Ecuación virial

' ' 2
Z=1+B P+C P + …
2
Z=1+Bρ +C ρ + …
' B
B=
RT

h
R
=−T ∫
( ∂T )
∂z
dP
P
P
RT 0 P

S
R
=−T ∫
( ∂z
∂T ) dP−∫ z −1 dP
P
P
R

R 0 P 0 P

Pr BP
Z= =1+ =1+B ' P
RT RT

h R P B dB
= −
R T R T dT ( )
R
S −P dB
=
R R dT

hR
=−T ∫
( ∂T )
∂z
ρ
d ρ+ Z−1 ρ
RT 0 ρ

S
R
=ln Z−T ∫
( ∂T )
∂z
ρ
d ρ−∫
z−1
dρ
ρ
ρ

R 0 ρ 0 ρ

Correlaciones generalizadas

B Pc 0 1
=B +ω B
RTc
R Tc 0
B= [ B +ω B1 ]
Pc
Metodo de tsonopoulos

0 0.330 0.1385 0.0121 0.000607 d B0

- B =0.1445− − − −
Tr Tr2 T r3 T r8 d Tr
 1 0. 331 0.423 0.0 08 dB
1
- B =0. 0637+ − −
T r2 T r3 T r8 d Tr

[ ( )]
R 0 1
h 0 dB 1 dB
=Pr B −T r +ω B −T r
RT d Tr dTr

( )
R 0 1
S dB dB
=−P r +ω
R d Tr d Tr