AL/02-S-II(NEW) -1-

kj úIh ks¾foaYh | New Syllabus

ish¨ u ysñlï weúß‚' (All Right Reserved)
wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj - Wð;a wxck fyaupkaø - wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj - Wð;a wxck fyaupkaø - wO
General Certificate of Education (Adv. Level) Examination - Chemistry - Ujith Anjana Hemachandra - General Certificate of Education (Adv. Level) Examination - Chemistry - Ujith Anjana Hemachandra - General Certificate of Educatio
wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - foieïn¾
wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj - Wð;a wxck fyaupkaø - wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj - Wð;a wxck fyaupkaø - wO
NEW
General Certificate of Education (Adv. Level) Examination - Chemistry - Ujith Anjana Hemachandra - General Certificate of Education (Adv. Level) Examination - Chemistry - Ujith Anjana Hemachandra - General Certificate of Educatio
wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj
General - Wð;a wxck
Certificate of fya upkaø - wOHhk
Education fmdÿ iy;s
(Adv. l m;% Examination
Level) ^Wiia fm<& úNd.h -- ridhk úoHdj - Wð;a wxck fyaupkaø - wO
December
General Certificate of Education (Adv. Level) Examination - Chemistry - Ujith Anjana Hemachandra - General Certificate of Education (Adv. Level) Examination - Chemistry - Ujith Anjana Hemachandra - General Certificate of Educatio
wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj - Wð;a wxck fyaupkaø - wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h - ridhk úoHdj - Wð;a wxck fyaupkaø - wO

Battle Field Structure Essay Paper - 11 02 S II

ridhk úoHdj - II meh ;=khs' wu;r lshùï ld,h - ñks;a;= 10

Chemistry - II Three hours Additional Reading Time - 10 min.

* wdj¾;s;d j.=jla imhd we;'

úNd. wxlh (
* .Kl hka;% Ndú;hg bv fokq fkd,efí'
* id¾j;% jdhq ksh;h" R = 8.314 J mol-1 K-1
* wej.dâfrda ksh;h" Na = 6.022 ´ 1023 mol-1
* fuu m%Yak m;%hg ms<s;=re iemhSfï § we,alhs,a ldKav ixlaIsma; wdldrhlska ksrEmKh l< yels h'

H H
WodyrKh ( H C C ldKavh CH3CH2 f,i oelaúh yels h'
H H
A - fldgi $ jHqy.; rpkd
* ish¨u m%Yak j,g fuu m%Yak m;%fha u ms<s;=re imhkak'
* Tfí ms<s;=re tla tla m%Yakhg bv f,i we;s ;ekaj, ,súh hq;= h' fï bv m%udKh ms<s;=re ,sùug
m%udKj;a nj o §¾> ms<s;=re n,dfmdfrd;a;= fkdjk nj o i,lkak'

B - fldgi iy C - fldgi $ rpkd

* tla tla fldgiska m%Yak fol ne.ska f;dard .ksñka m%Yak y;rlg ms<s;=re imhkak' fï i|yd imhkq
,nk lvÞis Ndú; lrkak'
* iïmQ¾K m%Yak m;%hg kshñ; ld,h wjika jQ miq A, B yd C fldgiaj,g ms<s;=re" A fldgi uq,ska
;sfnk mßÈ tla ms<s;=re m;%hla jk fia wuqKd úNd. Yd,dêm;sg ndr fokak'
* m%Yak m;%fhka B iy C fldgia muKla úNd. Yd,dfjka msg;g f.k hd yels h'

mÍCIljrekaf.a m%fhdackh i|yd mu‚'

fldgi m%Yak wxlh ,enQ ,l=Kq

tl;=j
1
b,lalfuka
2
A wl=ßka
3
4
5
B 6 ixfla; wxl

7 W;a;r m;% mÍCIl 1

8 W;a;r m;% mÍCIl 2
C 9 mÍCId lf<a (
10 wëCIKh lf<a (
tl;=j $ Total

Chemistry - Ujith Anjana Hemachandra [fojk msgqj n,kak'

AL/02-S-II(A)(NEW) -2-

A fldgi - jHqy.; rpkd fuu

;Srfha
m%Yak y;rgu fuu m;%fhau ms<s;=re imhkak' ^tla tla m%Yakh i|yd kshñ; ,l=Kq m%udKh 100 ls' lsisjla
fkd ,shkak'

