Chemistry The Central Science 14th Edition Brown Test Bank Download

Solution Manual for Chemistry The Central Science 14th
Edition by Brown LeMay Bursten Murphy Woodward

Stoltzfus ISBN 0134292812 9780134292816
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Chemistry: The Central Science, 14e (Brown, et al.)
Chapter 6 Electronic Structure of Atoms
6.1 Multiple-Choice Questions
1) Which one of the following is correct?

A) ν + λ = c
B) ν ÷ λ = c
C) ν = cλ
D) λ = c ν
E) νλ = c
Answer: E
Diff: 1 Var: 1 Page Ref: Sec. 6.1
LO: 6.1
GO: G2
2) Of the following, ________ radiation has the shortest wavelength.

A) X-ray
B) radio
C) microwave
D) ultraviolet
E) infrared
Answer: A
LO: 6.2
GO: G2
3) The photoelectric effect is ________.

A) the total reflection of light by metals giving them their typical luster
B) the production of current by silicon solar cells when exposed to sunlight
C) the ejection of electrons by a metal when struck with light of sufficient energy
1
Copyright © 2018 Pearson Education, Inc.
D) the darkening of photographic film when exposed to an electric field
E) a relativistic effect
Answer: C
LO: 6.3
GO: G2
2
4) Which one of the following is considered to be ionizing radiation?
A) visible light
B) radio waves
C) X-rays
D) microwaves
E) infrared radiation
Answer: C
LO: 6.2
GO: G2
5) Of the following transitions in the Bohr hydrogen atom, the ________ transition results in the
emission of the lowest-energy photon.
A) n = 1 → n = 6
B) n = 6 → n = 1
C) n = 6 → n = 3
D) n = 3 → n = 6
E) n = 1 → n = 4
Answer: C
LO: 6.4
GO: G2
6) In the Bohr model of the atom, ________.

A) electrons travel in circular paths called orbitals
B) electrons can have any energy
C) electron energies are quantized
D) electron paths are controlled by probability
E) both A and C
Answer: C
LO: 6.4
GO: G2
7) According to the Heisenberg Uncertainty Principle, it is impossible to know precisely both the
position and the ________ of an electron.
A) mass
B) color
C) momentum
D) shape
E) charge
Answer: C
LO: 6.6
GO: G2
3
8) All of the orbitals in a given electron shell have the same value as the ________ quantum
number.
A) principal
B) angular momentum
C) magnetic
D) spin
E) psi
Answer: A
LO: 6.6
GO: G2
9) The de Broglie wavelength of a ________ will have the shortest wavelength when traveling at
30 cm/s.
A) marble
B) car
C) planet
D) uranium atom
E) hydrogen atom
Answer: C
LO: 6.5
GO: G2
10) The uncertainty principle states that ________.

A) matter and energy are really the same thing
B) it is impossible to know anything with certainty
C) it is impossible to know the exact position and momentum of an electron
D) there can only be one uncertain digit in a reported number
E) it is impossible to know how many electrons there are in an atom
Answer: C
LO: 6.6
GO: G2
11) All of the orbitals in a given subshell have the same value as the ________ quantum number.
A) principal
B) spin
C) magnetic
D) A and B
E) B and C
Answer: A
LO: 6.7
GO: G2
4
12) Which one of the following is not a valid value for the magnetic quantum number of an
electron in a 5d subshell?
A) 2
B) 3
C) 0
D) 1
E) -1
Answer: B
LO: 6.7
GO: G2
13) Which of the subshells below do not exist due to the constraints upon the angular momentum
quantum number?
A) 2d
B) 2s
C) 2p
D) all of the above
E) none of the above
Answer: A
LO: 6.7
GO: G2
14) Which of the subshells below do not exist due to the constraints upon the angular momentum
quantum number?
A) 4f
B) 4d
C) 4p
D) 4s
Answer: E
LO: 6.7
GO: G2
15) An electron cannot have the quantum numbers n = ________, l = ________, ml = ________.
A) 2, 0, 0
B) 2, 1, -1
C) 3, 1, -1
D) 1, 1, 1
E) 3, 2, 1
Answer: D
LO: 6.7
GO: G2
5
16) An electron cannot have the quantum numbers n = ________, l = ________, ml = ________.
A) 6, 1, 0
B) 3, 2, 3
C) 3, 2, -2
D) 1, 0, 0
E) 3, 2, 1
Answer: B
LO: 6.7
GO: G2
17) Which one of the following is an incorrect subshell notation?

A) 4f
B) 2d
C) 3s
D) 2p
E) 3d
Answer: B
LO: 6.7
GO: G2
18) Which one of the following is an incorrect orbital notation?

A) 2s
B) 3py
C) 3f
D) 4dxy
E) 4s
Answer: C
LO: 6.7
GO: G2
19) Which quantum number determines the energy of an electron in a hydrogen atom?
A) n
B) E
C) ml
D) l
E) n and l
Answer: A
LO: 6.7
GO: G2
6
20) All of the following are a result from the solution of the Schrodinger equation except
________.
A) spin
B) principal
C) azimuthal
D) magnetic
E) angular momentum
Answer: A
LO: 6.7
GO: G2
21) Which quantum numbers must be the same for the orbitals that they designate to be
degenerate in a one-electron system (such as hydrogen)?
A) n, l, and ml
B) n and l only
C) l and ml
D) ml only
E) n only
Answer: E
LO: 6.8
GO: G2
22) In a px orbital, the subscript x denotes the ________.

A) energy of the electron
B) spin of the electrons
C) probability of the shell
D) size of the orbital
E) axis along which the orbital is aligned
Answer: E
LO: 6.8
GO: G2
23) A 4pz orbital in a many-electron atom is degenerate with ________.

