UNIVERSIDAD NACIONAL AUTONOMA DE MÉXICO

BALANCE DE MASA Y ENERGIA DE UN REACTOR SEMIBATCH

ALUMNOS: Cuba Segura Maria del Rocio

Cruz Mondragon Egdar
Rosas Francisco Patricia Edaena
BALANCE DE ENERGIA

DATOS:
La ley de la Velocidad es:
−�_𝑂𝑁�𝐵= 〖��〗 _𝑂𝑁�𝐵 �_( 〖𝑁�〗 _3 ) Con: k=
0.00017Ts=
a 188 °C
448.15 K
Vr= 3.26 m3
N (ONCB) ó NA0= 3.17 Kmol
N H2O= 103.6 Kmol
N (NH3) ó NB0= 43 Kmol
EA= 11273 cal/mol
ΔHR= 590000 kcal/kmol
CpONCB=CpA= 40 cal/mol*K
CpH2O=CpW= 18 cal/mol*K
CpNH3=CpB= 8.38 cal/min*K
UA= 35.85 kcal/mol*°K
P= 500 psi
R= 1.987 cal/mol*K

Calculo de k @ 468 K �=0.00017 𝑒^[11273/1.987

k= 0.00011945 m kmol*min
3/ (1/461−1/�)]

Calculo de CA, CB y - rA: �_𝐴𝑂 (1−𝑋_𝐴)

CA=
𝐾𝑚𝑜�/𝑚^3
CA= 0.972392638
�_𝐴0 𝑁_𝐵0/(𝑁_𝐴𝑂−2𝑋_𝐴 )
CB=
𝐾𝑚𝑜�/𝑚^3
CB= 13.19018405

rA= 𝐾𝑚𝑜�/
0.00153211 (𝑚^3∗𝑚𝑖𝑛)
𝐾𝑚𝑜�/𝑚^3 (𝑑𝑋_𝐴)/𝑑𝑡=
CA0= 0.97239264 0.0015756 min-1
XA= 0 (𝑑�_�)/𝑑𝑡=
Vr al 10%= 0.326 m3 -1.035748 K/min
NB0/NA0= 13.5646688 (𝑑�_𝑗)/𝑑𝑡=
WCpw= 3600 BTU/k 1.4952438 K/min
FW= 382.055 lbmol/min
Tj^k+1= 298.149524
 Operación @ 175 °C hasta los 45 minutos
Calculo de k @ 468 K
𝑑𝑋/𝑑𝑡= 〖��〗 _𝐴0 (1−𝑋)(�_𝐵−2�)
�_𝐵=𝑁_𝐵0/𝑁_𝐴0 k= 0.0001195 m3/kmol*min
𝑡=[𝑉_�/ 〖�𝑁〗 _𝐴0 ](1/(�_𝐵−2))�𝑛 (�_𝐵−2�)/ Datos: 𝑑�/𝑑𝑡=(3830 �𝑐𝑎�/𝑚𝑖𝑛−38
(�_𝐵 (1−�) )
N (ONCB) ó NA0= 9.044 Kmol
�=(𝑒^(𝑡/[𝑉_�/ 〖�𝑁〗 _𝐴0 ](1/ N (NH3) ó NB0= 33 Kmol
(�_𝐵−2)) ) �_𝐵−�_𝐵)/(𝑒^(𝑡/[𝑉_�/ 〖� �^2 (38.35 �𝑐𝑎�)/(2 𝑚
t= 45 min
𝑁〗 _𝐴0 ](1/(�_𝐵−2)) ) �_𝐵−2)
Vr= 5.119 m3
θB= 3.64882795
kNA0= 0.00108033
(Vr/KNA0)= 4738.35026
(1/θB-2)= 0.60649142
(t/(Vr/KNA0)*(1/θB-2))= 0.01565888
x= 0.03374694

CE DE ENERGIA DEL FLUIDO DE LA CAMISA

MODELO DE MEZCLA PERFECTA
Datos:
〖𝑑�〗 _𝐽/𝑑𝑡=(𝐹_𝑤∗(�_𝐽𝑜−�_𝐽))/𝑉_𝐽 +𝑄_𝑗/(𝑉_𝑗∗𝜌_𝑗∗�_𝑗 ) VJ= 0.326 m3
TJ= 298.15 K
(𝑑�_𝐽)/𝑑𝑡= TJo= 448.15 k
17579.4045 k WCpw= 0.18666 cal/k
Fwal 10% 38.2055 lbmol/min
 t (min) XA t (min) XA
0 0 24 0.01822074
1 0.0007696 25 0.01896878
2 0.00153829 26 0.01971595
3 0.00230606 27 0.02046223
4 0.00307292 28 0.02120764
5 0.00383887 29 0.02195217
6 0.00460391 30 0.02269583
7 0.00536804 31 0.02343862
8 0.00613126 32 0.02418053
9 0.00689358 33 0.02492158
10 0.00765499 34 0.02566176
11 0.0084155 35 0.02640108
12 0.00917511 36 0.02713953
13 0.00993382 37 0.02787712
14 0.01069164 38 0.02861385
15 0.01144856 39 0.02934971
16 0.01220458 40 0.03008472
17 0.01295971 41 0.03081887
18 0.01371395 42 0.03155217
19 0.01446729 43 0.03228461
20 0.01521976 44 0.0330162
21 0.01597133 45 0.03374694
22 0.01672202
23 0.01747182

