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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET


DREWTAN RC
1. Identification of the substance/preparation and of the company/undertaking
Product name : DREWTAN RC
Material Uses : Industrial applications: Rust Preventative Coating for ballast tanks, etc.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Aqueous solution containing: Chelating agent / polymers

Chemical name* CAS No. % EC Number Classification


2-Butoxyethano 111-76-2 1-5 203-905-0 Xn; R20/21/22
Xi; R36/38
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation (lung irritant).
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.
Skin contact : Slightly hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Slightly hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: blood,
kidneys, liver, lymphatic system, upper respiratory tract, skin, central nervous
system (CNS), eye, lens or cornea.

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DREWTAN RC

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. Get medical attention if symptoms appear.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. If
affected person is conscious, give a copious amount of water to drink. Never
give anything by mouth to an unconscious person. If large quantities of this
material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Obtain medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Unusual fire/explosion Hazards : Aqueous solutions are nonflammable. In a fire, the following can be released:
carbon oxides (CO, CO2)
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures


Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Prevent entry into sewers, basements or confined
cleanup methods areas; dike if needed. Store in an appropriate container. Small Spill and Leak:
Absorb with liquid-binding material (sand, diatomite,universal binders), or use a
spill kit. Finish cleaning by spreading water on the contaminated surface
and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage


Handling : Do not ingest. Do not breathe gas/fumes/vapour/spray. Wear suitable
protective clothing. If ingested, seek medical advice immediately and show
the container or the label. Keep away from incompatibles such as oxidizing
agents.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not store below 5°C (41°F).
Packaging materials
Recommended use : Use original container.

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DREWTAN RC

8. Exposure controls/personal protection


Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits


2-Butoxyethano EH40-OES (United Kingdom (UK), 2001). skin Notes:
OES
TWA: 123 mg/m3
TWA: 25 ppm

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Overalls buttoned to the neck and wrist. Lab coat.
Hands : Nitrile gloves. PVC gloves. Latex gloves.
Eyes : Safety glasses.

9. Physical and chemical properties


Physical state : Liquid.
Colour : Off-white.
Odour : Slight.
Boiling point : 100°C (212°F)
Melting point : -5°C (23°F)
Density : 1 g/cm3
Vapour density : The highest known value is 4.07 (Air = 1) (2-Butoxyethanol).
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : The highest known value is 0.36 (Water) .

Solubility : Soluble in cold water.


pH : 1.6 (1%)
Flash point : Not applicable.
Viscosity : Dynamic: 15 cP

10. Stability and reactivity


Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents, alkalis.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

11. Toxicological information


Acute toxicity
Ingredient Name Test Result Route Species
2-Butoxyethanol LD50 470 mg/kg Oral Rat
LD50 300 mg/kg Oral Rabbit
LD50 1200 mg/kg Oral Guinea pig
LD50 220 mg/kg Dermal Rabbit

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DREWTAN RC

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Skin irritation : Slightly hazardous in case of skin contact (irritant).
Eye irritation : Slightly hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.


Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations


Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 160503


Hazardous Waste : To present knowledge of the supplier, this product is not regarded as
hazardous waste as defined by EU Directive 91/689/EC.
Additional Information : EWC 160503

14. Transport information


International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information


EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications, Used by Spraying.

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16. Other information


Full text of R-Phrases with no. : R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
appearing in Section 2 - United R36/38- Irritating to eyes and skin.
Kingdom (UK)
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
DREWTAN™ is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 5/5

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