A) 5s
B) 3pz
C) 4dxy
D) 4px
E) 4d2
Answer: D
LO: 6.8
GO: G2
7
24) Which one of the following orbitals can hold two electrons?
A) 2px
B) 3s
C) 4dxy
D) all of the above
Answer: D
LO: 6.8
GO: G2
25) Which of the quantum number(s) below represent the principal quantum number?
A) n, l, and ml
B) n only
C) n, l, ml, and ms
D) ms only
E) n and l only
Answer: B
LO: 6.9
GO: G2
26) Which of the following is not a valid set of four quantum numbers? (n, l, ml, ms)
A) 2, 0, 0, +1/2
B) 2, 1, 0, -1/2
C) 3, 1, -1, -1/2
D) 1, 0, 0, +1/2
E) 1, 1, 0, +1/2
Answer: E
LO: 6.9
GO: G2
27) Which of the following is a valid set of four quantum numbers? (n, l, ml, ms)
A) 2, 1, 0, +1/2
B) 2, 2, 1, -1/2
C) 1, 0, 1, +1/2
D) 2, 1, +2, +1/2
E) 1, 1, 0, -1/2
Answer: A
LO: 6.9
GO: G2
8
28) Which electron configuration represents a violation of the Pauli exclusion principle?
A)
B)
C)
D)
E)
Answer: C
LO: 6.10
GO: G2
9
29) Which electron configuration represents a violation of the Pauli exclusion principle?
A)
B)
C)
D)
E)
Answer: B
LO: 6.10
GO: G2
10
30) Which electron orbital diagram represents a violation of the Aufbau principle?
A)
B)
C)
D)
E)
Answer: A
LO: 6.10
GO: G2
11
31) Which one of the following is the correct electron configuration for a ground-state nitrogen
atom?
A)
B)
C)
D)
E) None of the above is correct.

Answer: D
LO: 6.10
GO: G2
12
32) Which electron configuration denotes an atom in its ground state?
A)
B)
C)
D)
E)
Answer: D
LO: 6.10
GO: G2
33) The ground state electron configuration of Ga is ________.

A) 1s22s23s23p64s23d104p1
B) 1s22s22p63s23p64s24d104p1
C) 1s22s22p63s23p64s23d104p1
D) 1s22s22p63s23p64s23d104d1
E) [Ar]4s23d11
Answer: C
LO: 6.10
GO: G2
13
34) The ground-state electron configuration of the element ________ is [Kr]5s14d5.
A) Nb
B) Mo
C) Cr
D) Mn
E) Tc
Answer: B
LO: 6.11
GO: G2
35) The ground-state electron configuration of ________ is [Ar]4s13d5.

A) V
B) Mn
C) Fe
D) Cr
E) K
Answer: D
LO: 6.11
GO: G2
36) Which is the correct electron configuration for a nitrogen atom?

A) 1s22s22p2
B) 1s22s22p1
C) 1s22s22p4
D) 1s22s22p3
E) [He]2s22p5
Answer: D
LO: 6.10
GO: G2
37) Which is the correct electron configuration for an oxide ion?

A) 1s22s22p3
B) 1s22s22p1
C) 1s22s22p6
D) 1s22s23s2
E) 1s22s22p2
Answer: C
LO: 6.10
GO: G2
14
38) Which electron configuration represents a violation of Hund's rule for an atom in its ground
state?
A)
B)
C)
D)
E)
Answer: C
LO: 6.10
GO: G2
15
39) Which electron configuration represents a violation of Hund's rule for an atom in its ground
state?
A)
B)
C)
D)
E)
Answer: B
LO: 6.10
GO: G2
16
40) Which electron orbital diagram is written correctly for an atom without any violations?
A)
B)
C)
D)
E)
Answer: E
LO: 6.10
GO: G2
41) The ground-state configuration of fluorine is ________.

A) [He]2s22p2
B) [He]2s22p3
C) [He]2s22p4
D) [He]2s22p5
E) [He]2s22p6
Answer: D
LO: 6.11
GO: G2
17
42) The ground-state configuration of tungsten is ________.
A) [Ar]4s23d3
B) [Xe]6s24f145d4
C) [Ne]3s1
D) [Xe]6s24f7
E) [Kr]5s24d105p5
Answer: B
LO: 6.11
GO: G2
43) No two electrons within the same orbtial can have the same set of quantum numbers. This
statement describes ________.
A) Planck's constant
B) Heisenberg Uncertainty Principle
C) Pauli Exclusion Principle
D) deBroglie hypothesis
E) Hund's rule
Answer: C
LO: 6.10
GO: G2
44) Which of the following elements has a ground-state electron configuration different from the
predicted one?
A) Cu
B) Ca
C) Xe
D) Cl
E) Ti
Answer: A
LO: 6.10
GO: G2
45) Which two elements have the same ground-state electron configuration?
A) Pd and Pt
B) Cu and Ag
C) Fe and Cu
D) Cl and Ar
E) No two elements have the same ground-state electron configuration.
Answer: E
LO: 6.10
GO: G2
18
46) How many different principal quantum numbers can be found in the ground-state electron
configuration of nickel?
A) 2
B) 3
C) 4
D) 5
E) 6
Answer: C
LO: 6.11
GO: G2
47) The valence shell of the element X contains 2 electrons in a 5s subshell. Below that shell,
element X has a partially filled 4d subshell. What type of element is X?
A) main group element
B) chalcogen
C) halogen
D) transition metal
E) alkali metal
Answer: D
LO: 6.11
GO: G2
6.2 Bimodal Questions
1) Electromagnetic radiation travels through vacuum at a speed of ________ m/s.

A) 186,000
B) 125
C) 3.00 × 108
D) 10,000
E) It depends on wavelength.
Answer: C
LO: 6.1
GO: G4
2) The wavelength of light that has a frequency of 1.20 × 1013 s-1 is ________ m.
A) 25.0
B) 2.50 × 10-5
C) 0.0400
D) 12.0
E) 2.5
Answer: B
LO: 6.1
GO: G4
19
3) The wavelength of light that has a frequency of 1.66 × 109 s-1 is ________ m.
A) 0.181
B) 5.53
C) 2.00 × 10-9
D) 5.53 × 108
Answer: A
LO: 6.1
GO: G4
4) Ham radio operators often broadcast on the 6-meter band. The frequency of this
electromagnetic radiation is ________ MHz.
A) 500
B) 200
C) 50
D) 20
E) 2.0
Answer: C
LO: 6.1
GO: G4
5) Visible light with a wavelength of 550 nm has a frequency of ________ Hz.

