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DKK-TOA CORPORATION
SDS No.: E1079-8
PRODUCT NAME: Powder for pH6.86 Standard Solution

Created: Oct. 28, 1997

Revised: Aug. 19, 2021

SAFETY DATA SHEET

1. PRODUCT AND MANUFACTURER

Product Name : Powder for pH6.86 Standard Solution
Product Code : 143F061, 143F251, 143F308, 143F0611, 143F211
Manufacturer : DKK-TOA CORPORATION
Address : 29-10, Takadanobaba 1-Chome, Shinjuku-ku, Tokyo 169-8648 Japan
Department : Sensor Technology Dept.
Phone : +81-3-3202-0225
Fax : +81-3-3202-5685

2. HAZARDS IDENTIFICATION
GHS Classification
Physical/Chemical Hazards: Flammable solids Not classified
Pyrophoric solids Not classified
Self-heating chemicals Not classified
Human Health Hazards: Acute toxicity (Oral) Category 4
Skin corrosion/irritation Not classified
Specific target organ toxicity Not classified
(Repeated exposure)
(Hazard categories not described in the above are classified either as Not applicable or
as Not classifiable.)

GHS Label Elements

Pictogram and Symbol:

Signal Word: Warnng

Hazard Statements: Harmful if swallowed.
Precautionary Statements:
【Safety Measures】 Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
【First Aid】 If swallowed: If the victim feels unwell, get medical advice/attention.
Rinse mouth.
【Disposal】 Contents/containers should be properly disposed of in accordance with the
related laws and regulations or consign the disposal of contents/containers to
a hazardous waste disposal firm approved by the competent authority.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Form: Mixture
Potassium Disodium
Chemical Name Dihydrogenphosphate、 Hydrogenphosphate
Percent Range ≧49% ≧49%
Chemical Formula KH2PO4 Na2HPO4
1
Official Act* 1-452 1-497
Gazette No. ISHA*2 －
CAS No. 7778-77-0 7558-79-4
【NOTE】*1: Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc.
*2: Industrial Safety and Health Act
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DKK-TOA CORPORATION
SDS No.: E1079-8
PRODUCT NAME: Powder for pH6.86 Standard Solution

4. FIRST AID
Inhalation : Immediately, remove the victim to fresh air and let him/her blow nose and
rinse mouth.
Skin Contact : Wash the contaminated or contact spot of the skin thoroughly with a large
amount of water.
Eye Contact : Immediately, rinse the eye with running water for more than 15 minutes.
Ingestion : Give the victim plenty of water. If experiencing any symptoms, get
medical advice/attention.

5. FIRE FIGHTING MEASURES

Extinguishing Media
Firefighting Instruction
Protection of Firefighters
: This product is non-combustible. In case of a fire in the vicinity, use media
appropriate to surrounding fire conditions.
: In case of a fire in the vicinity, however, immediately remove containers
to a safe place or spray water onto them and the surrounding area to cool
down.
: When fighting fire, make sure to wear protective equipment.

6. ACCIDENTAL RELEASE MEASURES

For Humans : Wear appropriate protective equipment such as eye protection, rubber
gloves, etc. so that the product will not get on skin as practicably as possible.
For Environment : Pay attention to stop spilled material from entering sewage and drainage
systems or bodies of water to protect the environment. When diluting with
plenty of water, take necessary measures so that the contaminated water may
not be released to the environment without proper treatment.
Clean-up Method : Sweep up to collect the spilled and scattered product to empty containers as
and Equipment much as possible. Then, thoroughly flush and decontaminate the spilled area
with plenty of water.

7. HANDLING/STORAGE
Handling
Technical Measures
Precautions
Storage
Storage Conditions
Container Material
: Wear appropriate protective equipment such as eye protection, rubber
gloves, etc. if necessary.
: Pay attention as practicably as possible so that the product will not get on
skin and others.
: Tightly close containers and store in a cool and dark place.
: Glass, Polyethylene, Polypropylene, etc.

8. EXPOSURE CONTROLS/PROTECTIVE EQUIPMENT

Equipment : In case generation of dust is anticipated in the workplace, provide local
ventilation equipment if available.
Control Concentration : Not established
Threshold Limit Value : Data on the product are not available.
Data on each component are as follows:
･OEL (2020): Not established
･ACGIH(2020): Not established
【NOTE】 OEL: Occupational Exposure Limits recommended by
The Japan Society for Occupational Health
Personal Protective Equipment
For respiratory organs : Wear appropriate protective equipment if necessary.
For hands : Wear appropriate protective equipment if necessary.
For eyes : Wear appropriate protective equipment if necessary.
For skin & body : Wear appropriate protective equipment if necessary.
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DKK-TOA CORPORATION
SDS No.: E1079-8
PRODUCT NAME: Powder for pH6.86 Standard Solution

