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ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj - Tiauka chisxy
q e we.hSï mÍCIKh – 58
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Osman Jayasinghe-Chemistry Osman Jayasinghe
ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj-Tiauka chisxy ridhk úoHdj - Tiauka chisxy
Impression Assessment Test (IAT)
Osman–Jayasinghe-Chemistry
58
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wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2022 foieïn¾

fy;tpg;; nghJj; juhjug; gj;ju (cau; ju)g; ghPl;ir" 2022 bnrk;gu;
General Certificate of Education (Adv. Level) Examination, December 2022
ridhk úoHdj II inr.uq m<d;a wOHdmk fomd¾;fïka;=j
,urhadtpay II 13 fY%aKsh - fojk jdr mÍCIKh - 2022 02 S II
Chemistry II Revision 2022
i¾j;% jdhq ksh;h" R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h" NA = 6.02214 × 1023 mol-1
ma,Ekalaf.a ksh;h = 6.626 × 10-34 J s wdf,dalfha m%fõ.h = 3 × 108 m s-1
B fldgi - rpkd
m%Yak follg muKla ms<s;=re imhkak' ^tla tla m%Yakhg ,l=Kq 15 ne.ska ,efí'&
05' (a) iam¾Y l%ufhka H2SO4 wï, ksIamdokfha mshjrlg wod<j 298K § my; iu;=,s; moaO;shg wod< o;a; lSmhla
my; j.=fõ ±lafõ'
2SO2(g) + O2(g) 2SO3(g)

ixfhda.h Gθf / kJ mol-1 ∆𝐻fθ / kJ mol-1 𝑆fθ / JK-1 mol-1

SO2(g) -300 -297 248
O2(g) 0 0 205
SO3(g) -371 -396 257
(i) 298K by; m%;sl%shdfõ H fidhkak'
(ii) tu WIaK;ajfha § S fidhkak'
(iii) by; (i) yd (ii) ys ms<s;=re weiqßk G fidhkak'
(iv) WIaK;ajh 1000K olajd jeäl<fyd;a by; m%;sl%shdfõ iajhxisoaO;dj ms<sn| woyia olajkak' ^,l=Kq 50&

(b) my; olajd we;af;a m%;sl%shdj isÿjk m%udKhg tfrysj we¢ .síia fhdacH Yla;s a
úp,k m%ia;drhhs'
d b
(i) a yd b ,CIHj,g wod< .síia Yla;Ska bÈßm;a lrkak' e
c
(ii) m%ia;drfha d yd e ,CIHj,g wod< wkql%uKhka i,ld Q yd K weiqfrka
tu ,CIHj, § m%;sl%shdfõ iajhxisoaO;dj ms<sn| woyia olajkak'
(iii) c ,CIHfha § G = 0 f,i .efka' tu ,CIHfha § Q yd K iïnkaO;dj ixY=oaO ixY=oaO
X
bÈßm;alr moaO;sfha iajNdjh ms<sn| woyia olajkak' ^,l=Kq 50& m%;sl%shl m%;sM,

06' (a) (i) my; i|yka m%;sl%shdj isÿjk m<uq ;;amr 15 wjidkfha § HBr(g) ys idkaøKh 0.50 moldm-3 isg
0.455 moldm-3 olajd wvq úh'
2HBr(g) H2(g) + Br2(g)
(I) m%;sl%sh; yd M, wdY%fhka by; ±lajQ m%;sl%shdfõ iS>%;d ,shd olajkak'
(II) m%;sl%shdfõ HBr jehùfï iS>; % djh .Kkh lrkak'
(III) H2 iE§fï iS>%;djh .Kkh lrkak'
(IV) Br2 iE§fï iS>%;djh .Kkh lrkak'
(V) by; m%;sl%shdj isÿ jq Ndckfha mßudj" 0.50 dm3 kï m<uq ;;amr 15 § iEÈ we;s Br2 ujq, m%udKh
fidhkak
(ii) A yd B m%;sls%hl fol w;r m%;sl%shdfjka C kï M,h ,ndfohs'
A(g) + B(g) 2C(g)
A yd B ys wdrïNl idkaøK fjkia lrñka WIaK;aj foll§ by; m%;sl%shdj i|yd ,nd.;a wdrïNl
iS>%;d my; olajd we;'
mÍCIK wdrïNl idkaøKh moldm-3 wdrïNl iS>%;djh mol dm-3 S-1
wxlh A(g) B(g) 300K 320K
1 2.5 × 10-4 3.0 × 10-5 5.0 × 10-4 2.0 × 10-3
2 5.0 × 10-4 6.0 × 10-5 4.0 × 10-3 -
3 1.0 × 10-3 6.0 × 10-5 1.6 × 10-2 -

