Named Aleutians

-
i -
1510911
-

I .

Rei¥on : -

phenols on

CHU, in the presale or

reaction with

NaOH forms Salicylaldehyde

-

go ' 'to

ÉÉ+ + city tzwaoa →

Imad 2-
hydroxy
-

-211-20 benzaldehyde .

Mati -

Kept ;
Formation of neutral elector

+a+ÑÉ,:#
a
'
a-c-
I -11-20 Tri chloro Ghb -

4
eve .

its
step :c , -4
3. o
→ c
IF - at dichldoealbae

electrophile
Neutral

ftp.j-EW-wphihicatlaek-onphnol : -

É¥P→É¥¥%→#¥¥¥
ÉÉFÉ ÷÷¥¥¥ñÉ¥¥¥¥
it
'
- it

Satiny aldehyde -2N au

(2)
Kolbeleaihon phenol on reaction

hydrolysis
the arid
with coz followed by
arid at 180 atm
forms salicylic
zoo
. - .

oooh
/ OH
¥4m
t + us
11-30-1 arid
salicylic

ÑE+ɱss→
"

multi -
10 µ
-1

⑤
g-
2-5
V35

¥¥%±
2-
hydroxy -

benzoic arid
 Ethers [R -

&
.

=
-
R
.
]
→ 9--1×1 F -
is Gnltzntzo
__

and ethers have same

→ Bork alcohols

Mf but differ M FG that's

why grey
exhibits functional im .

enhibits metamerism
→ ethers
.

egqH
-
GHÉO-
-

Gts Ctb -9 -8¥

,
, .

IUPAE Nomenclature : -

IUPA -

Alkoxy Alkene

G. Ht
eg-i-i.cl/-g-cHz
-
-

Ellioxypmyiane Cl
£
city -
OH
,
- É -
É -
CATCH}
'
'
13 4 5

cytzoz
3-
Ebhrtxy 3-
chhnopentameatz
-

,
?⃝
 classification of ethers

Elh①
--

§Yt÷ge ethers
mixed

ethers
/complen
-
'
R -
Q -
R

ey
:-
R -

E -
R
where R -4121
Hohne R=R

eg
:
CHJOGHI
ef CH, o
city
- -

preparation I
-

Italo alkanes on reaction with sodium -

alkoxide forms ethers .

R-&
RaoR -1
-
R
-
1
y
: -
. .

Naa

symmetrical
-

ether
.

while R= at
, ;

2-
GH5-XJ-NORslts-cslts-o-s.lk
Max -
GI city -
É¥- Est Nao at}
→ No

125 ethers
-

city
-

ye
why f- ✗
°

yay CHG c=cHz

¥
-

C. ④
/↳ 191-3
Hats
9TH
3°C -
c
( more stable )
not prepared
Bulky ethers are
N0 D
'

by letting ,30RX .

ethers are prepared by taking

2) Bulky

butoxide.1cH3eoIc_itz-izrt@8-q-cHsCH3Sod.t
30

uhtiahgrbutoaide

d-CH
warm

,
1

&
ab
¥+3
-

methoxy amentpropane
2- -
(2) Forswore : Rx reaction with
-

on

forms ethers
dhy Ago
.

Ñto=A④R → R - o -
R
eg
:

2AyXcaHs@tAy0D-gtBrJG1ts-GHs-o-EHs-2AgBr3.t
-

Alcohols on healing
withContltzsoy
or
Anhy .

Also, at low temp forms

ethers .

GiIII%H5 ¥04 gits E-sits

eg :-.
-

413K
-

HW

GHg-oH#GHg¥h°s 200 -280°C

GHz -0-5*5

properties Iz Hoo
-

: -

-
Celts -

& -
sits
what
hyb
.

is the state tellin'd

.

oxyI
and ÉrboT?
 L↳÷
Sohni Ctb -
CH
,
-

§ -
cha -

011-3

MG
of
the above
comp ?

