You are on page 1of 15

Safety Data Sheet in compliance with Indian Manufacture, Storage and Import

of Hazardous Chemical (Amendment) Rules, 2000


Page 1 of 15
Loctite 7299TF 5L. SDS No. : 587817
V001.1
Revision: 17.03.2021
printing date: 28.08.2021

SECTION 1: Identification of the substance/mixture and of the company/undertaking


Product identifier
Loctite 7299TF 5L.
Material: 2218932

Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Solvent based adhesive

Identification of manufacturer, importer or distributor:


Henkel Adhesives Tech. India Pvt Ltd.
L&T Seawoods, Grand Central 401, B Wing, 4th Floor, Tower 1
Seawoods
400706 Navi M umbai, M aharashtra

India

Phone: +91 022-7130-1112


Fax-no.: +91 022-7130-1400

Emergency telephone number


+91-22-39266510

In case of any emergency call Poison Information Centre, JSS Hospital, M ysore: 24x7 Helpline No: +916363539153/ Toll
Free No: 18004250207/ M obile: +91 9901218640.

SECTION 2: Hazards identification

Classification of the substance or mixture


Classification (DPD):
F - Highly flammable
R11 Highly flammable.
Xn - Harmful
R65 Harmful: may cause lung damage if swallowed.
Xi - Irritant
R36/38 Irritating to eyes and skin.
N - Dangerous for the
environment
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 Vapours may cause drowsiness and dizziness.

Label elements
SDS No.: 587817 Loctite 7299TF 5L. Page 2 of 15
V001.1
Label elements (DPD):

Risk phrases:
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.

Safety phrases:
S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition - No smoking.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33 Take precautionary measures against static discharges.
S37 Wear suitable gloves.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

SECTION 3: Composition/information on ingredients

Declaration of ingredients according to DPD (EC) No 1999/45:

Hazardous components EC Number content Classification


CAS-No.
Ethyl acetate 205-500-4 >= 10 - <= 70 % F - Highly flammable; R11
141-78-6 R66
Xi - Irritant; R36
R67
cyclohexane 203-806-2 >= 10 - <= 50 % F - Highly flammable; R11
110-82-7 Xn - Harmful; R65
R67
N - Dangerous for the environment; R50/53
Xi - Irritant; R38
rosin 232-475-7 >= 0,01 - <= 10 % R43
8050-09-7
2-methoxy-1-methylethyl acetate 203-603-9 >= 0,01 - <= 10 % R10
108-65-6
n-butyl acetate 204-658-1 >= 0,01 - <= 10 % R10
123-86-4 R67
R66
Ethanol 200-578-6 >= 0,01 - <= 10 % F - Highly flammable; R11
64-17-5

For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
S ubstances without classification may have community workplace exposure limits available.

Section 4. First aid measures


Inhalation: M ove to fresh air.
In case of adverse health effects seek medical advice.

S kin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated
clothing.
In case of adverse health effects seek medical advice.

Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If
pains remain (intensive smarting, sensitivity to light, visual disturbance) continue flushing
and contact/seek doctor or hospital.

Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.
SDS No.: 587817 Loctite 7299TF 5L. Page 3 of 15
V001.1

Section 5. Fire fighting measures


S uitable extinguishing media: Carbon dioxide, foam, powder

S pecific hazards arising from the Formation of toxic gases is possible during heating or in fires.
chemical:

S pecial protection equipment and Wear self-contained breathing apparatus.


precautions for firefighters:

Hazardous combustion products: Carbon dioxide

Additional fire fighting advice: Cool endangered containers with water spray jet.

Section 6. Accidental release measures


Personal precautions: Avoid contact with skin and eyes.
Wear appropriate personal protective equipment.
Keep unprotected persons away.
Danger of slipping on spilled product.

Environmental precautions: Do not empty into drains / surface water / ground water.
Do not allow to enter the ground / soil.

Clean-up methods: Remove with liquid-absorbing material (sand, peat, sawdust).