Chemistry | Osman Jayasinghe fojk msgj

q n,kak'
 -02-

(I) by; m%;sl%shd i|yd iS>%;d kshuh ,shkak'

(II) 300K § A yd B wkqnoaOj m%;sl%shdfõ fm< fidhkak'
(III) 300K § iS>%;d ksh;fha w.h .Kkh lrkak'
(IV) 320K § m%;sl%shd iS>%;djfha fjkiaùu meyeÈ,s lrkak' ^,l=Kq 75&

(b) my; iu;,s; moaO;sh i,lkak'

CO2(g) + H2(g) CO(g) + H2O(g)
0
25 C § moaO;sh .;sl iu;=,s;;djfha mj;sk úg ñY%Kh ;=< CO2 jdhq ujq, 0.01 lao" H2 jdhq ujq, 0.01 la o
CO jdhq ujq, 0.08 la o" H2O jdIam ujq, 0.02 la o we;s nj fidhd .kak ,§'
(i) by; iu;=,s;;d moaO;sh i|yd KC whk iu;=,s;;d ksh; m%ldYkh ,shkak'
(ii) moaO;sfha mßudj V dm 3 kï 250C § KC w.h fidhkak'
(iii) iu;=,s;;djh we;s ù 10s lg miq H2O(g) jdIam 0.06 mol tl;= l< úg moaධ;s‍fha kj QC fidhkak'
(iv) tkhska moaO;sh l=uk ÈYdjlg fhduqfõ±hs i|yka lrkak'
(v) 20 jk ;;amrfha § iu;=,s;;djhg t<öfï § tla tla ix>gl j, ujq, ixLHdj fidhkak'
(vi) wdrïNfha isg CO2(g) yd CO(g) idkaøK úp,kh ld,hg tfrysj m%ia;dr.; lrkak' ^,l=Kq 50&

07' (a) (i) ´kEu c,Sh ødjKhla ;=< H2O(l) H+(aq) + OH-(aq) hk iu;=,s;h mj;S' c,fha whksl .=Ks;h
KW i|yd m%ldYkhla ,shkak'
(ii) ´kEu c,Sh ødjKhla i|yd pH + pOH + pKW nj fmkajkak'
(iii) idkaøKh C o ú>gk ksh;h Kb o jk B kï ÿn, tal wdï,sl NIau ødjKhl pOH w.h i|yd
1 1
pOH = PKb – log10 C ,nd .kak'
2 2
(iv) 250C § idkaøKh 0.1 mol dm-3 jk B kï ÿn, NIau ødjKfha pH w.h .Kkh lrkak' 250C § B ys
Kb = 1.0 × 10-5 mol dm-3, Kw = 1.0 × 10_14 mol2 dm-6
(v) wdrïNl idkaøKh 0.05 moldm-3 jk c,Sh NH3 ødjK 60cm3 la" wdrïNl idkaøKh 0.05 moldm-3 jk
HCl ødjK 40cm3 la iuÕ ñY% l< úg" ,efnk ødjKfha pH w.h fidhkak'
K b (NH 3 ) = 1.0 × 105 moldm-3 ^,l=Kq 75&

(b) A, B iy C hkq 3d f.dkqjg wh;a uQ,øjH ;=kla u.ska idok Tlafid wekdhk ;=kls' tu wekdhk iïnkaOj
§ we;s my; úia;r i,lñka wid we;s m%Yakj,g ms<s;=re imhkak'

ksÍCIK
mÍCIKh
A B C
1' wdï,sl udOHfha § Fe2+(aq) ødjKhla j¾Kh * j¾Kh fjkia fõ' fjkila ke;'
tl;= lsÍu' fjkia fõ'
2' ;kql H2SO4 ìxÿ jYfhka tl;= lsÍu' fjkila ødjKfha j¾Kh * iqÿ wjlafIamhla *
ke;' fjkia jk w;r ,efí'
wjlafIamhla we;s fõ'
3' ;kql NaOH ìxÿ jYfhka tl;= lsÍu' j¾Kh * fjkila isÿ fkdfõ' fjkila isÿ fkd fõ'
fjkia fõ'
4' NdIañl udOHfha § H2O2 tl;= lsÍu fjkila j¾Kj;a wjlafIamhla fjkila ke;'
ke;' we;s fõ' *

(i) A, B iy C Tlafid wekdhk tajdfha j¾K iuÕska y÷kdf.k ,shkak'

