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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET


MAGNAKOTE PLUS
1. Identification of the substance/preparation and of the company/undertaking
Product name : MAGNAKOTE PLUS
Material Uses : Industrial applications: Coating. Rust Preventative Coating for ballast tanks,
etc.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification


Baseoil; Distillates (petroleum), solvent-dewaxed 64742-65-0 30-40 265-169-7
heavy paraffinic
Baseoil; Distillates (petroleum), solvent-dewaxed 64742-65-0 10-20 265-169-7
heavy paraffinic
Baseoil; distillates (petroleum), hydrotreated heavy 64742-52-5 5-10 265-155-0 R53
naphthenic
Alkyl aryl sulphonate (Calcium salt) 61789-86-4 5-10 263-093-9 Xi; R36
Baseoil; distillates (petroleum), hydrotreated light 64742-53-6 5-10 265-156-6
naphthenic
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms

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MAGNAKOTE PLUS

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : Wash with soap and water. Get medical attention if irritation develops.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. WARM
water MUST be used. Obtain medical attention

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, sulphur oxides (SO2,
products SO3, etc.). Some metallic oxides.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures


Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Neutralize the residue with a dilute solution of acetic acid.
Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage


Handling : Keep away from heat. Keep away from sources of ignition. Empty containers
pose a fire risk, evaporate the residue under a fume hood. Ground all
equipment containing material. Do not ingest. Do not breathe vapour/spray.
If ingested, seek medical advice immediately and show the container or the
label. Keep away from incompatibles such as oxidizing agents.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection


Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Occupational Exposure Limits

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MAGNAKOTE PLUS

Ingredient Name Occupational Exposure Limits


Baseoil; Distillates (petroleum), solvent-dewaxed EH40 (United Kingdom (UK), 1999). Notes: Supplier's
heavy paraffinic information
TWA: 5 mg/m3 Form: Mist
Baseoil; Distillates (petroleum), solvent-dewaxed EH40 (United Kingdom (UK), 1999). Notes: Supplier's
heavy paraffinic information
TWA: 5 mg/m3 Form: Mist
Baseoil; distillates (petroleum), hydrotreated heavy EH40 (United Kingdom (UK)).
naphthenic STEL: 10 mg/m3 Form: Mist
TWA: 5 mg/m3 Form: Mist
Baseoil; distillates (petroleum), hydrotreated light EH40 (United Kingdom (UK)). Notes: Supplier's
naphthenic information
TWA: 5 mg/m3 Form: Mist

Skin and body : Lab coat.


Eyes : Safety glasses.

9. Physical and chemical properties


Physical state : Liquid.
Colour : Amber.
Odour : Mineral oil
Boiling point : >218°C (424°F)
Density : 0.935 g/cm3
Vapour pressure : <0.13 kPa (<1 mmHg) (at 20°C)
Solubility : Easily soluble in hot water.
Insoluble in cold water.
pH : Basic.
Flash point : OPEN CUP: 177°C (350.6°F)(Cleveland.).
Autoignition temperature : The lowest known value is >270°C (518°F) (Baseoil; distillates (petroleum),
hydrotreated heavy naphthenic).
Viscosity : Kinetic: 700 cSt

10. Stability and reactivity


Stability : The product is stable.
Conditions to Avoid : exposure to heat
Materials to avoid : Reactive with oxidizing agents.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, sulphur oxides (SO2,
SO3, etc.). Some metallic oxides.

11. Toxicological information


Acute toxicity
Ingredient Name Test Result Route Species
Baseoil; distillates (petroleum), hydrotreated LD50 >5000 Oral Rat
heavy naphthenic mg/kg
LD50 >2000 Dermal Rabbit
mg/kg

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Carcinogenic effects : Not available.

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MAGNAKOTE PLUS

Mutagenic Effects : Not available.


Reproduction toxicity : Not available.

12. Ecological information


Ecotoxicity Data
Ingredient Name Species Period Result
Baseoil; distillates (petroleum), hydrotreated heavy Fish (LC50) 96 hours >1000 mg/l
naphthenic
Persistence/degradability : Not available.

13. Disposal considerations


Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 03


Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 16 05 03 other waste containing organic chemicals, e.g. lab chemicals not
otherwise specified

14. Transport information


International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information


EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Safety Phrases : S23- Do not breathe vapour/spray.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications, Used by Spraying.

16. Other information


Full text of R-Phrases with no. : R36- Irritating to eyes.
appearing in Section 2 - United R53- May cause long-term adverse effects in the aquatic environment.
Kingdom (UK)
Text of classifications appearing in : Xi - Irritant
Section 2 - United Kingdom (UK)
HISTORY

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MAGNAKOTE PLUS

Date of printing : 10/17/2002.


Date of issue : 10/16/2002.
Version : 3
MAGNAKOTE® PLUS is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 5/5

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