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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET


PRODUCT FORMULA No. 6
1. Identification of the substance/preparation and of the company/undertaking
Product name : PRODUCT FORMULA No. 6
Material Uses : Industrial applications: Cleaner for removal of vegetable or animal oil from
soiled surfaces.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification


Ethoxylated isononyl phenol 37205-87-1 1-5 Xi; R36/38
R53
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation (lung irritant).
Ingestion : discomfort (gastrointestinal)
Skin contact : Slightly hazardous in case of skin contact (irritant). Repeated exposure
may cause skin dryness or cracking.
Eye Contact : Slightly hazardous in case of eye contact (irritant).

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PRODUCT FORMULA No. 6

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. Get medical attention if symptoms appear.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : Wash with soap and water. Cold water may be used. Get medical attention if
irritation develops.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures


Personal Precautions : Splash goggles. Boots. Gloves.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Finish cleaning by spreading water on the contaminate
surface and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage


Handling : Avoid contact with skin and eyes. Do not breathe gas/fumes/vapour/spray. If
ingested, seek medical advice immediately and show the container or the
label.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection


Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

Respiratory system : A respirator is not needed under normal and intended conditions of product
use. Wear appropriate respirator when ventilation is inadequate.

Skin and body : Overalls buttoned to the neck and wrist. Lab coat.
Hands : Impervious gloves.
Eyes : Safety glasses.

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PRODUCT FORMULA No. 6

9. Physical and chemical properties


Physical state : Liquid.
Colour : Colourless.
Odour : Not available.
Boiling point : 100°C (212°F)
Melting point : -3°C (27°F)
Density : 1.01 g/cm3 (20°C / 68°F)
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.


pH : 7 [Neutral.]
Flash point : Not applicable.

10. Stability and reactivity


Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents, acids.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

11. Toxicological information


Acute toxicity
Ingredient Name Test Result Route Species
PRODUCT FORMULA No. 6 LD50 >3000 Oral Rat
mg/kg
Ethoxylated isononyl phenol LD50 5600 mg/kg Oral Rat
LD50 5800 mg/kg Oral Rat
LD50 4700 mg/kg Oral Mouse

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Slightly hazardous in case of skin contact (irritant).
Eye irritation : Slightly hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.


Reproduction toxicity : Not available.
Additional Information :

12. Ecological information


Ecotoxicity Data
Ingredient Name Species Period Result
Ethoxylated isononyl phenol Fish (LC50) 96 hours 7.2 mg/l
Daphnia (EC50) 48 hours 15 mg/l
Algae (IC50) 72 hours 30 mg/l
Persistence/degradability : Not available.

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PRODUCT FORMULA No. 6

13. Disposal considerations


Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 160503


Hazardous Waste : To present knowledge of the supplier, this product is not regarded as
hazardous waste as defined by EU Directive 91/689/EC.
Additional Information : 16 05 03 other waste containing organic chemicals, e.g. lab chemicals not
otherwise specified

14. Transport information


International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information


EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information


Full text of R-Phrases with no. : R36/38- Irritating to eyes and skin.
appearing in Section 2 - United R53- May cause long-term adverse effects in the aquatic environment.
Kingdom (UK)
Text of classifications appearing in : Xi - Irritant
Section 2 - United Kingdom (UK)
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
PRODUCT FORMULA No. 6 is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.

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PRODUCT FORMULA No. 6

Date of issue Version


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