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Battle Field Papers 01 - 10

Yla;s úoHdj .eg`M

Battle Field 01 (5 - b)

01. ;dm ridhksl o;a; lsysmhla fufia h.

øjHh CS2 (g) H2 (g) CH4 (g) H2S (g)

Δl H⦵ / kJ mol-1 88 0 -75 -20
S⦵ / J mol-1 K-1 151 130.6 +86 122

CS2 (g) + 4 H2 (g) → CH4 (g) + 2 H2 S (g) hk m%;sl%shdj i,lkak'

⦵ ⦵ ⦵
i. 25 °C § fï m%;sl%shdj i|yd Δ H , Δ S yd ΔG .Kkh lrkak.
⦵ ⦵
ii. Δ H yd Δ S WIaK;ajfhka iajdhla; kï 650 °C § ΔG fidhkak'
iii. 25 °C § yd 650 °C § fï m%;sl%shdfõ iajhxisoaO;dj idlÉPd lrkak.

Battle Field 02 (5 - b)

02. jdhqf.da,Sh N2 Wmfhda.S lr .ksñka HNO3 ksmoùug fhdacs; m%;sl%shd fY%AKshl m%;sl%shd folla yd Bg wod<
;dm.;sl o;a; my; oelafõ'

θ -1 θ -1 -1
∆H (kJ mol ) ∆S (J K mol )
2 NO(g) + O2(g) 2 NO2(g) -114 -146
NO(g) + NO2(g) N2O3(g) -32 -136

(i) N2O3(g) + ½ O2(g) → 2 NO2(g) ys iïu; tka;e,ams úm¾hdih .Kkh lrkak'

θ
(ii) by; m%;sl%shd i|yd ∆S .Kkh lrkak' tu w.hg wod< ,l=K m%;sl%shdj i|yd tlÕ fõ o hkak fya;=
iys;j i|yka lrkak'
(iii) by; m%;sl%shdfõ iajhxisoaO;dj yd WIAK;ajh w;r iïnkaO;djh meyeos,s lrkak'

Chemistry - Ujith Anjana Hemachandra [fojk msgqj n,kak'

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Battle Field 03 (5 - a)
03. (i) iïu; tka;e,ams úm¾hdi lsysmhla my; olajd we;' tajd i|yd ;=,s; ridhksl iólrK ,shkak'
I. TiCl4(I) ys W;amdok tka;e,amsh = -804 kJ mol-1
II. Cl2(g) ys nkaOk ú>gk tka;e,amsh = 241 kJ mol-1
III. Mg(s) ys W!¾Ojmd;k tka;e,amsh = 167 kJ mol-1
-1
IV. Mg(g) ys m<uq whkSlrk tka;e,amsh = 738 kJ mol
V. Mg(g) ys fojk whkSlrk tka;e,amsh = 1450 kJ mol-1
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VI. MgCl2(s) oe,sia tka;e,amsh = - 2500kJ mol
VII. Cl(g) ys m%:u bf,lafg%dak ,nd.ekSfï tka;e,amsh = - 350 kJ mol-1

(ii) rEghs,a (TiO2) iy ldnka iu. Cl2(g) m%;sl%shdfjka TiCl4(l) ksmojhs' TiCl4(l) Mg iu. m%;sl%shdfjka Ti
f,dayh ksiaidrKh lr .kS'
TiCl4(l) + 2 Mg(s) Ti(s) + 2 MgCl2(s)

by; i|yka tka;e,ams w.hhka Ndú;fhka Ti(s) ujq, tlla ksmoùu i|yd iïu; tka;e,amsh fjkia ùu
.Kkh lrkak.
Battle Field 04 (5 - b)
04. CaCO3(s) ;dm úfhdackh ;dm wjfYdaIl m%;sls%hdjla fõ.
0
fuu ;dm úfhdackh (m%;Hdj¾;) i|yd jk ;dm ridhksl o;a; lsysmhla (27 C oS) my; oelafõ.
CaCO3(s) CaO(s) CO2(g)
-1
ΔHɵ, (kJmol ) -1207 -636 -394
-1 -1
ΔS (Jmol K ) 93 40 213
ΔGɵ = -2.303RT log10K f,i oS we;. (K – iu;=,s;;d ksh;h)
3
mrsudj 10 dm jk oDv n÷kl jk by; iu;=,s; moaO;sfha CO2 ys wdxYsl mSvkh .Kkh lrkak.
Battle Field 05 (5 - b)
05. (i) iïu; ±,sia Yla;sh hkak w¾: olajkak.
(ii) ;dm ridhksl o;a; lSmhla my; mßÈh'
· Ba(g) iïu; W;amdok tka;e,amsh = + 180 kJ mol-1
· I(g) iïu; mrudKql tka;e,amsh = + 106 kJ mol-1
· Ba(g) m%:u yd fojk whkSlrK Yla;s tl;=j = + 1145 kJ mol-1
· Ba2+ (g) ys iïu; ic,k tka;e,amsh = -1309 kJ mol-1
_
· I (g) ys iïu; ic,k tka;e,amsh = -308 kJ mol-1
· I(g) iïu; m%:u bf,lafg%dakSlrK tka;e,amsh = -295 kJ mol-1
· BaI2 (s) iïu; ødjK tka;e,amsh = + 252 kJ mol-1
(1) by; tla tla o;a;hg wod< ridhksl iólrK ,shd olajkak'
(2) by; wjYH o;a; fhdod.ksñka BaI2(s) iïu; W;amdok tka;e,amsh .Kkh lrkak'
(iii) Ba(OH)2 (s) iïu; ødjK tka;e,amsh = -28 kJ mol-1
m%n, wï, yd m%n, NIau w;r m%;sl%shdj isÿù
-1
H2O(l) 1 mol W;amdok tka;e,amsh = -57 kJ mol
-1
BaSO4 (s) wjlafIamK tka;e,amsh = -18 kJ mol
-3 3
Ba(OH)2 (s) 17.1 g H2SO4 (s) 1 mol dm ødjK 500.00 cm ;=< ødjKh l< úg isÿjk WIAK;aj úm¾hdih
fldmuKo@
Chemistry - Ujith Anjana Hemachandra [;=kajk msgqj n,kak'
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Battle Field 08 (5 - b)

