Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

SOOT RELEASE STICK
1. Identification of the substance/preparation and of the company/undertaking
Product name : SOOT RELEASE STICK
Material Uses : Industrial applications: Combustion catalyst for the reduction of fireside
deposits in boilers

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Product contains: Zinc oxide , Copper(II) oxide , Chloride salt. , etc.

Chemical name* CAS No. % EC Number Classification

Zinc oxide 1314-13-2 10-20 215-222-5
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation (lung irritant).
Ingestion : Slightly hazardous in case of ingestion.
Skin contact : Slightly hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Slightly hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: upper
respiratory tract, skin, eye, lens or cornea, stomach.
Contains material which may cause damage to the following organs: lungs.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention if symptoms appear.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove
contaminated clothing and shoes. Cold water may be used. Wash clothing
before reuse. Clean shoes thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are halogenated compounds. Some metallic oxides.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves.
Environmental precautions and : Use a shovel to put the material into a convenient waste disposal container.
cleanup methods Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe dust. If ingested, seek medical advice immediately and show
the container or the label. Keep away from incompatibles such as reducing
agents.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures
Hygiene measures
Occupational Exposure Limits
: Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits. If user
operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
: Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

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Ingredient Name Occupational Exposure Limits

Zinc oxide EH40-OES (United Kingdom (UK), 2001). Notes: OES
STEL: 10 mg/m3 Form: Fume
TWA: 5 mg/m3 Form: Fume

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Dust respirator.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Solid. (Sticks.)
Colour : Grey.
Odour : Not available.
Boiling point : Decomposition Temperature: >800°C (1472°F)
Melting point : Decomposition Temperature: >800°C (1472°F)
Density : 1.25 to 1.3 g/cm3
Solubility : Soluble in cold water.
pH : Not available.
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Conditions to Avoid : moisture
Materials to avoid : Reactive with reducing agents.
Slightly reactive to reactive with acids, moisture.
Hazardous decomposition products : These products are halogenated compounds. Some metallic oxides.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Zinc oxide LD50 7950 mg/kg Oral Mouse
LDLo 500 mg/kg Oral human

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Slightly hazardous in case of skin contact (irritant).
Eye irritation : Slightly hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

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12. Ecological information

Persistence/degradability : Ecological testing has not been conducted on this product.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 06 03 05

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 06 03 05 solid salts containing chlorides, fluorides and other halogenated solid
salts

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Safety Phrases : S24/25- Avoid contact with skin and eyes.
S56- Dispose of this material and its container at hazardous or special waste
collection point.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. :
appearing in Section 2 - United
Kingdom (UK)
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
SOOT RELEASE STICK™ is a trademark of Ashland Inc.
Notice to Reader

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To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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