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DKK-TOA CORPORATION
SDS No.: E1080-8
PRODUCT NAME: Powder for pH4.01 Standard Solution

Created: Oct. 28, 1997

Revised: Jul. 26, 2021

SAFETY DATA SHEET

1. PRODUCT AND MANUFACTURER

Product Name : Powder for pH4.01 Standard Solution
Product Code : 143F060, 143F252, 143F307, 143F0601
Manufacturer : DKK-TOA CORPORATION
Address : 29-10, Takadanobaba 1-Chome, Shinjuku-ku, Tokyo 169-8648 Japan
Department : Sensor Technology Dept.
Phone : +81-3-3202-0225
Fax : +81-3-3202-5685

2. HAZARDS IDENTIFICATION
GHS Classification
Physical/Chemical Hazards: Flammable solids Not classified
Pyrophoric solids Not classified
Self-heating chemicals Not classified
Human Health Hazards: Acute toxicity (Oral) Not classified
Acute toxicity (Skin) Not classified
Skin corrosion/irritation Not classified
(Hazard categories not described in the above are classified either as Not applicable or
as Not classifiable.)

3. COMPOSITION/INFORMATION ON INGREDIENTS
Form: Single Substance
Potassium Hydrogen
Chemical Name
Phthalate
Percent Range ≧99.5%
【NOTE】
Chemical Formula C6H4(COOK)(COOH)
*1: Act on the Evaluation of Chemical
Official Act*1 3-1272, 3-1342 Substances and Regulation of Their
Gazette No. Manufacture, etc.
ISHA*2 － *2: Industrial Safety and Health Act
CAS No. 877-24-7

4. FIRST AID
Inhalation : Immediately, remove the victim to fresh air and let him/her blow nose and
rinse mouth.
Skin Contact : Wash the skin thoroughly with a large amount of water.
Eye Contact : Immediately, rinse the eye thoroughly with running water. If necessary, get
medical advice/attention.
Ingestion : Immediately, give the victim water or salt water to induce vomiting. If
necessary, get medical advice/attention.

5. FIRE FIGHTING MEASURES

Extinguishing Media : Plenty of water, Water spray, Carbon dioxide, Dry chemical, Fire-
extinguishing foam, Dry sand, etc.
Firefighting Instruction : This product is non-combustible. In case of a fire in the vicinity, however,
immediately remove containers to a safe place or spray water onto them
and the surrounding area to cool down.
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DKK-TOA CORPORATION
SDS No.: E1080-8
PRODUCT NAME: Powder for pH4.01 Standard Solution

6. ACCIDENTAL RELEASE MEASURES

For Humans : Wear appropriate protective equipment such as eye protection, rubber
gloves, etc. so that the product will not get on skin as practicably as possible.
For Environment : Not specifically designated.
Clean-up Method : Sweep up to collect the spilled and scattered product to empty containers as
and Equipment much as possible. Then, thoroughly flush and decontaminate the spilled area
with plenty of water.

7. HANDLING/STORAGE
Handling
Technical Measures : Wear appropriate protective equipment such as eye protection, rubber
gloves, etc. if necessary. Pay attention as practicably as possible so that
the product will not get on skin. Provide local ventilation equipment if
generation of dust is anticipated in the workplace.
Precautions : Pay attention so that generation of dust will be minimized as practicably
as possible .
Storage
Storage Conditions : Tightly close containers and store in a cool and dark place.
Container Material : Glass, Polyethylene, Polypropylene, etc.

8. EXPOSURE CONTROLS/PROTECTIVE EQUIPMENT

Equipment : In case generation of dust is anticipated in the workplace, provide local
ventilation equipment if available.
Control Concentration : Not established
Threshold Limit Value : Data on the product are not available.
Data on its component are as follows:
･OEL (2020): Not established
･ACGIH(2013): Not established
【NOTE】 OEL: Occupational Exposure Limits recommended by
The Japan Society for Occupational Health
Personal Protective Equipment
For respiratory organs : Wear a dust mask if necessary.
For hands : Wear appropriate protective equipment such as rubber gloves, etc. if
necessary.
For eyes : Wear appropriate protective equipment such as eye protection, etc. if
necessary.
For skin & body : Wear appropriate protective equipment if necessary.