06. my; i|yka tka;e,ams úm¾hdihka w¾: olajkak.

(i) iïu; ic,k tka;e,ams úm¾hdih
(ii) c,fha øjKh ùfï iïï; ødjK tka;e,ams úm¾hdih
MBr2(s) hkq iDK whksl ixfhda.hla jk w;r my; i|yka o;a; Ndú;fhka MBr2(s) ys ødjK tka;e,ams
úm¾hdih .Kkh lrkak.
MBr2(s) ys iïu; W;amdok tka;e,ams úm¾hdih -524 kJ mol-1
Br2(l) ys iïu; jdIamSlrK tka;e,ams úm¾hdih +31 kJ mol-1
Br-(g) ys iïu; c,SlrK tka;e,ams úm¾hdih -380 kJ mol-1
M2+(g) ys iïu; c,SlrK tka;e,ams úm¾hdih -1890 kJ mol-1
M(s) ys iïu; mrudKqlrK tka;e,ams úm¾hdih + 148 kJ mol-1
Br- (g) ys iïu; bf,lafg%dak ,nd .ekSfï tka;e,ams úm¾hdih -331 kJ mol-1
Br2(g) ys iïu; nkaOk ú>gk tka;e,ams úm¾hdih +193 kJ mol-1
M(g) ys iïu; m<uq whkSlrK tka;e,ams úm¾hdih +450 kJ mol-1
M+ ys iïu; fojk whkSlrK tka;e,ams úm¾hdih +1200 kJ mol-1

Battle Field 09 (5 - b)

07. my; i|yka tAka;e,ams o;a; i,lkak'

C(s) ys iïu; oyk tka;e,amsh =-393 kJ mol-1
H2(g) ys iïu; oyk tka;e,amsh =-285 kJ mol-1
C6H12(l) ys iïu; W;amdok tka;e,amsh =-156 kJ mol-1
c,fha jdIamSlrK tka;e,amsh =40 kJ mol-1
C6H12jdIamSlrK tka;e,amsh =30 kJ mol-1
(i) by; wjia:djg wod< tka;e,ams iólrK ,shkak'
(ii) C6H12(l) iïu; oyk tka;e,amsh fidhkak'
(iii) O = O, C - C, C – H, C = O yd O – H ys iïu; uOH nkaOk ú>gk tka;e,ams (kJ mol-1 j,ska) ms<sfj,ska 498,
348, 412, 830 yd 464 fõ' pl%Sh C6H12 ys nkaOk ú.gkh i,ld tys iïu; oyk tka;e,amsh fidhkak.
(iv) by; ii yd iii ys Tn ,enQ w.hka w;r fjkig fya;=j meyeÈ,s lrkak'

Battle Field 10 (5 - a)
0
08. 25 C oS my; oelafjk m%;sl%shdj i,lkak'
2NaHCO3(s) → Na2CO3(s) + CO2(g) + H2O(g)
0 o o
25 C oS ΔH f iy S i|yd o;a; my; oS we;'
o -1
ΔH f / kJ mol So/ J K-1 mol-1
NaHCO3(s) -950 102
Na2CO3(s) -1130 136
CO2(g) -394 204
H2O(g) -242 189
(i) 250C oS fuu m%;sl%shdj iajhxisoaO fkdjk nj fmkajkak'
(ii) by; m%;sl%shdj iajhxisoaO ùu i|yd wjYH;djh meyeos,s lrkak'
(iii) m%;sl%shdj iajhxisoaO jk wju WIAK;ajh .Kkh lrkak'
Chemistry - Ujith Anjana Hemachandra [y;rjk msgqj n,kak'
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ld,h ld oukakdf.a wkd.;h ld,h úiska ld oukq ,efí'''

Wð;a wxck fyaupkaø

Chemistry - Ujith Anjana Hemachandra