12559 0.00311
615.90 0.00000 0.00000 615.90 0.00000
573.48512 0.00000 0.00012 573.48512 0.00000
2904100 0.00000 0.00982 2904100 0.00000
1109.10 0.00000 0.00000 1109.10 0.00000
502.00956 0.00000 0.00212 502.00956 0.00000
754.46077 0.02516 18.98269 754.46077 0.02516
5408.58
K
Keluar
2
NCpdT
2657.86307602339
1321.84391088517
1382.88345
5362.59043690856
K
Keluar
3 4
NCpdT N (kmol) NCpdT
132.89315380117 0.0024273888889 2524.96992222222
66.0921955442584 0.0085116233766 1255.75171534091
69.1441725 0.131079 1313.7392775
268.129521845428 5094.46091506313
5362.59043690856
K
Keluar
5
NCpdT
2524.96992222222
1255.75171534091
1313.7392775
5094.46091506313
101.3 kPa
373.15 K
1673 cm3/g
2676 kj/kg
419.1 kj/kg
eadaan setimbang pada tekanan atmosfer
tion of chemical engineering thermodynamic'
P3.29c hal 75 van ness et al (2005) introduction of chemical engineering thermodynamic'
3. Menghitung Entalpi Aliran output
Komponen Cp m N.Cp.dT
Selulosa 96.314814814815 393.237 37874.5488

Hemiselulosa 95.801136363636 58.98555 5650.8827
Hemiselulosa(aq) 95.801136363636 137.63295 13185.3930
Lignin 100.225 196.6185 19706.0892
H2O (g) 1258.3584 3367367.0784
H2O (l) 314.5896 131844.5014
3575628.4935
〗 _Hemiselulosa(aq) +
a hal 219 van ness et al (2005) introduction of chemical engineering thermodynamic'

Keluar
9
m (kg) mCpdT
1258.3584 3367367.0784
3367367.0784
3575628.4935
suhu Steam = 170 C

Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg)
10 Err:509 2767.1 719.1
mCpdT
63124.2480555556
9418.13786505682
21975.6550184659
32843.4819375
Err:509
Err:509
Err:509
Masuk
12 13
Cp (kJ/kg) m (kg) mCpdT Cp (kJ/kg) m (kg)
Err:508 1101.0636 Err:508
Err:509 1101.0636 Err:509 Err:509 3303.1908
Err:508
Masuk Keluar
14 15
Err:508 1101.0636 Err:508 Err:508 1101.0636
Err:509 4404.2544 Err:509 Err:509 4404.2544
Err:508
Err:508
Masuk
10 15
160.524691358025 393.237 63124.2480555556
159.668560606061 58.98555 9418.13786505682
159.668560606061 137.63295 21975.6550184659
167.041666666667 196.6185 32843.4819375
314.5896 Err:509 Err:509 4404.2544

Err:508 1101.0636
Err:509
Masuk Keluar
16 17
160.524691358025 393.237 63124.2480555556 160.52469135803 393.237
159.668560606061 196.6185 31393.7928835227 159.66856060606 196.6185
167.041666666667 9.830925 1642.174096875 167.04166666667 9.830925
167.041666666667 186.787575 31201.307840625 167.04166666667 186.787575
4718.844 Err:509 4718.844
Err:508 1101.0636 Err:508 Err:508 1101.0636
Err:509
Masuk Keluar
17 18
160.524691358025 393.237 63124.2480555556 70.630864197531 393.237
159.668560606061 196.6185 31393.7928835227 70.254166666667 196.6185
167.041666666667 9.830925 1642.174096875 73.498333333333 9.830925
167.041666666667 186.787575 31201.307840625 73.498333333333 186.787575
Err:509 4718.844 Err:509 Err:509 4718.844
Err:508 1101.0636 Err:508 Err:508 1101.0636
Err:509 Err:509
Err:509
Err:509
Masuk Keluar
19 20
Err:509 13212.7632 Err:509 Err:509 13212.7632
Err:509
Err:509
Masuk
18 20
70.6308641975309 393.237 27774.6691444444
70.2541666666667 196.6185 13813.26886875
73.4983333333333 9.830925 722.556602625
73.4983333333333 186.787575 13728.575449875
Err:509 4718.844 Err:509 Err:509 13212.7632
Err:508 1101.0636 Err:508
Err:509
suhu steam = 100

Keluar Q (kj/jam) Hv (kJ/kg)
24 Err:509 2676
m (kg) mCpdT
228.5100207 Err:509
Err:509
Masuk
21 24
70.6308641975309 393.237 27774.6691444444
73.4983333333333 9.830925 722.556602625
Err:509 358.632144 Err:509

Err:509 228.5100207
Err:509
Masuk Keluar
25 26
Err:509 2466.081753353 Err:509 Err:509 2466.081753353
Err:509
Err:509
Masuk Keluar
28 29
Err:509 6912.5836861059 Err:509 Err:509 6912.5836861059
Err:509
Err:509
Masuk
27 29
70.6308641975309 393.237 27774.6691444444
73.4983333333333 9.830925 722.556602625
Err:509 2824.713897353 Err:509 Err:509 6912.5836861059
Err:509 228.5100207 Err:509
Err:509
oplis 1993:857)
y's 7th ed gambar 12-3 hal 12-6)
C = 324.15 K
/ TG1 - 51
/ TG1 - 51
(TG1- 51)
TG1 - 228.566142587241
TG1
C
K
T31 = 80 C = 353.15 K T33 = 200C = 473.15

31 33
Cp (kj/kg) m (kg) Q (kj/jam) Cp (kj/kg) m (kg)
70.63086 419.41324 29623.51928
Err:509 194.74595 Err:509
0.1690015039481 ?
Err:509
T34=84,2C = 357.4 K T35 = 90 C = 363.15

34 35
83.472839506173 419.41
Err:509 172.6715708547 Err:509 Err:509 22.07
0.0576345 ? 0.0576345
Err:509 + 0.0576345 m
Err:509 + 0.05763 m +
Err:509
Err:509 kg udara/jam
T31 = 80 C = 353.15 K T33 = 200C = 473.15

31 33
70.63086 419.41324 29623.51928
Err:509 194.74595 Err:509
0.16900 Err:509
Err:509
Masuk Keluar
32 33
Err:509 Err:509 Err:509 Err:509 Err:509
Err:509
Err:509
Masuk Keluar
36 37
168.206333333333 419.41323547509 70547.9624907344 97.575469135803 419.41323547509
Err:509 22.074380814478 Err:509 Err:509 22.074380814478
Err:509
Err:509
Masuk Keluar
40 41
0 0.2935799445384 0 0 0.2935799445384
Err:509 0.0828045997416 Err:509 Err:509 0.0828045997416
Err:509
Err:509
Masuk Keluar
40 41
Err:509 0.2112600000912 Err:509 Err:509 0.2112600000912
Err:509 0.3923400001693 Err:509 Err:509 0.3923400001693
Err:509
Err:509
Masuk
37 38
0 0.2935799445384 0
Err:509 0.0029654539852 Err:509 Err:509 0.0798391457564
Err:509
Masuk
41 42
Err:508 0.2112600000912 Err:508
Err:509 0.2112600000912 Err:509 Err:509 0.18
Err:508
35 C = 308.15 K
25 C = 298.15 K
A B C D Cp (J/mol.K) N (kmol)
-55.75 5.99E-01 1257.126 0.00311
92.053 -0.039953 -0.00021103 0.00000053469 754.461 0.00460
30 C = 303.15 K
25 C = 298.15 K
A B C D E Cp (kJ/kg)
29.526 -0.0088999 0.000038083 -0.000000032629 8.8607E-12 147.39143
29.342 -0.0035395 0.000010076 -4.3116E-09 2.59E-13 145.36792
292.7593467676
35 C = 308.15 K
25 C = 298.15 K
A B C D E Cp (J/mol)
208040
200480
-55.75 0.59859 1257.125585
61.59
290410
110.91
92.053 -0.039953 -0.00021103 0.00000053469 754.4607657591
51.234 0.013088 0.000023359 573.4851214801
41.293 0.033607 -0.000013927 502.0095577101
29.526 -0.0088999 0.000038083 -0.000000032629 8.8607E-12 294.9373837169
29.342 -0.0035395 0.000010076 -4.3116E-09 2.5935E-13 290.7710818701
…...(1)
…...(2)
…...(3)
…...(4)
5961.53676351129 + 60.2175430657706 + 294.9373837169 N O2