^01&' a). my; i|yka m%Yak wdj¾;s;d j.=fõ fojk yd f;jk wdj¾;fha f.dkqfõ uQ,øjH yd fojk
wdj¾;fha f.dkqfõ uQ,øjH yd iïnkaO fõ' fldgia (i) isg (vi) olajd ms<s;=re ,nd§fï § ,nd §
we;s wjldYfha uQ,øjH ixfla;h ,shkak'
ii). by<u øjdxlh iys; f,dayh y÷kd.kak'

ii). *q,Íka nyqrEmS wdldrhla jk uQ,øjH y÷kd.kak'

iii). by<u fojk whkSlrK Yla;sh iys; uQøjH y÷kd.kak'

iv). wia:dhS Tlafid wï,hla idok uQ,øjH y÷kd.kak'

v). m%n,;ajfhka jeä u yhsv%cka nkaO idok uQ,øjH y÷kd.kak'

vi). —m<uq whkSlrK Yla;sh wdj¾hla Èf.a jeä fõ'˜

by; m5ldYh ms<sfkdmÈk uQ,øjH l=ula o@

b).ii). H2S2O5 wKqj i|yd jvd;a u ms<s.; yels ¨úia ;s;a bß jHqyh w¢kak' tys iels,a, my; olajd we;'

O O H
H O S S O
O

ii). OCN whkh i|yd we¢h yels ¨úia ;s;a-bß jHqyh w¢kak' ^tu whkfha mrudKq jvd;a wia:dhS
¨úia ;s;a-bß jHqyh háka —wia:dhS˜f,i ,shd olajkak'&

iii). my; ¨úia ;s;a-bß jHqyh mokï lrf.k j.=fõ we;s C, S yd N mrudKqj,"
1. mrudKqj jgd VSEPR hq.,
2. mrudKqj jgd bf,lafg%dak hq., cHdñ;sh
3. mrudKqj jgd yevh
4. mrudKqfõ uqyqïlrKh i|yka lrkak'
my; wdldrhg mrudKqj wxlkh lr we;'
H H O H
H C C S 2 N 3 C4 H
1
O O H

C1 S2 N3 C4

I). VSEPR hq.,a

ii). bf,lafg%dak hq.,a .Kk

iii). yevh
iv). uqyqïlrKh

Chemistry - Ujith Anjana Hemachandra [;=kajk msgqj n,kak'

AL/02-S-II(A)(NEW) -3- úNd. wxlh (-
fuu
iv). by; (iii) fldgfiys fok ,o ¨úia ;s;a-bß jHqyfhys my; nkaOk iE§ug iyNd.S jk mrudKq $ ;Srfha
lsisjla
uqyqï ldCIsl y÷kd.kak' fkd ,shkak'
^mrudKq wxlkh (iii) fldgfiys wdldrhg u fõ'&
I). H C1 H C1

II). O S2 O S2

III). C 1 S2 C1 S2

IV). N 3 H N3 1

V). N 3 C4 N3 C4

VI). C 4 H C4 H

v). by; (iii) fldgfia fok ,o ¨úia ;s;a - bß jHqyfha my; i|yka p nkaOk iE§ug iyNd.S jk
mrudKq ldCIsl y÷kd .kak'
^mrudKq wxlkh (iii) fldgfiys wdldrhg u fõ'&
I). C C1 C C1

II). S 2 O S2 O

c).ii). my; mrudKqj, bf,lafg%dak úkHdih ,shd olajkak'

30 Zn

29Cu

N
7

ii). § we;s bf,lafg%dakj, mrudKq ldCIsl úia;r lsÍu i|yd my; j.=j iïmQ¾K lrkak'

n l ml mrudKq ldCIslh
a. Cu2+ ys wjidk
-1
bf,lafg%dakh
b. N ys wjidk
+1
bf,lafg%dakh
c. Zn ys wjidk
bf,lafg%dakh

iii). jryka ;=< olajd we;s .=Kh jeäjk ms<sfj<g my; i|yka oE ilikak'
I). CH3OH, H2O, C6H5OH, C2H5OH ^wdï,sl;dj&

< < <

II). {n = 3, l = 2}, {n = 4, l = 0}, {n = 3, l = 0}, {n = 3, l = 1} ^bf,lafg%dakj, Yla;sh&

< < <

3 2
III). K, P , S , Cl ^whkfhys wrh&

< < <

Chemistry - Ujith Anjana Hemachandra [y;rjk msgqj n,kak'