SECTION 7: Handling and storage


Precautions for safe handling
Avoid skin and eye contact.
Ensure that workrooms are adequately ventilated.
Open and handle container with care.
Take measures to prevent the build-up of electrostatic charges.

Conditions for safe storage, including any incompatibilities


6 months
Do not handle or store near an open flame, heat or other sources of ignition.
Keep away from heat and direct sunlight.
Storage at 10 to 35°C is recommended.

Section 8. Exposure controls / personal protection

Ingre dient [Regulated substance] Value type ppm mg/m 3 Remarks


ET HYL ACETATE T ime Weighted Average 400 1.400 IN OEL
141-78-6 (T WA):
N-BUT YL ACETATE T ime Weighted Average 150 710 IN OEL
123-86-4 (T WA):
ET HYL ALCOHOL T ime Weighted Average 1.000 1.900 IN OEL
64-17-5 (T WA):
SDS No.: 587817 Loctite 7299TF 5L. Page 4 of 15
V001.1

Respiratory protection: In case of aerosol formation, we recommend wearing of appropriate respiratory protection
equipment with ABEK P2 filter (EN 14387).
This recommendation should be matched to local conditions.

Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or
splashes (recommended: at least protection index 2, corresponding to > 30 minutes
permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural
rubber (NR; >=1 mm thickness) Suitable materials for longer, direct contact
(recommended: protection index 6, corresponding to > 480 minutes permeation time as per
EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm
thickness) This information is based on literature references and on information provided
by glove manufacturers, or is derived by analogy with similar substances. Please note that
in practice the working life of chemical-resistant protective gloves may be considerably
shorter than the permeation time determined in accordance with EN 374 as a result of the
many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the
gloves should be replaced.

Eye protection: Goggles which can be tightly sealed.

Body protection: Protective clothing that covers arms and legs.

Engineering controls: Ensure good ventilation/suction at the workplace.

Hygienic measures: Keep away from food, beverages and animal feed. Wash hands before work breaks and
after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene
practices should be observed.

SECTION 9: Physical and chemical properties


Appearance: black
liquid
Odor: of solvent
Odor threshold (CA): No data available.
pH: No data available.
Melting point / freezing point: No data available.
S pecific gravity: No data available.
Boiling point: No data available.
Flash point: -18 °C (0.4 °F)
(no method)
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Lower explosive limit: No data available.
Upper explosive limit: No data available.
Vapor pressure: No data available.
Vapor density: No data available.
Density: 0,86 g/cm3
S olubility:
Partition coefficient: n- No data available.
octanol/water:
Auto ignition: No data available.
Decomposition temperature: No data available.
Viscosity: 1.500 - 1.900 mPa.s
(; 30 °C (86 °F); speed of
rotation: 30 min-1; M ethod: ;;
LCT STM 10; Viscosity
Brookfield)
VOC content: No data available.
SDS No.: 587817 Loctite 7299TF 5L. Page 5 of 15
V001.1

Section 10. Stability and reactivity


Reactivity/Incompatible Bases.
materials: None if used properly.
Chemical stability: Stable under recommended storage conditions.
Conditions to avoid: No decomposition if used according to specifications.
Hazardous decomposition None if used for intended purpose.
products: In case of fire toxic gases can be released.

SECTION 11: Toxicological information


Information on toxicological effects

General toxicological information:


No experimental toxicological data on the preparation as such is available.