9. PHYSICAL/CHEMICAL PROPERTIES
Physical State
Appearance : Solid (Powder) Odor : None
Color : White pH : －
Particular temperature/temperature range to cause changes in physical state
Melting Point : Potassium Dihydrogenphosphate…252℃
Boiling Point : Potassium Dihydrogenphosphate…Decomposes at 253℃
Disodium Hydrogenphosphate…240℃
Flush Point : No data
Combustion/Explosion Upper Limit and Lower Limit : No data
Vapor pressure : No data
Specific Gravity (Water=1) : No data
Solubility : Water : Potassium Dihydrogenphosphate…18.2% at 20℃
Disodium Hydrogenphosphate…7% at 20℃
: Organic Solvent : Insoluble in Ethanol
Spontaneous Ignition Temp. : No data

10. STABILITY/REACTIVITY
Reactivity
Chemical Stability
Conditions to avoid
Hazardous decomposition
product
: The product may react in contact with oxidizing agent.
: Stable when used under proper conditions.
: Avoid sunlight, heat, oxidizing agent, etc.
: Phosphoric oxides

11. TOXICOLOGICAL INFORMATION

Acute Toxicity(Oral)
Information on the product : Classified as Category 4 based on the estimated LD50 value of the
mixture.
Information on component : Potassium Dihydrogenphosphate…Category 4
Disodium Hydrogenphosphate…Not classified
Skin corrosion/irritation
Information on the product :
Classified as Not classified based on the concentration of the
component of skin corrosion/irritation in the mixture.
Information on component : Potassium Dihydrogenphosphate…Not classified
Disodium Hydrogenphosphate…Not classified
Specific target organ toxicity (Repeated exposure)
Information on the product : Classified as Not classified based on the concentration of the
component of specific target organ toxicity in the mixture.
Information on component : Potassium Dihydrogenphosphate…Not classified
Disodium Hydrogenphosphate…Not classified

12. ECOLOGICAL INFORMATION

Aquatic environment toxicity
Information on the product : No data
Information on component : No data

13. DISPOSAL CONSIDERATIONS

Waste Chemicals : Dissolve the waste chemical in a large amount of water.
Be sure to comply with phosphorus pollution control. Then, discharge
to the drain in accordance with the related laws and regulations.
Or consign the disposal to a hazardous waste disposal firm approved
by the competent authority.
Empty Containers : When disposing of empty containers, thoroughly remove contents and
dispose of in accordance with your national and local regulations.
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DKK-TOA CORPORATION
SDS No.: E1079-8
PRODUCT NAME: Powder for pH6.86 Standard Solution

14. TRANSPORT INFORMATION

Be sure to handle this material in compliance with environmental, safety and health laws and regulations
of your national and local government.
National Regulations
For Ground Transportation : Observe the Road Act.
For Marine Transportation : Observe the Ship Safety Act and Port Regulation Act.
For Air Transportation : Observe the Civil Aeronautics Act.
UN Identification No. : Not applicable
UN Hazard Classification : Not applicable
UN Packing Group : Not applicable
Guide Number for Emergency Response: None
Precautions for Transportation : During transportation of the product, avoid direct sunlight and
ensure that there is no leakage. Avoid dropping, falling and
damaging the container of the material when the material is
loaded onto a truck or the like. Be sure to prevent collapse of
cargo piles.
International Regulations
For Ground Transportation
UN Proper Shipping Name : Not applicable
UN Hazard Classification : Not applicable
UN Subsidiary Risk : Not applicable
UN Identification No. : Not applicable
UN Packing Group : Not applicable
For Marine Transportation
UN Proper Shipping Name Not applicable
UN Hazard Classification : Not applicable
UN Subsidiary Risk : Not applicable
UN Identification No. : Not applicable
UN Packing Group : Not applicable
For Air Transportation
UN Proper Shipping Name : Not applicable
UN Hazard Classification : Not applicable
UN Subsidiary Risk : Not applicable
UN Identification No. : Not applicable
UN Packing Group : Not applicable

15. REGULATORY INFORMATION

Be sure to handle this material in compliance with environmental, safety and health laws and regulations
of your national and local government. In Japan this material is regulated as follows:
The Pollutant Release and Transfer : ・Not applicable
Register Promotion Act (PRTR)
Industrial Safety and Health Act : ・Not applicable
Poisonous and Deleterious Substance : ・Not applicable
Control Act

16. OTHER INFORMATION

References
(1) Chemical Risk Information Platform (CHRIP), National Institute of Technology and Evaluation
(2) ezCRIC, Japan Chemical Database Ltd.
(3) JIS Z7252-2014 and Z7253-2012
(4) Site for Safety in Workplace (Shokuba-no-Anzen Site),Ministry of Health, Labour & Welfare, Japan
Coverage
- The information contained herein is based on data collected from many technical documents and is
considered to be accurate, but is not necessarily inclusive. Due care should be exercised in handling
the material.
- All data herein are intended to provide information but not assured.
- All of the notes are for normal handling. In case of special handling, take safety measures suitable for
the use or application.