(ii) 1" 2" 3 iy 4 u.ska fok ,o mÍCIdj, § —*˜ fhdod we;s wjia:djkays ,.efnk ksÍCIK i|yd jk
ridhksl m%;sls%hd i|yd ;=,s; whksl iólrK ,shkak'
(iii) m<uq mÍCIdfjka miq A whkfhka ,efnk d f.dkqfõ f,day legdhkh" Cl- iy NH3 hk nkaO ldKav
iuÕ ix.; wxlh 6 jk mßÈ iy ix.; f.da,fha wdfrdamKh Y=kH" +1 iy +2 jk mßÈ ms<sfj<ska P, Q
iy R hk ixlS¾K whk ;=kla idohs' P, Q iy R ys jHqy fokak'
(iv) P ys IUPAC kduh ,shkak' ^,l=Kq 75&

C fldgi - rpkd
m%Yak follg muKla ms<s;=re imhkak' ^tla tla m%Yakhg ,l=Kq 15 ne.ska ,efí'&

08' (a) tlu ldnksl ixfhda.h f,i

O
C – O – CH2 – CH – CH3 Ndú;d lrñka P ixfhda.h ixYaf,aIKh lsÍu iïnkaO m%;sls%hd
wkql%uhla my; § we;'
C2H5

Chemistry | Osman Jayasinghe f;jk msgqj n,kak'

 -03-

A, B, C, D, E, F iy G hk ixfhda.j, jHqy w¢ñka yd R1 yd R2 f,i y÷kajd we;s iqÿiq m%;sldrl § we;s

m%;sldrl ,ehsia;=fjka muKla f;dard ,shñka fuu m%;sl%shd wkql%uh iïmQ¾K lrkak'

COOCH2 – CH – CH3
C2H5 m%;sldrl ,ehsia;=j (
R1
NaOH(aq), idkaø H2SO4,
PCl3, H+/KMnO4, LiAlH4,
A B idkaø HNO3, ;kql H2SO4
A
R2
R5
C
R3 F
D
R6
R4
E G
B
O A
^,l=Kq 60&
P – CH2 – O – C – CH – CH3
NO2 C2H5

(b) (i) tlu m%;sldrl l=,lh muKla fhdod .ksñka mshjr 3 g fkdjeä mshjr .Kklska my; i|yka
mßj¾;k isÿ lrkafka flfiao@
(I) benzene m – bromobenzoic acid
(II) benzene p – bromobenzoic acid ^,l=Kq 40&

(c) CH3CH = CH2 hk ixfhda.h HBr iuÕ isÿ lrk m%;sl%shdj i,lkak'
(i) fuys§ iEfok m%Odk M,fha yd iq¿;r M,fha jHqyh ,shkak'
(ii) tfia M, folla iE§ug fya;=j l=ulao@
(iii) m%Odk M,h iE§ug wod< hdka;%Kh ,shkak' ^,l=Kq 50&

09' (a) legdhk folla yd wekdhk folla wvx.= c,Sh ødjKhl tu whk y÷kd.ekSu i|yd isÿ lrk ,o mÍCIK yd
,nd.;a ksÍCIK iïnkaO .e,Sï igykla my; ±lafõ'

c,Sh ødjKh

;kql HCl fh§u NaOH(aq) fh§u

fmÍu

(A) iqÿ wjlafIamh fmrkh jdhqjla ksoyia fkdfõ ødjKh (P)

;kql NH3 fh§u ;kql NH4OH fhdod Al l=vq oud
H2S(g) nqnq,kh r;a lsÍu
(D) wjlafIamh Èhúh
Q jdhqj msgfõ'
(B) l¿ wjlafIamh fmrkh
kegùu Pb(NO3) ødjKh
idkaø HNO3
tl;= lsÍu

fld< meye;s ødjKh (C) ly wjlafIamh

jeämqr ;kql NH3
kegùu
ødjKh fh§u

(E) ks,a ødjKh (F) wj¾K ødjKh

Chemistry | Osman Jayasinghe isõjk msgqj n,kak'

 -04-

(i) ñY%Kfha wvx.= legdhk fol yd wekdhk fol y÷kd.kak'

(ii) A, B yd C wjlafIam y÷kd.kak'
(iii) D iy E ys iEfok ixlS¾K whkj, iQ;% ,shd IUPAC l%uhg kï lrkak'
(iv) F wj¾K ødjKh isis,a l< úg l=ula ksÍCIKh l< yelso@
(v) P ødjKfhka Q jdhqj ksoyia ùug wod< ;=,s; whksl $ ridhksl iólrKh ,shkak' ^,l=Kq 75&

