“Boost your film performance with Omyacarb ®

and Omyalite ® products

“让Omyacarb ®和Omyalite ®的产品来大力提升
您的薄膜性能”
您的薄膜性能”

Andy Liew
Regional Sales & Bus Development Manager – Polymers

04/11/2012
Table of Contents

- Introduction to Omya
欧米亚的介绍
- The different Calcium Carbonate should be your
preferred choice ?
不同的碳酸钙应该是你的首选？
不同的碳酸钙应该是你的首选？
- Advancements in : 进展在
Films 薄膜
Raffia 编织袋
Breathable Film 透气膜
Open discussion
公开讨论·
公开讨论

2
Key Facts & Figures
• Corporate head office in Oftringen,
Switzerland
总部在瑞士的Oftringen
总部在瑞士的
• Over 6000 employees
全球 6000 位雇员
• More than 100 plants in over 50 countries
全球在 个国家超过 100间
全球在50个国家超过 间 生产基地
• Group sales 2009: over EUR 2,5 billion
销售额 25 亿欧元 （2009）
销售额: ）
• Ownership of mineral deposits for the next
100 years of business
拥有100年
拥有 年 碳酸钙的储存量
• Most plants are ISO 9001 / ISO 14001
certified
多数工厂 ISO 9001 / ISO 14001 certified 认证
多数工厂
• Pioneer in ISO 14001 for quarries
是矿山获得ISO
是矿山获得 14001 认证的先驱
• In business for over 125 years
经营超过125
经营超过 年
• 4th Generation privately held Swiss based
Corporation
第四代私人经营管理层
3
04.11.2012
 Omya : Our Global Coverage

4
Omya Asia Pacific Region
OMYA Asia Pacific in Brief
欧米亚亚太区简介
 Territory of 25 countries
遍布 25 个国家
 Regional Head Office in Kuala Lumpur,
OmyaJapan Malaysia
Tokyo
亚太区总部在马来西亚的吉隆坡
 28 plant locations
28间工厂
间工厂
Omya Changxing Plant  13 slurry manufacturing lines
 20 dry powder manufacturing lines
Omya Philipines Plant
 1 PCC plant for paper making
 19 quarries locations
19个矿区
个矿区
 Exclusive technology and marketing partner
in Japan
在日本的独家技术和营销合作伙伴
 10 joint ventures
10个合资公司
个合资公司
 2 distribution company in Philippines &
Indonesia
两间分销公司在菲律宾和印尼

5
6
 MOST IMPORTANT MINERAL PROPERTIES

最重要的矿物特性

• Chemical composition 化学成分

• Impurities present 杂质
• Aspect Ratio = Shape 长宽比
长宽比=形状 形状
• Fineness 细度
•Specific Surface Area 表比面积
•Surface Energy = Surface Tension 表面能量=表面张力
表面能量 表面张力
• Hardness 硬度

7
 MOST IMPORTANT MINERAL PROPERTIES

最重要的矿物特性

• Colour 颜色
• Top Cut = Coarsest Particles 最大粒径 = 粗粒子
• Refractive index 折射率
• Surface Treatment 表面处理
•Thermal properties 热性能。
热性能。
• Density 密度
• Abrasivity 耐磨性

8
 CaCO3-powder: most important properties 最重要特质
Surface treatment: Purity:
Ground CaCO3-Marble
表面处理 纯洁度

Composition
Color
成分 颜色

Suface coverage
Metal-free
表面包覆 无金属

Surface tension
Insolubles
表面张力 无不溶解物

Particle Size Distribution

Particle size:
Wt-% finer than

粒径大小

Particle size distribution
粒径分布

Top cut
最大粒径

Median particle size
Particle size (µm) 粒径中位数

9
 ASPECT RATIO
高宽比

10
 MINERAL CHOICES
矿产可供选择

Sphere Cube Block Flake Fibre

1 Approx 1 1.4-4 5-100 >10

Glass Spheres CaCO3 SiO2 Mica Glass

Silicate Spheres Feldspar BaSO4 Talc Asbestos
Clay Wollastonite
Graphite Organics
AI(OH)3 Carbon
Whiskers