5961.53676351129 + 60.2175430657706 + 1562.353425122 N O2
6021.75430657706 + 1562.35342512228 N O2
6021.754 - -267050.53992955
273072.294
-314.5626 kmol/jam
-10066.0016 kg/jam
-10.0660 ton/jam
-1183.4 kmol/jam
-16566.9610 kg/jam
-16.6 ton/jam
-26633.0 kg/jam
-26.6 ton/jam
55 C = 328.15 K
25 C = 298.15 K
A B C D Cp (J/mol K) N (kmol)
62412000 0.00256
60144000 0.00001
-55.75 0.59859 3950.95376 0.00308
18477.00000 0.00000
87123000 0.00000
33273.00000 0.00000
92.053 -0.039953 -0.00021103 0.00000053469 2258.66467 0.00000
51.234 0.013088 0.000023359 1728.74733 0.00000
41.293 0.033607 -0.000013927 1513.50796 1.24545
Qsteam =
55 C = 328.15 K
25 C = 298.15 K
A B C D Cp N (kmol)
6241200 0.002557857427
6014400 5.22010996E-06
-55.75 0.59859 3950.9538 0.003075692877
1847.7000 0
51.234 0.013088 0.000023359 1728.7473 2.091474E-07
8712300 3.3463584E-09
3327.3000 8.365896E-10
41.293 0.033607 -0.000013927 1513.5080 4.182948E-06
92.053 -0.039953 -0.00021103 0.00000053469 2258.6647 1.245451537057
35 C = 308.15 K
25 C = 298.15 K
A B C D Cp (J/kg K) N (kmol)
2080400 0.002557857427
2004800 5.22010996E-06
-55.75 0.59859 1257.1256 0.003075692877
615.9000 0
51.234 0.013088 0.000023359 573.4851 2.091474E-07
2904100 3.3463584E-09
1109.1000 8.365896E-10
41.293 0.033607 -0.000013927 502.0096 4.182948E-06
92.053 -0.039953 -0.00021103 0.00000053469 754.4608 1.245451537057
308.15 K
308.15 K
51 52
N (kmol) Q (kj/jam) Cp N (kmol) Q (kj/jam)
2.5836943709E-07 0.537512 2080400 2.557857427E-05 53.21366591425
5.2728383423E-10 0.001057 2004800 5.220109959E-08 0.104652764455
3.106760482E-07 0.000391 1257.125585 3.075692877E-05 0.038665322075
0 0.000000 615.9 0 0
2.1126000009E-11 0.000000 573.485121480108 2.091474001E-09 1.19942922E-06
3.3801600015E-13 0.000001 2904100 3.346358401E-11 9.71815943E-05
8.4504000036E-14 0.000000 1109.1 8.365896004E-12 9.27861526E-09
4.2252000018E-10 0.000000 502.009557710092 4.182948002E-08 2.09987988E-05
0.00012580318556 0.094914 754.460765759055 0.0124545153706 9.396443203636
31.25 9216.79
71.4285714285714 20769.36
29986.79 62.7535
30049.5437
308.15 K
308.15 K
53 54
N (kmol) Q (kj/jam) Cp N (kmol) Q (kj/jam)
0.000000 0.0053751 2080400.000 2.557857427E-07 0.5321367
0.000000 0.0000106 2004800.000 5.220109959E-10 0.0010465
0.000000 0.0000039 1257.126 3.075692877E-07 0.0003867
0.000000 0.0000000 615.900 0 0.0000000
0.000000 0.0000000 573.485 2.091474001E-11 0.0000000
0.000000 0.0000000 2904100.000 3.346358401E-13 0.0000010
0.000000 0.0000000 1109.100 8.365896004E-14 0.0000000
0.000000 0.0000000 502.010 4.182948002E-10 0.0000002
0.000001 0.0009491 754.461 0.0001245451537 0.0939644
31.250000 9216.79
71.428571 20769.36
29986.16 0.6275
29986.79
K
K
52 54 55
Q (kj/jam) Cp N (kmol) Q (kj/jam) Cp N (kmol)
53.214 2080400.00 0.0000 0.532137 2080400.00 0.003
0.105 2004800.00 0.0000 0.001047 2004800.00 0.000
0.039 1257.13 0.0000 0.000387 1257.13 0.003
0.000 615.90 0.0000 0.000000 615.90 0.000
0.000 573.49 0.0000 0.000000 573.49 0.000
0.000 2904100.00 0.0000 0.000001 2904100.00 0.000
0.000 1109.10 0.0000 0.000000 1109.10 0.000
0.000 502.01 0.0000 0.000000 502.01 0.000
9.396 754.46 0.0001 0.093964 754.46 1.258
62.754 0.62754
6338.736
423.15 K
57
N (kmol) Q (kj/jam)
? ?
? ?
333.15 K
59
N (kmol) Q (kj/jam)
0.00 18812.893379
0.00 36.99841508162
0.00 14.48315196995
0.00 0
0.00 2.147318434606
0.00 0.034357094954
0.00 3.280315245E-06
0.00 0.007469809932
0.03 66.27723799946
Q59 = 18932.841
294.93738 N O2 + 290.77108 N N2 +
294.937 N O2 + 1093.853 N O2 +
+ 23393.232
6339.339
423.15 K T steam = 170 C

57 P steam = kPa
N (kmol) Q (kj/jam) Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg)
1.45665364586099 5444.534617188 24424.555 2767.1 719.1
5.47979228681038 19991.30476659
25435.839
24424.555
K
60 T CW in = 30 C 303.15
Q (kj/jam) T CW out = 49 C 323.15
5375.11 Q Cp
325.74 -13206.644 1505.5337126063
3.91
0.00 Q = N.Cp.dT
0.00 N = Q/(Cp.dT)
0.30 N = -8.772068190404 kmol/jam
0.00 F Cw = -157.8972274273 kg/jam
0.00 F Cw = -0.157897227427 ton/jam
18.98
5724.05
-13206.644
K
60
Q (kj/jam)
5375.11
10.57
3.91
0.00
0.00
0.01
0.00
0.00
18.98
5408.58
λs (Kj/kg) m (kg/jam)
2047.9 Err:509
Keluar
13 14
mCpdT Cp (kJ/kg) m (kg) mCpdT
Err:508 1101.0636 Err:508
Err:509 Err:509 4404.2544 Err:509
Err:509 Err:508
Err:509 Err:508
suhu steam = 170 C

Keluar Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
15 Err:508 2767.1 719.1 2047.9
mCpdT
Err:508
Err:509
Err:508
Keluar
15 16
160.524691358 393.237 63124.248055556
159.6685606061 196.6185 31393.792883523
167.0416666667 9.830925 1642.174096875
167.0416666667 186.787575 31201.307840625
Err:509 4718.844 Err:509
Err:508 Err:508 1101.0636 Err:508
Err:509 Err:509
Err:509 Err:509
Keluar
17
mCpdT
63124.2480555556
31393.7928835227
1642.174096875
31201.307840625
Err:509
Err:508
Err:509
Keluar T CW in = 30 C 303.15
18 T CW out = 50 C 323.15
mCpdT Q Cp dT m
27774.6691444444 Err:509 4.2 20 Err:509
13813.26886875
722.556602625
13728.575449875
Err:509
Err:508
rr:509
Err:509
suhu steam = 100 C

20 Err:509 2676 419.1 2256.9
mCpdT
Err:509
Err:509
Keluar
20 21 22
mCpdT Cp (kJ/kg) m (kg) mCpdT Cp (kJ/kg) m (kg)
70.63086419753 393.237 27774.669144445
70.25416666667 196.6185
73.49833333333 9.830925 722.556602625
73.49833333333 186.787575
Err:509 Err:509 358.632144 Err:509 Err:509 17572.975056
Err:508 Err:508 1101.0636
Err:509 Err:509
Err:509
C
Hl (kJ/kg) λs (Kj/kg) m (kg/jam)
419.1 2256.9 Err:509
asuk Keluar
24 26 27
70.63086419753 393.237
73.49833333333 9.830925
Err:509 2466.08175335294 Err:509 Err:509 2824.713897353
Err:509 Err:509 228.5100207
Err:509 Err:509
Err:509
suhu steam = 100 C

26 Err:509 2676 419.1 2256.9
mCpdT
Err:509
Err:509
suhu steam = 100 C

29 Err:509 2676 419.1 2256.9
mCpdT
Err:509
Err:509
Keluar
29 30 31
70.63086419753 393.237
73.49833333333 9.830925 722.556602625
Err:509 Err:509 9542.55163178965 Err:509 Err:509 194.7459516692
Err:509 228.5100207 Err:509
Err:509 Err:509
Err:509
K
33
Q (kj/jam)
0.16900150394805
0.16900 m
K
35
Q (kj/jam)
35009.6136915767
Err:509
Err:509
Err:509 + 0.042250375987 m
K T60=73,1C = 346.25 K T61 = 60 C = 333.15

33 34 35
Q (kj/jam) Cp (kj/kg) m (kg) Q (kj/jam) Cp (kj/kg) m (kg)
83.47284 419.41324
Err:509 172.67157 Err:509 Err:509 22.07438
Err:509 0.05763 Err:509 Err:509
Err:509 Err:509
steam 220
33 Err:509 2799.9 943.7 1856.2
mCpdT
Err:509
Err:509
Keluar T CW in = 30 C 303.15
37 T CW out = 50 C 323.15
mCpdT Q Cp m
40924.4432132465 Err:509 84 Err:509
Err:509
Err:509
suhu steam = 55 C
41 Err:509 2601 230.2 2370.8
mCpdT
0
Err:509
Err:509
suhu steam = 55 C
41 Err:509 2601 230.2 2370.8
mCpdT
Err:509
Err:509
Err:509
Keluar
38 39
0 0.29357994453844 0
Err:509 Err:509 0.0828045997416 Err:509
Err:509 Err:509
Err:509 Err:509
Keluar
42 43
Err:508 0.2112600000912 Err:508
Err:509 Err:509 0.3923400001693 Err:509
Err:509 Err:508
Err:509 Err:508
Q (kj/jam)
3.905593400025
3.470712318302
7.376305718326
N (kmol) Q (kj/jam)
? ?
? ?
? ?
N (kmol) Q (kj/jam)
0.0000 53.751177691
0.0000 0.1057098631
0.0000 0.0390558809
0.0000 0
0.0000 0.0061352017
0.0000 3.748935E-08
0.0000 6.375495E-09
0.0000 2.423089E-05
0.0126 6.3154401542
? ?
? ?
60.217543066
+ 1093.8531175 N O2 + 36.8478568429 N O2
T steam = 75 C 348.15
P steam = kPa
Q (kj/jam) Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
159640.998 155908.80 2635.4 313.9 2321.5
313.958
12.15192
0.00000
18.222
0.00011
0.00000
0.00723
1885.00081
161870.3377
155908.80
Q (kj/jam)
15964.09977428
31.39582933652
12.15192032241
0
0.000361563009
0.029154478301
2.783584577E-06
0.006330925081
2813.057390626
18820.741
T CW in = 30 C 303.15
T CW out = 49 C 323.15
Q (kj/jam) Q Cp.dT N
5321.366591425 12545.3861 1505.53371261
10.46527644551
3.866532207534 Q = N.Cp.dT
0 N = Q/(Cp.dT)
0.000119942922 N = 8.33284967312 kmol/jam
0.009718159434 F Cw = 149.991294116 kg/jam
9.278615258E-07 F Cw = 0.14999129412 ton/jam
0.002099879876
939.6443203636
6275.3547
12545.3861
55
Q (kj/jam)
5375.1124
10.5710
3.9056
0.0000
0.0001
0.0098
0.0000
0.0021
949.1347
6338.736
6338.736
18932.841 + 934.425048922676 N O2 + 912.046648863
18932.841 + 934.425 N O2 + 3431.033
443.15 K
atm
λs (Kj/kg) m (kg/jam) m (ton/jam)
2047.9 11.927 0.012
K
K
m (kg/jam)
Err:508
K
K
m (kg/jam)
Err:509
22
mCpdT
13813.26886875
0
13728.57544988
Err:509
Err:508
Err:509
Err:509
Keluar suhu steam = 100 C