Acute oral toxicity:

Haz ardous components Value Value Route of Exposure Species Method


CAS-No. type application time
Ethyl acetate LD50 6.100 mg/kg oral rat not specified
141-78-6
cyclohexane LD50 > 5.000 mg/kg oral rat equivalent or similar to OECD
110-82-7 Guideline 401 (Acute Oral
T oxicity)
rosin LD50 2.800 mg/kg oral rat not specified
8050-09-7
2-methoxy-1-methylethyl LD50 6.190 mg/kg oral rat OECD Guideline 401 (Acute
acetate Oral T oxicity)
108-65-6
n-butyl acetate LD50 10.760 mg/kg oral rat OECD Guideline 423 (Acute
123-86-4 Oral toxicity)
Ethanol LD50 10.470 mg/kg oral rat OECD Guideline 401 (Acute
64-17-5 Oral T oxicity)

Acute inhalative toxicity:

Haz ardous components Value Value Route of Exposure Species Method


CAS-No. type application time
Ethyl acetate LC0 > 22,5 mg/l inhalation 6h rat other guideline:
141-78-6
Ethyl acetate LC50 > 22,5 mg/l 6h rat other guideline:
141-78-6
cyclohexane LC50 > 32,880 mg/l inhalation 4h rat equivalent or similar to OECD
110-82-7 Guideline 403 (Acute
Inhalation Toxicity)
2-methoxy-1-methylethyl LC50 > 35,7 mg/l inhalation 4h rat not specified
acetate
108-65-6
n-butyl acetate LC50 > 23,4 mg/l inhalation 4h rat OECD Guideline 403 (Acute
123-86-4 Inhalation Toxicity)
Ethanol LC50 124,7 mg/l inhalation 4h rat OECD Guideline 403 (Acute
64-17-5 Inhalation Toxicity)
SDS No.: 587817 Loctite 7299TF 5L. Page 6 of 15
V001.1

Acute dermal toxicity:

Haz ardous components Value Value Route of Exposure Species Method


CAS-No. type application time
Ethyl acetate LD50 > 20.000 mg/kg dermal rabbit Draize T est
141-78-6
cyclohexane LD50 > 2.000 mg/kg dermal rabbit equivalent or similar to OECD
110-82-7 Guideline 402 (Acute Dermal
T oxicity)
rosin LD50 > 2.000 mg/kg dermal rat OECD Guideline 402 (Acute
8050-09-7 Dermal T oxicity)
2-methoxy-1-methylethyl LD50 > 5.000 mg/kg dermal rabbit OECD Guideline 402 (Acute
acetate Dermal T oxicity)
108-65-6
n-butyl acetate LD50 > 14.112 mg/kg dermal rabbit OECD Guideline 402 (Acute
123-86-4 Dermal T oxicity)
Ethanol LD50 > 2.000 mg/kg dermal rabbit OECD Guideline 402 (Acute
64-17-5 Dermal T oxicity)

S kin corrosion/irritation:

Haz ardous components Result Exposure Species Method


CAS-No. time
Ethyl acetate slightly irritating 24 h rabbit equivalent or similar to OECD
141-78-6 Guideline 404 (Acute Dermal
Irritation / Corrosion)
rosin not irritating 4h rabbit OECD Guideline 404 (Acute
8050-09-7 Dermal Irritation / Corrosion)
2-methoxy-1-methylethyl not irritating 4h rabbit OECD Guideline 404 (Acute
acetate Dermal Irritation / Corrosion)
108-65-6
n-butyl acetate not irritating rabbit OECD Guideline 404 (Acute
123-86-4 Dermal Irritation / Corrosion)
Ethanol not irritating rabbit OECD Guideline 404 (Acute
64-17-5 Dermal Irritation / Corrosion)

S erious eye damage/irritation:

Haz ardous components Result Exposure Species Method


CAS-No. time
Ethyl acetate slightly irritating rabbit OECD Guideline 405 (Acute
141-78-6 Eye Irritation / Corrosion)
cyclohexane slightly irritating rabbit equivalent or similar to OECD
110-82-7 Guideline 405 (Acute Eye
Irritation / Corrosion)
rosin not irritating rabbit OECD Guideline 405 (Acute
8050-09-7 Eye Irritation / Corrosion)
2-methoxy-1-methylethyl not irritating rabbit OECD Guideline 405 (Acute
acetate Eye Irritation / Corrosion)
108-65-6
n-butyl acetate not irritating rabbit OECD Guideline 405 (Acute
123-86-4 Eye Irritation / Corrosion)
Ethanol irritating rabbit OECD Guideline 405 (Acute
64-17-5 Eye Irritation / Corrosion)
SDS No.: 587817 Loctite 7299TF 5L. Page 7 of 15
V001.1