11
 PROPERTIES FROM ASPECT RATIOS
高宽比带来的属性

 FIBRES 纤维状
 Increase : tensile strength, stiffness. 增加拉伸强度，刚性
 Decrease : 3D shrinkage 降低3D收缩

 PLATELETS 板状
 Increase : stiffness 增加刚性
 Decrease : tensile strength, impact strength, 3D shrinkage
降低 拉伸强度，冲击强度， 3D收缩

 SPHERES 球面
 Increase : stiffness (medium), impact strength (PE, PPH)
 增加刚性（中程度），冲击强度（聚乙烯，聚丙烯）
Decrease : tensile strength, 3D shrinkage
12 降低 拉伸强度， 3D收缩
 PARTICLE
SIZE
粒径大下

13
 PARTICLE SIZE, TOP CUT, MEAN & DISTRIBUTION
粒径大小，
粒径大小，最大粒径，
最大粒径，中位数和分布
• ALL HAVE AN EFFECT ON MECHANICAL PROPERTIES
全部都会影响物理性质

• TOP CUT = PARTICLE SIZE AT 98% 最大粒径 = 粒径在98%

- a measure of the coarser particles 测试粗粒子

• COARSE ARE STRESS CONCENTRATORS 粗颗粒应力集中

- can limit impact strength 影响冲击强度
-higher Wear & Abrasion 更高的磨损和损耗

•FINES AFFECT RHEOLOGY & SURFACE FINISH

细影响流变性能和表面光洁度
-high fines give high surface area 高细度提高比表面积

•SPECIFIC SURFACE AREA 比较面积

•High value will reduce compounding efficiency 越高会减少造粒效能
14
 Particle Size Distribution Curve
粒径分布
Wt % Finer Than
100

90
Narrow
80 Distribution

70 Broad
Distribution
60

50

40

30

20

10

0
10 5 Microns 2 1
15
 THERMAL
PROPERTIES
热性能

16
 Thermal Properties Of CaCO3
碳酸钙的热性能

Calcium Carbonate has a higher thermal conductivity over 5 times

than Polyethylene and Polypropylene.Therefore, the heat transfer
coefficient changes.
碳酸钙具有较高的热传导性，超过聚乙烯和聚丙烯5倍以上。以因此，其传
热系数的会变化。

Higher thermal conductivity ensures that as the CaCO3 level

increases, the temperature becomes more uniform more quickly.
在更高的导热性特性下，碳酸钙添加量增加后，温度变得更均匀更迅速

This increases the rate of cooling and can improve production rates.
这增加了冷却速率，
这增加了冷却速率，并能提高生产率

17
 Thermal Properties Of Thermoplastics & Mineral Fillers
热塑性塑料的热性能和矿物填料

Material Thermal Conductivity Specific Heat

(W/K'm) (kJ/kgK')
LDPE 0.32-0.40 2.1-2.5
HDPE 0.38-0.51 2.1-2.7
PP 0.17-0.23 1.6-2.0
PS, ABS 0.18 1.3
Rigid PVC 0.14-0.17 0.85-0.90
Nylon 0.23-0.29 1.6-2.0
Polycarbonate 0.21 1.2

CaCO3 2.4-3.0 0.86

Talc 2.1 0.86
Clay 1.9 0.92
Mica 2.5 0.86

PP 0.23 1.68
PP + 20% CaCO3 0.42 1.47
PP + 40% CaCO3 0.56 1.34

18
 Productivity
Enhancement
生产率的提升

19
 产能的提升

Volume Output Improvement

20% mineral level
40% mineral level
2
Output in cm3 /rev.