An Angular/ Bentos hope

→
1090¥
⇐
10€

Comparison 8W
-
alcohols Gethers
CHU -

E -
H CH, -0: -
at
}
→ Ethers are less reactive than alcohols

due to absence
of acidic It -
on

ethereal oxygen
.

have lower BP than choir

→ letters
of due to them douottoniinteemoleudnr
H -

bonds built it felt -

 i l Ethers reaction wilt
-

.
on

cone .

Hd & lone Has oy.

forms
oxonium Salts .

eg :-, r-E.at#i-fr-iEr]
te 4-
Hunted Nucleophile oxiomumsatt .

2. R -
& Rt Hvsoy
.

↳ At ^
-
→ [R -

Ér)¥sog
itsoy Oxonians salt

-Éa±
of ethers with HNoz .

②tm*É at 150ohm
BB Loo -

in pne
.

of

BR-ñ
esters
forms
.

R :O -121 + co
egi
-

-150dm Ester
-

100
1€43 GHS +10 -2341-3-1%-01145
-

-
e -
3 .

Ethers on reaction with acid

acids

alcohols carboxylic
chlorides ; are

forms uditferat
compounds
they
.
¥¥fi

[+%É
eg : -

R-÷%É¥É
u
r -0-12
-

+ NOH

i¥ ✗

Er : -

É
Rio
:-# ab

§¥?→ ?
+
-

2cHz-É-0R-
4 . Ethers on reaction with
pots
forms halo alkanes

' Pels → Rcltrkl

R § +
-
- -
r

tpodg-caltg-o-glts-tpd5-72.CI/tg-4
+ putz .

5) Ekins on
healing with are

in the pine
-

of Ag they forms
enplosiue peroxides
.

eg q°
¥
'
'
R -

E -
R + ¥02 R -
o -
R

CH}
+0
o Gets -1%02 ?→

CHz-o-SHSF%2e-adi-onwik-dil.lt/-audon.Hxi-
- -

Ethers on reaction with

dit HX
they forms alcohols
G
-

halo alkanes .
** *

R - o -
k
' t H → Rxtrbit
"

= dilute
smaller Jaeger
R' 1- Hx → Rlxt Ugo
OH

* **the smaller alkyl group

No
-

forms halo alkanes and the

always
larger alkyl group forms alcohols

eg-i-CHz-0-GHx-HI-CHZIIGH-g-OHG.lt
]- OH + HI → czHzI + Hoo

MI :-, .
R -

f+¥→r-É-r 4)
protonated
'

Ñ É
-

2 .
I -
f- -
N ester
' R I
-
+ NOH
it
3. R'
&_ItE-fRjÉ "

¥ ,
RI
 Ethers on reaction with Cvncitx
eyi
-

Qmobs A Rx at a time
forms
they
-

R -
O -
R 1- ZHI → 2 RI + Hoo
Cone

Exception : -

"
B
i 't
E- sits
g
- -

_①
9-13

G- eÉr*abndmd✓
←
greats
'm
its
city -
c-OH u

L ,+
,
+ GH5I CH
}
É¥ItGHsoH
-

'

É¥ÉH5
city

meets : -

at -

.
, ' '

cleavage
ICH}
e ,+
,
-

g +
÷i±¥7i¥:B
-1¥
"to
Typ-ldeavage-pnodu.it : -

"_o- -4%-04
"

Cltz
d - + Itt → city
'

city CHS

↳ its
- ④ +I
-

→ GHSI
Less stable

Types cleavage product : -

¥_ ICH}
-15
cHz
-

+ I →
f
-

city
- C -10
,
Eltz
Utz
Mile Stable

GH5O° + til → GHSOH

Exception
:-p
at
}
-

§+s
atgottcttz -
CH - CH
}
HI
Major
101T
CH} -

Minor
at -

city -1 CASI
£-2
 is
cleavage
In 20C
Rez : T
- - C
,

more stable than cHz④ .

HI → xty
Y § GHz 1-
CHZ
Cft
-
- -
-

i. .

GHz
here .

what are ✗ q g.

Emi & +Ñ
atz
Yt
- - -

↳ 11-7 f
"

EH at
,
- ¥-6 -

ga ,
at
}
-

+ GHy0H← I
④
↳ Hz 811-7
MM
protonated
T.EE#-Eb-a+-g.H+ II ever
Unstable