A) 5.5 × 105
B) 1.7 × 1011
C) 5.5 × 1014
D) 1.7 × 102
E) 5.5 × 1017
Answer: C
LO: 6.1
GO: G4
6) What is the frequency (s-1) of electromagnetic radiation that has a wavelength of 2.3 m?
A) 1.3 × 108 s-1
B) 1.8 × 10-9 s-1
C) 1.6 × 108 s-1
D) 1.3 × 10-33 s-1
E) 1.3 × 1033 s-1
Answer: A
LO: 6.1
GO: G4
20
7) What is the frequency of light (s-1) that has a wavelength of 1.23 × 10-6 cm?
A) 3.69
B) 2.44 × 1016 s-1
C) 4.10 × 10-17 s-1
D) 9.62 × 1012 s-1
E) 1.04 × 10-13 s-1
Answer: B
LO: 6.1
GO: G4
A) 7.77 × 1014 s-1
B) 6.32 × 10-12 s-1
C) 1.04 × 10-13 s-1
D) 9.62 × 1012 s-1
E) 2.14 × 10-16 s-1
Answer: A
LO: 6.1
GO: G4
A) 3.69 s-1
B) 2.44 × 1016 s-1
C) 9.62 × 1012 s-1
D) 4.10 × 10-17 s-1
E) 1.04 × 10-13 s-1
Answer: C
LO: 6.1
GO: G4
10) What is the wavelength of light (nm) that has a frequency of 3.22 × 1014 s-1?
A) 932 nm
B) 649 nm
C) 9.66 × 1022 nm
D) 9.32 × 10-7 nm
E) 1.07 × 106 nm
Answer: A
LO: 6.1
GO: G4
21
11) What is the wavelength of light (nm) that has a frequency of 6.44 × 1013 s-1?
A) 4660 nm
B) 6490 nm
C) 4.66 × 10-8 nm
D) 6.49 × 10-8 nm
E) 932 nm
Answer: A
LO: 6.1
GO: G4
12) What is the wavelength of light (nm) that has a frequency 4.62 × 1014 s-1?
A) 932 nm
B) 649 nm
C) 1.39 × 1023 nm
D) 1.54 × 10-3 nm
E) 1.07 × 106 nm
Answer: B
LO: 6.1
GO: G4
13) The wavelength of a photon that has an energy of 6.33 × 10-18 J is ________ m.
A) 3.79 × 10-7
B) 3.10 × 10-8
C) 2.38 × 1023
D) 4.21 × 10-24
E) 9.55 × 1015
Answer: B
LO: 6.3
GO: G4
14) The energy of a photon of light is ________ proportional to its frequency and ________
proportional to its wavelength.
A) directly, directly
B) inversely, inversely
C) inversely, directly
D) directly, inversely
E) indirectly, not
Answer: D
LO: 6.3
GO: G4
22
15) The wavelength of a photon that has an energy of 5.25 × 10-19 J is ________ m.
A) 3.79 × 10-7
B) 2.64 × 106
C) 2.38 × 1023
D) 4.21 × 10-24
E) 3.79 × 107
Answer: A
LO: 6.3
GO: G4
16) The energy of a photon that has a wavelength of 9.0 m is ________ J.

A) 2.2 × 10-26
B) 4.5 × 1025
C) 6.0 × 10-23
D) 2.7 × 109
E) 4.5 × 10-25
Answer: A
LO: 6.3
GO: G4
17) The energy of a photon that has a wavelength of 8.33 × 10-6 m is ________ J.
A) 2.20 × 10-26
B) 3.60 × 1013
C) 2.39 × 10-20
D) 2.7 × 109
E) 4.5 × 10-25
Answer: C
LO: 6.3
GO: G4
18) The frequency of a photon that has an energy of 3.7 × 10-18 J is ________ s-1.
A) 5.6 × 1015
B) 1.8 × 10-16
C) 2.5 × 10-15
D) 5.4 × 10-8
E) 2.5 × 1015
Answer: A
LO: 6.3
GO: G4
23
19) The frequency of a photon that has an energy of 8.5 × 10-12 J is ________ s-1.
A) 1.3 × 1022
B) 1.8 × 10-16
C) 2.5 × 10-15
D) 5.4 × 10-8
E) 2.5 × 1015
Answer: A
LO: 6.3
GO: G4
20) What is the energy of a photon (J) that has a wavelength of 105 nm?
A) 1.89 × 10-13
B) 1.89 × 10-32
C) 1.89 × 10-18
D) 1.89 × 10-36
E) 1.89 × 10-27
Answer: C
LO: 6.3
GO: G4
21) The energy of a photon that has a wavelength of 13.2 nm is ________ J.

A) 9.55 × 10-25
B) 1.62 × 10-17
C) 1.99 × 10-25
D) 4.42 × 10-23
E) 1.51 × 10-17
Answer: E
LO: 6.3
GO: G4
22) What is the energy of a photon (J) that has a frequency of 4.39 × 1019 Hz?
A) 2.91 × 10-14
B) 2.91 × 1020
C) 6.83 × 10-12
D) 2.91 × 10-52
E) 2.91 × 1054
Answer: A
LO: 6.3
GO: G4
24
23) The energy of a photon that has a frequency of 1.821 × 1016 s-1 is ________ J.
A) 5.44 × 10-18
B) 1.99 × 10-25
C) 3.49 × 10-48
D) 1.21 × 10-17
E) 5.46 × 10-24
Answer: D
LO: 6.3
GO: G4
24) What is the frequency (s-1) of a photon that has an energy of 4.38 × 10-18 J?
A) 436 s-1
B) 6.61 × 1015 s-1
C) 1.45 × 10-16 s-1
D) 2.30 × 107 s-1
E) 1.31 × 10-9 s-1
Answer: B
LO: 6.3
GO: G4
25) What is the wavelength (angstroms) of a photon that has an energy of 4.38 × 10-18 J?
A) 45.4 angstroms
B) 2.30 × 107 angstroms
C) 6.89 × 1015 angstroms
D) 1.45 × 10-16 angstroms
E) 1.31 × 10-9 angstroms
Answer: A
LO: 6.3
GO: G4
26) A photon that has an energy of 8.63 × 10-12 J would emit light at which wavelength (m)?
A) 230
B) 2.30 × 10-14
C) 2.30
D) 3.48 × 1019
E) 2.30 × 10-5
Answer: B
LO: 6.3
GO: G4
25
27) A mole of red photons of wavelength 725 nm has ________ kJ of energy.
A) 2.74 × 10-19
B) 4.56 × 10-46
C) 6.05 × 10-3
D) 165
E) 227
Answer: D
LO: 6.3
GO: G4
28) A mole of yellow photons of wavelength 527 nm has ________ kJ of energy.