27 Q (kj/jam) Hv (kJ/kg) Hl (kJ/kg) λs (Kj/kg)
mCpdT 0.0000 0 0 0
27774.66914444
722.556602625
Err:509
Err:509
Err:509
Err:509
m (kg/jam)
Err:509
m (kg/jam)
Err:509
31
mCpdT
27774.66914444
Err:509
Err:509
Err:509
K
35
Q (kj/jam)
35009.61369
Err:509
Err:509 #REF! kg/jam

#REF! kg/jam
m (kg/jam)
Err:509
K
K
D
m (kg/jam)
Err:509
m (kg/jam)
Err:509
+ 136.7150671 N O2
K
atm
m (kg) (ton/jam)
67.159 0.067158648
K
K
Ball Mill (BM-101)
Tref = 25 C
T56 = 35 C
T57 = 35 C
Komponen A B
Selulosa
MCA
CMC
Na-Glikolat
H2O 51.234 0.013088
NaOH 0 0
NaCl 0 0
N N2
N O2
m (kg/jam)
#DIV/0!
BM N2 = 28.014
BM O2 = 31.998
298.15 K
308.15 K
308.15 K
56 57
C D Komponen
Cp (kj/kg) m (kg) Q (kj/jam) Cp (kj/kg) m (kg) Q (kj/jam)
2080.4 0.00258 5.3751124 ### 0.00258 5.3751124 Selulosa
1.2571256 0.00311 0.0039056 1.25713 0.00311 0.0039056 MCA
0.5734851 0.00000 1.212E-07 0.57349 0.00000 1.212E-07 NaOH
2904.1 0.00000 9.816E-06 ### 0.00000 9.816E-06 CMC
2.336E-05 1.1091 0.00000 9.372E-10 1.10910 0.00000 9.372E-10 NaGlikolat
0 0.5020096 0.00000 2.121E-06 0.50201 0.00000 2.121E-06 NaCl
0.7544608 1.25803 0.9491347 0.75446 1.25803 0.9491347 H2O_x000D_
6.3281648 6.3281648
Masuk Keluar
56 57
5.37511 5.37511
0.00391 0.00391
0.00000 0.00000
0.00000 0.00000
0.00001 0.00001
0.94913 0.94913
0.00000 0.00000
6.328 6.328
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW)
E-103 H1 150 80 Err:509 Err:509 70 Err:509
E-109 H2 90 35 Err:509 Err:509 55 Err:509
E-113 H3 55 35 0 0 20 0.000000000
E-115 H4 60 35 13206.6444 3.66851233 25 0.146740493
E-101 C1 100 150 Err:509 Err:509 50 Err:509
E-102 C2 30 150 Err:508 Err:508 120 Err:508
E-104 C3 30 80 Err:509 Err:509 50 Err:509
E-105 C4 30 80 Err:509 Err:509 50 Err:509
E-106 C5 30 80 Err:509 Err:509 50 Err:509
E-107 C6 30 80 Err:509 Err:509 50 Err:509
E-108 C7 30 200 Err:509 Err:509 170 Err:509
E-110 C8 30 35 Err:509 Err:509 5 Err:509
E-111 C9 30 35 Err:509 Err:509 5 Err:509
E-112 C10 35 55 155908.801 43.3080002 20 2.165400012
E-114 C11 30 150 24424.5551 6.78459864 120 0.056538322
H1 H2 H3
200 50 200-150
150 10 150-140
140 40 140-100 Err:509
100 20 100-80 Err:509
80 10 80-70 Err:509 Err:509
70 15 70-55 Err:509
55 5 55-50 Err:509
50 5 50-45 Err:509
45 10 45-35 Err:509 0
35 5 35-30 Err:509 0
30 5 30-25 Err:509 0
25 5 25-20
20 20 20-0
T QH initial Pass Final pass

QH=0 Qh min
200 0 Err:509
Err:509
150 Err:509 Err:509
Err:509
140 Err:509 Err:509
Err:509
100 Err:509 Err:509
Err:509
80 Err:509 Err:509
Err:509
70 Err:509 Err:509
Err:509
55 Err:509 Err:509
Err:509
50 Err:509 Err:509
Err:509
45 Err:509 Err:509
Err:509
35 Err:509 Err:509
Err:509
30 Err:509 Err:509
Err:509
25 Err:509 Err:509
0.7337025
20 Err:509 Err:509
Qc
H1 150
H2 90
H3 55
H4 60
Err:509 kW Err:509
Err:509
C1 150
Err:508 kW
C2 150
C3 80
Err:509
C4 80
C5 80
C6 80
Err:509 kW
C7 200
C8 35
C9 35
C10 55
2.8269161 Kw
C11 150
Beban Heater = Err:509

Stream Ts Tt Tadj adjusted T
Ts Tt
ceklis H1 150 80 10 140 70
ceklis H2 90 35 10 80 25
ceklis H3 55 35 10 45 25
ceklis H4 60 30 10 50 20
ceklis C1 100 150 100 150
ceklis C2 30 150 30 150
ceklis C3 30 80 30 80
ceklis C4 30 80 30 80
ceklis C5 30 80 30 80
ceklis C6 30 80 30 80
ceklis C7 30 200 30 200
ceklis C8 30 35 30 35
ceklis C9 30 35 30 35
ceklis C10 35 55 35 55
ceklis C11 30 150 30 150
H4 C1 C2 C3 C4 C5 C6 C7
Err:509
Err:509 Err:508 Err:509
Err:509 Err:508 Err:509
Err:508 Err:509
Err:508 Err:509 Err:509 Err:509 Err:509 Err:509
0.1467405 Err:508 Err:509 Err:509 Err:509 Err:509 Err:509
0.1467405
0.1467405
QH min = Err:509
Qc min = Err:509
T pinch hot = 110 C
T pinch cold = 100 C
C Q
110 Err:509 Err:509 Err:509
110 Err:509
110 0
110 0.146740493221
kW
C
100 Err:509 Err:509
100 Err:508 Err:508

100 Err:509
100 Err:509
100 Err:509
100 Err:509
100 Err:509 Err:509
100 Err:509
100 Err:509
100 2.165400012453
100 0.056538322038 2.8269161

C8 C9 C10 C11 delta H sigma C
Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
Err:509 Err:509 0.0565383 Err:509 Err:509
Err:509 Err:509
0.1467405 0.733702466107
Ch > Cc
3.9576825 kW
Err:509 C
110
H
E
Err:509 kW
Err:509
110
90
110
55
110
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
Err:509 kW
C Err:509 C
43.308 kW
#DIV/0! C
Err:509 kW Err:509 kW
Err:509 C Err:509
Beban Cooler = Err:509
Err:509 kW
Err:509 C
Err:508 kW
Err:508 C
Err:509 kW
C Err:509 C
C
80 Err:509
Err:509 kW
35 Err:509
Err:508 kW
35 0
Err:509 Kw
Err:509 C
30 0.146740493221
Err:509 kW
100 Err:509
30 Err:508
30 Err:509
30 Err:509
30 Err:509
30 Err:509
30 Err:509
30 Err:509
30 Err:509
35 2.165400012453
30 0.056538322038
Q
Err:509
Err:509
4.402214797
Err:508
Err:509
Err:509
Err:509
Err:509
Err:509
Err:509
Err:509
43.30800025
3.957682543
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW)
E-103 H1 150 80 Err:509 Err:509 70 Err:509
E-109 H2 90 35 Err:509 Err:509 55 Err:509
E-113 H3 55 35 0 0 20 0.000000000
E-115 H4 60 35 13206.6444 3.66851233 25 0.146740493
E-101 C1 100 150 Err:509 Err:509 50 Err:509
E-102 C2 30 150 Err:508 Err:508 120 Err:508
E-104 C3 30 80 Err:509 Err:509 50 Err:509
E-105 C4 30 80 Err:509 Err:509 50 Err:509
E-106 C5 30 80 Err:509 Err:509 50 Err:509
E-107 C6 30 80 Err:509 Err:509 50 Err:509
E-108 C7 30 200 Err:509 Err:509 170 Err:509
E-110 C8 30 35 Err:509 Err:509 5 Err:509
E-111 C9 30 35 Err:509 Err:509 5 Err:509
E-112 C10 35 55 155908.801 43.3080002 20 2.165400012
E-114 C11 30 150 24424.5551 6.78459864 120 0.056538322
H1 H2 H3
200 50 200-150
150 10 150-140
140 5 140-135
135 35 135-100 Err:509
100 20 100-80 Err:509
80 5 80-70 Err:509
75 5 75-70 Err:509 Err:509
70 5 70-65 Err:509 Err:509
65 10 65-55 Err:509
55 5 55-50 Err:509
50 5 50-45 Err:509
45 5 45-40 Err:509
40 5 40-35 Err:509 0
35 5 35-30 Err:509 0
30 5 30-25 Err:509 0
25 5 25-20 Err:509 0
20 5 20-15
15 15 15-0
T QH initial Pass Final pass