(b) FeC2O4, FeCl3 iy ksIal%Sh øjHhla wvx.= >k ñY%Khl FeC2O4 iy FeCl3 ialkaO m%;sY;h fiùu i|yd my;
i|yka l%shd ms<sfj< wkq.ukh lrk ,§'
>k ksheÈfhka 8g la ;kql H2SO4 ys Èhlr mßudñ;sl ma,dial=jlg oud 250cm3 jk f;la wdi%e; c,h
tl;= lr B ødjKh idok ,§'
1 ls%hdj,sh (- B ødjKfhka 25cm3 la wkqudmk ma,dial=jlg f.k thg ;kql H2SO4 20cm3 la tl;= lr
ødjKh 600C g muK r;alr KMnO4 ødjKh iuÕ wkqudmkh lrk ,§' wka; ,CIHfha § ìhqfrÜgq
mdGdxlh 30.00 cm3 ls'
2 ls%hdj,sh ( by; ^1& ys Ndú; l< KMnO4 ødjKj ìhqfrÜgqfjys ;nd 0.1 moldm-3 FeSO4 ødjKhl
25cm3 la iuÕ wdï,sl udOHfha § wkqudmkh lrk ,§' túg jeh jQ KMNO4 mßudj 20.00 cm3 ls'
3 ls%hdj,sh ( B ødjKfhka 25cm3 lg jeämqr KI ødjKhla tl;= lr" ksoyia jk I2, 0.05 mol dm-3 jq
Na2S2O3 ødjKhla iuÕ o¾Ylh fi msIagh fhdod wkqudmkh lrk ,§'
túg jeh jQ 0.05 mol dm-3 Na2S2O3 mßudj 28.00cm3 la úh'
^jeo.;a ( ksIal%Sh øjH fyda FeC2O4, KI iuÕ m%;sl%shd fkdlrk nj i,lkak'
wkqudmkfha § Cl- u.ska we;sjk n,mEï fkdi,ld yßkak'

(i) wod< ish¨u m%;sl%shd i|yd ;=,s; whksl $ ridhksl iólrK ,shkak'
(ii) ñY%Kfha FeC2O4 iy FeCl3 ialkaO m%;sY; .Kkh lrkak'
(iii) ^1& yd ^2& ys isÿl< wkqudmk j,§ wka; ,CIHfha § isÿjk j¾K úm¾hdi fjk fjk u iyka lrkak'
^Fe = 56, Cl = 35.5, O = 16, C = 12) ^,l=Kq 75&

10' (a) iam¾Y l%uh hgf;a ld¾ñlj H2SO4 wï,h ksmoùu i,lkak'
(i) by; ksmoùug wjYH wuqøjH i|yka lrkak'
(ii) by; wï,h ksmoùug wjYH m%;sl%shd wkqms<sfj< ,shkak'
(iii) by; wï,h ksmoùfï § Ndú;d jk fN!;sl uQ,O¾u i|yka lrkak'
(iv) H2SO4 wï,h my; ±lafjk wjia:d ksrEmKh lsÍug WodyrKhla fokak'
^1& Tlaisydrlhla f,i
^2& úc,ldrlhla f,i
(v) H2SO4 wï,h ksmojk ld¾ñl fmfoil my; ±lafjk ia:dkj, isÿúh yels wys;lr n,mEula
i|yka lrkak'
^1& jdhqf.da,h
^2& c,f.da,h
^3& Ys,df.da,h ^,l=Kq 70&

(b) ld¾ñlj NH3 ksmoùfï fyan¾ l%uh i,lkak

(i) ksIamdokhg wjYh wuqøjH ,nd.kafka flfiao@
(ii) ksIamdokhg wod< fN!;sl ridhk uQ,O¾u olajkak'
(iii) NH3 j, m%fhdack 2 la i|yka lrkak' ^,l=Kq 45&

(c) mßir ¥IKh wju lsÍu i|yd fmdis, bkaOk Ndú;h wju lsÍug fhdackd lr we;' fmdis, bkaOk
oykhg wod<j my; wid we;s m%Yakj,g ms<s;=re imhkak'
(i) Yajik wdndO we;s lrk ¥Il 2 la kï lrkak'
(ii) yß;d.dr jdhqjla kï lrkak'
(iii) wï,jeis i|yd wjYH jk jdhq 2 la
(iv) O3 ia:rhg ydks muqKqjk jdhqjla olajd Bg wod< iólrK ,shkak'
(v) jeämqr fudag¾ r: ;onoh mj;sk m%foaYj, weia ±ú,a,g fya;=jk PAN we;s fõ' wod< ;;a;aj
iys;j m%;sl%shd ,shkak'
(vi) fmdis, bkaOk oykfha § mßir ¥IKh wju lsÍu i|yd iqÿiq l%shdud¾. fhdackd lrkak'
^,l=Kq 35&

Chemistry | Osman Jayasinghe