A) 165
B) 227
C) 4.56 × 10-46
D) 6.05 × 10-3
E) 2.74 × 10-19
Answer: B
LO: 6.3
GO: G4
29) Of the following, ________ radiation has the longest wavelength and ________ radiation has
the greatest energy.
gamma ultraviolet visible
A) ultraviolet, gamma
B) visible, ultraviolet
C) gamma, gamma
D) visible, gamma
E) gamma, visible
Answer: D
LO: 6.2
GO: G2
30) What color of visible light has the longest wavelength?

A) blue
B) violet
C) red
D) yellow
E) green
Answer: C
LO: 6.2
GO: G2
26
31) Which of the following radiation sources from the electromagnetic spectrum has the shortest
wavelength and greatest energy?
A) radio
B) microwave
C) gamma
D) visible
E) ultraviolet
Answer: C
LO: 6.2
GO: G2
32) What color of visible light has the highest energy?

A) violet
B) blue
C) red
D) green
E) yellow
Answer: A
LO: 6.2
GO: G2
33) Using Bohr's equation for the energy levels of the electron in the hydrogen atom, determine
the of an electron in the n = 4 level.
A) -1.36 × 10-19
B) -5.45 × 10-19
C) -7.34 × 1018
D) -1.84 × 10-29
E) +1.84 × 10-29
Answer: A
LO: 6.4
GO: G4
34) An electron in a Bohr hydrogen atom with a n = 4 value would have an energy of ________.
A) 1.362 × 10-19 J
B) -1.362 × 10-16 J
C) -1.362 × 1019 J
D) 1.362 × 1019 J
E) -1.362 × 10-19 J
Answer: E
LO: 6.4
GO: G4
27
35) The energy (J) required for an electronic transition in a Bohr hydrogen atom from n = 2 to n
= 3 is ________ J.
A) 4.00 × 10-19
B) 3.00 × 10-19
C) -3.00 × 10-19
D) -7.90 × 10-19
E) 4.60 × 1014
Answer: B
LO: 6.4
GO: G4
36) The energy (J) required for an electronic transition in a Bohr hydrogen atom from n = 1 to n
= 3 is ________ J.
A) -8.90 × 10-1
B) 3.00 × 10-19
C) -3.00 × 10-19
D) 1.94 × 10-18
E) 8.90 × 10-1
Answer: D
LO: 6.4
GO: G4
37) An electron transition from n = 2 to n = 5 in a Bohr hydrogen atom would correspond to the
following energy.
A) 4.9 × 10-19 J
B) 4.9 × 1019 J
C) -4.9 × 10-19 J
D) -4.9 × 1019 J
E) 4.9 × 10-16 J
Answer: A
LO: 6.4
GO: G4
28
38) The frequency of electromagnetic radiation required to promote an electron from n = 2 to n =
4 in a Bohr hydrogen atom is ________ Hz.
A) 4.13 × 10-19
B) 6.17 × 1014
C) 5.46 × 10-19
D) 8.22 × 1014
E) 4.13 × 1019
Answer: B
LO: 6.4
GO: G4
39) A spectrum containing only ________ wavelengths is called a line spectrum.

A) Rydberg
B) specific
C) continuous
D) visible
E) invariant
Answer: B
LO: 6.4
GO: G4
40) When the electron in a hydrogen atom moves from n = 6 to n = 1, light with a wavelength of
________ nm is emitted.
A) 487
B) 411
C) 434
D) 93.8
E) 657
Answer: D
LO: 6.4
GO: G4
41) What is the wavelength (nm) of light emitted when an electron in a hydrogen atom moves
from n = 4 to n = 2?
A) -486
B) 2.06 × 1015
C) 486
D) 2.06 × 106
E) 4.86 × 10-7
Answer: C
LO: 6.4
GO: G4
29
42) The n = 2 to n = 6 transition in the Bohr hydrogen atom corresponds to the ________ of a
photon with a wavelength of ________ nm.
A) emission, 410
B) absorption, 410
C) absorption, 660
D) emission, 94
E) emission, 390
Answer: B
LO: 6.4
GO: G4
43) The n = 5 to n = 3 transition in the Bohr hydrogen atom corresponds to the ________ of a
photon with a wavelength of ________ nm.
A) absorption, 657
B) absorption, 1280
C) emission, 657
D) emission, 1280
E) emission, 389
Answer: D
LO: 6.4
GO: G4
44) A transition in the Bohr hydrogen atom from n = 4 to n = 2 occurs in the ________ region of
the electromagnetic spectrum.
A) infrared
B) microwave
C) ultraviolet
D) visible
E) X-ray
Answer: D
LO: 6.4
GO: G4
30
45) A transition in the Bohr hydrogen atom from n = 6 to n = 1 occurs in the ________ region of
the electromagnetic spectrum.
A) radio
B) ultraviolet
C) infrared
D) X-ray
E) microwave
Answer: B
LO: 6.4
GO: G4
46) The de Broglie wavelength of a particle is given by ________.