Respiratory or skin sensitization:

Haz ardous components Result Test type Species Method


CAS-No.
Ethyl acetate not sensitising Guinea pig guinea pig OECD Guideline 406 (Skin
141-78-6 maximisat Sensitisation)
ion test
cyclohexane not sensitising Buehler guinea pig equivalent or similar to OECD
110-82-7 test Guideline 406 (Skin
Sensitisation)
2-methoxy-1-methylethyl not sensitising Guinea pig guinea pig OECD Guideline 406 (Skin
acetate maximisat Sensitisation)
108-65-6 ion test
n-butyl acetate not sensitising Guinea pig guinea pig not specified
123-86-4 maximisat
ion test
Ethanol not sensitising Guinea pig guinea pig OECD Guideline 406 (Skin
64-17-5 maximisat Sensitisation)
ion test
Ethanol not sensitising Mouse mouse OECD Guideline 429 (Skin
64-17-5 local Sensitisation: Local Lymph
lymphnod Node Assay)
e assay
(LLNA)
SDS No.: 587817 Loctite 7299TF 5L. Page 8 of 15
V001.1

Germ cell mutagenicity:

Haz ardous components Result Type of study / Metabolic Species Method


CAS-No. Route of activation /
administration Exposure time
Ethyl acetate negative bacterial reverse with and without equivalent or similar to OECD
141-78-6 mutation assay (e.g Guideline 471 (Bacterial
Ames test) Reverse Mutation Assay)
negative in vitro mammalian with and without equivalent or similar to OECD
chromosome Guideline 473 (In vitro
aberration test Mammalian Chromosome
Aberration Test)
Ethyl acetate negative oral: gavage hamster, equivalent or similar to OECD
141-78-6 Chinese Guideline 474 (Mammalian
Erythrocyte Micronucleus
T est)
cyclohexane negative bacterial reverse with and without equivalent or similar to OECD
110-82-7 mutation assay (e.g Guideline 471 (Bacterial
Ames test) Reverse Mutation Assay)
negative mammalian cell with and without equivalent or similar to OECD
gene mutation assay Guideline 476 (In vitro
Mammalian Cell Gene
Mutation Test)
cyclohexane negative inhalation: vapour rat equivalent or similar to OECD
110-82-7 Guideline 475 (Mammalian
Bone Marrow Chromosome
Aberration Test)
rosin negative bacterial reverse with and without OECD Guideline 471
8050-09-7 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
2-methoxy-1-methylethyl negative bacterial reverse with and without OECD Guideline 471
acetate mutation assay (e.g (Bacterial Reverse Mutation
108-65-6 Ames test) Assay)
negative in vitro mammalian with and without OECD Guideline 473 (In vitro
chromosome Mammalian Chromosome
aberration test Aberration Test)
negative DNA damage and without OECD Guideline 482 (Genetic
repair assay, T oxicology: DNA Damage
unscheduled DNA and Repair, Unscheduled
synthesis in DNA Synthesis in Mammalian
mammalian cells in Cells In Vitro)
vitro
n-butyl acetate negative bacterial reverse with and without OECD Guideline 471
123-86-4 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
negative mammalian cell with and without OECD Guideline 476 (In vitro
gene mutation assay Mammalian Cell Gene
Mutation Test)
n-butyl acetate negative oral: gavage mouse OECD Guideline 474
123-86-4 (Mammalian Erythrocyte
Micronucleus T est)
Ethanol negative bacterial reverse OECD Guideline 471
64-17-5 mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
negative in vitro mammalian without OECD Guideline 473 (In vitro
chromosome Mammalian Chromosome
aberration test Aberration Test)
negative mammalian cell with and without OECD Guideline 476 (In vitro
gene mutation assay Mammalian Cell Gene
Mutation Test)
Ethanol negative OECD Guideline 475
64-17-5 (Mammalian Bone Marrow
Chromosome Aberration T est)

