Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

AMERGY 5000
1. Identification of the substance/preparation and of the company/undertaking
Product name : AMERGY 5000
Material Uses : Industrial applications: Fuel additive. Combustion improver for oil, coal and
other fuels.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Distillates (petroleum) 68476-30-2 30-40 265-044-7 Carc. Cat. 3; R40
Xn; R65
R66
R52/53
Dichlorotoluene, mixture of isomers 29797-40-8 20-30 249-854-8 Xi; R38
N; R51/53
Naphtha (petroleum), hydrotreated (desulfurised) 64742-82-1 10-20 265-185-4 R10
heavy Xn; R65
N; R51/53
Solvent naphtha (petroleum), heavy aromatic 64742-94-5 1-5 265-198-5 Xn; R65
R66, 67
N; R51/53
Distillates (petroleum), hydrotreated light (kerosine) 64742-47-8 1-5 265-149-8 Xn; R65
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful, Dangerous for the environment
R38- Irritating to skin.
R40- Limited evidence of a carcinogenic effect.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
Effects and symptoms
Inhalation : Hazardous in case of inhalation.

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Ingestion : Hazardous in case of ingestion.

Skin contact : Hazardous in case of skin contact (irritant, permeator). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: central
nervous system (CNS).
Contains material which may cause damage to the following organs: lungs,
the nervous system.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : If swallowed, do NOT induce vomiting. Do NOT induce vomiting unless
directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a
physician immediately. Aspiration hazard if swallowed- can enter lungs and
cause damage. Loosen tight clothing such as a collar, tie, belt or waistband.
Obtain medical attention.
Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
irritated skin with an emollient. Remove contaminated clothing and shoes.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain
medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Obtain
medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, halogenated
products compounds.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Keep away from heat. Keep away from sources of ignition. Stop leak if
cleanup methods without risk
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep locked up. Keep away from heat. Keep away from sources of ignition.
Ground all equipment containing material. Do not ingest. Do not breathe
vapour. Avoid contact with skin. Wear suitable protective clothing. If
ingested, seek medical advice immediately and show the container or the
label. Keep away from incompatibles such as oxidizing agents.
Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed
and sealed until ready for use. Avoid all possible sources of ignition (spark or
flame).

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Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures
Hygiene measures
Occupational Exposure Limits
: Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
: Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

Ingredient Name Occupational Exposure Limits

Distillates (petroleum) EH40 (United Kingdom (UK)). Notes: Supplier's
information
TWA: 500 mg/m3
Naphtha (petroleum), hydrotreated (desulfurised) RPC (United Kingdom (UK), 2001). Notes: Supplier's
heavy information
TWA: 275 mg/m3
Solvent naphtha (petroleum), heavy aromatic RCP (United Kingdom (UK), 2000). Notes: Supplier's
information
TWA: 100 mg/m3

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Splash goggles.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Brown. (Dark.)
Odour : Chlorinated hydrocarbon odour.
Boiling point : >180°C (356°F)
Melting point : <-20°C (-4°F)
Density : 0.95 to 0.99 g/cm3
Vapour density : The highest known value is 5.3 (Air = 1) (Distillates (petroleum), hydrotreated
light (kerosine)).
Vapour pressure : The highest known value is 0.67 kPa (5 mmHg) (at 20°C) (Naphtha
(petroleum), hydrotreated (desulfurised) heavy ).
Evaporation Rate : 0.05 (Solvent naphtha (petroleum), heavy aromatic) compared to Butyl
acetate
Solubility : Insoluble in cold water.
pH : Not applicable.
Flash point : CLOSED CUP: >61°C (141.8°F).(Pensky-Martens.)
Autoignition temperature : The lowest known value is 216.11°C (421°F) (Distillates (petroleum),
hydrotreated light (kerosine)).
Lower explosion limit : The greatest known range is LOWER: 1.3% UPPER: 8.1% (Distillates
(petroleum), hydrotreated light (kerosine))

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10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, halogenated
compounds.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Distillates (petroleum) LD50 >5000 Oral Rat
mg/kg
LD50 >2000 Dermal Rabbit
mg/kg
LC50 2500 mg/m3 Inhalation Rat
(4 hours)
Dichlorotoluene, mixture of isomers LD50 >2000 Oral Rat
mg/kg

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Local effects
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Specific effects
Carcinogenic effects : Classified 3 (Possible for humans.) by European Union [Distillates
(petroleum)].

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
Dichlorotoluene, mixture of isomers Fish (LC50) 96 hours 3.1 mg/l

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 14 02 01

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 14 02 01 halogenated solvents and solvent mixes

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14. Transport information

International transport regulations
Land - Road/Railway
UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Dichlorotoluene, mixture of isomers)
ADR/RID Class : 9
Packing group : III
ADR/RID label :

Other information : Hazard identification number

9
Sea
UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Dichlorotoluene, mixture of isomers)
IMDG Class : 9
Packing group : III
IMDG label :

Other information : Emergency Schedules (EmS)

-

Marine pollutant
IMDG Class: Marine Pollutant. (Pollutant.)

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Harmful, Dangerous for the environment

Risk Phrases : R38- Irritating to skin.
R40- Limited evidence of a carcinogenic effect.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
Safety Phrases : S23- Do not breathe vapour.
S28- After contact with skin, wash immediately with plenty of soap and water.
S37/39- Wear suitable gloves and eye/face protection.
S56- Dispose of this material and its container at hazardous or special waste
collection point.
Contains : Distillates (petroleum) 265-044-7
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

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16. Other information

Full text of R-Phrases with no. : R10- Flammable.
appearing in Section 2 - United R38- Irritating to skin.
Kingdom (UK) R40- Limited evidence of a carcinogenic effect.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
Text of classifications appearing in : Carc. Cat.3 - Carcinogen Category 3
Section 2 - United Kingdom (UK) Xn - Harmful
Xi - Irritant
N - Dangerous for the environment.
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
AMERGY® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
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