A) h + mv
B) hmv
C) h/mv
D) mv/c
E) mv
Answer: C
LO: 6.5
GO: G4
47) What is the de Broglie wavelength (m) of a 2.0-kg object moving at a speed of 50 m/s?
A) 6.6 × 10-36 m
B) 1.5 × 1035 m
C) 5.3 × 10-33 m
D) 2.6 × 10-35 m
E) 3.8 × 1034 m
Answer: A
LO: 6.5
GO: G4
48) A 934 g object is traveling at a velocity of 35.0 m/s. What is the de Broglie wavelength of
this object?
A) 2.03 × 10-38 m
B) 2.03 × 10-32 m
C) 2.03 × 1033 m
D) 2.03 × 10-35 m
E) 2.03 × 1036 m
Answer: D
LO: 6.5
GO: G4
31
49) A 13 kg object is traveling at a velocity of 12.0 m/s. What is the de Broglie wavelength of
this object?
A) 4.25 × 10-36 m
B) 4.25 × 1037 m
C) 4.25 × 1034 m
D) 4.25 × 10-39 m
E) 4.25 × 10-33 m
Answer: A
LO: 6.5
GO: G4
50) At what speed (m/s) must a 10.0-mg object be moving to have a de Broglie wavelength of
3.3 × 10-41 m?
A) 4.1 m/s
B) 1.9 × 10-11 m/s
C) 2.0 × 1012 m/s
D) 3.3 × 10-42 m/s
E) 1.9 × 1013 m/s
Answer: C
LO: 6.5
GO: G4
51) A 34.0 mg object with a de Broglie wavelength of is traveling at what speed?

A) 8.12 × 10-7 m/s
B) 2.76 × 10-14 m/s
C) 2.76 × 10-11 m/s
D) 8.12 × 10-10 m/s
E) 8.12 × 10-13 m/s
Answer: A
LO: 6.5
GO: G4
32
52) The de Broglie wavelength of an electron is 8.7 × 10-11 m. The mass of an electron is 9.1 ×
10-31 kg. The velocity of this electron is ________ m/s.
A) 8.4 × 103
B) 1.2 × 10-7
C) 6.9 × 10-5
D) 8.4 × 106
E) 8.4 × 10-3
Answer: D
LO: 6.5
GO: G4
53) What is the de Broglie wavelength (m) of a 1.0 × 109 kg train car traveling at 95 km/hr?
A) 2.51 × 10-41
B) 2.51 × 10-47
C) 6.97 × 10-45
D) 2.51 × 10-44
E) 6.97 × 10-48
Answer: D
LO: 6.5
GO: G4
54) What is the de Broglie wavelength (m) of a 1.00 × 103 kg race car traveling at 145 mi/hr?
A) 1.02 × 10-41
B) 1.02 × 10-35
C) 1.02 × 10-38
D) 4.57 × 10-39
E) 4.57 × 10-42
Answer: C
LO: 6.5
GO: G4
33
55) The wavelength of an electron whose velocity is 1.7 × 104 m/s and whose mass is 9.1 × 10-
28 g is ________ m.
A) 4.3 × 10-11
B) 12
C) 4.3 × 10-8
D) 2.3 × 107
E) 2.3 × 10-7
Answer: C
LO: 6.5
GO: G4
56) The ________ quantum number defines the shape of an orbital.

A) spin
B) magnetic
C) principal
D) angular momentum
E) psi
Answer: D
LO: 6.7
GO: G2
57) There are ________ orbitals in the third shell.

A) 25
B) 4
C) 9
D) 16
E) 1
Answer: C
LO: 6.7
GO: G2
58) The ________ subshell contains only one orbital.

A) 5d
B) 6f
C) 4s
D) 3d
E) 1p
Answer: C
LO: 6.7
GO: G2
34
59) There are ________ orbitals in the second shell.
A) 1
B) 2
C) 4
D) 8
E) 9
Answer: C
LO: 6.7
GO: G2
60) The angular momentum quantum number is 3 in ________ orbitals.

A) s
B) p
C) d
D) f
E) a
Answer: D
LO: 6.7
GO: G2
61) The n = 1 shell contains ________ p orbitals. All the other shells contain ________ p
orbitals.
A) 3, 6
B) 0, 3
C) 6, 2
D) 3, 3
E) 0, 6
Answer: B
LO: 6.7
GO: G2
62) The lowest energy shell that contains f orbitals is the shell with n = ________.
A) 3
B) 2
C) 4
D) 1
E) 5
Answer: C
LO: 6.7
GO: G2
35
63) The principal quantum number of the first d subshell is ________.
A) 1
B) 2
C) 3
D) 4
E) 0
Answer: C
LO: 6.7
GO: G2
64) The total number of orbitals in a shell is given by ________.

A) I2
B) n2
C) 2n
D) 2n + 1
E) 2l + 1
Answer: B
LO: 6.7
GO: G2
65) In a hydrogen atom, an electron in a 1s orbital can ________ a photon, but cannot ________
a photon.
A) accept, absorb
B) absorb, accept
C) absorb, emit
D) emit, absorb
E) emit, accept
Answer: C
LO: 6.7
GO: G2
66) ________-orbitals are spherically symmetrical.

A) s
B) p
C) d
D) f
E) g
Answer: A
LO: 6.8
GO: G2
36
67) Each p-subshell can accommodate a maximum of ________ electrons.
A) 6
B) 2
C) 10
D) 3
E) 5
Answer: A
LO: 6.9
GO: G2
68) Each d-subshell can accommodate a maximum of ________ electrons.

A) 6
B) 2
C) 10
D) 3
E) 5
Answer: C
LO: 6.9
GO: G2
69) How many quantum numbers are necessary to designate a particular electron in an atom?
A) 3
B) 4
C) 2
D) 1
E) 5
Answer: B
LO: 6.9
GO: G2
70) Which orbital is degenerate with a 3dz2 in a many-electron atom?

