Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

DREW ABD
1. Identification of the substance/preparation and of the company/undertaking
Product name : DREW ABD
Material Uses : Industrial applications: Cleaner for removal of vegetable or animal oil from
soiled surfaces.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Sodium hydroxide 1310-73-2 20-30 215-185-5 C; R35
Glucoside 68515-73-1 0.5-1 Xi; R41
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Corrosive
R35- Causes severe burns.
Effects and symptoms
Inhalation : Inhalation of the spray mist may produce severe irritation of respiratory tract,
characterized by coughing, choking or shortness of breath. Overexposure by
inhalation may cause respiratory irritation.
Ingestion : May be fatal if swallowed. May cause burns to mouth, throat and stomach.
Skin contact : Corrosive to skin on contact. Skin contact may produce burns.
Eye Contact : Corrosive to eyes.
Target Organs : Contains material which causes damage to the following organs: lungs, upper
respiratory tract, skin, eye, lens or cornea.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention immediately.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Obtain medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention immediately.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water. Some metallic
products oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Absorb with dry earth, sand or other noncombustible
cleanup methods material. Use water spray curtain to divert vapour drift. Prevent entry into
sewers, basements or confined areas; dike if needed. Call for assistance on
disposal. Neutralize the residue with a dilute solution of acetic acid.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep container dry. Keep away from heat. Keep away from sources of
ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Do not ingest. Do not breathe gas/fumes/vapour/spray. Wear
suitable protective clothing. If ingested, seek medical advice immediately and
show the container or the label. Keep away from incompatibles such as
acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures
Hygiene measures
Occupational Exposure Limits
: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
: Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

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Ingredient Name Occupational Exposure Limits

Sodium hydroxide EH40-OES (United Kingdom (UK), 2001). Notes: OES
STEL: 2 mg/m3

Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Full suit.

Hands : Impervious gloves.
Eyes : Face shield.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Light brown.
Odour : Not available.
Boiling point : 105°C (221°F)
Melting point : -22°C (-8°F)
Density : 1.32 g/cm3
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.

pH : 14 [Basic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Highly reactive with acids.
Slightly reactive to reactive with organic materials, metals.
Incompatible with copper alloys. Incompatible with magnesium, zinc, sodium,
potassium and aluminium.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water. Some metallic
oxides.
Remarks : Flammable hydrogen gas may be produced on prolonged contact with metals
such as aluminium, zinc, etc.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Sodium hydroxide LDLo 500 mg/kg Oral Rabbit
Glucoside LD50 >5000 Oral Rat
mg/kg
LD50 >5000 Dermal Rabbit
mg/kg

Chronic toxicity : Repeated or prolonged contact with spray mist may produce chronic eye
irritation and severe skin irritation. Repeated or prolonged exposure to spray
mist may produce respiratory tract irritation, leading to frequent attacks of
bronchial infection.
Skin irritation : Extremely hazardous in case of skin contact (corrosive).
Eye irritation : Extremely hazardous in case of eye contact (corrosive).

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Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 160502

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 1824
Proper shipping name : SODIUM HYDROXIDE SOLUTION
ADR/RID Class : 8
Packing group : II
ADR/RID label :

Other information : Hazard identification number

80
Sea
UN number : 1824
Proper shipping name : SODIUM HYDROXIDE SOLUTION
IMDG Class : 8
Packing group : II
IMDG label :

Other information : Emergency Schedules (EmS)

8-06

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Corrosive

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Risk Phrases : R35- Causes severe burns.

Safety Phrases : S26- In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Contains : Sodium hydroxide 215-185-5
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R35- Causes severe burns.
appearing in Section 2 - United R41- Risk of serious damage to eyes.
Kingdom (UK)
Text of classifications appearing in : C - Corrosive
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
DREW™ ABD is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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