Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

O&GR
1. Identification of the substance/preparation and of the company/undertaking
Product name : O&GR
Material Uses : Industrial applications: Cleaning agent for machinery and equipment. Oil and
grease remover.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Distillates (petroleum) 68476-30-2 90-100 265-044-7 Carc. Cat. 3; R40
Xn; R65
R66
R52/53
Ethoxylated alcohol 68439-45-2 1-5 Xn; R22
Xi; R36/38
Ethoxylated alcohol 68439-45-2 1-5 Xn; R22
Xi; R41
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful
R40- Limited evidence of a carcinogenic effect.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation.
Target Organs : Contains material which causes damage to the following organs: central
nervous system (CNS).
Contains material which may cause damage to the following organs: the
nervous system.

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : If swallowed, do NOT induce vomiting. Do NOT induce vomiting unless
directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Aspiration hazard if swallowed- can enter lungs and
cause damage. Loosen tight clothing such as a collar, tie, belt or waistband.
Obtain medical attention. Get medical attention if symptoms appear.
Skin contact : Wash with soap and water. Get medical attention if irritation develops. Cold
water may be used
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Environmental precautions and : Keep away from heat. Keep away from sources of ignition. Stop leak if
cleanup methods without risk
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep locked up. Keep away from heat. Keep away from sources of ignition.
Ground all equipment containing material. Do not breathe
gas/fumes/vapour/spray. Wear suitable protective clothing. If ingested, seek
medical advice immediately and show the container or the label. Keep away
from incompatibles such as oxidizing agents.
Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed
and sealed until ready for use. Avoid all possible sources of ignition (spark or
flame).
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures
Hygiene measures
Occupational Exposure Limits
: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
: Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

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Ingredient Name Occupational Exposure Limits

Distillates (petroleum) EH40 (United Kingdom (UK)). Notes: Supplier's
information
TWA: 500 mg/m3

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Green.
Odour : Aromatic.
Boiling point : >160°C (320°F)
Melting point : <-20°C (-4°F)
Density : 0.87 g/cm3
Vapour density : The highest known value is >5 (Air = 1) (Distillates (petroleum)).
Vapour pressure : <0.13 kPa (<1 mmHg) (at 20°C)
Evaporation Rate : <0.1 compared to Butyl acetate.

Solubility : Soluble in cold water.

pH : Neutral.
Flash point : CLOSED CUP: 63°C (145.4°F).
Autoignition temperature : >240°C (464°F)
Lower explosion limit : The greatest known range is LOWER: 0.6% UPPER: 6.5% (Distillates
(petroleum))

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
O&GR LD50 >5000 Oral Rat
mg/kg
LD50 >2000 Dermal Rabbit
mg/kg
Distillates (petroleum) LD50 >5000 Oral Rat
mg/kg
LD50 >2000 Dermal Rabbit
mg/kg
LC50 2500 mg/m3 Inhalation Rat
(4 hours)
Ethoxylated alcohol LD50 >1000 Oral Rat
mg/kg

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LD50 >2000 Dermal Rabbit

mg/kg
LC50 >5 mg/l (4 Inhalation Rat
hours)
Ethoxylated alcoho LD50 >500 mg/kg Oral Rat
LD50 >2000 Dermal Rabbit
mg/kg
LC50 >5 mg/l (4 Inhalation Rat
hours)

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Local effects
Specific effects
Carcinogenic effects : Classified 3 (Possible for humans.) by European Union [Distillates
(petroleum)].

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
Ethoxylated alcohol Fish (LC50) 96 hours 1 to 10 mg/l
Daphnia (EC50) 48 hours 1 to 10 mg/l
Algae (IC50) 72 hours 1 to 10 mg/l
Ethoxylated alcohol Fish (LC50) 96 hours 10 to 100 mg/l
Daphnia (EC50) 48 hours 1 to 10 mg/l
Algae (IC50) 72 hours 10 to 100 mg/l
Persistence/degradability : The BOD is 1.17e+006 mg/kg[ day(s)]. The COD is 1.68e+006 mg/kg[ day(s)].

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 14 02 02

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 14 02 02 solvent mixes or organic liquids free of halogenated solvents

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Distillates (petroleum))
Other information : -
Sea
UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Distillates (petroleum))
Other information : Emergency Schedules (EmS)
-

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15. Regulatory information

EU Regulations
Hazard symbol(s) :

Harmful
Risk Phrases : R40- Limited evidence of a carcinogenic effect.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
Safety Phrases : S23- Do not breathe vapour/spray.
S24- Avoid contact with skin.
S37/39- Wear suitable gloves and eye/face protection.
S56- Dispose of this material and its container at hazardous or special waste
collection point.
Contains : Distillates (petroleum) 265-044-7
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R22- Harmful if swallowed.
appearing in Section 2 - United R36/38- Irritating to eyes and skin.
Kingdom (UK) R40- Limited evidence of a carcinogenic effect.
R41- Risk of serious damage to eyes.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
Text of classifications appearing in : Carc. Cat.3 - Carcinogen Category 3
Section 2 - United Kingdom (UK) Xn - Harmful
Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
O&GR™ is a trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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