1.5

1
Virgin PPH Carbonate fine Carbonate medium

20
 降低螺杆压力和扭矩

Reduced Extruder Pressure and Torque

115 pressure 25D 60

110 torque 50
pressure in bar

105

torque in Nm
40
100
30
95
20
90

85 10

80 0

virgin PPH carbonate non carbonate

treated treated

21
 CaCO3 Reduces Cooling Time
碳酸钙让冷却时间减少
Cooling Time (%)
100

90

80

70

60

50

40
0 5 10 15 20 25 30
Carbonate phr
LDPE HDPE PP

22
Why using treated CaCO3 in your process ?
为何选择表面处理的碳酸钙

Increases Hydrophobicity 增加疏水性

Decreases Surface Energy 降低表面能
Better Dispersion 更好的分散
Better Compoundability 更好的造粒
Reduction in Stabilizers & Lubricants 减少稳定剂和润滑剂
Better Surface Finish 更好的表面光滑性

23
 Films
薄膜
24
Film weight vs. thickness when adding Omyafilm®

添加Omyafilm
添加 ® 后，薄膜厚度和重量对比

By adding Omyafilm® the density of the film increases, i.e. to keep a constant film weight,
the film gauge has to be reduced:
添加Omyafilm® 后，薄膜密度会增加。例如，维持薄膜的重量不变，薄膜的厚度会减少:
1.16 50

Thickness of film (micron)

Density of film (kg/dm3)

1.12 48

1.08 46

1.04 44

1 42

0.96 40

0.92 38
30% Omyafilm -content
®
0% 5% 10% 15% 20% 25%

100% PE +15% Omyafilm

Example: 46g/m2 @ 50µm 46g/m2 @ 45µm
(ρfilm: 0.92 kg/dm3) (ρfilm: 1.02 kg/dm3)

25
Description of the study 该研究的说明

Production of 5 blown films with the “Dr. Collin Lab. Line”

使用“Dr. Collin Lab. Line”的吹膜机准备了五种样品
• Reference参考样品: 33% LDPE + 67% C4-LLDPE
• 10% Omyafilm®: 30% LDPE + 55% C4-LLDPE + 15% MB
• 20% Omyafilm®: 27% LDPE + 45% C4&C6-LLDPE + 28% MB
• 25% Omyafilm®: 25% LDPE + 39% C6-LLDPE + 36% MB
• 30% Omyafilm®: 23% LDPE + 34% C6-LLDPE + 43% MB
Remarks

“Reference” is related to a typical carrier bag formulation
“参考样品” 一个典型的购物袋配方

All films were produced at constant weight (43g/m2)
所有薄膜的制作是以固定的重量 (43g/m2)

LDPE/LLDPE ratio was kept constant in all formulations
所有的配方，LDPE/LLDPE ratio的比例保持不变
26
Description of the study (2) 该研究的说明(2)
该研究的说明

Dr. Collin laboratory line

 Circular Die: Ø 60 mm
 Die gap: 1.2 mm
 Single Screw: Ø 30 mm
 Screw Length: 30 L/D

Processing conditions
 Temperature profile:
 BUR:
 Frost line height:
 Lay-flat width:
170°– 205°– 215°– 215°- …. - 215°C
2.2
2.5 x die-diameter (i.e. 150 mm)
220mm

27
Film performance
Most important mechanical properties for bags 包装袋的最重要物理性能
 Film weight (or film thickness) 薄膜重量（薄膜重量（或薄膜厚度） 或薄膜厚度）
 end user’s perception of “heavy film” when “touching” it
终端用户当触摸的时候重薄膜的感觉
 Yield strength 降伏强度
 significant for end use 终端用户的重要要求
 Elmendorf tear propagation resistance 抗撕裂强度 抗撕裂强度
 to avoid bag tearing in case of “slit”
以避免在“裂缝“的情况撕裂
 E-modulus 弹性模量参数E值
弹性模量参数 值
 stiffness is important for stacking and printing process
刚度是在堆积和印刷过程中是重要指数
Dart drop impact resistance 落镖冲击试验
 sometimes a requirement 有些时候是一种必要规定
 Sealing force 热封能力
 important for both: confectioning process and end use
对两方面很重要: 成型 和 终端用途

28
Film performance 薄膜的性能

Film weight (g/m2):薄膜重量 (g/m2):

50

43.6 43.8
45 42.8 42.6
Grammage (g/m2)