Carcinogenicity:

Haz ardous components Result Species Sex Exposure Route of Method


CAS-No. timeFrequenc application
y of treatment
Ethanol not carcinogenic Expert judgement
64-17-5
SDS No.: 587817 Loctite 7299TF 5L. Page 9 of 15
V001.1

Repeated dose toxicity

Haz ardous components Result Route of Exposure time / Species Method


CAS-No. application Frequency of
treatment
Ethyl acetate NOAEL=900 oral: gavage 90 ddaily rat EPA OT S 795.2600
141-78-6 mg/kg (Subchronic Oral T oxicity
T est)
cyclohexane inhalation: 13-14 w6 h/d, 5 d/w mouse EPA OPPTS 870.3465 (90-
110-82-7 vapour Day Inhalation Toxicity)
2-methoxy-1-methylethyl NOAEL=>= 1.000 oral: gavage 41 - 45 ddaily rat OECD Guideline 422
acetate mg/kg (Combined Repeated Dose
108-65-6 T oxicity Study with the
Reproduction / Developmental
T oxicity Screening T est)
n-butyl acetate NOAEL=125 oral: gavage 6 (interim sacrifice) rat EPA OT S 798.2650 (90-Day
123-86-4 mg/kg or 13 wdaily Oral T oxicity in Rodents)

SECTION 12: Ecological information


General ecological information:
Do not empty into drains, soil or bodies of water.
SDS No.: 587817 Loctite 7299TF 5L. Page 10 of 15
V001.1
Toxicity

