AL/2022/02/S-II

2022 – Season 2 - Paper 03 (Essay) - Marking Scheme

A fldgi - jHqy.; rpkd

1.
(a)
(i) A – O
B–C
C–N

(ii) O=C−N=O
H

(iii) O=C−N=O ⟷ O=C=N=O ⟷ O−C−N O

H H H

(iv) CH4 < NH3 < H2 O

(v)
(1) sp2 uqyqï ldlaIsl – sp2 uqyï
q ldlaIsl
(2) sp2 uqyqï ldlaIsl – 1s uqyï
q ldlaIsl

(b)
m%%fNaoh cd, iajrEmh m%d:ñl wka;¾l%shd oaú;Sl wka;¾l%shd

 SiO2 úIu mrudKql cd, O%eùh iyixhqc nkaOk -

 CO2 (s) O%eùh wKql oe,si O%eùh iyixhqc nkaOk ,kavka n,

 Na 2 CO3 whksl oe,si whksl nkaOk -

 ue.ak,shï f,dayl nkaOk cd,h f,dayl nkaOk -

(c)
(i) COCl2 < H2 CO3 < CO < CO2
(ii) Al3+ < O2− < N 3− < S 2−
(iii) Al(OH)3 < Mg(OH)2 < Ca(OH)2 < KOH
(iv) NO < NO2− < NO− 3−
3 < NO4

2.
(a)
(i) A – Sb2 S3 R – NO X – SO2
B – HCl I –S Y – Cl2
P – NO2 J – HNO3 Z – H2 S
Q – SO3 H – H2 SO4 T – H2 S2 O7

CHEMISTRY Amila Dasanayake

 AL/2022/02/S-II

(ii) SbCl2 + H2 O SbOCl + 2 HCl

fuys iEfok SbOCl iqÿ meye;s wjlafIamhls.

(iii)
(1) Pb(CH3 COO)2 j,ska f;;a lrk ,o fmryka lvodishla yryd heùu. H2 S heùfïoS fmryka
lvodish l¿ meyehg yef¾.
(2) j¾Kj;a u,a fm;s yryd heùu. SO2 u.ska u,a fm;s úrxckh lrkq ,nk w;r H2 S tfia fkdlrhs.

(iv)
A. ×
B.

(b)
(i) TlaislrKh Cl2 + 2e 2Cl−
TlaisyrKh Cl2 + 12OH − 2ClO−
3 + 10𝑒 + 6H2 O

(ii) 6NaOH + 3Cl2 5NaCl + NaClO2 + 3H2 O

(iii)
[Cl− ] 0.5 moldm−3
I. [ClO−
3] = =
5 5

= 0.1 moldm−3
[Cl− ] 0.5
II. jehjQ [OH − ] = iEÿK ×6= × 6 moldm−3
5 5
= 0.6 moldm−3
∴ [OH − ] = 2 moldm−3 − 0.6 moldm−3
= 1.4 moldm−3
3
III. jehjQ Cl2 ujq, .Kk = iEÿKq Cl− mol .Kk ×
5
3
= 0.5 × 100 × 10−3 ×
5
= 0.3 × 10−1
= 0.03 moldm−3

3.
(a)
(i) 1 – 0.00015 moldm−3
2 – 0.00045 moldm−3
3 – 0.00060 moldm−3

𝑎 b
(ii) R = k [𝐼(𝑎𝑞)
−
] [ClO−
(aq) ] [R = m%;sl%shd Y%S>%;dj]
0.00015 moldm−3 s −1 = k [0.01 moldm−3 ]𝑎 [0.02 moldm−3 ]b 1
0.00045 moldm−3 s −1 = k [0.03 moldm−3 ]𝑎 [0.02 moldm−3 ]b 2
0.0006 moldm−3 s −1 = k [0.01 moldm−3 ]𝑎 [0.08 moldm−3 ]b 3
2⁄ ka, 3 = 3𝑎 3⁄ ka, 4 = 4b 0.00015
1 1 ∴ 1 ka, k = moldm−3
0.0002
𝑎=1 b=1 = 0.75 moldm−3 s −1
(iii)

[ClO−
(aq) ] / moldm
−3

CHEMISTRY Amila Dasanayake

 AL/2022/02/S-II

(b)
(i) I2 + Na 2 S2 O3 2NaI + Na 2 S4 O6
1
∴ iEÿKq I2 mol .Kk = jehjQ Na 2 S2 O3 mol .Kk
2
1
= × 0.1 × 40 × 10−3
2
= 2 × 10−3 mol
n+1
I Cln + nI − I2 + Cl−
2

+n −1 0

I2 mol .Kk
𝑛+1⁄2 n+1 2×10−3
I Cln mol .Kk = ⟶ =
1 2 1×10−3
n+1=4⟶n=3

(ii) I2 + 3Cl2 2 ICl3

4.
(a)
R S
il%Sh úfYaIh m%%Odk M,(h)

COOH COOH

NO2+
NO2 NO2 D
OH OH

CH3
CH3+ fyda

CH3 − Cl AlCl3

CH3 CH3
Br
Br +

OH

H− CH3 CHOHCH2 CH2 COOH

Cl CH3 Cl , CH2 Cl2 , CCl4

,
O O
(b) CH2 = CH2 H−O−S−O−H CH3 − CH O−S−O−H
O O

O − SO2 OH
H2 O
CH3 − CH2 OH + H2 SO4 CH3 − CH2

CHEMISTRY Amila Dasanayake

 AL/2022/02/S-II

CHEMISTRY Amila Dasanayake