QH=0 Qh min
200 0 Err:509
Err:509
150 Err:509 Err:509
Err:509
140 Err:509 Err:509
Err:509
135 Err:509 Err:509
Err:509
100 Err:509 Err:509
Err:509
80 Err:509 Err:509
Err:509
75 Err:509 Err:509
Err:509
70 Err:509 Err:509
Err:509
65 Err:509 Err:509
Err:509
55 Err:509 Err:509
Err:509
50 Err:509 Err:509
Err:509
45 Err:509 Err:509
Err:509
40 Err:509 Err:509
Err:509
35 Err:509 Err:509
Err:509
30 Err:509 Err:509
Err:509
25 Err:509 Err:509
Err:509
20 Err:509 Err:509
0.7337025
15 Err:509 Err:509
Qc
H1 150
H2 90
H3 55
H4 60
Err:509 kW Err:509
Err:509
C1 150
Err:508 kW
C2 150
C3 80
Err:509
C4 80
C5 80
C6 80
Err:509 kW
C7 200
C8 35
C9 35
C10 55
2.8269161 Kw
C11 150
Beban Heater = Err:509

Stream Ts Tt Tadj adjusted T
Ts Tt
ceklis H1 150 80 15 135 65
ceklis H2 90 35 15 75 20
ceklis H3 55 35 15 40 20
ceklis H4 60 30 15 45 15
ceklis C1 100 150 100 150
ceklis C2 30 150 30 150
ceklis C3 30 80 30 80
ceklis C4 30 80 30 80
ceklis C5 30 80 30 80
ceklis C6 30 80 30 80
ceklis C7 30 200 30 200
ceklis C8 30 35 30 35
ceklis C9 30 35 30 35
ceklis C10 35 55 35 55
ceklis C11 30 150 30 150
H4 C1 C2 C3 C4 C5 C6 C7
Err:509
Err:509 Err:508 Err:509
Err:509 Err:508 Err:509
Err:509 Err:508 Err:509
Err:508 Err:509
0.1467405
0.1467405
0.1467405
QH min = Err:509
Qc min = Err:509
T pinch hot = 115 C

T pinch cold = 100 C
C Q
115 Err:509 Err:509 Err:509
115 Err:509
115 0
115 0.146740493221
kW
C
100 Err:509 Err:509
100 Err:508 Err:508
100 Err:509
100 Err:509
100 Err:509
100 Err:509
100 Err:509 Err:509
100 Err:509
100 Err:509
100 2.165400012453
100 0.056538322038 2.8269161
C8 C9 C10 C11 delta H sigma C
Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
2.1654 0.0565383 Err:509 Err:509
Err:509 Err:509 0.0565383 Err:509 Err:509
Err:509 Err:509
Err:509 Err:509
0.1467405 0.733702466107
Ch > Cc
3.9576825 kW
Err:509 C
115
H
E
Err:509 kW
Err:509
115
90
115
55
115
60
100
100
100
80
100
80
100
80
100
80
100
100
35
100
35
100
55
100
Err:509 kW
C Err:509 C
43.308 kW
#DIV/0! C
Err:509 kW Err:509 kW
Err:509 C Err:509
Beban Cooler = Err:509
Err:509 kW
Err:509 C
Err:508 kW
Err:508 C
Err:509 kW
C Err:509 C
C
80 Err:509
Err:509 kW
35 Err:509
Err:508 kW
35 0
Err:509 Kw
Err:509 C
30 0.146740493221
Err:509 kW
100 Err:509
30 Err:508
30 Err:509
30 Err:509
30 Err:509
30 Err:509
30 Err:509
30 Err:509
30 Err:509
35 2.165400012453
30 0.056538322038
Q
Err:509
Err:509
0
4.402214797
Err:508
Err:509
Err:509
Err:509
Err:509
Err:509
Err:509
Err:509
43.30800025
3.957682543
Stream Ts Tt ΔH (kj/h) ΔH (kW/h) ΔT (oC) C (kW/C)
E-103 H1 150 80 Err:509 Err:509 70 Err:509
E-109 H2 90 35 Err:509 Err:509 55 Err:509
E-113 H3 55 35 0 0.00000 20 0.000000
E-115 H4 60 35 13206.64 3.66851 25 0.146740
E-101 C1 100 150 Err:509 Err:509 50 Err:509
E-102 C2 30 150 Err:508 Err:508 120 Err:508
E-104 C3 30 80 Err:509 Err:509 50 Err:509
E-105 C4 30 80 Err:509 Err:509 50 Err:509
E-106 C5 30 80 Err:509 Err:509 50 Err:509
E-107 C6 30 80 Err:509 Err:509 50 Err:509
E-108 C7 30 200 Err:509 Err:509 170 Err:509
E-110 C8 30 35 Err:509 Err:509 5 Err:509
E-111 C9 30 35 Err:509 Err:509 5 Err:509
E-112 C10 35 55 155908.8 43.30800 20 2.165400
E-114 C11 30 150 24424.56 6.78460 120 0.056538
Hot Stream
Interval Tstart Tend ΔT H1 H2 H3 H4 sum C ΔH (kW)
1 150 90 60 Err:509 Err:509 Err:509
2 90 80 10 Err:509 Err:509 Err:509 Err:509
3 80 60 20 Err:509 Err:509 Err:509
4 60 55 5 Err:509 0.146740 Err:509 Err:509
5 55 35 20 Err:509 0.000000 0.146740 Err:509 Err:509
Cold Stream
Interval Tstart Tend ΔT C1 C2 C3 C4 C5 C6
1 200 150 50
2 150 100 50 Err:509 Err:508
3 100 80 20 Err:508
4 80 55 25 Err:508 Err:509 Err:509 Err:509 Err:509
Hot Cold 250

T ΔH T ΔH
150 0 200 0
200
90 Err:509 150 Err:509
80 Err:509 100 Err:509
60 Err:509 80 Err:509 150
55 Err:509 55 Err:509
35 Err:509 35 Err:509
100
30 Err:509
50
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
100
50
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Hot Cold
T ΔH T ΔH Penentuan Pinch
150 23.3 200 0 250
90 Err:509 150 Err:509
80 Err:509 100 Err:509 200
60 Err:509 80 Err:509
55 Err:509 55 Err:509 150
Suhu (C)
35 Err:509 35 Err:509
30 Err:509 100
Tpinch hot = 100 C 50

Tpinch cold = 100 C Err:509 kW
0
0 5 10 15 2
Entalpi (ΔH)
Hot Cold f(x) = NaN x + NaN

T ΔH T ΔH T ΔH T ΔH
150 26.26 200 0 110 0 200 Err:509
250
90 Err:509 150 Err:509 110 Err:509 150 Err:509
80 Err:509 100 Err:509 110 Err:509 100 Err:509
200
60 Err:509 80 Err:509 110 Err:509 80 Err:509
55 Err:509 55 Err:509 110 Err:509 55 Err:509
150
35 Err:509 35 Err:509 110 Err:509 35 Err:509 Suhu (C)
30 Err:509 110 Err:509 30 Err:509
100
Qhmin = 26.26 kW
Qcmin = Err:509 kW 50
Tpinch hot = 110 C
Tpinch cold = 100 C 0
0 5
Hot
Linear (Cold)
Hot Cold f(x) = NaN x + NaN

T ΔH T ΔH T ΔH T ΔH
150 27.764 200 0 115 0 200 Err:509 250
90 Err:509 150 Err:509 115 Err:509 150 Err:509
80 Err:509 100 Err:509 115 Err:509 100 Err:509 200
150
Suhu (C)
100
250
200
60 Err:509 80 Err:509 115 Err:509 80 Err:509
55 Err:509 55 Err:509 115 Err:509 55 Err:509 150
Suhu (C)
35 Err:509 35 Err:509 115 Err:509 35 Err:509
100
30 Err:509 115 Err:509 30 Err:509
50
Qhmin = 27.764 kW
Qcmin = Err:509 kW 0
0 5
Tpinch hot = 115 C
Tpinch cold = 100 C
Hot
Linear (Cold)
C7 C8 C9 C10 C11 sum C ΔH (kW)
Err:509 Err:509 Err:509
Err:509 0.056538 Err:509 Err:509
Err:509 0.056538 Err:508 Err:508
Err:509 0.056538 Err:508 Err:508
Err:509 2.165400 0.056538 Err:508 Err:508
Err:509 Err:509 Err:509 0.056538 Err:508 Err:508
0.4 0.5 0.6 0.7 0.8 0.9 1

