ld,h uekúka l<uKdlrKh lrkak. tfia fkdue;s úg ld,h úiska Tnj ld oukq we;.

Daily Essay Program (Tuesday Inorganic)

Marking Scheme

01. f,day legdhk wvx.= ødjKhlg NaOH tl;= lsÍfï§ ÿUqre meye;s wjlafIamhla ,nd foa kï
th ksielju Ag+ whk ødjKhla úh hq;=h.

(i) Ag+(aq) + NaOH(aq) AgOH(s) Ag2O(s) (R)

(iqÿ wia:dhs) (ÿUqre)

tfukau Ag+, HCl iu`. iqÿ meye;s AgCl wjlafIamhla idohs.

(Q)
(ii) Ag+(aq) + HCl(aq) AgCl(s) (iqÿ)

by; wjlafIam folu c,Sh NH3 ;=< ødjH fjñka ødjH ixlS¾Khla idohs.

Ag2O
(ÿUqre)
2NH4OH [Ag(NH3)2]+(aq)(wj¾K)
AgCl
(iqÿ)

(iii)Na2S2O3 iu`. uq,ska iqÿ wjlafIamhla ,eì miqj th l`M meye;s wjlafIamhla njg m;a
jkafka kï th Pb2+ fyda Ag+ whk wvx.= ødjKhla úh hq;=h. kuq;a fmr ksÍlaIK j,g
wkql+, jkafka Ag+ whk hhs.

Ag2S2O3(s) c, úÉfÊokh Ag2S(s) (l`M)

Na2S2O3
Ag+(aq)
(iqÿ)

Na2S2O3
Pb2+(aq) PbS2O3(s) c, úÉfÊokh PbS(s) (l`M)
(iqÿ)
tu ksid ødjKh ;=, wvx.= jkafka Ag+ whkhhs.

B ødjKh Al l=vq iy NaOH iu`. kegùfï § lgql .kaOhla we;s jdhqjla msg jkafka kï o
tu.ska HCl ;ejrE ùÿre l+rla u;ska iqÿ ÿudrhla msg jkafka kïo, tu jdhqj NH3 jk w;r
– –
whk ødjKh ;=< fyda mej;sh hq;=h. kuq;a ;kql HCl fh§fï § NO2 ÿUqre
–
jdhjla msg jkafka kï ,jKh úh hq;=h. kuq;a fuys§ lsisÿ jdhqjla msg fkdfõ
– –
hkafkka woyia jkafka fuu ,jKh njh. tuksid (B) ;=< wka;¾.; jkafka o
+
(A) ;=< wka;¾.; jkafka Ag o fõ. tuksid ,jKh AgNO3 iy KNO3 h.

liqka i`orejka B.Sc. Engineering