t vs XA
0.04

0.035

0.03

0.025
XA

0.02

0.015

0.01

0.005

0
0 0.002 0.004 0.006 0.008 0.01 0.012 0.014 0.016 0.018

t (tiempo)
 BALANCE PARA DETERMINAR LA TEMPERATURA EN FUNCION DEL TIEMPO
Datos:
𝑑�/𝑑𝑡=(𝑄𝑔−𝑄�)/𝑁�� Qg= 3830 kcal/min
m3/kmol*min Qr= 38.35 kcal/min°K
𝑑�/𝑑𝑡=(3830 �𝑐𝑎�/𝑚𝑖𝑛−38.35 �𝑐𝑎�/(�𝑐𝑎�/𝑚𝑖𝑛𝐾))/(2504 �𝑐𝑎�/�)
NCp= 2504 kcal/K
T= 448.15 min
490
�^2 (38.35 �𝑐𝑎�)/(2 𝑚𝑖𝑛𝐾)+� 2504 �𝑐𝑎�/�−2761.67 �𝑐𝑎�/𝑚𝑖𝑛∗𝑡=0 480
470

T (Temperatura)
Por metodo solver 460

t(min) T t(min) T 450

0 448.15 26 472.3432 440

1 449.2437 27 473.1444 430

2 450.3197 28 473.9385 420
0 5 10
3 451.3788 29 474.7257
4 452.4218 30 475.5062
5 453.4494 31 476.2803
6 454.4622 32 477.0479
7 455.461 33 477.8094
8 456.4461 34 478.5648
9 457.4131 35 479.3143
10 458.3779 36 480.058 t
11 459.3255 37 480.796 315
12 460.2615 38 481.5285
13 461.1863 39 482.2557 310
14 462.1003 40 482.9775
T (Temperatura)

15 463.0039 41 483.6942 305

16 463.8974 42 484.4059
300
17 464.7812 43 485.1125
18 465.6555 44 485.8144 295
19 466.5207 45 486.5114
20 467.3771 290
0 5 10
21 468.2248
22 469.0643
23 469.8956
24 470.719
25 471.5349
 BALANCE PARA DETERMINAR LA TEM

〖𝑑�〗 _𝐽/𝑑𝑡=(𝐹_𝑤∗(�_𝐽𝑜−�_𝐽))/𝑉_𝐽 +𝑄_𝑗/(𝑉_𝑗

t VS T (reactor) 〖𝑑�〗 _𝐽/𝑑𝑡=(382.055 �𝑏𝑚𝑜�/𝑚𝑖𝑛−(448.15𝐾−�_𝐽))/

490
480
�𝑗=([((36000 𝐵�𝑈/𝐾)(0.326𝑚^3 ))+328.055 �
470
T (Temperatura)

460
450
440 Por metodo solver
430 t(min)
420 0
0 5 10 15 20 25 30 35 40 45 50
1
t (tiempo)
2
3
4
5
6
7
t vs T (enchaquetado) 8
315
9
10
310 11
12
T (Temperatura)

305 13
14
300
15
295 16
17
290 18
0 5 10 15 20 25 30 35 40 45 50
19
t (Tiempo)
20
21
22
23
24
25
ARA DETERMINAR LA TEMPERATURA EN FUNCION DEL TIEMPO
DEL ENCHAQUETADO
Datos
∗(�_𝐽𝑜−�_𝐽))/𝑉_𝐽 +𝑄_𝑗/(𝑉_𝑗∗𝜌_𝑗∗�_𝑗 ) WCpw= 3600 BTU/k
TJ0= 448.15 K
Fw= 382.055
𝑚𝑜�/𝑚𝑖𝑛−(448.15𝐾−�_𝐽))/(0.326 𝑚^3 )+3600 𝐵�𝑈/𝐾 lbmol/min
VJ= 0.326 m3

𝐾)(0.326𝑚^3 ))+328.055 �𝑏𝑚𝑜�/𝑚𝑖𝑛] ln𝑡)/((448.15−1))

T t(min) T
298.15 26 309.09
298.15 27 309.21
300.47 28 309.34
301.83 29 309.45
302.8 30 309.57
303.55 31 309.68
304.16 32 309.78
304.68 33 309.89
305.13 34 309.99
305.52 35 310.08
305.88 36 310.18
306.2 37 310.27
306.49 38 310.36
306.76 39 310.45
307.01 40 310.53
307.24 41 310.62
307.46 42 310.7
307.66 43 310.78
307.85 44 310.85
308.03 45 310.93
308.21
308.37
308.53
308.67
308.82
308.95