A) 3dyz
B) 5dz2
C) 4dz2
D) 3dzz
E) 4dxz
Answer: A
LO: 6.10
GO: G2
37
71) The 3p subshell in the ground state of atomic xenon contains ________ electrons.
A) 2
B) 6
C) 8
D) 10
E) 36
Answer: B
LO: 6.10
GO: G2
72) The 3p subshell in the ground state of atomic silicon contains ________ electrons.
A) 2
B) 6
C) 8
D) 10
E) 36
Answer: A
LO: 6.10
GO: G2
73) The first shell in the ground state of a krypton atom can contain a maximum of ________
electrons.
A) 6
B) 36
C) 8
D) 18
E) 2
Answer: E
LO: 6.10
GO: G2
74) The 4d subshell in the ground state of atomic xenon contains ________ electrons.
A) 2
B) 6
C) 8
D) 10
E) 36
Answer: D
LO: 6.10
GO: G2
38
75) [Ar]4s23d104p3 is the electron configuration of a(n) ________ atom.
A) As
B) V
C) P
D) Sb
E) Sn
Answer: A
LO: 6.11
GO: G2
76) [Ne]3s23p3 is the electron configuration of a(n) ________ atom.

A) As
B) V
C) P
D) Sb
E) Sn
Answer: C
LO: 6.11
GO: G2
77) There are ________ unpaired electrons in a ground state fluorine atom.
A) 0
B) 1
C) 2
D) 3
E) 4
Answer: B
LO: 6.11
GO: G2
78) The electron configuration of a ground-state Ag atom is ________.

A) [Ar]4s24d9
B) [Kr]5s14d10
C) [Kr]5s23d9
D) [Ar]4s14d10
E) [Kr]5s24d10
Answer: B
LO: 6.11
GO: G2
39
79) The ground-state electron configuration for Zn is ________.
A) [Kr]4s23d10
B) [Ar]4s23d10
C) [Ar]4s13d10
D) [Ar]3s23d10
E) [Kr]3s23d10
Answer: B
LO: 6.11
GO: G2
80) What is the correct ground state electron configuration for copper?
A) [Ar]4s24d9
B) [Ar]4s14d10
C) [Ar]4s13d10
D) [Ar]4s23d10
E) [Ar]4s23d9
Answer: C
LO: 6.11
GO: G2
81) What is the correct ground state electron configuration for chromium?
A) [Ar]4s13d5
B) [Ar]4s14d5
C) [Ar]4s23d4
D) [Ar]4s24d5
E) [Kr]4s13d5
Answer: A
LO: 6.11
GO: G2
82) All of the ________ have a valence shell electron configuration ns1.
A) noble gases
B) halogens
C) chalcogens
D) alkali metals
E) alkaline earth metals
Answer: D
LO: 6.11
GO: G2
40
83) The elements in the ________ period of the periodic table have a core-electron configuration
that is the same as the electron configuration of neon.
A) first
B) second
C) third
D) fourth
E) fifth
Answer: C
LO: 6.11
GO: G2
84) Elements in group ________ have a np6 electron configuration in the outer shell.
A) 4A
B) 6A
C) 7A
D) 8A
E) 5A
Answer: D
LO: 6.11
GO: G2
85) Which group in the periodic table contains elements with the valence electron configuration
of ns2np1?
A) 1A
B) 2A
C) 3A
D) 4A
E) 8A
Answer: C
LO: 6.11
GO: G2
41
6.3 Algorithmic Questions
1) Electromagnetic radiation with a wavelength of 640 nm appears as orange light to the human
eye. The frequency of this light is ________ s-1.
A) 4.688 ×
B) 4.688 ×
C) 1.920 ×
D) 1.920 ×
E) 2.133 ×
Answer: A
LO: 6.1
GO: G4
2) The wavelength of light emitted from a traffic light having a frequency of 2.74 × 1014 Hz is
________ nm.
A) 1090
B) 109
C) 54.7
D) 36.5
E) 50.0
Answer: A
Diff: 1 Var: 50+ Page Ref: Sec. 6.1
LO: 6.1
GO: G4
3) An FM radio station broadcasts electromagnetic radiation at a frequency of 89.7 MHz. The

wavelength of this radiation is ________ m.
A) 3.34 ×
B) 3.34
C) 2.69 ×
D) 2.69 ×
E) 0.299
Answer: B
LO: 6.1
GO: G4
42
4) Calculate the energy (J) found in one photon of visible light if the wavelength is 589 nm.
A) 3.37 ×
B) 1.17 × 10-31
C) 1.17 × 10-22
D) 3.37 ×
E) 2.96 ×
Answer: A
LO: 6.3
GO: G4
5) Electromagnetic radiation with a wavelength of 641 nm appears as orange light to the human
eye. The energy of one photon of this light is 3.10 × J. Thus, a laser that emits of
energy in a pulse of light at this wavelength produces ________ photons in each pulse.
A) 2.4 ×
B) 6.3 × 10-24
C) 2.7 ×
D) 4.2 ×
E) 6.5 ×
Answer: D
LO: 6.3
GO: G4
6) Calculate the longest wavelength of light (nm) that can be used to remove electrons from
metal surfaces if 245 kJ/mol is required to eject electrons.
A) 233
B) 488
C) 725
D) 552
E) 165
Answer: B
LO: 6.3
GO: G4
7) A radio station broadcasts at 99.5 MHz. The wavelength of the signal is ________ m.
A) 3.10
B) 3.02
C) 2.90
D) 2.75
E) 4.71
Answer: B
LO: 6.1
GO: G4
43
8) When the electron in a hydrogen atom moves from n = 5 to n = 2, light with a wavelength of
________ nm is emitted.
A) 93.8
B) 410
C) 487
D) 657
E) 434
Answer: E
LO: 6.4
GO: G4
9) Of the following transitions in the Bohr hydrogen atom, the ________ transition results in the
emission of the highest-energy photon.
A) n = 6 → n = 4
B) n = 2 → n = 7
C) n = 4 → n = 6
D) n = 1 → n = 4
E) All transitions emit photons of equivalent energy.
Answer: A
LO: 6.4
GO: G2
10) Of the following transitions in the Bohr hydrogen atom, the ________ transition results in
the absorption of the highest-energy photon.
A) n = 2 → n = 5
B) n = 4 → n = 2
C) n = 3 → n = 2
D) n = 5 → n = 2
E) All transitions absorb photons of equivalent energy.
Answer: A
LO: 6.4
GO: G2
44
11) What is the de Broglie wavelength (m) of an electron traveling at a velocity of 6.10 × 106
m/s?
A) 1.19 × 10-10
B) 8.39 × 109
C) 8.39 × 1012
D) 1.19 × 10-16
E) 1.19 × 10-13
Answer: A
LO: 6.5
GO: G4
12) A 77.67 gram object traveling at a velocity of has a de Broglie wavelength of
A) 2.206 × 10-36
B) 2.206 × 10-37
C) 2.206 × 10-38
D) 1.990 × 10-32
E) 2.206 × 10-35
Answer: E
LO: 6.5
GO: G4
13) The de Broglie wavelength of a 0.02900 gram bullet traveling at the speed of is
A) 3.529 × 10-32
B) 3.529 × 10-33
C) 3.529 × 10-34
D) 3.529 × 10-35
E) 1.244 × 10-35
Answer: A
LO: 6.5
GO: G4
45
14) The symbol for the spin magnetic quantum number is ________.
A) ms
B) n
C) l
D) ml
E) sm
Answer: A
LO: 6.7
GO: G2
15) The angular momentum quantum number (l) value of 2 indicates the ________ subshell.
A) d
B) f
C) s
D) p
E) +1/2
Answer: A
LO: 6.7
GO: G2
16) At maximum, an d-subshell can hold ________ electrons.