41.6
40

35

30
Reference 10% OF 20% OF 25% OF 30% OF
 Films were produced at the same weight (grammage), i.e. the
film gauge was adjusted to the Omyafilm® content
薄膜是同样的重量（克重）情况下作出 , 比如，
薄膜是同样的重量（克重） 比如，薄膜的厚度会因Omyafilm
薄膜的厚度会因 ® 含量而调整

29
Film performance 薄膜的性能

Yield force 屈服力 ISO 527-3

9

8.5
8
8
Yield force (N)

8 7.8
7.4
7.5
7.4 7.3 7.3
MD
7.1 CD
6.9
7
6.5
6.5

6
Reference 10% OF 20% OF 25% OF 30% OF

 All 3 formulations with high Omyafilm® -content are okay

3个含有Omyafilm®的配方全部都还不错
30
Film performance 薄膜的性能

Elmendorf tear propagation resistance 抗撕裂强度 ISO 6383

600
Elmendorf tear resistance (cN)

503 778 962 1165

500
419
400

MD
300
212 CD
187
200 156 151 163

100

0
Reference 10% OF 20% OF 25% OF 30% OF

 MD: All formulations containing Omyafilm® are okay

MD: 含有Omyafilm® 配方的强度不错
 CD: Dramatic increase for all formulations containing Omyafilm®
31 CD: 含有Omyafilm® 配方的强度明显的改善了很多。
Film performance 薄膜的性能

E-modulus, i.e. secant 0.02-2% 弹性系数 ISO 527-3

600
550 502
498
500 449
E-modulus (N/mm2)

450 430
405
400 369
MD
350
266276 CD
300 243260
250
200
150
100
Reference 10% OF 20% OF 25% OF 30% OF

 Increase for all formulations containing Omyafilm®

添加Omyafilm®后，挺性有很大的改善
32
Film performance 薄膜的性能

Dart drop impact resistance抗落锤冲击能力 ASTM D 1709 A

225
200
200 182 192 189
176
Falling dart (g)

175

150

125

100
Reference 10% OF 20% OF 25% OF 30% OF

 Higher for all film formulations containing Omyafilm®

Omyafilm® 添加越高，能力也提高
33
Film performance 薄膜的性能

Sealing force (at 70 N, 2 sec)热封能力

Internal method* 内部的测设方法*
15

12.5
Sealing force (N)

10 Reference
10% OF
7.5 20% OF
25% OF
5 30% OF
2.5

0
120 130 140 150
Temperature of bars (°C)

 No significant variations for formulations containing Omyafilm®

对于含有Omyafilm®的配方，没有明显的变化
*: sealing equipment Kopp, lowest pressure set-up, film width of 15mm
34
Line output rate 生产线的产能
Extruder output rate (Collin teach line) at 100 rpm:
挤出机 (Collin teach line)， 在 100 rpm的产能:
3.5
3.25
3.25 3.02
Extruder out-put (kg/h)

3
2.75
2.75 2.55
2.39
2.5
2.25
2
1.75
1.5
Reference 10% OF 20% OF 25% OF 30% OF

 The extruder output rate increases with increasing Omyafilm® level

Omyafilm® 添加量越多，挤出机的产能更加提升
35
Variation of formulation cost (general) 配方成本的变化（
配方成本的变化（一般）
一般）

The use of Omyafilm® reduces the raw material cost (at

constant film grammage):
使用Omyafilm® 可以降低原材料 (在同样的定量下)
1400 14%

1200 12%

Reduction of cost (%)

Raw material cost for
bags (Euro/MT)

1000 10%

800 8.9% 9.1% 8%

8.4% 8.7%
7.8% 8.1%
7.4%
600 6.5%
7.0% 6%
6.1%
5.5%
400 4.9% 4%
4.1%
200 2%

0 0%
700 750 800 850 900 950 1000 1050 1100 1150 1200 1250 1300
Price of PE (euro/ton)

Reference Film with 15% Omyafilm Cost reduction (%)

、 With increasing polymer prices, the savings become more significant
塑料的价格越高，节约成本约更加明显
36
Summary 总结