Haz ardous components Value Value Acute Exposure Species Me thod


CAS-No. type Toxicity time
Study
Ethyl acetate LC50 220 mg/l Fish 96 h Pimephales promelas other guideline:
141-78-6
Ethyl acetate EC50 164 mg/l Daphnia 48 h Daphnia cucullata OECD Guideline
141-78-6 202 (Daphnia sp.
Acute
Immobilisation
T est)
Ethyl acetate EC50 > 2.000 mg/l Algae 96 h Selenastrum capricornutum OECD Guideline
141-78-6 (new name: Pseudokirchneriella 201 (Alga, Growth
subcapitata) Inhibition Test)
NOEC 2.000 mg/l Algae 96 h Selenastrum capricornutum OECD Guideline
(new name: Pseudokirchneriella 201 (Alga, Growth
subcapitata) Inhibition Test)
Ethyl acetate EC10 2.900 mg/l Bacteria 18 h Pseudomonas putida DIN 38412, part 8
141-78-6 (Pseudomonas
Zellvermehrungshe
mm-T est)
Ethyl acetate NOEC 2,4 mg/l chronic 21 d Daphnia magna OECD 211
141-78-6 Daphnia (Daphnia magna,
Reproduction Test)
cyclohexane LC50 4,53 mg/l Fish 96 h Pimephales promelas OECD Guideline
110-82-7 203 (Fish, Acute
T oxicity Test)
cyclohexane EC50 0,9 mg/l Daphnia 48 h Daphnia magna OECD Guideline
110-82-7 202 (Daphnia sp.
Acute
Immobilisation
T est)
cyclohexane EC50 9,317 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
110-82-7 (new name: Pseudokirchneriella 201 (Alga, Growth
subcapitata) Inhibition Test)
NOEC 0,95 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
(new name: Pseudokirchneriella 201 (Alga, Growth
subcapitata) Inhibition Test)
cyclohexane IC50 29 mg/l Bacteria 15 h other: not specified
110-82-7
rosin LC50 T oxicity > Water Fish 96 h Pimephales promelas OECD Guideline
8050-09-7 solubility 203 (Fish, Acute
T oxicity Test)
rosin EL50 T oxicity > Water Daphnia 48 h Daphnia magna OECD Guideline
8050-09-7 solubility 202 (Daphnia sp.
Acute
Immobilisation
T est)
rosin EL50 T oxicity > Water Algae 72 h Pseudokirchneriella subcapitata OECD Guideline
8050-09-7 solubility 201 (Alga, Growth
Inhibition Test)
NOELR T oxicity > Water Algae 72 h Pseudokirchneriella subcapitata OECD Guideline
solubility 201 (Alga, Growth
Inhibition Test)
rosin EC20 T oxicity > Water Bacteria 3h activated sludge of a OECD Guideline
8050-09-7 solubility predominantly domestic sewage 209 (Activated
Sludge, Respiration
Inhibition Test)
2-methoxy-1-methylethyl LC50 100 - 180 mg/l Fish 96 h Salmo gairdneri (new name: OECD Guideline
acetate Oncorhynchus mykiss) 203 (Fish, Acute
108-65-6 T oxicity Test)
LC50 63,5 mg/l Fish 14 d Oryzias latipes OECD Guideline
204 (Fish,
Prolonged T oxicity
T est: 14-day Study)
2-methoxy-1-methylethyl EC50 > 500 mg/l Daphnia 48 h Daphnia magna OECD Guideline
acetate 202 (Daphnia sp.
108-65-6 Acute
Immobilisation
T est)
2-methoxy-1-methylethyl NOEC > 1.000 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
acetate (new name: Pseudokirchneriella 201 (Alga, Growth
108-65-6 subcapitata) Inhibition Test)
SDS No.: 587817 Loctite 7299TF 5L. Page 11 of 15
V001.1
EC50 > 1.000 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
(new name: Pseudokirchneriella 201 (Alga, Growth
subcapitata) Inhibition Test)
2-methoxy-1-methylethyl EC 50 > 100 mg/l Bacteria not specified
acetate
108-65-6
2-methoxy-1-methylethyl NOEC > 100 mg/l chronic 21 d Daphnia magna OECD 211
acetate Daphnia (Daphnia magna,
108-65-6 Reproduction Test)
n-butyl acetate LC50 18 mg/l Fish 96 h Pimephales promelas OECD Guideline
123-86-4 203 (Fish, Acute
T oxicity Test)
n-butyl acetate EC50 44 mg/l Daphnia 48 h Daphnia sp. OECD Guideline
123-86-4 202 (Daphnia sp.
Acute
Immobilisation
T est)
n-butyl acetate EC50 674,7 mg/l Algae 72 h Scenedesmus subspicatus (new OECD Guideline
123-86-4 name: Desmodesmus 201 (Alga, Growth
subspicatus) Inhibition Test)
EC10 295,5 mg/l Algae 72 h Scenedesmus subspicatus (new OECD Guideline
name: Desmodesmus 201 (Alga, Growth
subspicatus) Inhibition Test)
n-butyl acetate IC50 356 mg/l Bacteria 40 h Ciliate (T etrahymena other guideline:
123-86-4 pyriformis)
n-butyl acetate NOEC 23,2 mg/l chronic 21 d Daphnia magna OECD 211
123-86-4 Daphnia (Daphnia magna,
Reproduction Test)
Ethanol LC50 14.200 mg/l Fish 96 h Pimephales promelas EPA-660 (Methods
64-17-5 for Acute T oxicity
T ests with Fish,
Macroinvertebrates
and Amphibians)
NOEC 250 mg/l Fish 120 h Danio rerio OECD Guideline
212 (Fish, Short-
term T oxicity T est
on Embryo and
Sac-Fry Stages)
Ethanol EC50 5.012 mg/l Daphnia 48 h Ceriodaphnia dubia other guideline:
64-17-5
Ethanol EC50 275 mg/l Algae 72 h Chlorella vulgaris OECD Guideline
64-17-5 201 (Alga, Growth
Inhibition Test)
EC10 11,5 mg/l Algae 72 h Chlorella vulgaris OECD Guideline
201 (Alga, Growth
Inhibition Test)
Ethanol IC50 > 1.000 mg/l Bacteria 3h activated sludge OECD Guideline
64-17-5 209 (Activated
Sludge, Respiration
Inhibition Test)
Ethanol NOEC 9,6 mg/l chronic 9d Daphnia magna not specified
64-17-5 Daphnia