A) 10
B) 6
C) 2
D) 8
E) 14
Answer: A
LO: 6.7
GO: G2
17) If an electron has a principal quantum number (n) of 7 and an angular momentum quantum
number (l) of 3, the subshell designation is ________.
A) 7f
B) 7s
C) 7p
D) 3f
E) 3d
Answer: A
LO: 6.7
GO: G2
46
18) Which one of the following represents an acceptable set of quantum numbers for an electron
in an atom? (arranged as n, l, ml, and ms )
A) 3, 2, -2, -1/2
B) 3, 3, -4, 1/2
C) 3, 4, 6, -1/2
D) 3, 2, 0, 0
E) 3, 3, 3, -1/2
Answer: A
LO: 6.7
GO: G2
19) Which one of the following represents an acceptable set of quantum numbers for an electron
in an atom? (arranged as n, l, ml, and ms)
A) 3, 0, 0, -1/2
B) 3, -1, -4, 1/2
C) 3, -3, 1, -1/2
D) 0, 2, 1, 0
E) 3, 3, 4, 3
Answer: A
LO: 6.7
GO: G2
20) Which one of the following represents an impossible set of quantum numbers for an electron
in an atom? (arranged as n, l, ml, and ms)
A) 4, 3, 0, 0
B) 4, 3, -3, 1/2
C) 4, 3, 3, -1/2
D) 4, 3, 0, +1/2
E) 4, 2, -2, -1/2
Answer: A
LO: 6.7
GO: G2
21) Which set of three quantum numbers (n, l, ml) corresponds to a 4s orbital?
A) 4,0,1
B) 4,0,2
C) 4,0,0
D) 4,1,0
E) 4,1,1
Answer: C
LO: 6.7
GO: G2
47
22) How many p-orbitals are occupied in a O atom?
A) 5
B) 6
C) 0
D) 3
E) 1
Answer: D
LO: 6.9
GO: G2
23) The element that corresponds to the electron configuration 1s22s22p2 is ________.
A) lithium
B) beryllium
C) boron
D) nitrogen
E) carbon
Answer: E
LO: 6.10
GO: G2
24) There are ________ unpaired electrons in a ground state chlorine atom.
A) 4
B) 3
C) 2
D) 1
E) 0
Answer: D
LO: 6.10
GO: G2
25) The ground-state electron configuration of V is ________.

A) 1s22s22p63s23p64s23d3
B) 1s22s22p63s23p63d5
C) 1s22s22p63s23p11
D) 1s22s22p63s23p64s23d4
E) None of the above
Answer: A
LO: 6.10
GO: G2
48
26) The complete electron configuration of sulfur, element 16, is ________.
A) 3s23p4
B) 2p103s2
C) 2p63s2
D) 2s42p8
E) 2s62p23s2
Answer: A
LO: 6.10
GO: G2
27) The complete electron configuration of vanadium, element 23, is ________.

A) 3p7
B) 3d34s2
C) 3p5
D) 3s43p1
E) 3p3
Answer: B
LO: 6.10
GO: G2
28) In a ground-state copper atom, the ________ subshell is partially filled.

A) 3s
B) 4s
C) 4p
D) 3d
E) 4d
Answer: D
LO: 6.10
GO: G2
29) What is the principal quantum number for the outermost electrons in a Te atom in the ground
state?
A) 5
B) 3
C) 4
D) 6
E) 7
Answer: A
LO: 6.10
GO: G2
49
30) What is the angular momentum quantum number for the outermost electrons in a manganese
atom in the ground state?
A) -1
B) 1
C) 3
D) 2
E) 0
Answer: D
LO: 6.10
GO: G2
31) The condensed electron configuration of argon, element 18, is ________.

A) [Ne]3s4
B) [Ar]3s23p2
C) [Ne]3s23p6
D) [He]2s42p10
E) [He]3s4
Answer: C
LO: 6.11
GO: G2
32) The condensed electron configuration of titanium, element 22, is ________.

A) [Ar]3s23p6
B) [Ne]3s4
C) [Ar]3s43p4
D) [Ar]3d24s2
E) [Ne]3s43p2
Answer: D
LO: 6.11
GO: G2
33) The element that has a valence configuration of 2s2 is ________.

A) Be
B) Mg
C) Ca
D) Sr
E) Ba
Answer: A
LO: 6.11
GO: G2
50
34) The element that has a valence configuration of 5s25p6 is ________.
A) Xe
B) Rn
C) Ne
D) Ar
E) Kr
Answer: A
LO: 6.11
GO: G2
35) The element that has a valence configuration of 2s1 is ________.