0.4 0.5 0.6 0.7 0.8 0.9 1
enentuan Pinch
Hot
Cold
10 15 20 25
Entalpi (ΔH)
N x + NaN
ΔTmin = 10
x pada 100C = Err:509
250
y pada pinch Err:509
200
150
100
50
0
0 5 10 15 20 25 30
Entalpi (kW)
Hot Linear (Hot) Cold

Linear (Cold) delta Tmin = 10 pinch
aN x + NaN
ΔTmin = 15
250
x pada 100C = Err:509
200 y pada pinch Err:509
150
100
ΔTmin = 15
250
200
150
100
50
0
0 5 10 15 20 25 30
Entalpi (kW)
Hot Linear (Hot) Cold

Linear (Cold) delta T min 15 pinch
1 2 3 4 5 6
Selulosa 413.9337 413.93368421 20.69668 393.237 393.237
Hemiselulosa 206.9668 206.96684211 10.34834 196.6185 196.6185
Lignin 206.9668 206.96684211 10.34834 196.6185 196.6185
MCA
NaOH
CMC
Na-Glikolat
NaCl
H2O 1179.711
H2O2
Udara
Total 827.8674 827.86736842 41.39337 786.474 786.474 1179.711
Suhu (K)
Tekanan (bar)
Laju Panas (kj/jam) 5362.59 5362.5904369 268.1295 5094.461 5094.461 4366976
0 #DIV/0!
0 0
0 0 0 0
0 0 0 0
0 0 0
0 0 0 0
0 0 0
F (kg)
0 0.0000
0 0.0000
0 0.0000
0 0.0000
0 0.0000
26.206 0.0000
26.206 0.00
#DIV/0!
0 0 0.35
#DIV/0! #DIV/0!
#DIV/0! 0
#DIV/0! 0 0
#DIV/0! 0
#DIV/0!
#DIV/0!
#DIV/0! 0
#DIV/0! 0
#DIV/0! 0
#DIV/0! 26.206
#DIV/0! 0 26.206
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.000
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
0.000 0
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.000
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
0 0
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.000
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
0 0
0.00
#DIV/0!
#DIV/0! 0
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! #DIV/0! #DIV/0!

#DIV/0! 0 #DIV/0! 0.0000 #DIV/0! 0.000
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
#DIV/0! #DIV/0! #DIV/0!
0 0 #DIV/0! 0.0000 #DIV/0! 0.000
0 0.0000
7 8 9 10 11 12 13 14 15 16
393.237 393.237 393.237 393.237
196.6185 196.6185 196.6185 196.6185
196.6185 196.6185 196.6185 196.6185
1101.357 1101.064 1101.064 1101.064 1101.0636
1572.948 314.5896 1258.358 314.5896 1101.064 3303.191 4404.254 4404.254 4718.844
2359.422 1101.064 1258.358 1101.064 1101.357 2202.127 3303.191 5505.318 5505.318 6606.3816
3575628 208261.4 3367367 Err:509 Err:508 Err:508 Err:509 Err:508 Err:508 Err:509
26.206
0 0
0 26.206
26.206
0
26.206
0 0
0 #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! 0.000 #DIV/0! 0.00
0.000
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0.000
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0! 0.000
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0
#DIV/0! #DIV/0!
#DIV/0! 0 #DIV/0! 0
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
#DIV/0! #DIV/0!
17 18 19 20 21 22 23 24 25 26
393.237 393.237 393.237
196.6185 196.6185 196.6185
196.6185 196.6185 9.830925 186.7876
1101.064 1101.064 1101.064
4718.844 4718.844 13212.76 13212.76 358.6321 17572.98 2466.082 2466.082

228.51 228.51
6606.382 6606.382 13212.76 13212.76 761.7001 19057.44 228.51 228.51 2466.082 2466.082
Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509
0
27 28 29 30 31 32 33 34 35 36
393.237 393.237 419.4132 419.4132
9.830925 9.830925
2824.714 6912.584 6912.584 9542.552 194.746 173 22 22

228.51 228.51
Err:509 Err:509 Err:509
3456.292 6912.584 6912.584 9780.893 587.983 Err:509 Err:509 Err:509 441.4876 441.4876
Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509 Err:509
37 38 39 40 41 42 43 44 45 46
0.002558
0.21126 0.29358 0.29358 0.003076

0.29358 0.005282 0.005282
8.366E-10
3.346E-09
4.183E-06
0.21126 0.18108 0.08 0.08 0.002965 0.079839 0.021797 0.021797 1.245452
883.7822
0.42252 0.18108 0.376385 0.376385 0.296545 0.079839 0.027078 0.027078 883.7822 1.251089
Err:509 Err:509 Err:509 Err:509 Err:509 Err:508 Err:509 Err:509 -172022 5961.537
47 48 49 50 51 52 53 54 55 56
2.584E-05 0.002558 0.002558 0.002558 0.041856 4.143729 0.000419 0.04144 418.56 418.56
3.107E-05 0.003076 0.003076 0.003076 2.936E-05 0.002906 0.000001 0.00010 0.29 0.29
8.45E-12 8.366E-10 8.366E-10 8.366E-10 8.281E-12 8.199E-10 0.000000 0.00000 0.00 0.00
3.38E-11 3.346E-09 3.346E-09 3.346E-09 8.18E-08 8.098E-06 0.000000 0.00000 0.00 0.00
4.225E-08 4.183E-06 4.183E-06 4.183E-06 2.472E-08 2.447E-06 0.000000 0.00000 0.00 0.00
0.01258 1.245452 1.245452 1.245452 1000 0 0.000000 0.00000 22.64 22.64
883.7822 883.7822
883.7948 1.251089 1.251089 1.251089 1883.824 4.146646 0.00042 0.041533 441.4973 441.4973
-436801 0 #NAME? 0 #NAME? #NAME? #NAME? #NAME? #NAME? 6.328165

57 58 59 60 61
0 418.56 418.56
0 0.29 0.29
0 0.00 0.00
0 0.00 0.00
0 0.00 0.00
22.19166 0.45 0.45
882.9945 882.9945 882.9945

882.9945 882.9945 905.1862 419.3056 419.3056
1011.284 19991.3 6483.378 18932.84 5724.05

Kapasitas Produksi : 6000 ton/tahun
Masa Aktif Produksi : 330 hari
Temperatur Referensi : 25 C_x000D_ : 298 K
o
Basis Perhitungan : kg/jam

Bahan Baku : Bagasse_x000D_
Produk : Carboxymethyl Cellulose (CMC)_x000D_
Kapasitas Perancangan Pabrik CMC

Kapasitas Produksi = 757.5758 kg/jam 757.5757576
Basis Perancangan = 786.474 kg/jam

Fungsi : Reaksi karboksimetilasi
Asumsi : 1. Konversi reaksi 80%
2. Basis F36 =_x000D_
3. Udara keluar F48 membawa 1% produk hasil reaksi_x000D_
4. Rasio Selulosa : MCA adalah 1:1,2
5. Rasio MCA : NaOH adalah 1:1,7
Data aliran 36 F36 =_x000D_ 413.9340 kg/jam Data Aliran 40

Komponen w F (kg/jam) Mr (kg/kmol) N (kmol) Komponen
Selulosa 0.95 393.2373 162000 0.002427391 MCA
H2O_x000D_ 0.05 20.6967 Err:509 Err:509 H2O_x000D_
1.07 1.7
0.8
Selulosa + NaOH → Selulosa-Na +
Mula 0.002427391 + 0.004 → +
Reaksi 0.001941912 + 0.002 → 0.002 +
Sisa 0.000485478 + 0.002 → 0.002 +
0.800
MCA + NaOH → MCA-Na +
Mula 0.003 + 0.002 → +
Reaksi 0.002 + 0.002 → 0.002 +
Sisa 0.000618499 + 0.000 → 0.002 +
0.800
Selulosa-Na + MCA-Na → Na-CMC +
Mula 0.002 + 0.001 → +
Reaksi 0.000 + 0.000 → 0.000 +
Sisa 0.001447113 + 0.000 → 0.000 +
0.8
MCA-Na + 2NaOH → Na-Glikolat +
Mula 0.000 + 0.000 → +
Reaksi 0.000 + 0.000 → 0.000 +
Sisa 0.000 + 0.000247303 → 0.000 +
Komponen N (kmol) Mr (kg/kmol) F (kg/jam) Komponen w

Selulosa 0.000 162000 78.6475 Selulosa Err:509
Selulosa-Na 0.001 184 0.2663
MCA 0.001 94.5 0.0584 MCA Err:509
MCA-Na 0.000 104.5 0.0000
NaOH 0.000 Err:509 Err:509 NaOH Err:509
Na-Glikolat 0.000 98 0.0121 Na-Glikolat Err:509
CMC 0.000 242000 119.7414 CMC Err:509
NaCl 0.001 0 0.0000 NaCl Err:509
H2O Err:509 Err:509 Err:509 H2O_x000D_ Err:509
Err:509 Err:509 Err:509
Masuk
Komponen
w 36
F36
w 40
F40
w44 F44
Selulosa 0.95 393
MCA #DIV/0! 0.000
NaOH Err:509 Err:509
Na-Glikolat
CMC
NaCl
H2O_x000D_ 0.05 21 #DIV/0! 0.00 Err:509 Err:509
Udara
Total 1 414 #DIV/0! 0 Err:509 Err:509
Err:509
27. Heater (E-204)