AL/02-S-II(A)(NEW) -4-
fuu
^02&' a). L, M, R iy T hkq wdj¾;s;d j.=jg wh;a wkqhd; wdka;ßl fkdjk uQ,øjH y;rls' ;Srfha
lsisjla
tajdfha m<uq whkSlrK tka;e,amsh L < R < M < T f,i jeä fõ' tAjdhska ;=kla muKla ldur fkd ,shkak'
WIaK;ajfha § jdhqjk w;r folla muKla nyqrEmS;djh fmkajhs'
ii). L, M, R iy T hk uQ,øjH y÷kd.kak' tAjdfha ksjerÈ ixfla; iy kï ,shd olajkak'
L: M:

R: T:
ii). by; uQ,øjH y;f¾ my; i|yka .=K jeäjk ksjerÈ ms<fj<g ilia lrkak'

I). úoHq;a RK;djh

II). uQ,øjH wjia:dfõ øjdxlh

III). by<u ixhqc;djh

b). A, B, C, D iy E f,i f,an,a lr we;s fmg%§is myl NH4NO2, (NH4)2CO3, Na2SO3, K2S2O3 iy LiNO2
hk ,jKj, >k kso¾Yl fjk fjk u ;nd we;' ^ms<sfj<ska fkdfõ'& tla tla idïm,fha
iaj,amh ne.ska f.k fjk fjk u ;kQl NaOH iy ;kQl HCl ødjK tl;= lrk ,È' ,efnk
ksÍCIK my; j.=fõ mßÈ fõ'
,jkh ;kQl NaOH tl;= lsÍu ;kQl HCl tl;= lsÍu
jdhqjla msg fkdfõ' meyeÈ,s wj¾K wj¾K lgql >kaOhla iys; jdhqjla
A
ødjKhla ,efí' msg fõ' meyeÈ,s ødjKhla ,efí'
lgql .kaOhla iys; jdhqjla msg fõ' wj¾K jdhqjla msg fõ' meyeÈ,s
B
meyeÈ,s ødjKhla ,efí' ødjKhla ,efí'
jdhqjla msg fkdfõ' meyeÈ,s wj¾K lgql .kaOhla iys; jdhqjla
C ødjKhla ,efí' msg fõ' wdú,;djhla iys; wmeyeÈ,s
ødjKhla ,efí'
jdhqjla msg fkdfõ' meyeÈ,s ÿUqre mdg jdhqjla msg fõ' meyeÈ,s
D
ødjKhla ,efí' ødjKhla ,efí'
lgql .kaOhla iys; jdhqjla msgfõ' ÿUqre mdg jdhqjla msg fõ' meyeÈ,s
E
meyeÈ,s ødjKhla ,efí' ødjKhla ,efí'

ii). A isg E olajd fmg%§iS j, we;s ,jkh y÷kd .kak'

A B

C D

ii). B isg E ;kQl NaOH iuÕ isÿjk m%;sl%shd i|yd ;=,s; iólrK ,shkak'

iii). A, B, C, D yd E ;kQl HCl iuÕ isÿjk m%;sl%shd i|yd ;=,s; iólrK ,shkak'

Chemistry - Ujith Anjana Hemachandra [miajk msgqj n,kak'

AL/02-S-II(A)(NEW) -5-
fuu
iv). my; olajd we;s m%;sl%shdj, § msgjk tla tla jdhqj y÷kd.ekSu i|yd iqÿiq ridhksl mßCIKhla ;Srfha
lsisjla
ne.ska ,shkak' fkd ,shkak'
ie'hq' wÞ, ksÍCIKh o i|yka lrkak'
I). A iy ;kQl HCl w;r m%;sl%shdj

II). B iy ;kQl NaOH w;r m%;sl%shdj

III). B iy ;kQl HCl w;r m%;sl%shdj

^03&' a).ii). fudfkdielrhsvhla jk .aÆfldaia (C6H12O6) oaú wjhùlrKfhka vhsielrhsvhla jk fuda,afgdaia