A) Li
B) Na
C) K
D) Rb
E) Cs
Answer: A
LO: 6.11
GO: G2
36) What is the maximum angular momentum quantum number in the ground state electron
configuration of iodine?
A) 3
B) 6
C) 7
D) 4
E) 5
Answer: D
LO: 6.11
GO: G2
51
6.4 Short Answer Questions
1) A 750 nm wavelength light corresponds to which color within the visible region of the
electromagnetic spectrum?
Answer: red
LO: 6.2
GO: G4
2) In the de Broglie formula describing the movement of an electron about the nucleus, the
quantity "mv" is called its ________.
Answer: momentum
LO: 6.5
GO: G2
3) A line spectrum contains radiation of ________ wavelengths.

Answer: specific
LO: 6.4
GO: G2
4) The shape of an orbital is defined by the angular momentum quantum number which is
represented as letter ________.
Answer: l
LO: 6.7
GO: G2
5) The maximum angular momentum quantum number in the ground state electron configuration
of carbon is ________.
Answer: 1
LO: 6.10
GO: G2
6) The maximum angular momentum quantum number in the ground state electron configuration
of argon is ________.
Answer: 2
LO: 6.10
GO: G2
52
7) The ground state electron configuration of scandium is ________.
Answer: [Ar]4s23d1
LO: 6.11
GO: G2
8) Which group is represented by a ns2np1 valence shell electron configuration?

Answer: 3A
LO: 6.11
GO: G2
9) Which group is represented by a ns2np6 valence shell electron configuration?

Answer: 8A
LO: 6.11
GO: G2
10) The ground state electron configuration of copper is ________.

Answer: [Ar]4s13d10
LO: 6.11
GO: G2
6.5 True/False Questions
1) The wavelength of radio waves can be longer than a football field.

Answer: TRUE
LO: 6.2
GO: G2
2) High energy and low wavelength light has the ability to eject electrons from metal surfaces.
Answer: TRUE
LO: 6.3
GO: G2
3) If a hydrogen atom electron jumps from the n=6 orbit to the n=2 orbit, energy is released.
Answer: TRUE
LO: 6.4
GO: G2
53
4) The square of Schrodinger's wave equation is called an orbital.
Answer: TRUE
LO: 6.6
GO: G2
5) The electron density of the 5s orbital is symmetric.

Answer: TRUE
LO: 6.7
GO: G2
6) The larger the principal quantum number of an orbital, the lower is the energy of the electrons
in that orbital.
Answer: FALSE
LO: 6.9
GO: G2
7) When the value of n is greater than or equal to 3, electrons can reside in d orbitals.
Answer: TRUE
LO: 6.9
GO: G2
8) An NMR spectrum results from photon irradiation in which the electron spin alignment is
flipped.
Answer: FALSE
LO: 6.10
GO: G2
54

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Solution Manual for Chemistry The Central Science 14th

Edition by Brown LeMay Bursten Murphy Woodward

6.1 Multiple-Choice Questions

1) Which one of the following is correct?

2) Of the following, ________ radiation has the shortest wavelength.

3) The photoelectric effect is ________.

6) In the Bohr model of the atom, ________.

10) The uncertainty principle states that ________.

17) Which one of the following is an incorrect subshell notation?

18) Which one of the following is an incorrect orbital notation?

22) In a px orbital, the subscript x denotes the ________.

23) A 4pz orbital in a many-electron atom is degenerate with ________.

E) None of the above is correct.

33) The ground state electron configuration of Ga is ________.

35) The ground-state electron configuration of ________ is [Ar]4s13d5.

36) Which is the correct electron configuration for a nitrogen atom?

37) Which is the correct electron configuration for an oxide ion?

41) The ground-state configuration of fluorine is ________.

6.2 Bimodal Questions

1) Electromagnetic radiation travels through vacuum at a speed of ________ m/s.

5) Visible light with a wavelength of 550 nm has a frequency of ________ Hz.

16) The energy of a photon that has a wavelength of 9.0 m is ________ J.

21) The energy of a photon that has a wavelength of 13.2 nm is ________ J.

28) A mole of yellow photons of wavelength 527 nm has ________ kJ of energy.

30) What color of visible light has the longest wavelength?

32) What color of visible light has the highest energy?

39) A spectrum containing only ________ wavelengths is called a line spectrum.

46) The de Broglie wavelength of a particle is given by ________.

51) A 34.0 mg object with a de Broglie wavelength of is traveling at what speed?

56) The ________ quantum number defines the shape of an orbital.

57) There are ________ orbitals in the third shell.

58) The ________ subshell contains only one orbital.

60) The angular momentum quantum number is 3 in ________ orbitals.

64) The total number of orbitals in a shell is given by ________.

66) ________-orbitals are spherically symmetrical.

68) Each d-subshell can accommodate a maximum of ________ electrons.

70) Which orbital is degenerate with a 3dz2 in a many-electron atom?

76) [Ne]3s23p3 is the electron configuration of a(n) ________ atom.

78) The electron configuration of a ground-state Ag atom is ________.

3) An FM radio station broadcasts electromagnetic radiation at a frequency of 89.7 MHz. The

12) A 77.67 gram object traveling at a velocity of has a de Broglie wavelength of

16) At maximum, an d-subshell can hold ________ electrons.

25) The ground-state electron configuration of V is ________.

27) The complete electron configuration of vanadium, element 23, is ________.

28) In a ground-state copper atom, the ________ subshell is partially filled.

31) The condensed electron configuration of argon, element 18, is ________.

32) The condensed electron configuration of titanium, element 22, is ________.

33) The element that has a valence configuration of 2s2 is ________.

35) The element that has a valence configuration of 2s1 is ________.

3) A line spectrum contains radiation of ________ wavelengths.

8) Which group is represented by a ns2np1 valence shell electron configuration?

9) Which group is represented by a ns2np6 valence shell electron configuration?

10) The ground state electron configuration of copper is ________.

6.5 True/False Questions

1) The wavelength of radio waves can be longer than a football field.

5) The electron density of the 5s orbital is symmetric.

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