Persistence and degradability

Haz ardous components Result Route of Degradability Method


CAS-No. application
SDS No.: 587817 Loctite 7299TF 5L. Page 12 of 15
V001.1
Ethyl acetate readily biodegradable aerobic 100 % OECD Guideline 301 D (Ready
141-78-6 Biodegradability: Closed Bottle
T est)
cyclohexane readily biodegradable aerobic 77 % OECD Guideline 301 F (Ready
110-82-7 Biodegradability: Manometric
Respirometry Test)
rosin readily biodegradable aerobic 71 % OECD Guideline 301 D (Ready
8050-09-7 Biodegradability: Closed Bottle
T est)
2-methoxy-1-methylethyl inherently biodegradable aerobic 100 % OECD Guideline 302 B (Inherent
acetate biodegradability: Zahn-
108-65-6 Wellens/EMPA Test)
readily biodegradable 90 % OECD Guideline 301 F (Ready
Biodegradability: Manometric
Respirometry Test)
n-butyl acetate readily biodegradable aerobic 83 % OECD Guideline 301 D (Ready
123-86-4 Biodegradability: Closed Bottle
T est)
Ethanol readily biodegradable aerobic 80 - 85 % OECD Guideline 301 D (Ready
64-17-5 Biodegradability: Closed Bottle
T est)

Bioaccumulative potential / Mobility in soil

Haz ardous components LogPow Bioconcentration Exposure Species Temperature Me thod


CAS-No. factor (BCF) time
Ethyl acetate 30 3d Leuciscus idus 22,5 °C other guideline:
141-78-6 melanotus
Ethyl acetate 0,68 25 °C EPA OPPTS 830.7560
141-78-6 (Partition Coefficient, n-
octanol / H2O, Generator
Column Method)
cyclohexane 167 Pimephales QSAR (Quantitative
110-82-7 promelas Structure Activity
Relationship)
cyclohexane 3,44 25 °C QSAR (Quantitative
110-82-7 Structure Activity
Relationship)
rosin > 3 - 6,2 OECD Guideline 117
8050-09-7 (Partition Coefficient (n-
octanol / water), HPLC
Method)
2-methoxy-1-methylethyl 0,56 not specified
acetate
108-65-6
n-butyl acetate 2,3 25 °C OECD Guideline 117
123-86-4 (Partition Coefficient (n-
octanol / water), HPLC
Method)
Ethanol -0,35 24 °C not specified
64-17-5

Results of PBT and vPvB assessment

Haz ardous components PBT/vPvB


CAS-No.
Ethyl acetate Not fulfilling Persistent, Bioaccumulative and T oxic (PBT), very Persistent and very
141-78-6 Bioaccumulative (vPvB) criteria.
cyclohexane Not fulfilling Persistent, Bioaccumulative and T oxic (PBT), very Persistent and very
110-82-7 Bioaccumulative (vPvB) criteria.
rosin Not fulfilling Persistent, Bioaccumulative and T oxic (PBT), very Persistent and very
8050-09-7 Bioaccumulative (vPvB) criteria.
2-methoxy-1-methylethyl acetate Not fulfilling Persistent, Bioaccumulative and T oxic (PBT), very Persistent and very
108-65-6 Bioaccumulative (vPvB) criteria.
n-butyl acetate Not fulfilling Persistent, Bioaccumulative and T oxic (PBT), very Persistent and very
123-86-4 Bioaccumulative (vPvB) criteria.
Ethanol Not fulfilling Persistent, Bioaccumulative and T oxic (PBT), very Persistent and very
64-17-5 Bioaccumulative (vPvB) criteria.
SDS No.: 587817 Loctite 7299TF 5L. Page 13 of 15
V001.1

Section 13. Disposal considerations


Waste disposal of product: Dispose of in accordance with local and national regulations.