(C12H22O11) iEfoa'
2C6H12O6(s) C12 + H2O(l) ; DHq = + 10 kJ mol-1
c,fha iïu; oyk tka;e,amsh -286 kJ mol-1 iy fuda,afgdaia j, iïu; oyk tka;e,amsh
-5640 kJ mol-1 kï .aÆfldaia j, iïu; oyk tka;e,amsh fidhkak'

ii). hï mqoa.,fhla fuda,aÜ mdkhla ,nd.kS' tu fuda,aÜ mdkh ;=< fuda,afgdaia 85.8 g la mj;S' fuu
fuda,afgdaia by; (i) fldgfiys mßÈ .aÆfldaia njg m;a fõ' .aÆfldaia oyk l%shdj,sfhka ksmojkq
,nk Yla;sfhka 25] la udxYfmaIs l%shdldÍ;ajhg m%fhdackhg .kS' 1 m la weú§fï § udxY fmaYs
l%shdldß;ajhg 100 kg l Yla;shla wjYH fõ kï" fuu fuda,aÜ mdkh ,nd.ekSfuka miq
ksmofjk Yla;s jeh lsÍu i|yd jHdhdu jYfhka mqoa.,fhl= weúÈh hq;= ÿr fldmuK o@
(C = 12, O = 16, H = 1)

b). f*ßla Tlaihsâ WNh.=Œ ixfhda.hla jk w;r th wï, iuÕ my; mßÈ l%shd lrhs'
Fe2O3(s) + 6HCl(aq) 2FeCl3(aq) + 3H2O(l)

Fe2O3(s) HCl(aq) FeCl3(aq) H2O(l)

q -1
DHf (kJ mol ) -825.5 -167.46 -399.5 -285.84
(25oC)
q -1
DSf (kJ mol ) 87.4 55.06 142 96.94
o
(25 C)

Chemistry - Ujith Anjana Hemachandra [yhjk msgqj n,kak'

AL/02-S-II(A)(NEW) -6-
fuu
fuu o;a; weiqßka" ;Srfha
lsisjla
ii). 25 oC § by; m%;sl%shdj i|yd DHq .Kkh lrkak' fkd ,shkak'

ii). by; m%;sl%shdj i|yd DSq .Kkh lrkak'

iii). 25 oC § by; m%;sl%shdj i|yd DGq .Kkh lrkak'

iv). tu.ska 25 oC § by; m%;sl%shdfõ iajhxisoaO;dj mqfrdal:kh lrkak'

^04&' a). A yd B hkq C5H8 wKql iQ;%h jk tlsfkflys iudjhúl ixfhda. folls' A muKla wefudakSh
is,ajkhsfÜ%Ü iuÕ iqÿ wjlafIamhla ,nd foa' ixfhda. fol u laúfkd,Ska j,ska úI lrk ,o
BaSO4 u; ;ekam;a lrk ,o Pd W;afm%arlh we;súg yhsv%ckSlrKh l< úg A j,ska C o B j,ska
D o ,nd fok w;r" C, HBr iuÕ m%;sl%shd l< úg E jeämqr o" F wvqfjka o iEfoa' E iy F ixfhda.
foflka F muKla m%ldY iudjhúl;dj olajhs' D, Br2(CCl4) iuÕ m%;sl%shd lrjd kej; uOHidÍh
KOH iuÕ r;al< úg B ,efí'
ii). E yd F ys jHqy w¢kak'

E F
ii). A, B, C yd D ys jHqy w¢kak'

A B

C D

Chemistry - Ujith Anjana Hemachandra [y;ajk msgqj n,kak'

AL/02-S-II(A)(NEW) -7-
fuu
Hg2 we;súg H2O / H iuÕ A yd B m%;sl%shd lrjQ úg A j,ska G o" B j,ska H o ,efí' ;Srfha
lsisjla
iii). G yd H ys jHqy w¢kak' fkd ,shkak'

G H
iv). by; C yd HBr m%;sl%shdfõ § jeämqr iEfok M,h jk E iE§fï hdka;%Kh ,shkak'

v). E jeämqr iE§ug fya;=j i|yka lrkak'

b). my; ±lafjk m%;sl%shdj, ysia fldgqj i|yd .e<fmk jHqy olajkak'

Range, Ni
ii). C6H6 + 3H2
150 oC

NO2
Conc. HNO3 / Conc. H2SO4
ii).
50 oC

Hg2
iii). C2H2
H / H2O / D

Hg2
iv). CH3COCH3
H / H 2O / D

O
NaOH(aq)
v). CH3 C H D

2, 4 DNP
vi). CH3-COCH3

OH
/ NaOH
vii). C6H5N2 Cl

C6H5OH
viii). CH3MgBr

HBr
ix). CH3 CH CH2 fmfrdlaihsâ
udOHfha

Chemistry - Ujith Anjana Hemachandra [wgjk msgqj n,kak'

AL/02-S-II(A)(NEW) -8-
fuu
;Srfha
lsisjla
fkd ,shkak'

Chemistry - Ujith Anjana Hemachandra