Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

STANNOUS CHLORIDE POWDER
1. Identification of the substance/preparation and of the company/undertaking
Product name : STANNOUS CHLORIDE POWDER
Material Uses : Industrial applications: Analytical reagent. Use only in accordance with Drew
Test Procedures.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Mixture containing: Sodium sulphate 96.5% and Stannous chloride 2.5%.

Chemical name* CAS No. % EC Number Classification

Stannous chloride 7772-99-8 1-5 231-868-0 Xn; R22
Xi; R36/37/38
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Target Organs : Contains material which causes damage to the following organs: upper
respiratory tract, eye, lens or cornea.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.

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Skin contact : In case of contact, immediately flush skin with plenty of water. Remove
contaminated clothing and shoes. Cold water may be used. Wash clothing
before reuse. Clean shoes thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are sulphur oxides (SO2, SO3, etc.), halogenated compounds.
products Some metallic oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Use a shovel to put the material into a convenient waste disposal container.
cleanup methods Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe dust. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits. If user
operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Lab coat.

Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Solid. (Powdered solid.)
Colour : White.
Odour : Odourless.
Melting point : 1700°C (3092°F) based on data for: Silica (SiO2).
Density : Weighted average: 2.68 g/cm3
: Soluble in cold water.

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Solubility
pH : Not available.
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Hazardous decomposition products : These products are sulphur oxides (SO2, SO3, etc.), halogenated compounds.
Some metallic oxides.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Stannous chloride LD50 700 mg/kg Oral Rat
LD50 250 mg/kg Oral Mouse
LDLo 60 mg/kg Oral Guinea pig
LDLo 500 mg/kg Oral Dog
Silica (SiO2) LD50 >5000 Oral Rat
mg/kg

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 02

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 16 05 02 other waste containing inorganic chemicals, e.g. lab chemicals not
otherwise specified, fire extinguishing powders

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -

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IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Safety Phrases : S37/39- Wear suitable gloves and eye/face protection.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R22- Harmful if swallowed.
appearing in Section 2 - United R36/37/38- Irritating to eyes, respiratory system and skin.
Kingdom (UK)
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/21/2002.
Date of issue : 7/18/2002.
Version : 2.07
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
7/18/2002. 2.07 Page: 4/4