Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

CIL
1. Identification of the substance/preparation and of the company/undertaking
Product name : CIL
Material Uses : Industrial applications: Corrosion inhibitor. Corrosion reduction in open and
closed hot water systems.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Sodium silicate 1344-09-8 30-40 215-687-4 Xi; R36/38
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Irritant
R36/38- Irritating to eyes and skin.
Effects and symptoms
Skin contact : Hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Hazardous in case of eye contact (irritant).

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.

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Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
irritated skin with an emollient. Remove contaminated clothing and shoes.
Cold water may be used. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable
Protection of fire-fighters
: Not applicable.
: Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Neutralize the residue with a dilute solution of acetic acid.
Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe gas/fumes/vapour/spray. Wear suitable protective clothing. If
ingested, seek medical advice immediately and show the container or the
label. Avoid contact with skin and eyes. Keep away from incompatibles such
as acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Splash goggles.

9. Physical and chemical properties

Physical state : Liquid. (Viscous liquid.)
Colour : Colourless.
Odour : Not available.
Boiling point : The lowest known value is 100°C (212°F) (Water).
Melting point : 0°C (32°F)
Density : 1.37 g/cm3

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Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.

pH : 10.5 to 12.5 [Basic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with acids.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
CIL LD50 >4000 Oral Rat
mg/kg
LD50 >4000 Dermal Rabbit
mg/kg
Sodium silicate LD50 1960 mg/kg Oral Rat
LD50 4640 mg/kg Dermal Rabbit

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not applicable.

Bioaccumulative potential : None.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 02

Hazardous Waste : To present knowledge of the supplier, this product is not regarded as
hazardous waste as defined by EU Directive 91/689/EC.
Additional Information : 16 05 02 other waste containing inorganic chemicals, e.g. lab chemicals not
otherwise specified, fire extinguishing powders

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14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Irritant
Risk Phrases : R36/38- Irritating to eyes and skin.
Safety Phrases : S37/39- Wear suitable gloves and eye/face protection.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R36/38- Irritating to eyes and skin.
appearing in Section 2 - United
Kingdom (UK)
Text of classifications appearing in : Xi - Irritant
Section 2 - United Kingdom (UK)
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
CIL ™ is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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