F F N N Fungsi :
Komponen
46 48 Mr 46 48 Asumsi :
Selulosa 77.8610 77.8610 162000.0 0.0005 0.0005
MCA 0.0579 0.0579 0.0 #DIV/0! #DIV/0!
NaOH Err:509 Err:509 Err:509 Err:509 Err:509
Na-Glikolat 0.0120 0.0120 98.0 0.0001 0.0001
CMC 118.5440 118.5440 84.0 1.4112 1.4112
NaCl 0.0000 0.0000 0.0 #DIV/0! #DIV/0!
H2O_x000D_ Err:509 Err:509 Err:509 Err:509 Err:509
Total Err:509 Err:509 Err:509 Err:509 Err:509
28. Aging vessel (V-103)

Masuk Keluar Masuk Keluar Fungsi :
Komponen
48 49 Mr N48 N49 Asumsi :
Selulosa 77.8610 77.8610 162000.0 0.0005 0.0005 Kondisi :
MCA 0.0579 0.0579 0.0 #DIV/0! #DIV/0!
NaOH Err:509 Err:509 Err:509 Err:509 Err:509
Na-Glikolat 0.0120 0.0120 98.0 0.0001 0.0001
CMC 118.5440 118.5440 84.0 1.4112 1.4112
NaCl 0.0000 0.0000 0.0 #DIV/0! #DIV/0!
29. Cooler (E-205)

Masuk Keluar Fungsi :
Komponen
F49 F50 Mr N49 N50 Asumsi :
Selulosa 77.861 77.861 162 0.480623337 0.480623337
MCA 0.058 0.058 94.5 0.000612314 0.000612314
NaOH Err:509 Err:509 40 Err:509 Err:509
Na-Glikolat 0.012 0.012 98 0.000122463 0.000122463
CMC 118.544 118.544 104.5 1.134392496 1.134392496
NaCl 0.000 0.000 58.5 0 0
H2O_x000D_ Err:509 Err:509 18 Err:509 Err:509
Total Err:509 Err:509

Komponen
F47 F51
F52
Mr N47 N 51
Selulosa 0.786 0.0079 0.7786 162000.000 0.000005 0.000000

MCA 0.001 0.0000 0.0006 0.000 #DIV/0! #DIV/0!
NaOH Err:509 Err:509 Err:509 Err:509 Err:509 Err:509
Na-Glikolat 0.000 0.0000 0.0001 98.000 0.000001 0.000000
CMC 1.197 0.0120 1.1854 84.000 0.014255 0.000143
NaCl 0.000 0.0000 0.0000 0.000 #DIV/0! #DIV/0!
H2O_x000D_ Err:509 Err:509 Err:509 Err:509 Err:509 Err:509
Udara 0.000 0.00 28.970 0.000 0.000000
Total Err:509 Err:509 Err:509 Err:509 #DIV/0! #DIV/0!
Err:509 Err:509 Err:509 #DIV/0! #DIV/0!

Komponen Mr
F51 F53 F54 N51 N53
Selulosa 0.0079 0.0001 0.0078 162000.000 0.0000000 0.0000000
MCA 0.0000 0.000000 0.0000 0.000 #DIV/0! #DIV/0!
NaOH Err:509 Err:509 Err:509 Err:509 Err:509 Err:509
Na-Glikolat 0.0000 0.000000 0.0000 98.000 0.0000000 0.0000000
CMC 0.0120 0.000120 0.0119 84.000 0.0001425 0.0000014
NaCl 0.0000 0.000000 0.0000 0.000 #DIV/0! #DIV/0!
H2O_x000D_ Err:509 Err:509 Err:509 Err:509 Err:509 Err:509
Udara 0.000 0.000 28.970 0.00 0.00
Total Err:509 Err:509 Err:509 Total #DIV/0! #DIV/0!
Err:509 Err:509
32. Silo (TK-107)
Masuk Keluar
Komponen
F
50
F52 F54
F55 Mr N50
Selulosa 77.8610 0.7786 0.0078 78.6474 162 0.48062333719
MCA 0.0579 0.0006 0.0000 0.0584 94.5 0.00061231413
NaOH Err:509 Err:509 Err:509 Err:509 40 Err:509
Na-Glikolat 0.0120 0.0001 0.0000 0.0121 98 0.00012246283
CMC 118.5440 1.1854 0.0119 119.7413 104.5 1.1343924964
NaCl 0.0000 0.0000 0.0000 0.0000 58.5 0
H2O_x000D_ Err:509 Err:509 Err:509 Err:509 18 Err:509
Err:509 Err:509 Err:509
35. Rotary Dryer (RD-301)

Masuk Keluar
Komponen
F
55
F57
F58
F59 Mr
Selulosa 78.65 78.647 162
MCA 0.06 0.058 94.5
NaOH Err:509 Err:509 40
Na-Glikolat 0.01 0.012 0.000 98
CMC 119.74 119.741 104.5
NaCl 0.00 0.000 58.5
H2O_x000D_ Err:509 Err:509 Err:509 18
Udara 17461.83 17461.831 3666.984452 28.97
Total Err:509 17462 Err:509 Err:509 13794.84627
Err:509 Err:509
34. Heater (E-302)

Masuk Keluar
Komponen
59 60 Mr 59 60
Udara 17461.831 17461.831 28.97 602.756 602.756
Total 17461.831 17461.831
36. Cooler (E-115)

Masuk Keluar
Komponen
F59 F60 Mr N59 N50
Selulosa 78.647 78.647 162 0.4855 0.485477633
MCA 0.058 0.058 94.5 0.0006 0.000618499
Na-Glikolat 0.000 0.000 98 0.0000 2.473994E-06
CMC 119.741 119.741 104.5 1.1458 1.145849861
NaCl 0.000 0.000 58.5 0.0000 0
Total Err:509 Err:509 Err:509 Err:509
33. Ball mill (BM-301)

Komponen
F60 F61 Mr N50 N61 Asumsi :
Selulosa 78.65 78.65 162 0.485477633 0.485477633
MCA 0.06 0.06 94.5 0.000618499 0.000618499
Na-Glikolat 0.01 0.01 98 0.0001237 0.0001237
CMC 119.74 119.74 104.5 1.145849861 1.145849861
NaCl 0.00 0.00 58.5 0 0
37. Product Tank (TK-108)

Masuk Keluar
Komponen
F61 F62 Mr N61 N62
Selulosa 78.65 78.65 162 0.48548 0.48548
MCA 0.06 0.06 94.5 0.00062 0.00062
Na-Glikolat 0.00 0.00 98 0.00000 0.00000
CMC 119.74 119.74 Err:509 104.5 1.14585 1.14585
NaCl 0.00 0.00 58.5 0.00000 0.00000
1. Roll crusher (RC-101)

Komponen
1 2 Mr 1 2 Asumsi :
Selulosa 413.934 413.934 162000 0.002555146 0.002555146
Hemiselulosa 206.967 206.967 23100 0.008959604 0.008959604
Lignin 206.967 206.967 1500 0.137977895 0.137977895 asumsi F1 =
827.867 827.867 0.149492644 0.149492644 Feed =
2. Vibrating screen (VS-101)

Masuk Keluar
Komponen
2 3 4 Mr 2 3
Selulosa 413.934 20.697 393.237 162000 0.002555146 0.00012775731
Hemiselulosa 206.967 10.348 196.619 23100 0.008959604 0.00044798018
Lignin 206.967 10.348 196.619 1500 0.137977895 0.00689889474
827.867 41.393 786.474 0.149492644 0.00747463222
827.867 827.867 0.149492644 0.149492644490013
3. Silo 1 (TK-101)
Komponen
4 5 Mr 4 5 Asumsi :
Selulosa 393.237 393.237 162000 0.002427389 0.002427389
Hemiselulosa 196.619 196.619 23100 0.008511623 0.008511623
Lignin 196.619 196.619 1500 0.131079 0.131079
786.474 786.474 0.142018012 0.142018012
4. Steam Explosion Tank (V-101)

Masuk Keluar
Komponen
5 6 7 Mr 5 6
Selulosa 393.237 393.237 162000 0.002427389
Hemi 196.619 58.986 23100 0.008511623
Hemi aq 137.633 23100
Lignin 196.619 196.619 1500 0.131079
H2O g 1244.624 18
H2O l 1572.948 328.324 18 87.386
786.474 1572.948 2359.422 0.142018012 87.386
2359.422 2359.422 87.5280180122655
5. Flash Tank (V-102)

Masuk Keluar
Komponen
7 8 9 Mr 7 8
Selulosa 393.237 393.237 162000 0.002427389 0.00242738889
Hemi 58.986 58.986 23100 0.002553487 0.00255348701
Hemi aq 137.633 137.633 23100 0.005958136 0.00595813636
Lignin 196.619 196.619 1500 0.131079 0.131079
H2O g 1244.624 1244.624 18 69.14577766
H2O l 328.324 328.324 18 18.24022234 18.2402223417
2359.422 1114.798 1244.624 87.52801801 18.382240354
2359.422 2359.422 87.52801801 87.5280180122655
6. Heater (E-101)
Komponen
8 10 Mr 8 10 Asumsi :
Selulosa 393.237 393.237 162000 0.002427389 0.002427389
Hemi 58.986 58.986 23100 0.002553487 0.002553487
Hemi aq 137.633 137.633 23100 0.005958136 0.005958136
Lignin 196.619 196.619 1500 0.131079 0.131079
H2O l 328.324 328.324 18 18.24022234 18.24022234
1114.798 1114.798 18.38224035 18.38224035
7. Mixer (M-101)
Masuk Keluar
Komponen
12 13 14 Mr 12 13
NaOH 1114.798 1114.798 40 27.86995005
H2O 1114.798 3344.394 4459.192 18 61.93322234 185.799667025
2229.596 3344.394 5573.990 89.8031724 185.799667025
5573.990 5573.990 275.6028394
8. Heater (E-102)
Komponen
14 15 Mr 14 15
NaOH 1114.798 1114.798 40 27.86995005 27.86995005
H2O 4459.192 4459.192 18 247.7328894 247.7328894
5573.990 5573.990 275.6028394 275.6028394
9. Delignification Tank (DT-101)