Disposal for uncleaned package: Dispose of in accordance with local and national regulations.

Section 14. Transport information

Road transport ADR:

Class: 3
Packing group: II
Classification code: F1
Hazard ident. number: 33
UN no.: 1133
Label: 3
Technical name: ADHESIVES
Additional information: Special provision 640D

Railroad transport RID:

Class: 3
Packing group: II
Classification code: F1
Hazard ident. number: 33
UN no.: 1133
Label: 3
Technical name: ADHESIVES
Additional information: Special provision 640D

Inland water transport ADN:

Class: 3
Packing group: II
Classification code: F1
Hazard ident. number:
UN no.: 1133
Label: 3
Technical name: ADHESIVES
Additional information: Special provision 640D

Marine transport IMDG:

Class: 3
Packing group: II
UN no.: 1133
Label: 3
EmS: F-E ,S-D
Seawater pollutant: Chemical kits
Proper shipping name: ADHESIVES (Cyclohexane)

Air transport IATA:

Class: 3
Packing group: II
Packing instructions (passenger) 353
Packing instructions (cargo) 364
UN no.: 1133
Label: 3
Proper shipping name: Adhesives
SDS No.: 587817 Loctite 7299TF 5L. Page 14 of 15
V001.1

Section 15. Regulations - classification and identification

Ethyl acetate IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
India. List of Hazardous Chemicals (M anufacture, Storage and Import of Hazardous
Chemical Rules, Schedule I (Part II))
cyclohexane IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
India. List of Hazardous Chemicals (M anufacture, Storage and Import of Hazardous
Chemical Rules, Schedule I (Part II))
American Cleaning Institute (ACI) Cleaning Product Ingredient Inventory
rosin Global Automotive Declarable Substances List (GADSL), Version 2
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
2-methoxy-1-methylethyl acetate IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
n-butyl acetate IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
IBC Code. International Bulk Chemical Code, Chapter 17, M inimum Requirements
India. List of Hazardous Chemicals (M anufacture, Storage and Import of Hazardous
Chemical Rules, Schedule I (Part II))
Ethanol American Cleaning Institute (ACI) Cleaning Product Ingredient Inventory
IBC Code. International Bulk Chemical Code, Chapter 18, Exempted Products
India. List of Hazardous Chemicals (M anufacture, Storage and Import of Hazardous
Chemical Rules, Schedule I (Part II))

SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text


of all abbreviations indicated by codes in this safety data sheet are as follows:
R10 Flammable.
R11 Highly flammable.
R36 Irritating to eyes.
R38 Irritating to skin.
R43 M ay cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Further information:
Dear Customer,
Henkel is committed to creating a sustainable future by promoting opportunities along the entire value chain. If you would like to
contribute by switching from a paper to the electronic version of SDS, please contact the local Customer Service representative.
We recommend to use a non-personal email address (e.g. SDS@your_company.com).

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.
SDS No.: 587817 Loctite 7299TF 5L. Page 15 of 15
V001.1

Disclaimer: This information is based on our current level of knowledge and relates to the product in
the state in which it is delivered. It is intended to describe our products from the point of
view of safety requirements and is not intended to guarantee any particular properties.

This Safety Data Sheet has been generated based on the Indian M anufacture, Storage and
Import of Hazardous Chemical (Amendment) Rules, 2000 and provides information in
accordance with Indian law only. No warranty or representation of any kind is given with
respect to the substantive or export laws of any other jurisdiction or country. Please
confirm that the information provided herein conforms to the substantive export or other
law of any other jurisdiction prior to export. For assistance, please contact Henkel Product
safety and Regulatory affairs for additional assistance.

You might also like