9. PHYSICAL/CHEMICAL PROPERTIES
Physical State
Appearance : Solid (Crystalline Powder) Odor : None
Color : White pH : pH4 (1% aqueous solution at 25℃)
Particular temperature/temperature range to cause changes in physical state
Melting Point : 295 - 300℃
Boiling Point : Decomposition occurs.
Flush Point : No data
Combustion/Explosion Upper Limit and Lower Limit : No data
Vapor pressure : No data
Specific Gravity (Water=1) : 1.64
Solubility : Water : 7.4% (at 20℃)
: Organic Solvent : Hardly soluble in Ethanol
Spontaneous Ignition Temp. : No data
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DKK-TOA CORPORATION
SDS No.: E1080-8
PRODUCT NAME: Powder for pH4.01 Standard Solution

10. STABILITY/REACTIVITY
Reactivity
Chemical Stability
Conditions to avoid
Hazardous decomposition
product
: The product may react in contact with oxidizing agent.
: Stable when used under proper conditions.
: Avoid sunlight, heat, etc.
: Carbon monoxide, Carbon dioxide

11. TOXICOLOGICAL INFORMATION

Acute Toxicity(Oral)
Information on the product : Classified as Not classified based on the LD50 value of the product.
Acute Toxicity(Skin)
Information on the product : Classified as Not classified based on the LD50 value of the product.
Skin corrosion/irritation
Information on the product : Classified as Not classified based on the concentration of the
component of skin corrosion/irritation.

12. ECOLOGICAL INFORMATION

Aquatic environment toxicity (Acute)
Information on the product : No data

13. DISPOSAL CONSIDERATIONS

Waste Chemicals : Dissolve the waste chemical in a large amount of water.
Then, adjusting its pH to neutral, discharge to the drain in accordance
with the related laws and regulations.
Or consign the disposal to a hazardous waste disposal firm approved
by the competent authority.
Empty Containers : When disposing of empty containers, thoroughly remove contents and
dispose of in accordance with your national and local regulations.

14. TRANSPORT INFORMATION

Be sure to handle this material in compliance with environmental, safety and health laws and regulations
of your national and local government.
National Regulations
For Ground Transportation : Observe the Road Act.
For Marine Transportation : Observe the Ship Safety Act and Port Regulation Act.
For Air Transportation : Observe the Civil Aeronautics Act.
UN Identification No. : Not applicable
UN Hazard Classification : Not applicable
UN Packing Group : Not applicable
Guide Number for Emergency Response: None
Precautions for Transportation : During transportation of the product, avoid direct sunlight and
ensure that there is no leakage. Avoid dropping, falling and
damaging the container of the material when the material is
loaded onto a truck or the like. Be sure to prevent collapse of
cargo piles.
International Regulations
For Ground Transportation
UN Proper Shipping Name : Not applicable
UN Hazard Classification : Not applicable
UN Subsidiary Risk : Not applicable
UN Identification No. : Not applicable
UN Packing Group : Not applicable
For Marine Transportation
UN Proper Shipping Name Not applicable
UN Hazard Classification : Not applicable
UN Subsidiary Risk : Not applicable
UN Identification No. : Not applicable
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DKK-TOA CORPORATION
SDS No.: E1080-8
PRODUCT NAME: Powder for pH4.01 Standard Solution

UN Packing Group : Not applicable

For Air Transportation
UN Proper Shipping Name
UN Hazard Classification
UN Subsidiary Risk
UN Identification No.
UN Packing Group
: Not applicable
: Not applicable
: Not applicable
: Not applicable
: Not applicable

15. REGULATORY INFORMATION

Be sure to handle this material in compliance with environmental, safety and health laws and regulations
of your national and local government. In Japan this material is regulated as follows:
The Pollutant Release and Transfer : ・Not applicable
Register Promotion Act (PRTR)
Industrial Safety and Health Act : ・Not applicable
Poisonous and Deleterious : ・Not applicable
Substance Control Act

16. OTHER INFORMATION

References
(1) Chemical Risk Information Platform (CHRIP), National Institute of Technology and Evaluation
(2) ezCRIC, Japan Chemical Database Ltd.
(3) JIS Z7252-2014 and Z7253-2012
(4) Site for Safety in Workplace (Shokuba-no-Anzen Site),Ministry of Health, Labour & Welfare, Japan
Coverage
- The information contained herein is based on data collected from many technical documents and is
considered to be accurate, but is not necessarily inclusive. Due care should be exercised in handling
the material.
- All data herein are intended to provide information but not assured.
- All of the notes are for normal handling. In case of special handling, take safety measures suitable for
the use or application.