Masuk Keluar
Komponen
8 15 16 Mr 8 15
Selulosa 393.237 393.237 162000 0.002427389
Hemi 58.986 23100 0.002553487
Hemi aq 137.633 196.619 23100 0.005958136
Lig 196.619 9.831 1500 0.131079
Lig aq 186.788 1500
H2O l 328.324 4459.192 4787.516 18 18.24022234 247.732889367
NaOH 1114.798 1114.798 40 27.8699500538
1114.798 5573.990 6688.788 18.38224035 275.602839421
6688.788 6688.788 293.985079774619
10. Expansion Valve (EV-101)

Komponen
16 17 Mr 16 17 Asumsi:
Selulosa 393.237 393.237 162000 0.002427389 0.002427389
Hemi aq 196.619 196.619 23100 0.008511623 0.008511623
Lig 9.831 9.831 1500 0.00655395 0.00655395
Lig aq 186.788 186.788 1500 0.12452505 0.12452505
H2O l 4787.516 4787.516 18 265.9731117 265.9731117
NaOH 1114.798 1114.798 40 27.86995005 27.86995005
6688.788 6688.788 293.9850798 293.9850798
11. Cooler (E-103)

Komponen
17 18 Mr 17 18 Asumsi:
Selulosa 393.237 393.237 162000 0.002427389 0.002427389
Hemi aq 196.619 196.619 23100 0.008511623 0.008511623
Lig 9.831 9.831 1500 0.00655395 0.00655395
Lig aq 186.788 186.788 1500 0.12452505 0.12452505
H2O l 4787.516 4787.516 18 265.9731117 265.9731117
NaOH 1114.798 1114.798 40 27.86995005 27.86995005
6688.788 6688.788 293.9850798 293.9850798
12. Heater (E-104)

Komponen
19 20 Mr 19 20 Asumsi:
H2O 13377.576 13377.576 18 743.1986681 743.1986681
13377.576 13377.576

Masuk Keluar
Komponen
18 20 22 21 Mr 18
Selulosa 393.237 393.237 162000 0.00242738889
Hemi aq 196.619 196.619 23100 0.00851162338
Lig 9.831 9.831 1500 0.00655395
Lig aq 186.788 186.788 1500 0.12452505
H2O l 4787.516 13377.576 363.302 17801.790 18 265.973111709
NaOH 1114.798 1114.798 40 27.8699500538
6688.788 13377.576 766.370 19299.994 293.985079775
20066.364 20066.364 1037.18374787521
14. Heater (E-105)

Komponen
23 24 Mr 23 24 Asumsi :
H2O2 229.911 229.911 Err:509 Err:509 Err:509
229.911 229.911
15. Heater (E-106)+B140

Komponen
25 26 Mr 23 24 Asumsi :
H2O 2495.990 2495.990 18 138.6661352 138.6661352
2495.990 2495.990
16. Bleaching Tank (BT-101)

Masuk Keluar
Komponen
21 24 26 27 Mr 21
Selulosa 393.237 393.237 162000 0.00242738889
Lig 9.831 1500 0.00655395
Lig aq 9.831 1500 0
H2O l 363.302 2495.990 2859.292 18 20.1834355962
H2O2 229.911 229.911 Err:509 Err:509
766.370 229.911 2495.990 3492.271 Err:509
3492.271 3492.271 Err:509
17. Heater (E-107)
Komponen
28 29 Mr 28 29 Asumsi :
H2O 6984.542 6984.542 18 388.0301255 388.0301255
6984.542 6984.542

Masuk Keluar
Komponen
27 29 30 31 Mr 27
Selulosa 393.237 393.237 162000 0.00242738889
Lig aq 9.831 9.831 1500 0.00655395
H2O l 2859.292 6984.542 9646.958 196.877 18 158.849570807
H2O2 229.911 229.911 Err:509 Err:509
3492.271 6984.542 9886.700 590.114 Err:509
10476.813 10476.813 Err:509
19. Heater (E-108)

Komponen
32 33 Mr 32 33 Asumsi :
Udara Err:509 Err:509 28.97 Err:509 Err:509
Err:509 Err:509
20. Rotary RD (RD-101)

Masuk Keluar
Komponen
31 33 34 35 Mr
Selulosa 393.237 393.237 162000
H2O 196.877 176.180 20.697 18
Udara Err:509 Err:509 Err:509 28.97
590.114 Err:509 Err:509 413.934 Err:509
Err:509 Err:509
21. Cooler (E-109)

Komponen
36 37 Mr 36 37 Asumsi :
Selulosa 393.237 393.237 162000 0.002427391 0.002427391
H2O 20.697 20.697 18 1.149816596 1.149816596
413.934 413.934 1.152243987 1.152243987
22. Mixer (M-102)

Komponen Masuk Keluar
38 39 40 mr 38 39
MCA 0.000 0.000 0 #DIV/0!
H2O 0 0 0.000 18 0 0
0 0 0.000 #DIV/0! 0
0.000 0.000 #DIV/0!
23. Heater (E-110)

Komponen
40 41 Mr 40 41 Asumsi :
MCA 0.000 0.000 0 #DIV/0! #DIV/0!
H2O 0.000 0.000 18 0 0
0.000 0.000 #DIV/0! #DIV/0!
24. Mixer (M-103)

Masuk Keluar
Komponen
42 43 44 Mr 42
NaOH Err:509 Err:509 Err:509 40 Err:509
H2O Err:509 Err:509 Err:509 Err:509 18 Err:509
Err:509 Err:509 Err:509
25. Heater (E-111)

Komponen
44 45 Mr 44 45 Asumsi :
H2O Err:509 Err:509 18 Err:509 Err:509
Err:509 Err:509 Err:509 Err:509
F41 =_x000D_ 0 kg/jam Data Aliran 44 F45 =_x000D_
w F (kg/jam) Mr (kg/kmol) N (kmol) Komponen w
0.78 0 0 0.003 NaOH 0.35
0.22 0 Err:509 Err:509 H2O_x000D_ 0.65
H2O
Err:509
0.002
Err:509
H2O
Err:509
0.002
Err:509
NaCl
0.000
0.000
NaCl
0.000
0.000
0.001
F (kg/jam) Mr (kg/kmol) N (kmol)

78.647455176 162000 0.000
0.2662688242 184 0.001
0.0584481671 94.5 0.001
0 104.5 0.000
Err:509 Err:509 0.000
0.0121225828 98 0.000
119.74143018 242000 0.000
0 0 0.001
Err:509 Err:509 Err:509
Err:509 Err:509
Keluar
w 45
F45
w 46
F46
w47 F47
Err:509 77.861 Err:509 0.7864745518
Err:509 0.058 Err:509 0.0005844817
Err:509 Err:509 Err:509 Err:509
Err:509 0.012 Err:509 0.0001212258
Err:509 118.544 Err:509 1.1974143018
Err:509 0.000 Err:509 0
Err:509 Err:509 Err:509 Err:509
#DIV/0! 0 Err:509 0.000
#DIV/0! 0 Err:509 Err:509 Err:509 Err:509
Err:509
Err:509
Meningkatkan suhu keluaran dari rotary reactor

1. Tidak terjadi perubahan massa
Pematangan produk
T= 55 o
C_x000D_ kg/jam
t= 8 jam
Menurunkan suhu dari aging vessel

N52
Asumsi : 1. 1% produk terbawa udara
0.000005
#DIV/0!
Err:509
0.000001
0.014112
#DIV/0!
Err:509
#DIV/0!
#DIV/0!

N54 Asumsi : 1. 1% produk terbawa udara
0.0000000
#DIV/0!
Err:509
0.0000000
0.0001411
#DIV/0!
Err:509
#DIV/0!
N52 N54 N55
0.0048062334 4.806233372E-05 0.4854776329
6.123141E-06 6.123141316E-08 0.0006184985
Err:509 Err:509 Err:509
1.224628E-06 1.224628263E-08 0.0001236997
0.011343925 0.00011343925 1.1458498606
0 0 0
Err:509 Err:509 Err:509
Err:509 Err:509 Err:509
Err:509 Err:509
N Fungsi : Mengurangi kadar air

55 57 58 59 Asumsi : 1. Efisiensi 95%
0.4854776329 0.485477633
0.0006184985 0.000618499
Err:509 Err:509
0.0001236997 0.0001212257 2.47399E-06
1.1458498606 1.145849861
0 0
Err:509 Err:509 Err:509
602.7556341537 602.75563415
Err:509 602.7556341537 Err:509 Err:509
Err:509 Err:509
Memperkecilkan ukuran prduk
tidak teriadi perubahan massa
Mencacah Bagasse menjadi 2 mm

1. Efisiensi Roll crusher 95%
2. Aliran F3 dimasukkan kembali kedalam roll crusher
827.867
786.474 kg bagasse
Fungsi : Untuk Screening bagasse yang memenuhi ukuran