Benefits of formulations containing Omyafilm® 、

含Omyafilm®配方的优点

higher output rate 较高的生产率

perception of same film thickness @ reduced gauge降低膜厚

better Elmendorf tear propagation resistance Elmendorf抗撕裂强度

better dart drop impact resistance 落镖冲击性好

constant yield tensile force 恒定屈服拉伸力

higher E-modulus 弹性模量参数E值

lower raw material costs 原材料成本下降

Others additional benefits

其他的优点

lower melt pressure 较低的熔体压力

lower extruder torque 较低挤出机扭矩

faster bubble cooling 泡沫冷却速度更快

no film blocking 无膜间合膜
37
Conclusion 总结

Why do numerous bag-producers add Omyafilm®

into their film formulations?
为什么许多袋生产商加入Omyafilm®到他们的薄
为什么许多袋生产商加入 到他们的薄
膜配方？
膜配方？

Higher productivity
更高的生产力
Excellent mechanical properties
优良的物理性质
优良的物理性质
Substantial lower raw material costs
原材料成本大幅降低
☺☺☺☺ ☺☺☺☺☺
38
CaCO3 in PP Woven Tapes 碳酸钙在PP编织带
碳酸钙在 编织带的应用
编织带的应用

Calcium carbonate is conventionally used in PE or PP

woven bags, weaving tapes or bands to offer anti-
splitting and anti-fibrillation effects.
碳酸钙是习惯上使用在聚乙烯或聚丙烯编织袋，在编织
带过程中，提供反分裂反颤动的效果
Polyolefin masterbatches based on appropriate
calcium carbonate offer:
含有适当的碳酸钙添加量的填充母粒基础上提供:
含有适当的碳酸钙添加量的填充母粒基础上提供
Reduced splitting propensity of oriented polypropylene
减少定向聚丙烯的拆分倾向
Increased stiffness
刚度增加
Reduced amount of titanium dioxide
减少二氧化钛的使用量
Reduced raw material consumption
减少原材料使用量
Conventional calcium carbonate loadings are in a range of 2% to 30% in final
articles.
39 传统的碳酸钙添加量，
传统的碳酸钙添加量，在于2％ 在于 ％至30％ ％的范围内。
的范围内。
CaCO3 in PP Woven tapes 碳酸钙在PP编织带
碳酸钙在 编织带的应用
编织带的应用

 Advantages of using Omyacarb® 2T in PP woven tapes :

在编织带使用 Omyacarb® 2T的好处 :

 Achieve high filler loading in Masterbatches

达到更高填充的填充母粒
 Optimized mineral dispersion ( Low FPV)
最优化分散性能（低FPV）
 Prevent using waxes and lubricants which reduces WCO and Die build up
防止使用蜡和润滑油从而降低WCO及模头积料
 Low humidity level in masterbatches
降低含水率
Reduce WCO
减少WCO
 Increase life time for knives and increased screen pack change overtime
随着时间增加刀具寿命和延长滤网更换时间
 Reduces dust accumulation ( spinning and knitting)
减少尘埃积聚（纺纱，针织）
40
CaCO3 in PP Woven tapes : Higher requirements 更高要求

 For high speed line or high demanding applications, Omyacarb® 1 T is the

optimum solution :
对于高速的生产线或者高要求的用途，Omyacarb® 1 T 是最佳的解决方案：

 Appropriate surface treatment to avoid Die build up during processing

and dust accumulation
良好的表面处理可以在生产过程中减少模头积料和减少尘埃积聚
 Lower WCO : Speed could be increased
低WCO : 可以提高生产速度
 Increased elongation @ break compare to coarser grades. Improves post-
weaving operation and production efficiency.
和较粗碳酸钙相比，可以增加 伸长率
 Improve knitting process less yarn breakage
改善后编织操作和生产效率
 Increase tensile strength thus enabling higher filler loading
改善编织过程时的断裂情况
 Higher tape surface smoothness
提高编织的表面光滑
41
Cost Savings 降低成本

