Calculations (3)

↳2
only .

.
Typed
1. Find the average Rate of Reaction

total volume of gas ) cms

Average R.o.pe =

( total time taken ) s

=
21
330

's
"
0 073
=
.

cm

Typed
1- Find the average R 0 R
. .
in the first 2 mins .

R.o.rs#-al- volume of gas ) cms

Average
(total time taken ) s

=
16 50.

120
'
=
0.14 cms 5 @ Cms /s
*

2- Find the average R 0 R . .

m the second mins .

Average
c.ms#a1-
R.o.rs#-al- volume of
time taken
gas )

) s

Viso -

V60 ° 08cm
}I
-

J
=
= .

60 #
= 16 5'
- µ pg,

60
 Collision theory

Key: - all particles of reactants must collide to form product R.O.IR

- but not all collision will form product

- only effective collision will form product Into # Factors

@ successive collision
calc .

Condition for effective collision

- Correct orientation of collision

> minimum amount

r
- Energy of reactants > Ea (activation energy) of energy required
in order to
F-
Energy become
product
^ ^

Mp
.

=a
=
800kg
R

Eas 150015
p
R
v

> >
?⃝
Factors affecting Rate of Reactions Size of reactants

Temperature
Catalyst
.

concentration
First factor : Size of reactants
F- xp I F- xp 2 Explain based on collision theory

w w.maeas?m&en&forise
- for powder
total surface area is
larger
i%: than chip .

-
.

°o°
frequency of collision increases .

Chip granules Powder -

frequency of effect, ,
- Rate of reaction is high .

Time (s) 0 30 60 90 120 150 180 210 240 270

Volume of
carbon dioxide 0 8.0 15 20.5 24.5 28 30.5 32.5 32.5 32.5
(cm ), Exp I
Volume of
carbon dioxide 0 4.5 8.5 12 15 17 19 21 29 32.5
(cm ), Exp II

Questions

1. Write equation for the following reaction

Caco, + 2h01 → Caclz 1- cos 1- H2O

2. Plot V vs t graph for both experiment

'
Volume of Goa / om
✗ 11 : powder PR(steeper)

t
"
1 :
chip HR

> Els

3. Find the rate of reaction for both experiment

volume of gas
R O .R=
-
-

total time

= 32.5 IF
I >
51
To
=
an

µ
-

*
4. Compare the answer in question 3.

I > I

5. Explain the difference based on collision theory.

:
*
-

6. Will the final volume for both experiment be the same? Why?

Yes because both experiment

,
using
same quantity of reactants
.