4 Asumsi : 1. Aliran 3 adalah 5% dari aliran 2
0.0024273889
0.0085116234
0.131079
0.1420180123
0.149492644490013
Untuk menyimpan bagasse sementara
tidak ada perubahan massa
Fungsi : Melunakan serta mengurangi ukuran partikel dan kandungan hemiselulosa bagasse
7 Asumsi : 1. Aliran keluar tangki dalam keadaan saturated pada tekanan atmosfer
0.0024273889 2. Adiabatic expansion process
0.002553487 3. 70% hemiselulosa terpisahkan dari bagasse
0.0059581364 4. Rasio saturated steam terhadap bagasse 1:2
0.131079
69.145777658 y= 0.7913
18.240222342 x= 0.2087
87.528018012
87.528018012
Fungsi : Untuk melepaskan uap air sisa steam explotion tank

9 Asumsi : 1. semua uap terlepas ke aliran 9
69.145777658
69.145777658
87.5280180122655
Untuk meningkatkan suhu keluaran dari flash tank (V-102) dari 100C menjadi 150C
1. Menggunakan steam suhu

14 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 : 1
27.869950054 F11= Err:509
247.73288937 Err:509
275.60283942 Err:509
275.60283942
Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)

Fungsi : Untuk memecahkan ikatan lignin

16 T= 150
0.0024273889 P= 7
Asumsi : 1. rasio bagasse : cairan NaOH adalah 1:5
0.0085116234 2. menghilangkan lignin sebesar 95%
0.00655395 3. melarutkan hemiselulosa yang masih tersisa dari dalam bagasse
0.12452505
265.97311171
27.869950054
293.98507977
293.98507977
Untuk menurunkan tekanan keluaran dari tangki delignifikasi (DT-101)

1. Tidak ada perubahan masa
2. Tekanan diturunkan dari 7 menjadi 1 bar
Untuk mendinginkan keluaran dari tangki delignifikasi

1. tidak ada perubahan massa
2. medinginkan dari suhu 150 ke suhu 80
Untuk meningkatkam suhu air pencucian yang akan masuk kedalam rotary filter 1
1. Tidak ada perubahan massa
2. Meningkatkan suhu air dari 30 menjadi 80
Fungsi : Untuk memisahkan selulosa dari sisa black liquor

20 22 21 Asumsi : 1. Efisiensi rotary filter 98%
0.002427388889 2. Rasio Air pencucian dan pulp 2 : 1
0.0085116234
0.00655395
0.12452505
743.1986681 20.18343559618 988.98834421
27.869950054
743.1986681 20.19241693507 1016.9913309
1037.18374787521 1037.18374787521
Untuk meningkatkan suhu H2O2 yang akan masuk kedalam tangki bleaching
1. Tidak ada perubahan massa
3. H2O2 yang akan digunakan adalah 30% dari aliran 21
Untuk meningkatkan suhu air yang akan digunakan pada proses bleaching
1. Tidal terjadi perubahan massa
Fungsi : Untuk menghilangkan sisa lignin dan sisa blackliquor

24 26 27 Asumsi : 1. Melarutkan sisa lignin yang ada
0 0 0.0024273889 2. Air yang digunakan untuk konsistensi pulp 15%
0 0 0
0 0 0.00655395
0 138.6661352112 158.84957081
Err:509 Err:509 Err:509
Err:509 Err:509 Err:509
Err:509 Err:509
Untuk meningkatkan suhu air pencucian yang akan digunakan pada rotary filter 2
1. Tidal terjadi perubahan massa
Fungsi : Untuk memisahkan selulosa dari sisa lignin dan bleaching a

29 30 31 Asumsi : 1. Rasio Air pencucian dan pulp 2 : 1
196.6185 355.86814133
0.00655395
388.03012547 535.9421023543 98.43834533
Err:509
388.03012547 Err:509 295.05684533
Err:509 Err:509
Untuk meningkatkan suhu udara pengering

Fungsi : Untuk mengurangi kadar air

31 33 34 35 Asumsi : 1. Efisiensi rotary dryer 95%
0.0024273906 0 0 0.002427391 2. Rasio Air pencucian dan pulp 2 : 1
10.937593926 0 9.7877773295 1.149816596
0 Err:509 Err:509 0
10.940021316 Err:509 Err:509 1.152243987
Err:509 Err:509
Untuk menurunkan suhu selulosa keluaran rotary dryer (RD-101)

2. Suhu diturunkan dari 90 menjadi 35
Fungsi : Untuk mengencerkan MCA 99% menjadi 78%

40 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 : 1
#DIV/0! F40 = 0
0
#DIV/0!
#DIV/0!
Untuk meningkatkan suhu MCA


43 44 Asumsi : 1. Rasio NaOH yang digunakan pada delignifikasi : Bagasse adalah 5 : 1
Err:509 F41 = Err:509 kg/jam
Err:509 Err:509
Err:509 Err:509
Err:509 Err:509
Untuk meningkatkan suhu NaOH

F45 =_x000D_ Err:509 kg
F (kg/jam) Mr (kg/kmol) N (kmol)
Err:509 Err:509 0.004
Err:509 Err:509 Err:509
Masuk
Komponen
x36_x000D_
N36_x000D_
x 40_x000D_
N40_x000D_
x44_x000D_
Selulosa Err:509 0.0024
MCA Err:509 0.003
NaOH
Na-Glikolat Err:509
CMC
NaCl

Err:509
n hemiselulosa bagasse
an atmosfer
ari sisa black liquor
n dan sisa blackliquor
nsistensi pulp 15%

ari sisa lignin dan bleaching agent
angi kadar air

ry dryer 95%
ncucian dan pulp 2 : 1
kasi : Bagasse adalah 5 : 1
Masuk Keluar
N44_x000D_
x 45_x000D_
N
45_x000D_
x46_x000D_
N46_x000D_
x47 N47
Err:509 0.0004806 Err:509 4.85478E-06
Err:509 0.0006123 Err:509 6.18499E-06
Err:509 0.0002448 Err:509 2.47303E-06
0.0044 Err:509 0.0001225 Err:509 1.237E-06
Err:509 0.0004899 Err:509 4.94799E-06
Err:509 0.0006123 Err:509 6.18499E-06
0 Err:509 0
Err:509 0.0000 0.000 Err:509 Err:509 Err:509 Err:509
r:509 Err:509

NME-Laporan 2 - Kelompok 25

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NME-Laporan 2 - Kelompok 25

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A.

Perhitungan Cp Menggunakan Metode Estimasi

Unsur Δe (J/moloK)_x000D_ (Perry, 1999)

CpSelulosa =_x000D_ 208040 J/mol.K 1284.1975 J/kg.K CpNa-CMC =_x000D_

CpHemiselulosa =_x000D_ 29506.75 J/mol.K 1277.3485 J/kg.K CpNa-MCA =_x000D_

CpNa-CMC =_x000D_ 290410 J/mol.K 1200.0413 J/kg.K CpSelulosa =_x000D_

CpNa-MCA =_x000D_ 61.59 J/molK 733.21429 J/kg.K

200480 J/mol.K 1089.5652 J/kg.K

Gas Cp = A+BT+CT2+DT3+ET4_x000D_ (Yaws)

2. Asam Monokloroasetat (MCA) C2H3ClO2_x000D_ 3. H2O2_x000D_

Kapasitas Perancangan Pabrik CMC

26. Rotary Reactor (R-101)

Data aliran 36 F36 =_x000D_ 441.4876 kg/jam

Tahap 1 : Alkalisasi Selulosa konversi = 0.999

Tahap 2 : Eterifikasi konversi = 0.8

Tahap 3 : Reaksi samping 0.8

Komponen Mr (kg/kmol) w F (kg/jam) X N (kmol)

27. Heater (E-204)

28. Aging vessel (V-103)

29. Cooler (E-205)

30. Cyclone (CY-301)

31. Cyclone (CY-302)

32. Silo (TK-107)

33. Rotary Dryer (RD-301)

34. Heater (E-301)

36. Cooler (E-302)

33. Ball mill (BM-301)

37. Product Tank (TK-108)

2. Vibrating screen (VS-101)

4. Steam Explosion Tank (V-101)

5. Flash Tank (V-102)

9. Delignification Tank (DT-101)

11. Cooler (E-103)

12. Heater (E-104)

13. Rotary Filter (RF-101)

14. Heater (E-105)

15. Heater (E-106)+B140

16. Bleaching Tank (BT-101)

17. Heater (E-107)

18. Rotary Filter (RF-102)

19. Heater (E-108)

21. Cooler (E-109)

22. Mixer (M-102)

23. Heater (E-110)

24. Mixer (M-103)

F (kg/jam) N (kmol) F (kg/jam) N (kmol)

Fungsi : Meningkatkan suhu keluaran dari rotary reactor

Fungsi : Pematangan produk

Fungsi : Menurunkan suhu dari aging vessel

Keluar Fungsi : Memisahkan produk dari udara

N50 N52 N54 N55

N Fungsi : Mengurangi kadar air

Keluar Fungsi : Untuk Screening bagasse yang memenuhi ukuran

Fungsi : Untuk menyimpan bagasse sementara

Fungsi : Untuk melepaskan uap air sisa steam explotion tank

Fungsi : Untuk mengencerkan NaOH 50% menjadi 20%

Fungsi : Untuk meningkatkan suhu NaOH hasil dari mixer (M-101)

Fungsi : Untuk memecahkan ikatan lignin

Fungsi : Untuk mendinginkan keluaran dari tangki delignifikasi

Fungsi : Untuk memisahkan selulosa dari sisa b

Fungsi : Untuk menghilangkan sisa lignin dan si

Fungsi : Untuk memisahkan selulosa dari sisa li

Fungsi : Untuk meningkatkan suhu udara pengering