5.5

5.0

4.5

4.0

g/D

3.5

3.0

2.5

2.0
7% Dosage 15% Dosage 22% Dosage 30% Dosage

Omyacarb 1T Omyacarb 2T Coarse Competitive

Finer product could allow you to increase final

content for same properties (+3%)
更细的产品可以让你增加填充量并且保留物理性能

42
Cost Savings 成本节约

Omyacarb 1 T Omyacarb 2 T
Compounding Costs 50
Formulation PE 2000
Omyacarb 1T USD + 30 / Ton
Omyacarb 2T
Masterbatch @ 80% OM 2T 562
Masterbatch @ 78% OM 1T 623

Tapes with 22 % Omyacarb 2T 28% 1614

Tapes with 25 % Omyacarb 1T 32% 1559

43
 BREATHABLE FILMS
透气膜
44
04.11.2012
 新一代产品 New generation : Omyafilm® 753-OM

Constant Quality 稳定的品质

Processability on Compounding Line 优秀的加工性能

Down – gauging 降低膜厚

Higher Speed on Processing Line 适合高速生产线

Excellent Particle Size Control 特出的粒径分布的控制

Superior Treatment Patented Technology Low Wear 已获得专利的出色表面处理技术-低耗损

已获得专利的出色表面处理技术 低耗损

Excellent thermal stability : Low volatile Content 优秀的稳定性：

优秀的稳定性：低挥发物质

Extremely low moisture Content and moisture pick-up 低水分含量和吸水性

45
 Omyafilm® 753-OM - Brightness Measurement 色相

Omyafilm 753-OM is based on a very white marble that features quite high
brightness for breathable films, especially for hygiene films
来自超白的云石，
来自超白的云石，适合用于卫生薄膜的透气膜
Brightness

100

90

94 93.3 94.1
80

70
Omyafilm 753 - OM Competitive Product Omyafilm 780 LR

46
Marketing
Plastic
 Grade Comparison - Particle distribution 粒径分布

Specific Surface Area

m ²/g 4.7
3.9 4.1

0
Omyafilm 753 - OM Competitve Product Omyafilm 780 LR

Sieve Residue @ 20 Microns

Omyafilm 753 allies low median particle size
and low SSA giving good compounding 120
processability providing film down-gauging
100
potential
Omyafilm 753因有较低的粒径和比较面积
因有较低的粒径和比较面积，
因有较低的粒径和比较面积，具有更 80
优秀的造粒能力和能降低膜厚的潜能
60
100
Omyafilm 753 showed a low level of oversized 40
90
particles reducing the risk of film breakage or 50
hole formation. 20

Omyafilm 753具有较低的大粒径
具有较低的大粒径，
具有较低的大粒径，能减少断膜或者有 0
孔的现象 Omyafilm 753 - OM Competitive Product Omyafilm 780 LR
Grade Comparison - Moisture & Moisture Pick-up

规格比较 – 含水率和吸水率
Omyafilm® 753 – OM protects Equipment 保护螺杆

The new patented treatment prevents wear

and corrosion on equipment and ancillaries.
新专利的
专利的表面处理几乎，
表面处理几乎，防止对设备
防止对设备和
对设备和辅助设备
的磨损和
磨损和腐蚀
• State of the screw after 4 years Omyafilm’s
utilisation
• 使用Omyafilm
使用 四年后螺杆的状态

49
 Product 产品介绍

Omyafilm 707
Omyacarb 1T
Omyalite 75T D 50% : 1.7
D 98% : 8
Brightness > 94 %

Omyafilm 720
Omyacarb 2T D 50%: 2.7
Omyalite 60T
D 98% : 14
Brightness > 94 %

50
Product 产品介绍

精选石灰石生产的、具有良好分散性、表面改性处理的超细碳酸钙粉末

中国工厂
林口
规格： Omyacarb 1T IK / Omycarb 2T IK
规格：
南京
规格： Omyacarb 1T IK / Omycarb 2T IK
规格：
长兴
规格： Omyalite 60T JI / Omyalite 75T JI
规格：

51
 Thank You
谢谢

www.omya.com

52